Effect of Coordination Modes of HL Ligand on the Molecular Architecture of Its Transition Metal Complexes (HL = 5-Methyl-2-Phenyl-4-[(2-o-Tolylamino)-Phenylmethylene]pyrazol-3(2H)-one)

Abstract Two $ Ag^{+} $ complexes [Ag(HL)2($ PF_{6} $)] (1) and [(AgL)n · n($ CH_{2} $$ Cl_{2} $) · n(0.$ 5H_{2} $O)] (2) (HL = 5-methyl-2-phenyl-4-[(2-o-tolylamino)-phenylmethylene]pyrazol-3(2H)-one) were synthesized and structurally characterized by EA analysis, IR spectra and X-ray crystallograph...
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Autor*in:	Wang, Tao [verfasserIn] Bao, Feng Liu, Yan Xing, Bin Tan, Zhe Tan, Zhifang Lü, Xing Qiang

Format:	Artikel
Sprache:	Englisch

Erschienen:	2008

Schlagwörter:	Crystal structure Ag complex Coordination mode Deprotonation

Anmerkung:	© Springer Science+Business Media, LLC 2008

Übergeordnetes Werk:	Enthalten in: Journal of inorganic and organometallic polymers and materials - Springer US, 1991, 18(2008), 3 vom: 17. Juni, Seite 420-425
Übergeordnetes Werk:	volume:18 ; year:2008 ; number:3 ; day:17 ; month:06 ; pages:420-425

