Characterization of Lithium Ion-Conducting Blend Biopolymer Electrolyte Based on CH–MC Doped with $ LiBF_{4} $
Abstract Lithium ion-conducting polymer blend electrolytes based on chitosan and methylcellulose complexed with lithium tetrafluoroborate ($ LiBF_{4} $) were prepared by a solution-casting method. The features of complexation of the solid polymer electrolytes were studied using X-ray diffraction tec...
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| Autor*in: |
Abdullah, Omed Gh. [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2018 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer Science+Business Media, LLC, part of Springer Nature 2018 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of inorganic and organometallic polymers and materials - Springer US, 1991, 28(2018), 4 vom: 06. Feb., Seite 1432-1438 |
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| Übergeordnetes Werk: |
volume:28 ; year:2018 ; number:4 ; day:06 ; month:02 ; pages:1432-1438 |
| Links: |
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| DOI / URN: |
10.1007/s10904-018-0802-2 |
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OLC2061523080 |
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| 520 | |a Abstract Lithium ion-conducting polymer blend electrolytes based on chitosan and methylcellulose complexed with lithium tetrafluoroborate ($ LiBF_{4} $) were prepared by a solution-casting method. The features of complexation of the solid polymer electrolytes were studied using X-ray diffraction techniques. Electrical conductivity of the prepared films was measured as a function of frequency at a different temperature. The increased trend of the electrical conductivity with increasing temperature and salt concentration can be attributed to increasing the mobility and number of lithium ions, respectively. The polymer electrolyte system exhibited Arrhenius-type, temperature-dependence ion conductivity behavior. Optical properties such as optical band gap, tail due to localized states and complex refractive index were estimated for present polymer electrolyte system from optical absorption measurement in the wavelength region 190–1100 nm. It was found that the optical direct band gap values shifted to lower energies upon addition of $ LiBF_{4} $ salt up to 40 wt% dopant concentration, and showed an increasing tendency for a further increase in dopant concentration. The high refractive index for this composition (2.44–2.63) at visible wavelengths eminently suitable for optical applications. | ||
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10.1007/s10904-018-0802-2 doi (DE-627)OLC2061523080 (DE-He213)s10904-018-0802-2-p DE-627 ger DE-627 rakwb eng 660 VZ Abdullah, Omed Gh. verfasserin aut Characterization of Lithium Ion-Conducting Blend Biopolymer Electrolyte Based on CH–MC Doped with $ LiBF_{4} $ 2018 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2018 Abstract Lithium ion-conducting polymer blend electrolytes based on chitosan and methylcellulose complexed with lithium tetrafluoroborate ($ LiBF_{4} $) were prepared by a solution-casting method. The features of complexation of the solid polymer electrolytes were studied using X-ray diffraction techniques. Electrical conductivity of the prepared films was measured as a function of frequency at a different temperature. The increased trend of the electrical conductivity with increasing temperature and salt concentration can be attributed to increasing the mobility and number of lithium ions, respectively. The polymer electrolyte system exhibited Arrhenius-type, temperature-dependence ion conductivity behavior. Optical properties such as optical band gap, tail due to localized states and complex refractive index were estimated for present polymer electrolyte system from optical absorption measurement in the wavelength region 190–1100 nm. It was found that the optical direct band gap values shifted to lower energies upon addition of $ LiBF_{4} $ salt up to 40 wt% dopant concentration, and showed an increasing tendency for a further increase in dopant concentration. The high refractive index for this composition (2.44–2.63) at visible wavelengths eminently suitable for optical applications. Solid polymer electrolyte Lithium-ion conducting Conductivity High refractive index polymer Hanna, Rawad R. aut Salman, Yahya A. K. aut Aziz, Shujahadeen B. aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 28(2018), 4 vom: 06. Feb., Seite 1432-1438 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:28 year:2018 number:4 day:06 month:02 pages:1432-1438 https://doi.org/10.1007/s10904-018-0802-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 28 2018 4 06 02 1432-1438 |
