Linear Coordination Polymers Assembled from Dinuclear Cu(I) Units: Interchain π–π and CH–π Interactions in Controlling Alignments of Polymeric Chains in Solid State
Abstract An axial substitution of the coordinated acetonitrile molecules in dinuclear Cu(I) compound, [$ Cu_{2} $(μ-$ PhPPy_{2} $)2($ CH_{3} $CN)2]($ ClO_{4} $)2 (1) ($ PhPPy_{2} $ = bis(2-pyridyl)phenylphosphine) by various dicarboxylates (isophthalate, terephthalate and naphthalene-2,6-dicarboxyla...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Zhang, Tianle [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2014 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer Science+Business Media New York 2014 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of inorganic and organometallic polymers and materials - Springer US, 1991, 24(2014), 5 vom: 14. Juli, Seite 865-873 |
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| Übergeordnetes Werk: |
volume:24 ; year:2014 ; number:5 ; day:14 ; month:07 ; pages:865-873 |
| Links: |
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| DOI / URN: |
10.1007/s10904-014-0051-y |
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OLC206151538X |
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| 520 | |a Abstract An axial substitution of the coordinated acetonitrile molecules in dinuclear Cu(I) compound, [$ Cu_{2} $(μ-$ PhPPy_{2} $)2($ CH_{3} $CN)2]($ ClO_{4} $)2 (1) ($ PhPPy_{2} $ = bis(2-pyridyl)phenylphosphine) by various dicarboxylates (isophthalate, terephthalate and naphthalene-2,6-dicarboxylate) led to a class of new linear coordination polymers, {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-1,3-$ C_{6} $$ H_{4} $($ CO_{2} $)2)}∞ (2), {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-1,4-$ C_{6} $$ H_{4} $($ CO_{2} $)2)}∞ (3) and {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-2,6-$ C_{12} $$ H_{6} $($ CO_{2} $)2)}∞ (4). X-ray crystallographic studies reveals that all the polymers adopt almost linear structures, where the dicarboxylate groups connect dinuclear Cu(I) units as linkers. In 2 and 4, polymeric chains are parallel to each other. However the chains in 3 are arranged layer by layer, where polymeric chains are parallel in one layer, but chains in the neighboring layers are aligned with the angle (42°). The detailed structural analyses demonstrate that in solid state, the polymeric chains display different orientations which are controlled by interchain π–π and CH–π interactions. In solid state, all the coordination polymers are highly emissive at room temperature, which exhibit phosphorescence characteristics and are assigned as metal to ligand charge transfer. | ||
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| 650 | 4 | |a 1D coordination polymer | |
| 650 | 4 | |a π–π/CH–π interaction | |
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| 650 | 4 | |a Luminescence | |
| 700 | 1 | |a Wang, Kaili |4 aut | |
| 700 | 1 | |a Ji, Changpeng |4 aut | |
| 700 | 1 | |a Meng, Xianggao |4 aut | |
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10.1007/s10904-014-0051-y doi (DE-627)OLC206151538X (DE-He213)s10904-014-0051-y-p DE-627 ger DE-627 rakwb eng 660 VZ Zhang, Tianle verfasserin aut Linear Coordination Polymers Assembled from Dinuclear Cu(I) Units: Interchain π–π and CH–π Interactions in Controlling Alignments of Polymeric Chains in Solid State 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2014 Abstract An axial substitution of the coordinated acetonitrile molecules in dinuclear Cu(I) compound, [$ Cu_{2} $(μ-$ PhPPy_{2} $)2($ CH_{3} $CN)2]($ ClO_{4} $)2 (1) ($ PhPPy_{2} $ = bis(2-pyridyl)phenylphosphine) by various dicarboxylates (isophthalate, terephthalate and naphthalene-2,6-dicarboxylate) led to a class of new linear coordination polymers, {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-1,3-$ C_{6} $$ H_{4} $($ CO_{2} $)2)}∞ (2), {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-1,4-$ C_{6} $$ H_{4} $($ CO_{2} $)2)}∞ (3) and {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-2,6-$ C_{12} $$ H_{6} $($ CO_{2} $)2)}∞ (4). X-ray crystallographic studies reveals that all the polymers adopt almost linear structures, where the dicarboxylate