Links:	Volltext

DOI / URN:	10.1007/s10904-008-9216-x

Katalog-ID:	OLC2061507425

Internformat


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245	1	0	\|a Effect of Coordination Modes of HL Ligand on the Molecular Architecture of Its Transition Metal Complexes (HL = 5-Methyl-2-Phenyl-4-[(2-o-Tolylamino)-Phenylmethylene]pyrazol-3(2H)-one)
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520			\|a Abstract Two $ Ag^{+} $ complexes [Ag(HL)2($ PF_{6} $)] (1) and [(AgL)n · n($ CH_{2} $$ Cl_{2} $) · n(0.$ 5H_{2} $O)] (2) (HL = 5-methyl-2-phenyl-4-[(2-o-tolylamino)-phenylmethylene]pyrazol-3(2H)-one) were synthesized and structurally characterized by EA analysis, IR spectra and X-ray crystallography. The result shows that two expected coordination modes (Modes I and III in Scheme 1) of the HL ligand, can be observed in its $ Ag^{+} $ complexes, while not in other transition metal ions ($ Ni^{2+} $, $ Co^{2+} $ or $ Cu^{2+} $) complexes whether deprotonation or not for the HL ligand. Graphical Abstract Three possible coordination modes (Modes I, II or III in Scheme 1) of the selected HL (HL = 5-methyl-2-phenyl-4-[(2-o-tolylamino)-phenylmethylene]pyrazol-3(2H)-one) ligand, can be adopted, in which Modes I and III can be observed in its two $ Ag^{+} $ complexes [Ag(HL)2($ PF_{6} $)](1) and [(AgL)n · n($ CH_{2} $$ Cl_{2} $) · n(0.$ 5H_{2} $O)] (2), while Mode II just observed in its transition metal ions ($ Cu^{2+} $, $ Ni^{2+} $, or $ Co^{2+} $) complexes, resulting from the deprotonatd form of the HL ligand and the coordination characters of transition metal ions.
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allfields	10.1007/s10904-008-9216-x doi (DE-627)OLC2061507425 (DE-He213)s10904-008-9216-x-p DE-627 ger DE-627 rakwb eng 660 VZ Wang, Tao verfasserin aut Effect of Coordination Modes of HL Ligand on the Molecular Architecture of Its Transition Metal Complexes (HL = 5-Methyl-2-Phenyl-4-[(2-o-Tolylamino)-Phenylmethylene]pyrazol-3(2H)-one) 2008 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2008 Abstract Two $ Ag^{+} $ complexes [Ag(HL)2($ PF_{6} $)] (1) and [(AgL)n · n($ CH_{2} $$ Cl_{2} $) · n(0.$ 5H_{2} $O)] (2) (HL = 5-methyl-2-phenyl-4-[(2-o-tolylamino)-phenylmethylene]pyrazol-3(2H)-one) were synthesized and structurally characterized by EA analysis, IR spectra and X-ray crystallography. The result shows that two expected coordination modes (Modes I and III in Scheme 1) of the HL ligand, can be observed in its $ Ag^{+} $ complexes, while not in other transition metal ions ($ Ni^{2+} $, $ Co^{2+} $ or $ Cu^{2+} $) complexes whether deprotonation or not for the HL ligand. Graphical Abstract Three possible coordination modes (Modes I, II or III in Scheme 1) of the selected HL (HL = 5-methyl-2-phenyl-4-[(2-o-tolylamino)-phenylmethylene]pyrazol-3(2H)-one) ligand, can be adopted, in which Modes I and III can be observed in its two $ Ag^{+} $ complexes [Ag(HL)2($ PF_{6} $)](1) and [(AgL)n · n($ CH_{2} $$ Cl_{2} $) · n(0.$ 5H_{2} $O)] (2), while Mode II just observed in its transition metal ions ($ Cu^{2+} $, $ Ni^{2+} $, or $ Co^{2+} $) complexes, resulting from the deprotonatd form of the HL ligand and the coordination characters of transition metal ions. Crystal structure Ag complex Coordination mode Deprotonation Bao, Feng aut Liu, Yan aut Xing, Bin aut Tan, Zhe aut Tan, Zhifang aut Lü, Xing Qiang aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 18(2008), 3 vom: 17. Juni, Seite 420-425 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:18 year:2008 number:3 day:17 month:06 pages:420-425 https://doi.org/10.1007/s10904-008-9216-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_21 GBV_ILN_70 GBV_ILN_2005 AR 18 2008 3 17 06 420-425