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10.1007/s10904-018-0802-2 doi (DE-627)OLC2061523080 (DE-He213)s10904-018-0802-2-p DE-627 ger DE-627 rakwb eng 660 VZ Abdullah, Omed Gh. verfasserin aut Characterization of Lithium Ion-Conducting Blend Biopolymer Electrolyte Based on CH–MC Doped with $ LiBF_{4} $ 2018 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2018 Abstract Lithium ion-conducting polymer blend electrolytes based on chitosan and methylcellulose complexed with lithium tetrafluoroborate ($ LiBF_{4} $) were prepared by a solution-casting method. The features of complexation of the solid polymer electrolytes were studied using X-ray diffraction techniques. Electrical conductivity of the prepared films was measured as a function of frequency at a different temperature. The increased trend of the electrical conductivity with increasing temperature and salt concentration can be attributed to increasing the mobility and number of lithium ions, respectively. The polymer electrolyte system exhibited Arrhenius-type, temperature-dependence ion conductivity behavior. Optical properties such as optical band gap, tail due to localized states and complex refractive index were estimated for present polymer electrolyte system from optical absorption measurement in the wavelength region 190–1100 nm. It was found that the optical direct band gap values shifted to lower energies upon addition of $ LiBF_{4} $ salt up to 40 wt% dopant concentration, and showed an increasing tendency for a further increase in dopant concentration. The high refractive index for this composition (2.44–2.63) at visible wavelengths eminently suitable for optical applications. Solid polymer electrolyte Lithium-ion conducting Conductivity High refractive index polymer Hanna, Rawad R. aut Salman, Yahya A. K. aut Aziz, Shujahadeen B. aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 28(2018), 4 vom: 06. Feb., Seite 1432-1438 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:28 year:2018 number:4 day:06 month:02 pages:1432-1438 https://doi.org/10.1007/s10904-018-0802-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 28 2018 4 06 02 1432-1438 |
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10.1007/s10904-018-0802-2 doi (DE-627)OLC2061523080 (DE-He213)s10904-018-0802-2-p DE-627 ger DE-627 rakwb eng 660 VZ Abdullah, Omed Gh. verfasserin aut Characterization of Lithium Ion-Conducting Blend Biopolymer Electrolyte Based on CH–MC Doped with $ LiBF_{4} $ 2018 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2018 Abstract Lithium ion-conducting polymer blend electrolytes based on chitosan and methylcellulose complexed with lithium tetrafluoroborate ($ LiBF_{4} $) were prepared by a solution-casting method. The features of complexation of the solid polymer electrolytes were studied using X-ray diffraction techniques. Electrical conductivity of the prepared films was measured as a function of frequency at a different temperature. The increased trend of the electrical conductivity with increasing temperature and salt concentration can be attributed to increasing the mobility and number of lithium ions, respectively. The polymer electrolyte system exhibited Arrhenius-type, temperature-dependence ion conductivity behavior. Optical properties such as optical band gap, tail due to localized states and complex refractive index were estimated for present polymer electrolyte system from optical absorption measurement in the wavelength region 190–1100 nm. It was found that the optical direct band gap values shifted to lower energies upon addition of $ LiBF_{4} $ salt up to 40 wt% dopant concentration, and showed an increasing tendency for a further increase in dopant concentration. The high refractive index for this composition (2.44–2.63) at visible wavelengths eminently suitable for optical applications. Solid polymer electrolyte Lithium-ion conducting Conductivity High refractive index polymer Hanna, Rawad R. aut Salman, Yahya A. K. aut Aziz, Shujahadeen B. aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 28(2018), 4 vom: 06. Feb., Seite 1432-1438 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:28 year:2018 number:4 day:06 month:02 pages:1432-1438 https://doi.org/10.1007/s10904-018-0802-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 28 2018 4 06 02 1432-1438 |
