Complexes Containing N-(2-hydroxyethyl)-ethylenediamine with Tetracyanometallate (II): Synthesis, IR Spectra, Thermal Behavior, Crystal Structure, Magnetic Properties and Catalysis
Abstract Two novel cyano-bridged $ Ni^{2+} $ and $ Cu^{2+} $ compounds, {[$ M^{2+} $(hydeten)2(μ-CN)2Ni(CN)2]n, $ M^{2+ } $= $ Ni^{2+} $ (c1) and $ Cu^{2+} $ (c2), N-(2-hydroxyethyl)-ethylenediamine (hydeten), were prepared and characterized by elemental analysis, IR spectroscopy and thermoanalytica...
Ausführliche Beschreibung
Autor*in: |
Karadağ, Ahmet [verfasserIn] |
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Format: |
Artikel |
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Sprache: |
Englisch |
Erschienen: |
2012 |
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Anmerkung: |
© Springer Science+Business Media, LLC 2012 |
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Übergeordnetes Werk: |
Enthalten in: Journal of inorganic and organometallic polymers and materials - Springer US, 1991, 22(2012), 2 vom: 28. Feb., Seite 369-378 |
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Übergeordnetes Werk: |
volume:22 ; year:2012 ; number:2 ; day:28 ; month:02 ; pages:369-378 |
Links: |
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DOI / URN: |
10.1007/s10904-011-9623-2 |
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Katalog-ID: |
OLC2061511090 |
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520 | |a Abstract Two novel cyano-bridged $ Ni^{2+} $ and $ Cu^{2+} $ compounds, {[$ M^{2+} $(hydeten)2(μ-CN)2Ni(CN)2]n, $ M^{2+ } $= $ Ni^{2+} $ (c1) and $ Cu^{2+} $ (c2), N-(2-hydroxyethyl)-ethylenediamine (hydeten), were prepared and characterized by elemental analysis, IR spectroscopy and thermoanalytical measurements. The one-dimensional polymeric structure of c2, which was determined by X-ray diffraction techniques, was formed with a 2,2-TT-type chain, –Cu(hydeten)2-NC-Ni(CN)2-CN-Cu(hydeten)2-, linkages. Also, while the EPR spectra and magnetic properties of complexes c1 and c2 with [Ni(hydeten)2Pd(CN)4] (c3) and [Cu(hydeten)2Pd(CN)4] (c4) [Karadağ, Z Kristallogr 222:39, 2007] were investigated, the catalytic activity of c3 and c4 was studied. The EPR spectra of c2 and c4 showed that $ Cu^{2+} $ was located in tetragonal distorted octahedral sites (D4h) and the ground state of the paramagnetic electron was $$ d_{{ x^{2} - y^{2} }} $$. The magnetic behavior exhibited weak antiferromagnetic interactions in all the complexes. Also, the catalytic properties of c3 and c4, which were assigned with Suzuki and Heck coupling reactions, showed that they did not have catalytic effects. | ||
650 | 4 | |a Tetracyanometallate(II) | |
650 | 4 | |a -(2-hydroxyethyl)-ethylenediamine | |
650 | 4 | |a Thermal behavior | |
650 | 4 | |a EPR | |
650 | 4 | |a Magnetic susceptibly | |
650 | 4 | |a Catalysis | |
700 | 1 | |a Şenocak, Ayşegül |4 aut | |
700 | 1 | |a Yerli, Yusuf |4 aut | |
700 | 1 | |a Şahin, Ertan |4 aut | |
700 | 1 | |a Topkaya, Ramazan |4 aut | |
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10.1007/s10904-011-9623-2 doi (DE-627)OLC2061511090 (DE-He213)s10904-011-9623-2-p DE-627 ger DE-627 rakwb eng 660 VZ Karadağ, Ahmet verfasserin aut Complexes Containing N-(2-hydroxyethyl)-ethylenediamine with Tetracyanometallate (II): Synthesis, IR Spectra, Thermal Behavior, Crystal Structure, Magnetic Properties and Catalysis 2012 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2012 Abstract Two novel cyano-bridged $ Ni^{2+} $ and $ Cu^{2+} $ compounds, {[$ M^{2+} $(hydeten)2(μ-CN)2Ni(CN)2]n, $ M^{2+ } $= $ Ni^{2+} $ (c1) and $ Cu^{2+} $ (c2), N-(2-hydroxyethyl)-ethylenediamine (hydeten), were prepared and characterized by elemental analysis, IR spectroscopy and thermoanalytical measurements. The one-dimensional polymeric structure