groups connect dinuclear Cu(I) units as linkers. In 2 and 4, polymeric chains are parallel to each other. However the chains in 3 are arranged layer by layer, where polymeric chains are parallel in one layer, but chains in the neighboring layers are aligned with the angle (42°). The detailed structural analyses demonstrate that in solid state, the polymeric chains display different orientations which are controlled by interchain π–π and CH–π interactions. In solid state, all the coordination polymers are highly emissive at room temperature, which exhibit phosphorescence characteristics and are assigned as metal to ligand charge transfer. Cuprous complex 1D coordination polymer π–π/CH–π interaction Alignment Luminescence Wang, Kaili aut Ji, Changpeng aut Meng, Xianggao aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 24(2014), 5 vom: 14. Juli, Seite 865-873 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:24 year:2014 number:5 day:14 month:07 pages:865-873 https://doi.org/10.1007/s10904-014-0051-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 24 2014 5 14 07 865-873 |
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10.1007/s10904-014-0051-y doi (DE-627)OLC206151538X (DE-He213)s10904-014-0051-y-p DE-627 ger DE-627 rakwb eng 660 VZ Zhang, Tianle verfasserin aut Linear Coordination Polymers Assembled from Dinuclear Cu(I) Units: Interchain π–π and CH–π Interactions in Controlling Alignments of Polymeric Chains in Solid State 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2014 Abstract An axial substitution of the coordinated acetonitrile molecules in dinuclear Cu(I) compound, [$ Cu_{2} $(μ-$ PhPPy_{2} $)2($ CH_{3} $CN)2]($ ClO_{4} $)2 (1) ($ PhPPy_{2} $ = bis(2-pyridyl)phenylphosphine) by various dicarboxylates (isophthalate, terephthalate and naphthalene-2,6-dicarboxylate) led to a class of new linear coordination polymers, {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-1,3-$ C_{6} $$ H_{4} $($ CO_{2} $)2)}∞ (2), {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-1,4-$ C_{6} $$ H_{4} $($ CO_{2} $)2)}∞ (3) and {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-2,6-$ C_{12} $$ H_{6} $($ CO_{2} $)2)}∞ (4). X-ray crystallographic studies reveals that all the polymers adopt almost linear structures, where the dicarboxylate groups connect dinuclear Cu(I) units as linkers. In 2 and 4, polymeric chains are parallel to each other. However the chains in 3 are arranged layer by layer, where polymeric chains are parallel in one layer, but chains in the neighboring layers are aligned with the angle (42°). The detailed structural analyses demonstrate that in solid state, the polymeric chains display different orientations which are controlled by interchain π–π and CH–π interactions. In solid state, all the coordination polymers are highly emissive at room temperature, which exhibit phosphorescence characteristics and are assigned as metal to ligand charge transfer. Cuprous complex 1D coordination polymer π–π/CH–π interaction Alignment Luminescence Wang, Kaili aut Ji, Changpeng aut Meng, Xianggao aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 24(2014), 5 vom: 14. Juli, Seite 865-873 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:24 year:2014 number:5 day:14 month:07 pages:865-873 https://doi.org/10.1007/s10904-014-0051-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 24 2014 5 14 07 865-873 |
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10.1007/s10904-014-0051-y doi (DE-627)OLC206151538X (DE-He213)s10904-014-0051-y-p DE-627 ger DE-627 rakwb eng 660 VZ Zhang, Tianle verfasserin aut Linear Coordination Polymers Assembled from Dinuclear Cu(I) Units: Interchain π–π and CH–π Interactions in Controlling Alignments of Polymeric Chains in Solid State 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2014 Abstract An axial substitution of the coordinated acetonitrile molecules in dinuclear Cu(I) compound, [$ Cu_{2} $(μ-$ PhPPy_{2} $)2($ CH_{3} $CN)2]($ ClO_{4} $)2 (1) ($ PhPPy_{2} $ = bis(2-pyridyl)phenylphosphine) by various dicarboxylates (isophthalate, terephthalate and naphthalene-2,6-dicarboxylate) led to a class of new linear coordination