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10.1007/s10904-018-0802-2 doi (DE-627)OLC2061523080 (DE-He213)s10904-018-0802-2-p DE-627 ger DE-627 rakwb eng 660 VZ Abdullah, Omed Gh. verfasserin aut Characterization of Lithium Ion-Conducting Blend Biopolymer Electrolyte Based on CH–MC Doped with $ LiBF_{4} $ 2018 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2018 Abstract Lithium ion-conducting polymer blend electrolytes based on chitosan and methylcellulose complexed with lithium tetrafluoroborate ($ LiBF_{4} $) were prepared by a solution-casting method. The features of complexation of the solid polymer electrolytes were studied using X-ray diffraction techniques. Electrical conductivity of the prepared films was measured as a function of frequency at a different temperature. The increased trend of the electrical conductivity with increasing temperature and salt concentration can be attributed to increasing the mobility and number of lithium ions, respectively. The polymer electrolyte system exhibited Arrhenius-type, temperature-dependence ion conductivity behavior. Optical properties such as optical band gap, tail due to localized states and complex refractive index were estimated for present polymer electrolyte system from optical absorption measurement in the wavelength region 190–1100 nm. It was found that the optical direct band gap values shifted to lower energies upon addition of $ LiBF_{4} $ salt up to 40 wt% dopant concentration, and showed an increasing tendency for a further increase in dopant concentration. The high refractive index for this composition (2.44–2.63) at visible wavelengths eminently suitable for optical applications. Solid polymer electrolyte Lithium-ion conducting Conductivity High refractive index polymer Hanna, Rawad R. aut Salman, Yahya A. K. aut Aziz, Shujahadeen B. aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 28(2018), 4 vom: 06. Feb., Seite 1432-1438 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:28 year:2018 number:4 day:06 month:02 pages:1432-1438 https://doi.org/10.1007/s10904-018-0802-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 28 2018 4 06 02 1432-1438 |
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10.1007/s10904-018-0802-2 doi (DE-627)OLC2061523080 (DE-He213)s10904-018-0802-2-p DE-627 ger DE-627 rakwb eng 660 VZ Abdullah, Omed Gh. verfasserin aut Characterization of Lithium Ion-Conducting Blend Biopolymer Electrolyte Based on CH–MC Doped with $ LiBF_{4} $ 2018 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2018 Abstract Lithium ion-conducting polymer blend electrolytes based on chitosan and methylcellulose complexed with lithium tetrafluoroborate ($ LiBF_{4} $) were prepared by a solution-casting method. The features of complexation of the solid polymer electrolytes were studied using X-ray diffraction techniques. Electrical conductivity of the prepared films was measured as a function of frequency at a different temperature. The increased trend of the electrical conductivity with increasing temperature and salt concentration can be attributed to increasing the mobility and number of lithium ions, respectively. The polymer electrolyte system exhibited Arrhenius-type, temperature-dependence ion conductivity behavior. Optical properties such as optical band gap, tail due to localized states and complex refractive index were estimated for present polymer electrolyte system from optical absorption measurement in the wavelength region 190–1100 nm. It was found that the optical direct band gap values shifted to lower energies upon addition of $ LiBF_{4} $ salt up to 40 wt% dopant concentration, and showed an increasing tendency for a further increase in dopant concentration. The high refractive index for this composition (2.44–2.63) at visible wavelengths eminently suitable for optical applications. Solid polymer electrolyte Lithium-ion conducting Conductivity High refractive index polymer Hanna, Rawad R. aut Salman, Yahya A. K. aut Aziz, Shujahadeen B. aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 28(2018), 4 vom: 06. Feb., Seite 1432-1438 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:28 year:2018 number:4 day:06 month:02 pages:1432-1438 https://doi.org/10.1007/s10904-018-0802-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 28 2018 4 06 02 1432-1438 |
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Abdullah, Omed Gh. |
| doi_str_mv |
10.1007/s10904-018-0802-2 |
| dewey-full |
660 |
| title_sort |
characterization of lithium ion-conducting blend biopolymer electrolyte based on ch–mc doped with $ libf_{4} $ |
| title_auth |
Characterization of Lithium Ion-Conducting Blend Biopolymer Electrolyte Based on CH–MC Doped with $ LiBF_{4} $ |
| abstract |
