A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone

Abstract A study of the oxidation mechanism of N-methyl pyrrolidinone ($ C_{5} $$ H_{9} $NO, NMP) initiated by hydroxyl radicals was made at EUPHORE at atmospheric pressure (1000 ± 10) mbar of air and ambient temperature (T = 300 ± 5 K). The main products were N-methyl succinimide (NMS) (52 ± 4)% an...
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Autor*in:	Solignac, G. [verfasserIn] Magneron, I. Mellouki, A. Muñoz, A. Reviejo, M. Martin Wirtz, K.

Format:	Artikel
Sprache:	Englisch

Erschienen:	2006

Schlagwörter:	-methyl pyrrolidinone -methyl succinimide -formyl pyrrolidinone hydroxyl radicals relative kinetic troposphere

Anmerkung:	© Springer Science+Business Media, Inc. 2006

Übergeordnetes Werk:	Enthalten in: Journal of atmospheric chemistry - Springer Netherlands, 1983, 54(2006), 2 vom: Juni, Seite 89-102
Übergeordnetes Werk:	volume:54 ; year:2006 ; number:2 ; month:06 ; pages:89-102

Links:	Volltext

DOI / URN:	10.1007/s10874-006-9017-y

Katalog-ID:	OLC2061777406

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520			\|a Abstract A study of the oxidation mechanism of N-methyl pyrrolidinone ($ C_{5} $$ H_{9} $NO, NMP) initiated by hydroxyl radicals was made at EUPHORE at atmospheric pressure (1000 ± 10) mbar of air and ambient temperature (T = 300 ± 5 K). The main products were N-methyl succinimide (NMS) (52 ± 4)% and N-formyl pyrrolidinone (FP) (23 ± 9)%. The relative rate technique was used to determine the rate constants of OH with NMP, NMS and FP, the measured values were (in units of $ cm^{3} $ molecule − 1 $ s^{− 1} $): $ k_{NMP} $ = (2.2 ± 0.4) × $ 10^{− 11} $, $ k_{NMS} $ = (1.4 ± 0.3) × $ 10^{− 12} $ and $ k_{FP} $ = (6 ± 1) × $ 10^{− 12} $. The results are presented and discussed in terms of the atmospheric impact.
650		4	\|a -methyl pyrrolidinone
650		4	\|a -methyl succinimide
650		4	\|a -formyl pyrrolidinone
650		4	\|a hydroxyl radicals
650		4	\|a relative kinetic
650		4	\|a troposphere
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700	1		\|a Mellouki, A. \|4 aut
700	1		\|a Muñoz, A. \|4 aut
700	1		\|a Reviejo, M. Martin \|4 aut
700	1		\|a Wirtz, K. \|4 aut
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allfields	10.1007/s10874-006-9017-y doi (DE-627)OLC2061777406 (DE-He213)s10874-006-9017-y-p DE-627 ger DE-627 rakwb eng 550 540 VZ Solignac, G. verfasserin aut A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone 2006 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, Inc. 2006 Abstract A study of the oxidation mechanism of N-methyl pyrrolidinone ($ C_{5} $$ H_{9} $NO, NMP) initiated by hydroxyl radicals was made at EUPHORE at atmospheric pressure (1000 ± 10) mbar of air and ambient temperature (T = 300 ± 5 K). The main products were N-methyl succinimide (NMS) (52 ± 4)% and N-formyl pyrrolidinone (FP) (23 ± 9)%. The relative rate technique was used to determine the rate constants of OH with NMP, NMS and FP, the measured values were (in units of $ cm^{3} $ molecule − 1 $ s^{− 1} $): $ k_{NMP} $ = (2.2 ± 0.4) × $ 10^{− 11} $, $ k_{NMS} $ = (1.4 ± 0.3) × $ 10^{− 12} $ and $ k_{FP} $ = (6 ± 1) × $ 10^{− 12} $. The results are presented and discussed in terms of the atmospheric impact. -methyl pyrrolidinone -methyl succinimide -formyl pyrrolidinone hydroxyl radicals relative kinetic troposphere Magneron, I. aut Mellouki, A. aut Muñoz, A. aut Reviejo, M. Martin aut Wirtz, K. aut Enthalten in Journal of atmospheric chemistry Springer Netherlands, 1983 54(2006), 2 vom: Juni, Seite 89-102 (DE-627)130612650 (DE-600)793876-7 (DE-576)016123026 0167-7764 nnns volume:54 year:2006 number:2 month:06 pages:89-102 https://doi.org/10.1007/s10874-006-9017-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO SSG-OPC-GEO GBV_ILN_24 GBV_ILN_40 GBV_ILN_47 GBV_ILN_62 GBV_ILN_70 GBV_ILN_130 GBV_ILN_601 GBV_ILN_602 GBV_ILN_2012 GBV_ILN_4012 GBV_ILN_4116 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 AR 54 2006 2 06 89-102