of c2, which was determined by X-ray diffraction techniques, was formed with a 2,2-TT-type chain, –Cu(hydeten)2-NC-Ni(CN)2-CN-Cu(hydeten)2-, linkages. Also, while the EPR spectra and magnetic properties of complexes c1 and c2 with [Ni(hydeten)2Pd(CN)4] (c3) and [Cu(hydeten)2Pd(CN)4] (c4) [Karadağ, Z Kristallogr 222:39, 2007] were investigated, the catalytic activity of c3 and c4 was studied. The EPR spectra of c2 and c4 showed that $ Cu^{2+} $ was located in tetragonal distorted octahedral sites (D4h) and the ground state of the paramagnetic electron was $$ d_{{ x^{2} - y^{2} }} $$. The magnetic behavior exhibited weak antiferromagnetic interactions in all the complexes. Also, the catalytic properties of c3 and c4, which were assigned with Suzuki and Heck coupling reactions, showed that they did not have catalytic effects. Tetracyanometallate(II) -(2-hydroxyethyl)-ethylenediamine Thermal behavior EPR Magnetic susceptibly Catalysis Şenocak, Ayşegül aut Yerli, Yusuf aut Şahin, Ertan aut Topkaya, Ramazan aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 22(2012), 2 vom: 28. Feb., Seite 369-378 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:22 year:2012 number:2 day:28 month:02 pages:369-378 https://doi.org/10.1007/s10904-011-9623-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 22 2012 2 28 02 369-378 |
spelling |
10.1007/s10904-011-9623-2 doi (DE-627)OLC2061511090 (DE-He213)s10904-011-9623-2-p DE-627 ger DE-627 rakwb eng 660 VZ Karadağ, Ahmet verfasserin aut Complexes Containing N-(2-hydroxyethyl)-ethylenediamine with Tetracyanometallate (II): Synthesis, IR Spectra, Thermal Behavior, Crystal Structure, Magnetic Properties and Catalysis 2012 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2012 Abstract Two novel cyano-bridged $ Ni^{2+} $ and $ Cu^{2+} $ compounds, {[$ M^{2+} $(hydeten)2(μ-CN)2Ni(CN)2]n, $ M^{2+ } $= $ Ni^{2+} $ (c1) and $ Cu^{2+} $ (c2), N-(2-hydroxyethyl)-ethylenediamine (hydeten), were prepared and characterized by elemental analysis, IR spectroscopy and thermoanalytical measurements. The one-dimensional polymeric structure of c2, which was determined by X-ray diffraction techniques, was formed with a 2,2-TT-type chain, –Cu(hydeten)2-NC-Ni(CN)2-CN-Cu(hydeten)2-, linkages. Also, while the EPR spectra and magnetic properties of complexes c1 and c2 with [Ni(hydeten)2Pd(CN)4] (c3) and [Cu(hydeten)2Pd(CN)4] (c4) [Karadağ, Z Kristallogr 222:39, 2007] were investigated, the catalytic activity of c3 and c4 was studied. The EPR spectra of c2 and c4 showed that $ Cu^{2+} $ was located in tetragonal distorted octahedral sites (D4h) and the ground state of the paramagnetic electron was $$ d_{{ x^{2} - y^{2} }} $$. The magnetic behavior exhibited weak antiferromagnetic interactions in all the complexes. Also, the catalytic properties of c3 and c4, which were assigned with Suzuki and Heck coupling reactions, showed that they did not have catalytic effects. Tetracyanometallate(II) -(2-hydroxyethyl)-ethylenediamine Thermal behavior EPR Magnetic susceptibly Catalysis Şenocak, Ayşegül aut Yerli, Yusuf aut Şahin, Ertan aut Topkaya, Ramazan aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 22(2012), 2 vom: 28. Feb., Seite 369-378 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:22 year:2012 number:2 day:28 month:02 pages:369-378 https://doi.org/10.1007/s10904-011-9623-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 22 2012 2 28 02 369-378 |
allfields_unstemmed |
