OH point defects in olivine from Pakistan
Abstract The infrared (IR) spectra of gem-quality olivine crystals from Pakistan, formed in serpentinised dunitic rocks, are characterised by strongly pleochroic absorption bands at 3,613, 3,597, 3,580 and 3,566 $ cm^{−1} $. These bands are assigned to O-H stretching vibrations of OH point defects c...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Gose, Jürgen [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2009 |
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| Schlagwörter: |
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| Systematik: |
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| Anmerkung: |
© Springer-Verlag 2009 |
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| Übergeordnetes Werk: |
Enthalten in: Mineralogy and petrology - Springer Vienna, 1987, 99(2009), 1-2 vom: 08. Nov., Seite 105-111 |
|---|---|
| Übergeordnetes Werk: |
volume:99 ; year:2009 ; number:1-2 ; day:08 ; month:11 ; pages:105-111 |
| Links: |
|---|
| DOI / URN: |
10.1007/s00710-009-0095-9 |
|---|
| Katalog-ID: |
OLC2062486375 |
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| 520 | |a Abstract The infrared (IR) spectra of gem-quality olivine crystals from Pakistan, formed in serpentinised dunitic rocks, are characterised by strongly pleochroic absorption bands at 3,613, 3,597, 3,580 and 3,566 $ cm^{−1} $. These bands are assigned to O-H stretching vibrations of OH point defects corresponding to $ H_{2} $O concentrations of about 35 wt ppm. Unlike other olivine spectra, the dominating bands are strongly polarised parallel to the b-axis. The unusual spectra type, excludes the presence of planar defects. This finding is supported by transmission electron microscopy. The 3,613 $ cm^{−1} $ band is related to vacant Si sites, the slightly lower energetic bands preferentially to vacant M2 sites. The exclusive presence of these bands is not only a characteristic feature of olivines treated under high P,T conditions equivalent to mantle environment, the presence of these bands in untreated natural olivine also indicates formation conditions equivalent to crustal rocks. | ||
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| 700 | 1 | |a Beran, Anton |4 aut | |
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10.1007/s00710-009-0095-9 doi (DE-627)OLC2062486375 (DE-He213)s00710-009-0095-9-p DE-627 ger DE-627 rakwb eng 550 VZ 13 ssgn TE 1000 VZ rvk Gose, Jürgen verfasserin aut OH point defects in olivine from Pakistan 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 2009 Abstract The infrared (IR) spectra of gem-quality olivine crystals from Pakistan, formed in serpentinised dunitic rocks, are characterised by strongly pleochroic absorption bands at 3,613, 3,597, 3,580 and 3,566 $ cm^{−1} $. These bands are assigned to O-H stretching vibrations of OH point defects corresponding to $ H_{2} $O concentrations of about 35 wt ppm. Unlike other olivine spectra, the dominating bands are strongly polarised parallel to the b-axis. The unusual spectra type, excludes the presence of planar defects. This finding is supported by transmission electron microscopy. The 3,613 $ cm^{−1} $ band is related to vacant Si sites, the slightly lower energetic bands preferentially to vacant M2 sites. The exclusive presence of these bands is not only a characteristic feature of olivines treated under high P,T conditions equivalent to mantle environment, the presence of these bands in untreated natural olivine also indicates formation conditions equivalent to crustal rocks. Olivine Mantle Olivine Dipole Direction Natural Olivine Forsterite Crystal Schmädicke, Esther aut Markowitz, Margit aut Beran, Anton aut Enthalten in Mineralogy and petrology Springer Vienna, 1987 99(2009), 1-2 vom: 08. Nov., Seite 105-111 (DE-627)129383856 (DE-600)166036-6 (DE-576)014770881 0930-0708 nnns volume:99 year:2009 number:1-2 day:08 month:11 pages:105-111 https://doi.org/10.1007/s00710-009-0095-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_31 GBV_ILN_40 GBV_ILN_70 GBV_ILN_2010 GBV_ILN_2015 GBV_ILN_2027 GBV_ILN_2399 GBV_ILN_4306 TE 1000 AR 99 2009 1-2 08 11 105-111 |
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10.1007/s00710-009-0095-9 doi (DE-627)OLC2062486375 (DE-He213)s00710-009-0095-9-p DE-627 ger DE-627 rakwb eng 550 VZ 13 ssgn TE 1000 VZ rvk Gose, Jürgen verfasserin aut OH point defects in olivine from Pakistan 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 2009 Abstract The infrared (IR) spectra of gem-quality olivine crystals from Pakistan, formed in serpentinised dunitic rocks, are characterised by strongly pleochroic absorption bands at 3,613, 3,597, 3,580 and 3,566 $ cm^{−1} $. These bands are assigned to O-H stretching vibrations of OH point defects corresponding to $ H_{2} $O concentrations of about 35 wt ppm. Unlike other olivine spectra, the dominating bands are strongly polarised parallel to the b-axis. The unusual spectra type, excludes the presence of planar defects. This finding is supported by transmission electron microscopy. The 3,613 $ cm^{−1} $ band is related to vacant Si sites, the slightly lower energetic bands preferentially to vacant M2 sites. The exclusive presence of these bands is not only a characteristic feature of olivines treated under high P,T conditions equivalent to mantle environment, the presence of these bands in untreated natural olivine also indicates formation conditions equivalent to crustal rocks. Olivine Mantle Olivine Dipole Direction Natural Olivine Forsterite Crystal Schmädicke, Esther aut Markowitz, Margit aut Beran, Anton aut Enthalten in Mineralogy and petrology Springer Vienna, 1987 99(2009), 1-2 vom: 08. Nov., Seite 105-111 (DE-627)129383856 (DE-600)166036-6 (DE-576)014770881 0930-0708 nnns volume:99 year:2009 number:1-2 day:08 month:11 pages:105-111 https://doi.org/10.1007/s00710-009-0095-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_31 GBV_ILN_40 GBV_ILN_70 GBV_ILN_2010 GBV_ILN_2015 GBV_ILN_2027 GBV_ILN_2399 GBV_ILN_4306 TE 1000 AR 99 2009 1-2 08 11 105-111 |