spelling	10.1007/s10874-006-9017-y doi (DE-627)OLC2061777406 (DE-He213)s10874-006-9017-y-p DE-627 ger DE-627 rakwb eng 550 540 VZ Solignac, G. verfasserin aut A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone 2006 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, Inc. 2006 Abstract A study of the oxidation mechanism of N-methyl pyrrolidinone ($ C_{5} $$ H_{9} $NO, NMP) initiated by hydroxyl radicals was made at EUPHORE at atmospheric pressure (1000 ± 10) mbar of air and ambient temperature (T = 300 ± 5 K). The main products were N-methyl succinimide (NMS) (52 ± 4)% and N-formyl pyrrolidinone (FP) (23 ± 9)%. The relative rate technique was used to determine the rate constants of OH with NMP, NMS and FP, the measured values were (in units of $ cm^{3} $ molecule − 1 $ s^{− 1} $): $ k_{NMP} $ = (2.2 ± 0.4) × $ 10^{− 11} $, $ k_{NMS} $ = (1.4 ± 0.3) × $ 10^{− 12} $ and $ k_{FP} $ = (6 ± 1) × $ 10^{− 12} $. The results are presented and discussed in terms of the atmospheric impact. -methyl pyrrolidinone -methyl succinimide -formyl pyrrolidinone hydroxyl radicals relative kinetic troposphere Magneron, I. aut Mellouki, A. aut Muñoz, A. aut Reviejo, M. Martin aut Wirtz, K. aut Enthalten in Journal of atmospheric chemistry Springer Netherlands, 1983 54(2006), 2 vom: Juni, Seite 89-102 (DE-627)130612650 (DE-600)793876-7 (DE-576)016123026 0167-7764 nnns volume:54 year:2006 number:2 month:06 pages:89-102 https://doi.org/10.1007/s10874-006-9017-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO SSG-OPC-GEO GBV_ILN_24 GBV_ILN_40 GBV_ILN_47 GBV_ILN_62 GBV_ILN_70 GBV_ILN_130 GBV_ILN_601 GBV_ILN_602 GBV_ILN_2012 GBV_ILN_4012 GBV_ILN_4116 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 AR 54 2006 2 06 89-102
allfields_unstemmed	10.1007/s10874-006-9017-y doi (DE-627)OLC2061777406 (DE-He213)s10874-006-9017-y-p DE-627 ger DE-627 rakwb eng 550 540 VZ Solignac, G. verfasserin aut A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone 2006 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, Inc. 2006 Abstract A study of the oxidation mechanism of N-methyl pyrrolidinone ($ C_{5} $$ H_{9} $NO, NMP) initiated by hydroxyl radicals was made at EUPHORE at atmospheric pressure (1000 ± 10) mbar of air and ambient temperature (T = 300 ± 5 K). The main products were N-methyl succinimide (NMS) (52 ± 4)% and N-formyl pyrrolidinone (FP) (23 ± 9)%. The relative rate technique was used to determine the rate constants of OH with NMP, NMS and FP, the measured values were (in units of $ cm^{3} $ molecule − 1 $ s^{− 1} $): $ k_{NMP} $ = (2.2 ± 0.4) × $ 10^{− 11} $, $ k_{NMS} $ = (1.4 ± 0.3) × $ 10^{− 12} $ and $ k_{FP} $ = (6 ± 1) × $ 10^{− 12} $. The results are presented and discussed in terms of the atmospheric impact. -methyl pyrrolidinone -methyl succinimide -formyl pyrrolidinone hydroxyl radicals relative kinetic troposphere Magneron, I. aut Mellouki, A. aut Muñoz, A. aut Reviejo, M. Martin aut Wirtz, K. aut Enthalten in Journal of atmospheric chemistry Springer Netherlands, 1983 54(2006), 2 vom: Juni, Seite 89-102 (DE-627)130612650 (DE-600)793876-7 (DE-576)016123026 0167-7764 nnns volume:54 year:2006 number:2 month:06 pages:89-102 https://doi.org/10.1007/s10874-006-9017-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO SSG-OPC-GEO GBV_ILN_24 GBV_ILN_40 GBV_ILN_47 GBV_ILN_62 GBV_ILN_70 GBV_ILN_130 GBV_ILN_601 GBV_ILN_602 GBV_ILN_2012 GBV_ILN_4012 GBV_ILN_4116 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 AR 54 2006 2 06 89-102