spelling	10.1007/s10904-008-9216-x doi (DE-627)OLC2061507425 (DE-He213)s10904-008-9216-x-p DE-627 ger DE-627 rakwb eng 660 VZ Wang, Tao verfasserin aut Effect of Coordination Modes of HL Ligand on the Molecular Architecture of Its Transition Metal Complexes (HL = 5-Methyl-2-Phenyl-4-[(2-o-Tolylamino)-Phenylmethylene]pyrazol-3(2H)-one) 2008 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2008 Abstract Two $ Ag^{+} $ complexes [Ag(HL)2($ PF_{6} $)] (1) and [(AgL)n · n($ CH_{2} $$ Cl_{2} $) · n(0.$ 5H_{2} $O)] (2) (HL = 5-methyl-2-phenyl-4-[(2-o-tolylamino)-phenylmethylene]pyrazol-3(2H)-one) were synthesized and structurally characterized by EA analysis, IR spectra and X-ray crystallography. The result shows that two expected coordination modes (Modes I and III in Scheme 1) of the HL ligand, can be observed in its $ Ag^{+} $ complexes, while not in other transition metal ions ($ Ni^{2+} $, $ Co^{2+} $ or $ Cu^{2+} $) complexes whether deprotonation or not for the HL ligand. Graphical Abstract Three possible coordination modes (Modes I, II or III in Scheme 1) of the selected HL (HL = 5-methyl-2-phenyl-4-[(2-o-tolylamino)-phenylmethylene]pyrazol-3(2H)-one) ligand, can be adopted, in which Modes I and III can be observed in its two $ Ag^{+} $ complexes [Ag(HL)2($ PF_{6} $)](1) and [(AgL)n · n($ CH_{2} $$ Cl_{2} $) · n(0.$ 5H_{2} $O)] (2), while Mode II just observed in its transition metal ions ($ Cu^{2+} $, $ Ni^{2+} $, or $ Co^{2+} $) complexes, resulting from the deprotonatd form of the HL ligand and the coordination characters of transition metal ions. Crystal structure Ag complex Coordination mode Deprotonation Bao, Feng aut Liu, Yan aut Xing, Bin aut Tan, Zhe aut Tan, Zhifang aut Lü, Xing Qiang aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 18(2008), 3 vom: 17. Juni, Seite 420-425 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:18 year:2008 number:3 day:17 month:06 pages:420-425 https://doi.org/10.1007/s10904-008-9216-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_21 GBV_ILN_70 GBV_ILN_2005 AR 18 2008 3 17 06 420-425
allfields_unstemmed	10.1007/s10904-008-9216-x doi (DE-627)OLC2061507425 (DE-He213)s10904-008-9216-x-p DE-627 ger DE-627 rakwb eng 660 VZ Wang, Tao verfasserin aut Effect of Coordination Modes of HL Ligand on the Molecular Architecture of Its Transition Metal Complexes (HL = 5-Methyl-2-Phenyl-4-[(2-o-Tolylamino)-Phenylmethylene]pyrazol-3(2H)-one) 2008 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2008 Abstract Two $ Ag^{+} $ complexes [Ag(HL)2($ PF_{6} $)] (1) and [(AgL)n · n($ CH_{2} $$ Cl_{2} $) · n(0.$ 5H_{2} $O)] (2) (HL = 5-methyl-2-phenyl-4-[(2-o-tolylamino)-phenylmethylene]pyrazol-3(2H)-one) were synthesized and structurally characterized by EA analysis, IR spectra and X-ray crystallography. The result shows that two expected coordination modes (Modes I and III in Scheme 1) of the HL ligand, can be observed in its $ Ag^{+} $ complexes, while not in other transition metal ions ($ Ni^{2+} $, $ Co^{2+} $ or $ Cu^{2+} $) complexes whether deprotonation or not for the HL ligand. Graphical Abstract Three possible coordination modes (Modes I, II or III in Scheme 1) of the selected HL (HL = 5-methyl-2-phenyl-4-[(2-o-tolylamino)-phenylmethylene]pyrazol-3(2H)-one) ligand, can be adopted, in which Modes I and III can be observed in its two $ Ag^{+} $ complexes [Ag(HL)2($ PF_{6} $)](1) and [(AgL)n · n($ CH_{2} $$ Cl_{2} $) · n(0.$ 5H_{2} $O)] (2), while Mode II just observed in its transition metal ions ($ Cu^{2+} $, $ Ni^{2+} $, or $ Co^{2+} $) complexes, resulting from the deprotonatd form of the HL ligand and the coordination characters of transition metal ions. Crystal structure Ag complex Coordination mode Deprotonation Bao, Feng aut Liu, Yan aut Xing, Bin aut Tan, Zhe aut Tan, Zhifang aut Lü, Xing Qiang aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 18(2008), 3 vom: 17. Juni, Seite 420-425 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:18 year:2008 number:3 day:17 month:06 pages:420-425 https://doi.org/10.1007/s10904-008-9216-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_21 GBV_ILN_70 GBV_ILN_2005 AR 18 2008 3 17 06 420-425