polymers, {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-1,3-$ C_{6} $$ H_{4} $($ CO_{2} $)2)}∞ (2), {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-1,4-$ C_{6} $$ H_{4} $($ CO_{2} $)2)}∞ (3) and {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-2,6-$ C_{12} $$ H_{6} $($ CO_{2} $)2)}∞ (4). X-ray crystallographic studies reveals that all the polymers adopt almost linear structures, where the dicarboxylate groups connect dinuclear Cu(I) units as linkers. In 2 and 4, polymeric chains are parallel to each other. However the chains in 3 are arranged layer by layer, where polymeric chains are parallel in one layer, but chains in the neighboring layers are aligned with the angle (42°). The detailed structural analyses demonstrate that in solid state, the polymeric chains display different orientations which are controlled by interchain π–π and CH–π interactions. In solid state, all the coordination polymers are highly emissive at room temperature, which exhibit phosphorescence characteristics and are assigned as metal to ligand charge transfer. Cuprous complex 1D coordination polymer π–π/CH–π interaction Alignment Luminescence Wang, Kaili aut Ji, Changpeng aut Meng, Xianggao aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 24(2014), 5 vom: 14. Juli, Seite 865-873 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:24 year:2014 number:5 day:14 month:07 pages:865-873 https://doi.org/10.1007/s10904-014-0051-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 24 2014 5 14 07 865-873 |
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10.1007/s10904-014-0051-y doi (DE-627)OLC206151538X (DE-He213)s10904-014-0051-y-p DE-627 ger DE-627 rakwb eng 660 VZ Zhang, Tianle verfasserin aut Linear Coordination Polymers Assembled from Dinuclear Cu(I) Units: Interchain π–π and CH–π Interactions in Controlling Alignments of Polymeric Chains in Solid State 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2014 Abstract An axial substitution of the coordinated acetonitrile molecules in dinuclear Cu(I) compound, [$ Cu_{2} $(μ-$ PhPPy_{2} $)2($ CH_{3} $CN)2]($ ClO_{4} $)2 (1) ($ PhPPy_{2} $ = bis(2-pyridyl)phenylphosphine) by various dicarboxylates (isophthalate, terephthalate and naphthalene-2,6-dicarboxylate) led to a class of new linear coordination polymers, {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-1,3-$ C_{6} $$ H_{4} $($ CO_{2} $)2)}∞ (2), {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-1,4-$ C_{6} $$ H_{4} $($ CO_{2} $)2)}∞ (3) and {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-2,6-$ C_{12} $$ H_{6} $($ CO_{2} $)2)}∞ (4). X-ray crystallographic studies reveals that all the polymers adopt almost linear structures, where the dicarboxylate groups connect dinuclear Cu(I) units as linkers. In 2 and 4, polymeric chains are parallel to each other. However the chains in 3 are arranged layer by layer, where polymeric chains are parallel in one layer, but chains in the neighboring layers are aligned with the angle (42°). The detailed structural analyses demonstrate that in solid state, the polymeric chains display different orientations which are controlled by interchain π–π and CH–π interactions. In solid state, all the coordination polymers are highly emissive at room temperature, which exhibit phosphorescence characteristics and are assigned as metal to ligand charge transfer. Cuprous complex 1D coordination polymer π–π/CH–π interaction Alignment Luminescence Wang, Kaili aut Ji, Changpeng aut Meng, Xianggao aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 24(2014), 5 vom: 14. Juli, Seite 865-873 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:24 year:2014 number:5 day:14 month:07 pages:865-873 https://doi.org/10.1007/s10904-014-0051-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 24 2014 5 14 07 865-873 |