10.1007/s10904-011-9623-2 doi (DE-627)OLC2061511090 (DE-He213)s10904-011-9623-2-p DE-627 ger DE-627 rakwb eng 660 VZ Karadağ, Ahmet verfasserin aut Complexes Containing N-(2-hydroxyethyl)-ethylenediamine with Tetracyanometallate (II): Synthesis, IR Spectra, Thermal Behavior, Crystal Structure, Magnetic Properties and Catalysis 2012 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2012 Abstract Two novel cyano-bridged $ Ni^{2+} $ and $ Cu^{2+} $ compounds, {[$ M^{2+} $(hydeten)2(μ-CN)2Ni(CN)2]n, $ M^{2+ } $= $ Ni^{2+} $ (c1) and $ Cu^{2+} $ (c2), N-(2-hydroxyethyl)-ethylenediamine (hydeten), were prepared and characterized by elemental analysis, IR spectroscopy and thermoanalytical measurements. The one-dimensional polymeric structure of c2, which was determined by X-ray diffraction techniques, was formed with a 2,2-TT-type chain, –Cu(hydeten)2-NC-Ni(CN)2-CN-Cu(hydeten)2-, linkages. Also, while the EPR spectra and magnetic properties of complexes c1 and c2 with [Ni(hydeten)2Pd(CN)4] (c3) and [Cu(hydeten)2Pd(CN)4] (c4) [Karadağ, Z Kristallogr 222:39, 2007] were investigated, the catalytic activity of c3 and c4 was studied. The EPR spectra of c2 and c4 showed that $ Cu^{2+} $ was located in tetragonal distorted octahedral sites (D4h) and the ground state of the paramagnetic electron was $$ d_{{ x^{2} - y^{2} }} $$. The magnetic behavior exhibited weak antiferromagnetic interactions in all the complexes. Also, the catalytic properties of c3 and c4, which were assigned with Suzuki and Heck coupling reactions, showed that they did not have catalytic effects. Tetracyanometallate(II) -(2-hydroxyethyl)-ethylenediamine Thermal behavior EPR Magnetic susceptibly Catalysis Şenocak, Ayşegül aut Yerli, Yusuf aut Şahin, Ertan aut Topkaya, Ramazan aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 22(2012), 2 vom: 28. Feb., Seite 369-378 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:22 year:2012 number:2 day:28 month:02 pages:369-378 https://doi.org/10.1007/s10904-011-9623-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 22 2012 2 28 02 369-378 |
allfieldsGer |
10.1007/s10904-011-9623-2 doi (DE-627)OLC2061511090 (DE-He213)s10904-011-9623-2-p DE-627 ger DE-627 rakwb eng 660 VZ Karadağ, Ahmet verfasserin aut Complexes Containing N-(2-hydroxyethyl)-ethylenediamine with Tetracyanometallate (II): Synthesis, IR Spectra, Thermal Behavior, Crystal Structure, Magnetic Properties and Catalysis 2012 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2012 Abstract Two novel cyano-bridged $ Ni^{2+} $ and $ Cu^{2+} $ compounds, {[$ M^{2+} $(hydeten)2(μ-CN)2Ni(CN)2]n, $ M^{2+ } $= $ Ni^{2+} $ (c1) and $ Cu^{2+} $ (c2), N-(2-hydroxyethyl)-ethylenediamine (hydeten), were prepared and characterized by elemental analysis, IR spectroscopy and thermoanalytical measurements. The one-dimensional polymeric structure of c2, which was determined by X-ray diffraction techniques, was formed with a 2,2-TT-type chain, –Cu(hydeten)2-NC-Ni(CN)2-CN-Cu(hydeten)2-, linkages. Also, while the EPR spectra and magnetic properties of complexes c1 and c2 with [Ni(hydeten)2Pd(CN)4] (c3) and [Cu(hydeten)2Pd(CN)4] (c4) [Karadağ, Z Kristallogr 222:39, 2007] were investigated, the catalytic activity of c3 and c4 was studied. The EPR spectra of c2 and c4 showed that $ Cu^{2+} $ was located in tetragonal distorted octahedral sites (D4h) and the ground state of the paramagnetic electron was $$ d_{{ x^{2} - y^{2} }} $$. The magnetic behavior exhibited weak antiferromagnetic interactions in all the complexes. Also, the catalytic properties of c3 and c4, which were assigned with Suzuki and Heck coupling reactions, showed that they did not have catalytic effects. Tetracyanometallate(II) -(2-hydroxyethyl)-ethylenediamine Thermal behavior EPR Magnetic susceptibly Catalysis Şenocak, Ayşegül aut Yerli, Yusuf aut Şahin, Ertan aut Topkaya, Ramazan aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 22(2012), 2 vom: 28. Feb., Seite 369-378 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:22 year:2012 number:2 day:28 month:02 pages:369-378 https://doi.org/10.1007/s10904-011-9623-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 22 2012 2 28 02 369-378 |