allfieldsGer	10.1007/s10874-006-9017-y doi (DE-627)OLC2061777406 (DE-He213)s10874-006-9017-y-p DE-627 ger DE-627 rakwb eng 550 540 VZ Solignac, G. verfasserin aut A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone 2006 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, Inc. 2006 Abstract A study of the oxidation mechanism of N-methyl pyrrolidinone ($ C_{5} $$ H_{9} $NO, NMP) initiated by hydroxyl radicals was made at EUPHORE at atmospheric pressure (1000 ± 10) mbar of air and ambient temperature (T = 300 ± 5 K). The main products were N-methyl succinimide (NMS) (52 ± 4)% and N-formyl pyrrolidinone (FP) (23 ± 9)%. The relative rate technique was used to determine the rate constants of OH with NMP, NMS and FP, the measured values were (in units of $ cm^{3} $ molecule − 1 $ s^{− 1} $): $ k_{NMP} $ = (2.2 ± 0.4) × $ 10^{− 11} $, $ k_{NMS} $ = (1.4 ± 0.3) × $ 10^{− 12} $ and $ k_{FP} $ = (6 ± 1) × $ 10^{− 12} $. The results are presented and discussed in terms of the atmospheric impact. -methyl pyrrolidinone -methyl succinimide -formyl pyrrolidinone hydroxyl radicals relative kinetic troposphere Magneron, I. aut Mellouki, A. aut Muñoz, A. aut Reviejo, M. Martin aut Wirtz, K. aut Enthalten in Journal of atmospheric chemistry Springer Netherlands, 1983 54(2006), 2 vom: Juni, Seite 89-102 (DE-627)130612650 (DE-600)793876-7 (DE-576)016123026 0167-7764 nnns volume:54 year:2006 number:2 month:06 pages:89-102 https://doi.org/10.1007/s10874-006-9017-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO SSG-OPC-GEO GBV_ILN_24 GBV_ILN_40 GBV_ILN_47 GBV_ILN_62 GBV_ILN_70 GBV_ILN_130 GBV_ILN_601 GBV_ILN_602 GBV_ILN_2012 GBV_ILN_4012 GBV_ILN_4116 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 AR 54 2006 2 06 89-102
allfieldsSound	10.1007/s10874-006-9017-y doi (DE-627)OLC2061777406 (DE-He213)s10874-006-9017-y-p DE-627 ger DE-627 rakwb eng 550 540 VZ Solignac, G. verfasserin aut A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone 2006 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, Inc. 2006 Abstract A study of the oxidation mechanism of N-methyl pyrrolidinone ($ C_{5} $$ H_{9} $NO, NMP) initiated by hydroxyl radicals was made at EUPHORE at atmospheric pressure (1000 ± 10) mbar of air and ambient temperature (T = 300 ± 5 K). The main products were N-methyl succinimide (NMS) (52 ± 4)% and N-formyl pyrrolidinone (FP) (23 ± 9)%. The relative rate technique was used to determine the rate constants of OH with NMP, NMS and FP, the measured values were (in units of $ cm^{3} $ molecule − 1 $ s^{− 1} $): $ k_{NMP} $ = (2.2 ± 0.4) × $ 10^{− 11} $, $ k_{NMS} $ = (1.4 ± 0.3) × $ 10^{− 12} $ and $ k_{FP} $ = (6 ± 1) × $ 10^{− 12} $. The results are presented and discussed in terms of the atmospheric impact. -methyl pyrrolidinone -methyl succinimide -formyl pyrrolidinone hydroxyl radicals relative kinetic troposphere Magneron, I. aut Mellouki, A. aut Muñoz, A. aut Reviejo, M. Martin aut Wirtz, K. aut Enthalten in Journal of atmospheric chemistry Springer Netherlands, 1983 54(2006), 2 vom: Juni, Seite 89-102 (DE-627)130612650 (DE-600)793876-7 (DE-576)016123026 0167-7764 nnns volume:54 year:2006 number:2 month:06 pages:89-102 https://doi.org/10.1007/s10874-006-9017-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO SSG-OPC-GEO GBV_ILN_24 GBV_ILN_40 GBV_ILN_47 GBV_ILN_62 GBV_ILN_70 GBV_ILN_130 GBV_ILN_601 GBV_ILN_602 GBV_ILN_2012 GBV_ILN_4012 GBV_ILN_4116 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 AR 54 2006 2 06 89-102
language	English
source	Enthalten in Journal of atmospheric chemistry 54(2006), 2 vom: Juni, Seite 89-102 volume:54 year:2006 number:2 month:06 pages:89-102
sourceStr	Enthalten in Journal of atmospheric chemistry 54(2006), 2 vom: Juni, Seite 89-102 volume:54 year:2006 number:2 month:06 pages:89-102
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author	Solignac, G.
spellingShingle	Solignac, G. ddc 550 misc -methyl pyrrolidinone misc -methyl succinimide misc -formyl pyrrolidinone misc hydroxyl radicals misc relative kinetic misc troposphere A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone