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10.1007/s10904-014-0051-y doi (DE-627)OLC206151538X (DE-He213)s10904-014-0051-y-p DE-627 ger DE-627 rakwb eng 660 VZ Zhang, Tianle verfasserin aut Linear Coordination Polymers Assembled from Dinuclear Cu(I) Units: Interchain π–π and CH–π Interactions in Controlling Alignments of Polymeric Chains in Solid State 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2014 Abstract An axial substitution of the coordinated acetonitrile molecules in dinuclear Cu(I) compound, [$ Cu_{2} $(μ-$ PhPPy_{2} $)2($ CH_{3} $CN)2]($ ClO_{4} $)2 (1) ($ PhPPy_{2} $ = bis(2-pyridyl)phenylphosphine) by various dicarboxylates (isophthalate, terephthalate and naphthalene-2,6-dicarboxylate) led to a class of new linear coordination polymers, {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-1,3-$ C_{6} $$ H_{4} $($ CO_{2} $)2)}∞ (2), {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-1,4-$ C_{6} $$ H_{4} $($ CO_{2} $)2)}∞ (3) and {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-2,6-$ C_{12} $$ H_{6} $($ CO_{2} $)2)}∞ (4). X-ray crystallographic studies reveals that all the polymers adopt almost linear structures, where the dicarboxylate groups connect dinuclear Cu(I) units as linkers. In 2 and 4, polymeric chains are parallel to each other. However the chains in 3 are arranged layer by layer, where polymeric chains are parallel in one layer, but chains in the neighboring layers are aligned with the angle (42°). The detailed structural analyses demonstrate that in solid state, the polymeric chains display different orientations which are controlled by interchain π–π and CH–π interactions. In solid state, all the coordination polymers are highly emissive at room temperature, which exhibit phosphorescence characteristics and are assigned as metal to ligand charge transfer. Cuprous complex 1D coordination polymer π–π/CH–π interaction Alignment Luminescence Wang, Kaili aut Ji, Changpeng aut Meng, Xianggao aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 24(2014), 5 vom: 14. Juli, Seite 865-873 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:24 year:2014 number:5 day:14 month:07 pages:865-873 https://doi.org/10.1007/s10904-014-0051-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 24 2014 5 14 07 865-873 |
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Enthalten in Journal of inorganic and organometallic polymers and materials 24(2014), 5 vom: 14. Juli, Seite 865-873 volume:24 year:2014 number:5 day:14 month:07 pages:865-873 |
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Zhang, Tianle @@aut@@ Wang, Kaili @@aut@@ Ji, Changpeng @@aut@@ Meng, Xianggao @@aut@@ |
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Zhang, Tianle |
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Zhang, Tianle ddc 660 misc Cuprous complex misc 1D coordination polymer misc π–π/CH–π interaction misc Alignment misc Luminescence Linear Coordination Polymers Assembled from Dinuclear Cu(I) Units: Interchain π–π and CH–π Interactions in Controlling Alignments of Polymeric Chains in Solid State |
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660 VZ Linear Coordination Polymers Assembled from Dinuclear Cu(I) Units: Interchain π–π and CH–π Interactions in Controlling Alignments of Polymeric Chains in Solid State Cuprous complex 1D coordination polymer π–π/CH–π interaction Alignment Luminescence |
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Linear Coordination Polymers Assembled from Dinuclear Cu(I) Units: Interchain π–π and CH–π Interactions in Controlling Alignments of Polymeric Chains in Solid State |
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Linear Coordination Polymers Assembled from Dinuclear Cu(I) Units: Interchain π–π and CH–π Interactions in Controlling Alignments of Polymeric Chains in Solid State |
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linear coordination polymers assembled from dinuclear cu(i) units: interchain π–π and ch–π interactions in controlling alignments of polymeric chains in solid state |
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Linear Coordination Polymers Assembled from Dinuclear Cu(I) Units: Interchain π–π and CH–π Interactions in Controlling Alignments of Polymeric Chains in Solid State |
