Entropic descriptors of quantum communications in molecules
Abstract The classical Information Theory (IT) deals with entropic descriptors of the probability distributions and probability-propagation (communication) systems, e.g., the electronic channels in molecules reflecting the information scattering via the system chemical bonds. The quantum IT addition...
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| Autor*in: |
Nalewajski, Roman F. [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2014 |
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| Schlagwörter: |
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| Anmerkung: |
© The Author(s) 2014 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of mathematical chemistry - Springer International Publishing, 1987, 53(2014), 1 vom: 25. Okt., Seite 1-28 |
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volume:53 ; year:2014 ; number:1 ; day:25 ; month:10 ; pages:1-28 |
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10.1007/s10910-014-0405-2 |
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| 520 | |a Abstract The classical Information Theory (IT) deals with entropic descriptors of the probability distributions and probability-propagation (communication) systems, e.g., the electronic channels in molecules reflecting the information scattering via the system chemical bonds. The quantum IT additionally accounts for the non-classical (current/phase)-related contributions in the resultant information content of electronic states. The classical and non-classical terms in the quantum Shannon entropy and Fisher information are reexamined. The associated probability-propagation and current-scattering networks are introduced and their Fisher- and Shannon-type descriptors are identified. The non-additive and additive information descriptors of the probability channels in both the Atomic Orbital and local resolution levels are related to the network conditional-entropy and mutual-information, which represent the IT covalency and ionicity components in the classical communication theory of the chemical bond. A similar partition identifies the associated bond indices in the molecular current/phase channels. The resultant bond descriptors combining the classical and non-classical terms, due to the probability and current distributions, respectively, are proposed as generalized communication-noise (covalency) and information-flow (iconicity) concepts in the quantum IT. | ||
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| 650 | 4 | |a Quantum information measures | |
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10.1007/s10910-014-0405-2 doi (DE-627)OLC2060420555 (DE-He213)s10910-014-0405-2-p DE-627 ger DE-627 rakwb eng 510 540 VZ Nalewajski, Roman F. verfasserin aut Entropic descriptors of quantum communications in molecules 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Author(s) 2014 Abstract The classical Information Theory (IT) deals with entropic descriptors of the probability distributions and probability-propagation (communication) systems, e.g., the electronic channels in molecules reflecting the information scattering via the system chemical bonds. The quantum IT additionally accounts for the non-classical (current/phase)-related contributions in the resultant information content of electronic states. The classical and non-classical terms in the quantum Shannon entropy and Fisher information are reexamined. The associated probability-propagation and current-scattering networks are introduced and their Fisher- and Shannon-type descriptors are identified. The non-additive and additive information descriptors of the probability channels in both the Atomic Orbital and local resolution levels are related to the network conditional-entropy and mutual-information, which represent the IT covalency and ionicity components in the classical communication theory of the chemical bond. A similar partition identifies the associated bond indices in the molecular current/phase channels. The resultant bond descriptors combining the classical and non-classical terms, due to the probability and current distributions, respectively, are proposed as generalized communication-noise (covalency) and information-flow (iconicity) concepts in the quantum IT. Bond multiplicity descriptors Communication systems Local communications Orbital communications Probability/current distributions Quantum information measures Enthalten in Journal of mathematical chemistry Springer International Publishing, 1987 53(2014), 1 vom: 25. Okt., Seite 1-28 (DE-627)129246441 (DE-600)59132-4 (DE-576)27906036X 0259-9791 nnns volume:53 year:2014 number:1 day:25 month:10 pages:1-28 https://doi.org/10.1007/s10910-014-0405-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-MAT GBV_ILN_70 GBV_ILN_4012 AR 53 2014 1 25 10 1-28 |
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10.1007/s10910-014-0405-2 doi (DE-627)OLC2060420555 (DE-He213)s10910-014-0405-2-p DE-627 ger DE-627 rakwb eng 510 540 VZ Nalewajski, Roman F. verfasserin aut Entropic descriptors of quantum communications in molecules 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Author(s) 2014 Abstract The classical Information Theory (IT) deals with entropic descriptors of the probability distributions and probability-propagation (communication) systems, e.g., the electronic channels in molecules reflecting the information scattering via the system chemical bonds. The quantum IT additionally accounts for the non-classical (current/phase)-related contributions in the resultant information content of electronic states. The classical and non-classical terms in the quantum Shannon entropy and Fisher information are reexamined. The associated probability-propagation and current-scattering networks are introduced and their Fisher- and Shannon-type descriptors are identified. The non-additive and additive information descriptors of the probability channels in both the Atomic Orbital and local resolution levels are related to the network conditional-entropy and mutual-information, which represent the IT covalency and ionicity components