allfieldsGer	10.1007/s10904-008-9216-x doi (DE-627)OLC2061507425 (DE-He213)s10904-008-9216-x-p DE-627 ger DE-627 rakwb eng 660 VZ Wang, Tao verfasserin aut Effect of Coordination Modes of HL Ligand on the Molecular Architecture of Its Transition Metal Complexes (HL = 5-Methyl-2-Phenyl-4-[(2-o-Tolylamino)-Phenylmethylene]pyrazol-3(2H)-one) 2008 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2008 Abstract Two $ Ag^{+} $ complexes [Ag(HL)2($ PF_{6} $)] (1) and [(AgL)n · n($ CH_{2} $$ Cl_{2} $) · n(0.$ 5H_{2} $O)] (2) (HL = 5-methyl-2-phenyl-4-[(2-o-tolylamino)-phenylmethylene]pyrazol-3(2H)-one) were synthesized and structurally characterized by EA analysis, IR spectra and X-ray crystallography. The result shows that two expected coordination modes (Modes I and III in Scheme 1) of the HL ligand, can be observed in its $ Ag^{+} $ complexes, while not in other transition metal ions ($ Ni^{2+} $, $ Co^{2+} $ or $ Cu^{2+} $) complexes whether deprotonation or not for the HL ligand. Graphical Abstract Three possible coordination modes (Modes I, II or III in Scheme 1) of the selected HL (HL = 5-methyl-2-phenyl-4-[(2-o-tolylamino)-phenylmethylene]pyrazol-3(2H)-one) ligand, can be adopted, in which Modes I and III can be observed in its two $ Ag^{+} $ complexes [Ag(HL)2($ PF_{6} $)](1) and [(AgL)n · n($ CH_{2} $$ Cl_{2} $) · n(0.$ 5H_{2} $O)] (2), while Mode II just observed in its transition metal ions ($ Cu^{2+} $, $ Ni^{2+} $, or $ Co^{2+} $) complexes, resulting from the deprotonatd form of the HL ligand and the coordination characters of transition metal ions. Crystal structure Ag complex Coordination mode Deprotonation Bao, Feng aut Liu, Yan aut Xing, Bin aut Tan, Zhe aut Tan, Zhifang aut Lü, Xing Qiang aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 18(2008), 3 vom: 17. Juni, Seite 420-425 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:18 year:2008 number:3 day:17 month:06 pages:420-425 https://doi.org/10.1007/s10904-008-9216-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_21 GBV_ILN_70 GBV_ILN_2005 AR 18 2008 3 17 06 420-425
allfieldsSound	10.1007/s10904-008-9216-x doi (DE-627)OLC2061507425 (DE-He213)s10904-008-9216-x-p DE-627 ger DE-627 rakwb eng 660 VZ Wang, Tao verfasserin aut Effect of Coordination Modes of HL Ligand on the Molecular Architecture of Its Transition Metal Complexes (HL = 5-Methyl-2-Phenyl-4-[(2-o-Tolylamino)-Phenylmethylene]pyrazol-3(2H)-one) 2008 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2008 Abstract Two $ Ag^{+} $ complexes [Ag(HL)2($ PF_{6} $)] (1) and [(AgL)n · n($ CH_{2} $$ Cl_{2} $) · n(0.$ 5H_{2} $O)] (2) (HL = 5-methyl-2-phenyl-4-[(2-o-tolylamino)-phenylmethylene]pyrazol-3(2H)-one) were synthesized and structurally characterized by EA analysis, IR spectra and X-ray crystallography. The result shows that two expected coordination modes (Modes I and III in Scheme 1) of the HL ligand, can be observed in its $ Ag^{+} $ complexes, while not in other transition metal ions ($ Ni^{2+} $, $ Co^{2+} $ or $ Cu^{2+} $) complexes whether deprotonation or not for the HL ligand. Graphical Abstract Three possible coordination modes (Modes I, II or III in Scheme 1) of the selected HL (HL = 5-methyl-2-phenyl-4-[(2-o-tolylamino)-phenylmethylene]pyrazol-3(2H)-one) ligand, can be adopted, in which Modes I and III can be observed in its two $ Ag^{+} $ complexes [Ag(HL)2($ PF_{6} $)](1) and [(AgL)n · n($ CH_{2} $$ Cl_{2} $) · n(0.$ 5H_{2} $O)] (2), while Mode II just observed in its transition metal ions ($ Cu^{2+} $, $ Ni^{2+} $, or $ Co^{2+} $) complexes, resulting from the deprotonatd form of the HL ligand and the coordination characters of transition metal ions. Crystal structure Ag complex Coordination mode Deprotonation Bao, Feng aut Liu, Yan aut Xing, Bin aut Tan, Zhe aut Tan, Zhifang aut Lü, Xing Qiang aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 18(2008), 3 vom: 17. Juni, Seite 420-425 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:18 year:2008 number:3 day:17 month:06 pages:420-425 https://doi.org/10.1007/s10904-008-9216-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_21 GBV_ILN_70 GBV_ILN_2005 AR 18 2008 3 17 06 420-425