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topic_title	550 540 VZ A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone -methyl pyrrolidinone -methyl succinimide -formyl pyrrolidinone hydroxyl radicals relative kinetic troposphere
topic	ddc 550 misc -methyl pyrrolidinone misc -methyl succinimide misc -formyl pyrrolidinone misc hydroxyl radicals misc relative kinetic misc troposphere
topic_unstemmed	ddc 550 misc -methyl pyrrolidinone misc -methyl succinimide misc -formyl pyrrolidinone misc hydroxyl radicals misc relative kinetic misc troposphere
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title	A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone
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title_full	A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone
author_sort	Solignac, G.
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author_browse	Solignac, G. Magneron, I. Mellouki, A. Muñoz, A. Reviejo, M. Martin Wirtz, K.
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title_sort	a study of the reaction of oh radicals with n-methyl pyrrolidinone,n-methyl succinimide and n-formyl pyrrolidinone
title_auth	A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone
abstract	Abstract A study of the oxidation mechanism of N-methyl pyrrolidinone ($ C_{5} $$ H_{9} $NO, NMP) initiated by hydroxyl radicals was made at EUPHORE at atmospheric pressure (1000 ± 10) mbar of air and ambient temperature (T = 300 ± 5 K). The main products were N-methyl succinimide (NMS) (52 ± 4)% and N-formyl pyrrolidinone (FP) (23 ± 9)%. The relative rate technique was used to determine the rate constants of OH with NMP, NMS and FP, the measured values were (in units of $ cm^{3} $ molecule − 1 $ s^{− 1} $): $ k_{NMP} $ = (2.2 ± 0.4) × $ 10^{− 11} $, $ k_{NMS} $ = (1.4 ± 0.3) × $ 10^{− 12} $ and $ k_{FP} $ = (6 ± 1) × $ 10^{− 12} $. The results are presented and discussed in terms of the atmospheric impact. © Springer Science+Business Media, Inc. 2006
abstractGer	Abstract A study of the oxidation mechanism of N-methyl pyrrolidinone ($ C_{5} $$ H_{9} $NO, NMP) initiated by hydroxyl radicals was made at EUPHORE at atmospheric pressure (1000 ± 10) mbar of air and ambient temperature (T = 300 ± 5 K). The main products were N-methyl succinimide (NMS) (52 ± 4)% and N-formyl pyrrolidinone (FP) (23 ± 9)%. The relative rate technique was used to determine the rate constants of OH with NMP, NMS and FP, the measured values were (in units of $ cm^{3} $ molecule − 1 $ s^{− 1} $): $ k_{NMP} $ = (2.2 ± 0.4) × $ 10^{− 11} $, $ k_{NMS} $ = (1.4 ± 0.3) × $ 10^{− 12} $ and $ k_{FP} $ = (6 ± 1) × $ 10^{− 12} $. The results are presented and discussed in terms of the atmospheric impact. © Springer Science+Business Media, Inc. 2006
abstract_unstemmed	Abstract A study of the oxidation mechanism of N-methyl pyrrolidinone ($ C_{5} $$ H_{9} $NO, NMP) initiated by hydroxyl radicals was made at EUPHORE at atmospheric pressure (1000 ± 10) mbar of air and ambient temperature (T = 300 ± 5 K). The main products were N-methyl succinimide (NMS) (52 ± 4)% and N-formyl pyrrolidinone (FP) (23 ± 9)%. The relative rate technique was used to determine the rate constants of OH with NMP, NMS and FP, the measured values were (in units of $ cm^{3} $ molecule − 1 $ s^{− 1} $): $ k_{NMP} $ = (2.2 ± 0.4) × $ 10^{− 11} $, $ k_{NMS} $ = (1.4 ± 0.3) × $ 10^{− 12} $ and $ k_{FP} $ = (6 ± 1) × $ 10^{− 12} $. The results are presented and discussed in terms of the atmospheric impact. © Springer Science+Business Media, Inc. 2006
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title_short	A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone
url	https://doi.org/10.1007/s10874-006-9017-y
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