in the classical communication theory of the chemical bond. A similar partition identifies the associated bond indices in the molecular current/phase channels. The resultant bond descriptors combining the classical and non-classical terms, due to the probability and current distributions, respectively, are proposed as generalized communication-noise (covalency) and information-flow (iconicity) concepts in the quantum IT. Bond multiplicity descriptors Communication systems Local communications Orbital communications Probability/current distributions Quantum information measures Enthalten in Journal of mathematical chemistry Springer International Publishing, 1987 53(2014), 1 vom: 25. Okt., Seite 1-28 (DE-627)129246441 (DE-600)59132-4 (DE-576)27906036X 0259-9791 nnns volume:53 year:2014 number:1 day:25 month:10 pages:1-28 https://doi.org/10.1007/s10910-014-0405-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-MAT GBV_ILN_70 GBV_ILN_4012 AR 53 2014 1 25 10 1-28 |
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10.1007/s10910-014-0405-2 doi (DE-627)OLC2060420555 (DE-He213)s10910-014-0405-2-p DE-627 ger DE-627 rakwb eng 510 540 VZ Nalewajski, Roman F. verfasserin aut Entropic descriptors of quantum communications in molecules 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Author(s) 2014 Abstract The classical Information Theory (IT) deals with entropic descriptors of the probability distributions and probability-propagation (communication) systems, e.g., the electronic channels in molecules reflecting the information scattering via the system chemical bonds. The quantum IT additionally accounts for the non-classical (current/phase)-related contributions in the resultant information content of electronic states. The classical and non-classical terms in the quantum Shannon entropy and Fisher information are reexamined. The associated probability-propagation and current-scattering networks are introduced and their Fisher- and Shannon-type descriptors are identified. The non-additive and additive information descriptors of the probability channels in both the Atomic Orbital and local resolution levels are related to the network conditional-entropy and mutual-information, which represent the IT covalency and ionicity components in the classical communication theory of the chemical bond. A similar partition identifies the associated bond indices in the molecular current/phase channels. The resultant bond descriptors combining the classical and non-classical terms, due to the probability and current distributions, respectively, are proposed as generalized communication-noise (covalency) and information-flow (iconicity) concepts in the quantum IT. Bond multiplicity descriptors Communication systems Local communications Orbital communications Probability/current distributions Quantum information measures Enthalten in Journal of mathematical chemistry Springer International Publishing, 1987 53(2014), 1 vom: 25. Okt., Seite 1-28 (DE-627)129246441 (DE-600)59132-4 (DE-576)27906036X 0259-9791 nnns volume:53 year:2014 number:1 day:25 month:10 pages:1-28 https://doi.org/10.1007/s10910-014-0405-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-MAT GBV_ILN_70 GBV_ILN_4012 AR 53 2014 1 25 10 1-28 |
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10.1007/s10910-014-0405-2 doi (DE-627)OLC2060420555 (DE-He213)s10910-014-0405-2-p DE-627 ger DE-627 rakwb eng 510 540 VZ Nalewajski, Roman F. verfasserin aut Entropic descriptors of quantum communications in molecules 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Author(s) 2014 Abstract The classical Information Theory (IT) deals with entropic descriptors of the probability distributions and probability-propagation (communication) systems, e.g., the electronic channels in molecules reflecting the information scattering via the system chemical bonds. The quantum IT additionally accounts for the non-classical (current/phase)-related contributions in the resultant information content of electronic states. The classical and non-classical terms in the quantum Shannon entropy and Fisher information are reexamined. The associated probability-propagation and current-scattering networks are introduced and their Fisher- and Shannon-type descriptors are identified. The non-additive and additive information descriptors of the probability channels in both the Atomic Orbital and local resolution levels are related to the network conditional-entropy and mutual-information, which represent the IT covalency and ionicity components in the classical communication theory of the chemical bond. A similar partition identifies the associated bond indices in the molecular current/phase channels. The resultant bond descriptors combining the classical and non-classical terms, due to the probability and current distributions, respectively, are proposed as generalized communication-noise (covalency) and information-flow (iconicity) concepts in the quantum IT. Bond multiplicity descriptors Communication systems Local communications Orbital communications Probability/current distributions Quantum information measures Enthalten in Journal of mathematical chemistry Springer International Publishing, 1987 53(2014), 1 vom: 25. Okt., Seite 1-28 (DE-627)129246441 (DE-600)59132-4 (DE-576)27906036X 0259-9791 nnns volume:53 year:2014 number:1 day:25 month:10 pages:1-28 https://doi.org/10.1007/s10910-014-0405-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-MAT GBV_ILN_70 GBV_ILN_4012 AR 53 2014 1 25 10 1-28 |
