Ionothermal Synthesis of Zn(II) Coordination Polymers with Fluorescent Sensing and Selective Dye Adsorption Properties
Abstract A series of zinc coordination polymers, {$ Zn_{2} $$ X_{2} $(BDC)(L)}n (X = Cl (1 and 3) or Br (2 and 4), BDC = 1,4-benzenedicarboxylate, L = 4,4′-bipyridine (1 and 2) or 1,4-diazabicyclo[2.2.2]octane (3 and 4)), have been synthesized by ionothermal reactions and characterized by X-ray crys...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Mai, Zhicai [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2019 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer Science+Business Media, LLC, part of Springer Nature 2019 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of inorganic and organometallic polymers and materials - Springer US, 1991, 29(2019), 5 vom: 18. März, Seite 1746-1754 |
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| Übergeordnetes Werk: |
volume:29 ; year:2019 ; number:5 ; day:18 ; month:03 ; pages:1746-1754 |
| Links: |
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| DOI / URN: |
10.1007/s10904-019-01136-w |
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OLC206152589X |
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| 520 | |a Abstract A series of zinc coordination polymers, {$ Zn_{2} $$ X_{2} $(BDC)(L)}n (X = Cl (1 and 3) or Br (2 and 4), BDC = 1,4-benzenedicarboxylate, L = 4,4′-bipyridine (1 and 2) or 1,4-diazabicyclo[2.2.2]octane (3 and 4)), have been synthesized by ionothermal reactions and characterized by X-ray crystallography and powder X-ray diffraction (PXRD). Compounds 1, 2 and 4 were also characterized by infrared spectroscopy (IR), thermogravimetric analysis (TGA) and their chemical stability towards various organic solvents were investigated. Compound 1 displays strong luminescence in the solid state and high luminescent selectivity and sensitivity for $ Fe^{3+} $ ions and nitroaromatics (NACs) in ethanol solutions, rendering it a potential fluorescence probe for these substrates. In addition, investigation on organic dye adsorptions shows that, among these coordination polymers, only complex 4 can selectively adsorb Congo red dye from other dye molecules. This demonstrates that the function of these coordination polymers can be regulated through subtle modification of their components. | ||
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10.1007/s10904-019-01136-w doi (DE-627)OLC206152589X (DE-He213)s10904-019-01136-w-p DE-627 ger DE-627 rakwb eng 660 VZ Mai, Zhicai verfasserin aut Ionothermal Synthesis of Zn(II) Coordination Polymers with Fluorescent Sensing and Selective Dye Adsorption Properties 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2019 Abstract A series of zinc coordination polymers, {$ Zn_{2} $$ X_{2} $(BDC)(L)}n (X = Cl (1 and 3) or Br (2 and 4), BDC = 1,4-benzenedicarboxylate, L = 4,4′-bipyridine (1 and 2) or 1,4-diazabicyclo[2.2.2]octane (3 and 4)), have been synthesized by ionothermal reactions and characterized by X-ray crystallography and powder X-ray diffraction (PXRD). Compounds 1, 2 and 4 were also characterized by infrared spectroscopy (IR), thermogravimetric analysis (TGA) and their chemical stability towards various organic solvents were investigated. Compound 1 displays strong luminescence in the solid state and high luminescent selectivity and sensitivity for $ Fe^{3+} $ ions and nitroaromatics (NACs) in ethanol solutions, rendering it a potential fluorescence probe for these substrates. In addition, investigation on organic dye adsorptions shows that, among these coordination polymers, only complex 4 can selectively adsorb Congo red dye from other dye molecules. This demonstrates that the function of these coordination polymers can be regulated through subtle modification of their components. Coordination polymers Ionothermal synthesis Fe(III) Nitroaromatics Dye adsorption Luo, Xiaojun aut Lei, Hao (orcid)0000-0002-8293-9358 aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 29(2019), 5 vom: 18. März, Seite 1746-1754 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:29 year:2019 number:5 day:18 month:03 pages:1746-1754 https://doi.org/10.1007/s10904-019-01136-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 29 2019 5 18 03 1746-1754 |