Abstract Lithium ion-conducting polymer blend electrolytes based on chitosan and methylcellulose complexed with lithium tetrafluoroborate ($ LiBF_{4} $) were prepared by a solution-casting method. The features of complexation of the solid polymer electrolytes were studied using X-ray diffraction techniques. Electrical conductivity of the prepared films was measured as a function of frequency at a different temperature. The increased trend of the electrical conductivity with increasing temperature and salt concentration can be attributed to increasing the mobility and number of lithium ions, respectively. The polymer electrolyte system exhibited Arrhenius-type, temperature-dependence ion conductivity behavior. Optical properties such as optical band gap, tail due to localized states and complex refractive index were estimated for present polymer electrolyte system from optical absorption measurement in the wavelength region 190–1100 nm. It was found that the optical direct band gap values shifted to lower energies upon addition of $ LiBF_{4} $ salt up to 40 wt% dopant concentration, and showed an increasing tendency for a further increase in dopant concentration. The high refractive index for this composition (2.44–2.63) at visible wavelengths eminently suitable for optical applications. © Springer Science+Business Media, LLC, part of Springer Nature 2018 |
| abstractGer |
Abstract Lithium ion-conducting polymer blend electrolytes based on chitosan and methylcellulose complexed with lithium tetrafluoroborate ($ LiBF_{4} $) were prepared by a solution-casting method. The features of complexation of the solid polymer electrolytes were studied using X-ray diffraction techniques. Electrical conductivity of the prepared films was measured as a function of frequency at a different temperature. The increased trend of the electrical conductivity with increasing temperature and salt concentration can be attributed to increasing the mobility and number of lithium ions, respectively. The polymer electrolyte system exhibited Arrhenius-type, temperature-dependence ion conductivity behavior. Optical properties such as optical band gap, tail due to localized states and complex refractive index were estimated for present polymer electrolyte system from optical absorption measurement in the wavelength region 190–1100 nm. It was found that the optical direct band gap values shifted to lower energies upon addition of $ LiBF_{4} $ salt up to 40 wt% dopant concentration, and showed an increasing tendency for a further increase in dopant concentration. The high refractive index for this composition (2.44–2.63) at visible wavelengths eminently suitable for optical applications. © Springer Science+Business Media, LLC, part of Springer Nature 2018 |
| abstract_unstemmed |
Abstract Lithium ion-conducting polymer blend electrolytes based on chitosan and methylcellulose complexed with lithium tetrafluoroborate ($ LiBF_{4} $) were prepared by a solution-casting method. The features of complexation of the solid polymer electrolytes were studied using X-ray diffraction techniques. Electrical conductivity of the prepared films was measured as a function of frequency at a different temperature. The increased trend of the electrical conductivity with increasing temperature and salt concentration can be attributed to increasing the mobility and number of lithium ions, respectively. The polymer electrolyte system exhibited Arrhenius-type, temperature-dependence ion conductivity behavior. Optical properties such as optical band gap, tail due to localized states and complex refractive index were estimated for present polymer electrolyte system from optical absorption measurement in the wavelength region 190–1100 nm. It was found that the optical direct band gap values shifted to lower energies upon addition of $ LiBF_{4} $ salt up to 40 wt% dopant concentration, and showed an increasing tendency for a further increase in dopant concentration. The high refractive index for this composition (2.44–2.63) at visible wavelengths eminently suitable for optical applications. © Springer Science+Business Media, LLC, part of Springer Nature 2018 |
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4 |
| title_short |
Characterization of Lithium Ion-Conducting Blend Biopolymer Electrolyte Based on CH–MC Doped with $ LiBF_{4} $ |
| url |
https://doi.org/10.1007/s10904-018-0802-2 |
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Hanna, Rawad R. Salman, Yahya A. K. Aziz, Shujahadeen B. |
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| up_date |
2024-07-04T03:47:34.341Z |
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