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10.1007/s10910-014-0405-2 doi (DE-627)OLC2060420555 (DE-He213)s10910-014-0405-2-p DE-627 ger DE-627 rakwb eng 510 540 VZ Nalewajski, Roman F. verfasserin aut Entropic descriptors of quantum communications in molecules 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Author(s) 2014 Abstract The classical Information Theory (IT) deals with entropic descriptors of the probability distributions and probability-propagation (communication) systems, e.g., the electronic channels in molecules reflecting the information scattering via the system chemical bonds. The quantum IT additionally accounts for the non-classical (current/phase)-related contributions in the resultant information content of electronic states. The classical and non-classical terms in the quantum Shannon entropy and Fisher information are reexamined. The associated probability-propagation and current-scattering networks are introduced and their Fisher- and Shannon-type descriptors are identified. The non-additive and additive information descriptors of the probability channels in both the Atomic Orbital and local resolution levels are related to the network conditional-entropy and mutual-information, which represent the IT covalency and ionicity components in the classical communication theory of the chemical bond. A similar partition identifies the associated bond indices in the molecular current/phase channels. The resultant bond descriptors combining the classical and non-classical terms, due to the probability and current distributions, respectively, are proposed as generalized communication-noise (covalency) and information-flow (iconicity) concepts in the quantum IT. Bond multiplicity descriptors Communication systems Local communications Orbital communications Probability/current distributions Quantum information measures Enthalten in Journal of mathematical chemistry Springer International Publishing, 1987 53(2014), 1 vom: 25. Okt., Seite 1-28 (DE-627)129246441 (DE-600)59132-4 (DE-576)27906036X 0259-9791 nnns volume:53 year:2014 number:1 day:25 month:10 pages:1-28 https://doi.org/10.1007/s10910-014-0405-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-MAT GBV_ILN_70 GBV_ILN_4012 AR 53 2014 1 25 10 1-28 |
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Abstract The classical Information Theory (IT) deals with entropic descriptors of the probability distributions and probability-propagation (communication) systems, e.g., the electronic channels in molecules reflecting the information scattering via the system chemical bonds. The quantum IT additionally accounts for the non-classical (current/phase)-related contributions in the resultant information content of electronic states. The classical and non-classical terms in the quantum Shannon entropy and Fisher information are reexamined. The associated probability-propagation and current-scattering networks are introduced and their Fisher- and Shannon-type descriptors are identified. The non-additive and additive information descriptors of the probability channels in both the Atomic Orbital and local resolution levels are related to the network conditional-entropy and mutual-information, which represent the IT covalency and ionicity components in the classical communication theory of the chemical bond. A similar partition identifies the associated bond indices in the molecular current/phase channels. The resultant bond descriptors combining the classical and non-classical terms, due to the probability and current distributions, respectively, are proposed as generalized communication-noise (covalency) and information-flow (iconicity) concepts in the quantum IT. © The Author(s) 2014 |
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Abstract The classical Information Theory (IT) deals with entropic descriptors of the probability distributions and probability-propagation (communication) systems, e.g., the electronic channels in molecules reflecting the information scattering via the system chemical bonds. The quantum IT additionally accounts for the non-classical (current/phase)-related contributions in the resultant information content of electronic states. The classical and non-classical terms in the quantum Shannon entropy and Fisher information are reexamined. The associated probability-propagation and current-scattering networks are introduced and their Fisher- and Shannon-type descriptors are identified. The non-additive and additive information descriptors of the probability channels in both the Atomic Orbital and local resolution levels are related to the network conditional-entropy and mutual-information, which represent the IT covalency and ionicity components in the classical communication theory of the chemical bond. A similar partition identifies the associated bond indices in the molecular current/phase channels. The resultant bond descriptors combining the classical and non-classical terms, due to the probability and current distributions, respectively, are proposed as generalized communication-noise (covalency) and information-flow (iconicity) concepts in the quantum IT. © The Author(s) 2014 |
| abstract_unstemmed |
Abstract The classical Information Theory (IT) deals with entropic descriptors of the probability distributions and probability-propagation (communication) systems, e.g., the electronic channels in molecules reflecting the information scattering via the system chemical bonds. The quantum IT additionally accounts for the non-classical (current/phase)-related contributions in the resultant information content of electronic states. The classical and non-classical terms in the quantum Shannon entropy and Fisher information are reexamined. The associated probability-propagation and current-scattering networks are introduced and their Fisher- and Shannon-type descriptors are identified. The non-additive and additive information descriptors of the probability channels in both the Atomic Orbital and local resolution levels are related to the network conditional-entropy and mutual-information, which represent the IT covalency and ionicity components in the classical communication theory of the chemical bond. A similar partition identifies the associated bond indices in the molecular current/phase channels. The resultant bond descriptors combining the classical and non-classical terms, due to the probability and current distributions, respectively, are proposed as generalized communication-noise (covalency) and information-flow (iconicity) concepts in the quantum IT. © The Author(s) 2014 |
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Entropic descriptors of quantum communications in molecules |
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