language	English
source	Enthalten in Journal of inorganic and organometallic polymers and materials 18(2008), 3 vom: 17. Juni, Seite 420-425 volume:18 year:2008 number:3 day:17 month:06 pages:420-425
sourceStr	Enthalten in Journal of inorganic and organometallic polymers and materials 18(2008), 3 vom: 17. Juni, Seite 420-425 volume:18 year:2008 number:3 day:17 month:06 pages:420-425
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Crystal structure Ag complex Coordination mode Deprotonation
dewey-raw	660
isfreeaccess_bool	false
container_title	Journal of inorganic and organometallic polymers and materials
authorswithroles_txt_mv	Wang, Tao @@aut@@ Bao, Feng @@aut@@ Liu, Yan @@aut@@ Xing, Bin @@aut@@ Tan, Zhe @@aut@@ Tan, Zhifang @@aut@@ Lü, Xing Qiang @@aut@@
publishDateDaySort_date	2008-06-17T00:00:00Z
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language_de	englisch
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author	Wang, Tao
spellingShingle	Wang, Tao ddc 660 misc Crystal structure misc Ag misc complex misc Coordination mode misc Deprotonation Effect of Coordination Modes of HL Ligand on the Molecular Architecture of Its Transition Metal Complexes (HL = 5-Methyl-2-Phenyl-4-[(2-o-Tolylamino)-Phenylmethylene]pyrazol-3(2H)-one)
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topic_title	660 VZ Effect of Coordination Modes of HL Ligand on the Molecular Architecture of Its Transition Metal Complexes (HL = 5-Methyl-2-Phenyl-4-[(2-o-Tolylamino)-Phenylmethylene]pyrazol-3(2H)-one) Crystal structure Ag complex Coordination mode Deprotonation
topic	ddc 660 misc Crystal structure misc Ag misc complex misc Coordination mode misc Deprotonation
topic_unstemmed	ddc 660 misc Crystal structure misc Ag misc complex misc Coordination mode misc Deprotonation
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title	Effect of Coordination Modes of HL Ligand on the Molecular Architecture of Its Transition Metal Complexes (HL = 5-Methyl-2-Phenyl-4-[(2-o-Tolylamino)-Phenylmethylene]pyrazol-3(2H)-one)
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title_full	Effect of Coordination Modes of HL Ligand on the Molecular Architecture of Its Transition Metal Complexes (HL = 5-Methyl-2-Phenyl-4-[(2-o-Tolylamino)-Phenylmethylene]pyrazol-3(2H)-one)
author_sort	Wang, Tao
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author_browse	Wang, Tao Bao, Feng Liu, Yan Xing, Bin Tan, Zhe Tan, Zhifang Lü, Xing Qiang
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author-letter	Wang, Tao
doi_str_mv	10.1007/s10904-008-9216-x
dewey-full	660
title_sort	effect of coordination modes of hl ligand on the molecular architecture of its transition metal complexes (hl = 5-methyl-2-phenyl-4-[(2-o-tolylamino)-phenylmethylene]pyrazol-3(2h)-one)
title_auth	Effect of Coordination Modes of HL Ligand on the Molecular Architecture of Its Transition Metal Complexes (HL = 5-Methyl-2-Phenyl-4-[(2-o-Tolylamino)-Phenylmethylene]pyrazol-3(2H)-one)
abstract	Abstract Two $ Ag^{+} $ complexes [Ag(HL)2($ PF_{6} $)] (1) and [(AgL)n · n($ CH_{2} $$ Cl_{2} $) · n(0.$ 5H_{2} $O)] (2) (HL = 5-methyl-2-phenyl-4-[(2-o-tolylamino)-phenylmethylene]pyrazol-3(2H)-one) were synthesized and structurally characterized by EA analysis, IR spectra and X-ray crystallography. The result shows that two expected coordination modes (Modes I and III in Scheme 1) of the HL ligand, can be observed in its $ Ag^{+} $ complexes, while not in other transition metal ions ($ Ni^{2+} $, $ Co^{2+} $ or $ Cu^{2+} $) complexes whether deprotonation or not for the HL ligand. Graphical Abstract Three possible coordination modes (Modes I, II or III in Scheme 1) of the selected HL (HL = 5-methyl-2-phenyl-4-[(2-o-tolylamino)-phenylmethylene]pyrazol-3(2H)-one) ligand, can be adopted, in which Modes I and III can be observed in its two $ Ag^{+} $ complexes [Ag(HL)2($ PF_{6} $)](1) and [(AgL)n · n($ CH_{2} $$ Cl_{2} $) · n(0.