allfieldsSound |
10.1007/s10904-011-9623-2 doi (DE-627)OLC2061511090 (DE-He213)s10904-011-9623-2-p DE-627 ger DE-627 rakwb eng 660 VZ Karadağ, Ahmet verfasserin aut Complexes Containing N-(2-hydroxyethyl)-ethylenediamine with Tetracyanometallate (II): Synthesis, IR Spectra, Thermal Behavior, Crystal Structure, Magnetic Properties and Catalysis 2012 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2012 Abstract Two novel cyano-bridged $ Ni^{2+} $ and $ Cu^{2+} $ compounds, {[$ M^{2+} $(hydeten)2(μ-CN)2Ni(CN)2]n, $ M^{2+ } $= $ Ni^{2+} $ (c1) and $ Cu^{2+} $ (c2), N-(2-hydroxyethyl)-ethylenediamine (hydeten), were prepared and characterized by elemental analysis, IR spectroscopy and thermoanalytical measurements. The one-dimensional polymeric structure of c2, which was determined by X-ray diffraction techniques, was formed with a 2,2-TT-type chain, –Cu(hydeten)2-NC-Ni(CN)2-CN-Cu(hydeten)2-, linkages. Also, while the EPR spectra and magnetic properties of complexes c1 and c2 with [Ni(hydeten)2Pd(CN)4] (c3) and [Cu(hydeten)2Pd(CN)4] (c4) [Karadağ, Z Kristallogr 222:39, 2007] were investigated, the catalytic activity of c3 and c4 was studied. The EPR spectra of c2 and c4 showed that $ Cu^{2+} $ was located in tetragonal distorted octahedral sites (D4h) and the ground state of the paramagnetic electron was $$ d_{{ x^{2} - y^{2} }} $$. The magnetic behavior exhibited weak antiferromagnetic interactions in all the complexes. Also, the catalytic properties of c3 and c4, which were assigned with Suzuki and Heck coupling reactions, showed that they did not have catalytic effects. Tetracyanometallate(II) -(2-hydroxyethyl)-ethylenediamine Thermal behavior EPR Magnetic susceptibly Catalysis Şenocak, Ayşegül aut Yerli, Yusuf aut Şahin, Ertan aut Topkaya, Ramazan aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 22(2012), 2 vom: 28. Feb., Seite 369-378 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:22 year:2012 number:2 day:28 month:02 pages:369-378 https://doi.org/10.1007/s10904-011-9623-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 22 2012 2 28 02 369-378 |
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Enthalten in Journal of inorganic and organometallic polymers and materials 22(2012), 2 vom: 28. Feb., Seite 369-378 volume:22 year:2012 number:2 day:28 month:02 pages:369-378 |
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Karadağ, Ahmet @@aut@@ Şenocak, Ayşegül @@aut@@ Yerli, Yusuf @@aut@@ Şahin, Ertan @@aut@@ Topkaya, Ramazan @@aut@@ |
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Karadağ, Ahmet |
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660 VZ Complexes Containing N-(2-hydroxyethyl)-ethylenediamine with Tetracyanometallate (II): Synthesis, IR Spectra, Thermal Behavior, Crystal Structure, Magnetic Properties and Catalysis Tetracyanometallate(II) -(2-hydroxyethyl)-ethylenediamine Thermal behavior EPR Magnetic susceptibly Catalysis |
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Karadağ, Ahmet Şenocak, Ayşegül Yerli, Yusuf Şahin, Ertan Topkaya, Ramazan |
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complexes containing n-(2-hydroxyethyl)-ethylenediamine with tetracyanometallate (ii): synthesis, ir spectra, thermal behavior, crystal structure, magnetic properties and catalysis |
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Complexes Containing N-(2-hydroxyethyl)-ethylenediamine with Tetracyanometallate (II): Synthesis, IR Spectra, Thermal Behavior, Crystal Structure, Magnetic Properties and Catalysis |
abstract |