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Abstract An axial substitution of the coordinated acetonitrile molecules in dinuclear Cu(I) compound, [$ Cu_{2} $(μ-$ PhPPy_{2} $)2($ CH_{3} $CN)2]($ ClO_{4} $)2 (1) ($ PhPPy_{2} $ = bis(2-pyridyl)phenylphosphine) by various dicarboxylates (isophthalate, terephthalate and naphthalene-2,6-dicarboxylate) led to a class of new linear coordination polymers, {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-1,3-$ C_{6} $$ H_{4} $($ CO_{2} $)2)}∞ (2), {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-1,4-$ C_{6} $$ H_{4} $($ CO_{2} $)2)}∞ (3) and {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-2,6-$ C_{12} $$ H_{6} $($ CO_{2} $)2)}∞ (4). X-ray crystallographic studies reveals that all the polymers adopt almost linear structures, where the dicarboxylate groups connect dinuclear Cu(I) units as linkers. In 2 and 4, polymeric chains are parallel to each other. However the chains in 3 are arranged layer by layer, where polymeric chains are parallel in one layer, but chains in the neighboring layers are aligned with the angle (42°). The detailed structural analyses demonstrate that in solid state, the polymeric chains display different orientations which are controlled by interchain π–π and CH–π interactions. In solid state, all the coordination polymers are highly emissive at room temperature, which exhibit phosphorescence characteristics and are assigned as metal to ligand charge transfer. © Springer Science+Business Media New York 2014 |
| abstractGer |
Abstract An axial substitution of the coordinated acetonitrile molecules in dinuclear Cu(I) compound, [$ Cu_{2} $(μ-$ PhPPy_{2} $)2($ CH_{3} $CN)2]($ ClO_{4} $)2 (1) ($ PhPPy_{2} $ = bis(2-pyridyl)phenylphosphine) by various dicarboxylates (isophthalate, terephthalate and naphthalene-2,6-dicarboxylate) led to a class of new linear coordination polymers, {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-1,3-$ C_{6} $$ H_{4} $($ CO_{2} $)2)}∞ (2), {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-1,4-$ C_{6} $$ H_{4} $($ CO_{2} $)2)}∞ (3) and {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-2,6-$ C_{12} $$ H_{6} $($ CO_{2} $)2)}∞ (4). X-ray crystallographic studies reveals that all the polymers adopt almost linear structures, where the dicarboxylate groups connect dinuclear Cu(I) units as linkers. In 2 and 4, polymeric chains are parallel to each other. However the chains in 3 are arranged layer by layer, where polymeric chains are parallel in one layer, but chains in the neighboring layers are aligned with the angle (42°). The detailed structural analyses demonstrate that in solid state, the polymeric chains display different orientations which are controlled by interchain π–π and CH–π interactions. In solid state, all the coordination polymers are highly emissive at room temperature, which exhibit phosphorescence characteristics and are assigned as metal to ligand charge transfer. © Springer Science+Business Media New York 2014 |
| abstract_unstemmed |
Abstract An axial substitution of the coordinated acetonitrile molecules in dinuclear Cu(I) compound, [$ Cu_{2} $(μ-$ PhPPy_{2} $)2($ CH_{3} $CN)2]($ ClO_{4} $)2 (1) ($ PhPPy_{2} $ = bis(2-pyridyl)phenylphosphine) by various dicarboxylates (isophthalate, terephthalate and naphthalene-2,6-dicarboxylate) led to a class of new linear coordination polymers, {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-1,3-$ C_{6} $$ H_{4} $($ CO_{2} $)2)}∞ (2), {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-1,4-$ C_{6} $$ H_{4} $($ CO_{2} $)2)}∞ (3) and {[$ Cu_{2} $(μ-$ PhPPy_{2} $)2](μ-2,6-$ C_{12} $$ H_{6} $($ CO_{2} $)2)}∞ (4). X-ray crystallographic studies reveals that all the polymers adopt almost linear structures, where the dicarboxylate groups connect dinuclear Cu(I) units as linkers. In 2 and 4, polymeric chains are parallel to each other. However the chains in 3 are arranged layer by layer, where polymeric chains are parallel in one layer, but chains in the neighboring layers are aligned with the angle (42°). The detailed structural analyses demonstrate that in solid state, the polymeric chains display different orientations which are controlled by interchain π–π and CH–π interactions. In solid state, all the coordination polymers are highly emissive at room temperature, which exhibit phosphorescence characteristics and are assigned as metal to ligand charge transfer. © Springer Science+Business Media New York 2014 |
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