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10.1007/s10904-019-01136-w doi (DE-627)OLC206152589X (DE-He213)s10904-019-01136-w-p DE-627 ger DE-627 rakwb eng 660 VZ Mai, Zhicai verfasserin aut Ionothermal Synthesis of Zn(II) Coordination Polymers with Fluorescent Sensing and Selective Dye Adsorption Properties 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2019 Abstract A series of zinc coordination polymers, {$ Zn_{2} $$ X_{2} $(BDC)(L)}n (X = Cl (1 and 3) or Br (2 and 4), BDC = 1,4-benzenedicarboxylate, L = 4,4′-bipyridine (1 and 2) or 1,4-diazabicyclo[2.2.2]octane (3 and 4)), have been synthesized by ionothermal reactions and characterized by X-ray crystallography and powder X-ray diffraction (PXRD). Compounds 1, 2 and 4 were also characterized by infrared spectroscopy (IR), thermogravimetric analysis (TGA) and their chemical stability towards various organic solvents were investigated. Compound 1 displays strong luminescence in the solid state and high luminescent selectivity and sensitivity for $ Fe^{3+} $ ions and nitroaromatics (NACs) in ethanol solutions, rendering it a potential fluorescence probe for these substrates. In addition, investigation on organic dye adsorptions shows that, among these coordination polymers, only complex 4 can selectively adsorb Congo red dye from other dye molecules. This demonstrates that the function of these coordination polymers can be regulated through subtle modification of their components. Coordination polymers Ionothermal synthesis Fe(III) Nitroaromatics Dye adsorption Luo, Xiaojun aut Lei, Hao (orcid)0000-0002-8293-9358 aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 29(2019), 5 vom: 18. März, Seite 1746-1754 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:29 year:2019 number:5 day:18 month:03 pages:1746-1754 https://doi.org/10.1007/s10904-019-01136-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 29 2019 5 18 03 1746-1754 |
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10.1007/s10904-019-01136-w doi (DE-627)OLC206152589X (DE-He213)s10904-019-01136-w-p DE-627 ger DE-627 rakwb eng 660 VZ Mai, Zhicai verfasserin aut Ionothermal Synthesis of Zn(II) Coordination Polymers with Fluorescent Sensing and Selective Dye Adsorption Properties 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2019 Abstract A series of zinc coordination polymers, {$ Zn_{2} $$ X_{2} $(BDC)(L)}n (X = Cl (1 and 3) or Br (2 and 4), BDC = 1,4-benzenedicarboxylate, L = 4,4′-bipyridine (1 and 2) or 1,4-diazabicyclo[2.2.2]octane (3 and 4)), have been synthesized by ionothermal reactions and characterized by X-ray crystallography and powder X-ray diffraction (PXRD). Compounds 1, 2 and 4 were also characterized by infrared spectroscopy (IR), thermogravimetric analysis (TGA) and their chemical stability towards various organic solvents were investigated. Compound 1 displays strong luminescence in the solid state and high luminescent selectivity and sensitivity for $ Fe^{3+} $ ions and nitroaromatics (NACs) in ethanol solutions, rendering it a potential fluorescence probe for these substrates. In addition, investigation on organic dye adsorptions shows that, among these coordination polymers, only complex 4 can selectively adsorb Congo red dye from other dye molecules. This demonstrates that the function of these coordination polymers can be regulated through subtle modification of their components. Coordination polymers Ionothermal synthesis Fe(III) Nitroaromatics Dye adsorption Luo, Xiaojun aut Lei, Hao (orcid)0000-0002-8293-9358 aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 29(2019), 5 vom: 18. März, Seite 1746-1754 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:29 year:2019 number:5 day:18 month:03 pages:1746-1754 https://doi.org/10.1007/s10904-019-01136-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 29 2019 5 18 03 1746-1754 |