Abstract Two novel cyano-bridged $ Ni^{2+} $ and $ Cu^{2+} $ compounds, {[$ M^{2+} $(hydeten)2(μ-CN)2Ni(CN)2]n, $ M^{2+ } $= $ Ni^{2+} $ (c1) and $ Cu^{2+} $ (c2), N-(2-hydroxyethyl)-ethylenediamine (hydeten), were prepared and characterized by elemental analysis, IR spectroscopy and thermoanalytical measurements. The one-dimensional polymeric structure of c2, which was determined by X-ray diffraction techniques, was formed with a 2,2-TT-type chain, –Cu(hydeten)2-NC-Ni(CN)2-CN-Cu(hydeten)2-, linkages. Also, while the EPR spectra and magnetic properties of complexes c1 and c2 with [Ni(hydeten)2Pd(CN)4] (c3) and [Cu(hydeten)2Pd(CN)4] (c4) [Karadağ, Z Kristallogr 222:39, 2007] were investigated, the catalytic activity of c3 and c4 was studied. The EPR spectra of c2 and c4 showed that $ Cu^{2+} $ was located in tetragonal distorted octahedral sites (D4h) and the ground state of the paramagnetic electron was $$ d_{{ x^{2} - y^{2} }} $$. The magnetic behavior exhibited weak antiferromagnetic interactions in all the complexes. Also, the catalytic properties of c3 and c4, which were assigned with Suzuki and Heck coupling reactions, showed that they did not have catalytic effects. © Springer Science+Business Media, LLC 2012 |
abstractGer |
Abstract Two novel cyano-bridged $ Ni^{2+} $ and $ Cu^{2+} $ compounds, {[$ M^{2+} $(hydeten)2(μ-CN)2Ni(CN)2]n, $ M^{2+ } $= $ Ni^{2+} $ (c1) and $ Cu^{2+} $ (c2), N-(2-hydroxyethyl)-ethylenediamine (hydeten), were prepared and characterized by elemental analysis, IR spectroscopy and thermoanalytical measurements. The one-dimensional polymeric structure of c2, which was determined by X-ray diffraction techniques, was formed with a 2,2-TT-type chain, –Cu(hydeten)2-NC-Ni(CN)2-CN-Cu(hydeten)2-, linkages. Also, while the EPR spectra and magnetic properties of complexes c1 and c2 with [Ni(hydeten)2Pd(CN)4] (c3) and [Cu(hydeten)2Pd(CN)4] (c4) [Karadağ, Z Kristallogr 222:39, 2007] were investigated, the catalytic activity of c3 and c4 was studied. The EPR spectra of c2 and c4 showed that $ Cu^{2+} $ was located in tetragonal distorted octahedral sites (D4h) and the ground state of the paramagnetic electron was $$ d_{{ x^{2} - y^{2} }} $$. The magnetic behavior exhibited weak antiferromagnetic interactions in all the complexes. Also, the catalytic properties of c3 and c4, which were assigned with Suzuki and Heck coupling reactions, showed that they did not have catalytic effects. © Springer Science+Business Media, LLC 2012 |
abstract_unstemmed |
Abstract Two novel cyano-bridged $ Ni^{2+} $ and $ Cu^{2+} $ compounds, {[$ M^{2+} $(hydeten)2(μ-CN)2Ni(CN)2]n, $ M^{2+ } $= $ Ni^{2+} $ (c1) and $ Cu^{2+} $ (c2), N-(2-hydroxyethyl)-ethylenediamine (hydeten), were prepared and characterized by elemental analysis, IR spectroscopy and thermoanalytical measurements. The one-dimensional polymeric structure of c2, which was determined by X-ray diffraction techniques, was formed with a 2,2-TT-type chain, –Cu(hydeten)2-NC-Ni(CN)2-CN-Cu(hydeten)2-, linkages. Also, while the EPR spectra and magnetic properties of complexes c1 and c2 with [Ni(hydeten)2Pd(CN)4] (c3) and [Cu(hydeten)2Pd(CN)4] (c4) [Karadağ, Z Kristallogr 222:39, 2007] were investigated, the catalytic activity of c3 and c4 was studied. The EPR spectra of c2 and c4 showed that $ Cu^{2+} $ was located in tetragonal distorted octahedral sites (D4h) and the ground state of the paramagnetic electron was $$ d_{{ x^{2} - y^{2} }} $$. The magnetic behavior exhibited weak antiferromagnetic interactions in all the complexes. Also, the catalytic properties of c3 and c4, which were assigned with Suzuki and Heck coupling reactions, showed that they did not have catalytic effects. © Springer Science+Business Media, LLC 2012 |
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Complexes Containing N-(2-hydroxyethyl)-ethylenediamine with Tetracyanometallate (II): Synthesis, IR Spectra, Thermal Behavior, Crystal Structure, Magnetic Properties and Catalysis |
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