$ 5H_{2} $O)] (2), while Mode II just observed in its transition metal ions ($ Cu^{2+} $, $ Ni^{2+} $, or $ Co^{2+} $) complexes, resulting from the deprotonatd form of the HL ligand and the coordination characters of transition metal ions. © Springer Science+Business Media, LLC 2008
abstractGer	Abstract Two $ Ag^{+} $ complexes [Ag(HL)2($ PF_{6} $)] (1) and [(AgL)n · n($ CH_{2} $$ Cl_{2} $) · n(0.$ 5H_{2} $O)] (2) (HL = 5-methyl-2-phenyl-4-[(2-o-tolylamino)-phenylmethylene]pyrazol-3(2H)-one) were synthesized and structurally characterized by EA analysis, IR spectra and X-ray crystallography. The result shows that two expected coordination modes (Modes I and III in Scheme 1) of the HL ligand, can be observed in its $ Ag^{+} $ complexes, while not in other transition metal ions ($ Ni^{2+} $, $ Co^{2+} $ or $ Cu^{2+} $) complexes whether deprotonation or not for the HL ligand. Graphical Abstract Three possible coordination modes (Modes I, II or III in Scheme 1) of the selected HL (HL = 5-methyl-2-phenyl-4-[(2-o-tolylamino)-phenylmethylene]pyrazol-3(2H)-one) ligand, can be adopted, in which Modes I and III can be observed in its two $ Ag^{+} $ complexes [Ag(HL)2($ PF_{6} $)](1) and [(AgL)n · n($ CH_{2} $$ Cl_{2} $) · n(0.$ 5H_{2} $O)] (2), while Mode II just observed in its transition metal ions ($ Cu^{2+} $, $ Ni^{2+} $, or $ Co^{2+} $) complexes, resulting from the deprotonatd form of the HL ligand and the coordination characters of transition metal ions. © Springer Science+Business Media, LLC 2008
abstract_unstemmed	Abstract Two $ Ag^{+} $ complexes [Ag(HL)2($ PF_{6} $)] (1) and [(AgL)n · n($ CH_{2} $$ Cl_{2} $) · n(0.$ 5H_{2} $O)] (2) (HL = 5-methyl-2-phenyl-4-[(2-o-tolylamino)-phenylmethylene]pyrazol-3(2H)-one) were synthesized and structurally characterized by EA analysis, IR spectra and X-ray crystallography. The result shows that two expected coordination modes (Modes I and III in Scheme 1) of the HL ligand, can be observed in its $ Ag^{+} $ complexes, while not in other transition metal ions ($ Ni^{2+} $, $ Co^{2+} $ or $ Cu^{2+} $) complexes whether deprotonation or not for the HL ligand. Graphical Abstract Three possible coordination modes (Modes I, II or III in Scheme 1) of the selected HL (HL = 5-methyl-2-phenyl-4-[(2-o-tolylamino)-phenylmethylene]pyrazol-3(2H)-one) ligand, can be adopted, in which Modes I and III can be observed in its two $ Ag^{+} $ complexes [Ag(HL)2($ PF_{6} $)](1) and [(AgL)n · n($ CH_{2} $$ Cl_{2} $) · n(0.$ 5H_{2} $O)] (2), while Mode II just observed in its transition metal ions ($ Cu^{2+} $, $ Ni^{2+} $, or $ Co^{2+} $) complexes, resulting from the deprotonatd form of the HL ligand and the coordination characters of transition metal ions. © Springer Science+Business Media, LLC 2008
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container_issue	3
title_short	Effect of Coordination Modes of HL Ligand on the Molecular Architecture of Its Transition Metal Complexes (HL = 5-Methyl-2-Phenyl-4-[(2-o-Tolylamino)-Phenylmethylene]pyrazol-3(2H)-one)
url	https://doi.org/10.1007/s10904-008-9216-x
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author2	Bao, Feng Liu, Yan Xing, Bin Tan, Zhe Tan, Zhifang Lü, Xing Qiang
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up_date	2024-07-04T03:45:05.106Z
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Effect of Coordination Modes of HL Ligand on the Molecular Architecture of Its Transition Metal Complexes (HL = 5-Methyl-2-Phenyl-4-[(2-o-Tolylamino)-Phenylmethylene]pyrazol-3(2H)-one)

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