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10.1007/s10904-019-01136-w doi (DE-627)OLC206152589X (DE-He213)s10904-019-01136-w-p DE-627 ger DE-627 rakwb eng 660 VZ Mai, Zhicai verfasserin aut Ionothermal Synthesis of Zn(II) Coordination Polymers with Fluorescent Sensing and Selective Dye Adsorption Properties 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2019 Abstract A series of zinc coordination polymers, {$ Zn_{2} $$ X_{2} $(BDC)(L)}n (X = Cl (1 and 3) or Br (2 and 4), BDC = 1,4-benzenedicarboxylate, L = 4,4′-bipyridine (1 and 2) or 1,4-diazabicyclo[2.2.2]octane (3 and 4)), have been synthesized by ionothermal reactions and characterized by X-ray crystallography and powder X-ray diffraction (PXRD). Compounds 1, 2 and 4 were also characterized by infrared spectroscopy (IR), thermogravimetric analysis (TGA) and their chemical stability towards various organic solvents were investigated. Compound 1 displays strong luminescence in the solid state and high luminescent selectivity and sensitivity for $ Fe^{3+} $ ions and nitroaromatics (NACs) in ethanol solutions, rendering it a potential fluorescence probe for these substrates. In addition, investigation on organic dye adsorptions shows that, among these coordination polymers, only complex 4 can selectively adsorb Congo red dye from other dye molecules. This demonstrates that the function of these coordination polymers can be regulated through subtle modification of their components. Coordination polymers Ionothermal synthesis Fe(III) Nitroaromatics Dye adsorption Luo, Xiaojun aut Lei, Hao (orcid)0000-0002-8293-9358 aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 29(2019), 5 vom: 18. März, Seite 1746-1754 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:29 year:2019 number:5 day:18 month:03 pages:1746-1754 https://doi.org/10.1007/s10904-019-01136-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 29 2019 5 18 03 1746-1754 |
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10.1007/s10904-019-01136-w doi (DE-627)OLC206152589X (DE-He213)s10904-019-01136-w-p DE-627 ger DE-627 rakwb eng 660 VZ Mai, Zhicai verfasserin aut Ionothermal Synthesis of Zn(II) Coordination Polymers with Fluorescent Sensing and Selective Dye Adsorption Properties 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2019 Abstract A series of zinc coordination polymers, {$ Zn_{2} $$ X_{2} $(BDC)(L)}n (X = Cl (1 and 3) or Br (2 and 4), BDC = 1,4-benzenedicarboxylate, L = 4,4′-bipyridine (1 and 2) or 1,4-diazabicyclo[2.2.2]octane (3 and 4)), have been synthesized by ionothermal reactions and characterized by X-ray crystallography and powder X-ray diffraction (PXRD). Compounds 1, 2 and 4 were also characterized by infrared spectroscopy (IR), thermogravimetric analysis (TGA) and their chemical stability towards various organic solvents were investigated. Compound 1 displays strong luminescence in the solid state and high luminescent selectivity and sensitivity for $ Fe^{3+} $ ions and nitroaromatics (NACs) in ethanol solutions, rendering it a potential fluorescence probe for these substrates. In addition, investigation on organic dye adsorptions shows that, among these coordination polymers, only complex 4 can selectively adsorb Congo red dye from other dye molecules. This demonstrates that the function of these coordination polymers can be regulated through subtle modification of their components. Coordination polymers Ionothermal synthesis Fe(III) Nitroaromatics Dye adsorption Luo, Xiaojun aut Lei, Hao (orcid)0000-0002-8293-9358 aut Enthalten in Journal of inorganic and organometallic polymers and materials Springer US, 1991 29(2019), 5 vom: 18. März, Seite 1746-1754 (DE-627)130968625 (DE-600)1069621-0 (DE-576)029153867 1574-1443 nnns volume:29 year:2019 number:5 day:18 month:03 pages:1746-1754 https://doi.org/10.1007/s10904-019-01136-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 29 2019 5 18 03 1746-1754 |
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ionothermal synthesis of zn(ii) coordination polymers with fluorescent sensing and selective dye adsorption properties |
| title_auth |
Ionothermal Synthesis of Zn(II) Coordination Polymers with Fluorescent Sensing and Selective Dye Adsorption Properties |
| abstract |
Abstract A series of zinc coordination polymers, {$ Zn_{2} $$ X_{2} $(BDC)(L)}n (X = Cl (1 and 3) or Br (2 and 4), BDC = 1,4-benzenedicarboxylate, L = 4,4′-bipyridine (1 and 2) or 1,4-diazabicyclo[2.2.2]octane (3 and 4)), have been synthesized by ionothermal reactions and characterized by X-ray crystallography and powder X-ray diffraction (PXRD). Compounds 1, 2 and 4 were also characterized by infrared spectroscopy (IR), thermogravimetric analysis (TGA) and their chemical stability towards various organic solvents were investigated. Compound 1 displays strong luminescence in the solid state and high luminescent selectivity and sensitivity for $ Fe^{3+} $ ions and nitroaromatics (NACs) in ethanol solutions, rendering it a potential fluorescence probe for these substrates. In addition, investigation on organic dye adsorptions shows that, among these coordination polymers, only complex 4 can selectively adsorb Congo red dye from other dye molecules. This demonstrates that the function of these coordination polymers can be regulated through subtle modification of their components. © Springer Science+Business Media, LLC, part of Springer Nature 2019 |
| abstractGer |
Abstract A series of zinc coordination polymers, {$ Zn_{2} $$ X_{2} $(BDC)(L)}n (X = Cl (1 and 3) or Br (2 and 4), BDC = 1,4-benzenedicarboxylate, L = 4,4′-bipyridine (1 and 2) or 1,4-diazabicyclo[2.2.2]octane (3 and 4)), have been synthesized by ionothermal reactions and characterized by X-ray crystallography and powder X-ray diffraction (PXRD). Compounds 1, 2 and 4 were also characterized by infrared spectroscopy (IR), thermogravimetric analysis (TGA) and their chemical stability towards various organic solvents were investigated. Compound 1 displays strong luminescence in the solid state and high luminescent selectivity and sensitivity for $ Fe^{3+} $ ions and nitroaromatics (NACs) in ethanol solutions, rendering it a potential fluorescence probe for these substrates. In addition, investigation on organic dye adsorptions shows that, among these coordination polymers, only complex 4 can selectively adsorb Congo red dye from other dye molecules. This demonstrates that the function of these coordination polymers can be regulated through subtle modification of their components. © Springer Science+Business Media, LLC, part of Springer Nature 2019 |
| abstract_unstemmed |
Abstract A series of zinc coordination polymers, {$ Zn_{2} $$ X_{2} $(BDC)(L)}n (X = Cl (1 and 3) or Br (2 and 4), BDC = 1,4-benzenedicarboxylate, L = 4,4′-bipyridine (1 and 2) or 1,4-diazabicyclo[2.2.2]octane (3 and 4)), have been synthesized by ionothermal reactions and characterized by X-ray crystallography and powder X-ray diffraction (PXRD). Compounds 1, 2 and 4 were also characterized by infrared spectroscopy (IR), thermogravimetric analysis (TGA) and their chemical stability towards various organic solvents were investigated. Compound 1 displays strong luminescence in the solid state and high luminescent selectivity and sensitivity for $ Fe^{3+} $ ions and nitroaromatics (NACs) in ethanol solutions, rendering it a potential fluorescence probe for these substrates. In addition, investigation on organic dye adsorptions shows that, among these coordination polymers, only complex 4 can selectively adsorb Congo red dye from other dye molecules. This demonstrates that the function of these coordination polymers can be regulated through subtle modification of their components. © Springer Science+Business Media, LLC, part of Springer Nature 2019 |
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| title_short |
Ionothermal Synthesis of Zn(II) Coordination Polymers with Fluorescent Sensing and Selective Dye Adsorption Properties |
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