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10.1007/s00710-009-0095-9 doi (DE-627)OLC2062486375 (DE-He213)s00710-009-0095-9-p DE-627 ger DE-627 rakwb eng 550 VZ 13 ssgn TE 1000 VZ rvk Gose, Jürgen verfasserin aut OH point defects in olivine from Pakistan 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 2009 Abstract The infrared (IR) spectra of gem-quality olivine crystals from Pakistan, formed in serpentinised dunitic rocks, are characterised by strongly pleochroic absorption bands at 3,613, 3,597, 3,580 and 3,566 $ cm^{−1} $. These bands are assigned to O-H stretching vibrations of OH point defects corresponding to $ H_{2} $O concentrations of about 35 wt ppm. Unlike other olivine spectra, the dominating bands are strongly polarised parallel to the b-axis. The unusual spectra type, excludes the presence of planar defects. This finding is supported by transmission electron microscopy. The 3,613 $ cm^{−1} $ band is related to vacant Si sites, the slightly lower energetic bands preferentially to vacant M2 sites. The exclusive presence of these bands is not only a characteristic feature of olivines treated under high P,T conditions equivalent to mantle environment, the presence of these bands in untreated natural olivine also indicates formation conditions equivalent to crustal rocks. Olivine Mantle Olivine Dipole Direction Natural Olivine Forsterite Crystal Schmädicke, Esther aut Markowitz, Margit aut Beran, Anton aut Enthalten in Mineralogy and petrology Springer Vienna, 1987 99(2009), 1-2 vom: 08. Nov., Seite 105-111 (DE-627)129383856 (DE-600)166036-6 (DE-576)014770881 0930-0708 nnns volume:99 year:2009 number:1-2 day:08 month:11 pages:105-111 https://doi.org/10.1007/s00710-009-0095-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_31 GBV_ILN_40 GBV_ILN_70 GBV_ILN_2010 GBV_ILN_2015 GBV_ILN_2027 GBV_ILN_2399 GBV_ILN_4306 TE 1000 AR 99 2009 1-2 08 11 105-111 |
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10.1007/s00710-009-0095-9 doi (DE-627)OLC2062486375 (DE-He213)s00710-009-0095-9-p DE-627 ger DE-627 rakwb eng 550 VZ 13 ssgn TE 1000 VZ rvk Gose, Jürgen verfasserin aut OH point defects in olivine from Pakistan 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 2009 Abstract The infrared (IR) spectra of gem-quality olivine crystals from Pakistan, formed in serpentinised dunitic rocks, are characterised by strongly pleochroic absorption bands at 3,613, 3,597, 3,580 and 3,566 $ cm^{−1} $. These bands are assigned to O-H stretching vibrations of OH point defects corresponding to $ H_{2} $O concentrations of about 35 wt ppm. Unlike other olivine spectra, the dominating bands are strongly polarised parallel to the b-axis. The unusual spectra type, excludes the presence of planar defects. This finding is supported by transmission electron microscopy. The 3,613 $ cm^{−1} $ band is related to vacant Si sites, the slightly lower energetic bands preferentially to vacant M2 sites. The exclusive presence of these bands is not only a characteristic feature of olivines treated under high P,T conditions equivalent to mantle environment, the presence of these bands in untreated natural olivine also indicates formation conditions equivalent to crustal rocks. Olivine Mantle Olivine Dipole Direction Natural Olivine Forsterite Crystal Schmädicke, Esther aut Markowitz, Margit aut Beran, Anton aut Enthalten in Mineralogy and petrology Springer Vienna, 1987 99(2009), 1-2 vom: 08. Nov., Seite 105-111 (DE-627)129383856 (DE-600)166036-6 (DE-576)014770881 0930-0708 nnns volume:99 year:2009 number:1-2 day:08 month:11 pages:105-111 https://doi.org/10.1007/s00710-009-0095-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_31 GBV_ILN_40 GBV_ILN_70 GBV_ILN_2010 GBV_ILN_2015 GBV_ILN_2027 GBV_ILN_2399 GBV_ILN_4306 TE 1000 AR 99 2009 1-2 08 11 105-111 |
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Gose, Jürgen Schmädicke, Esther Markowitz, Margit Beran, Anton |
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Gose, Jürgen |
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10.1007/s00710-009-0095-9 |
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550 |
| title_sort |
oh point defects in olivine from pakistan |
| title_auth |
OH point defects in olivine from Pakistan |
| abstract |
Abstract The infrared (IR) spectra of gem-quality olivine crystals from Pakistan, formed in serpentinised dunitic rocks, are characterised by strongly pleochroic absorption bands at 3,613, 3,597, 3,580 and 3,566 $ cm^{−1} $. These bands are assigned to O-H stretching vibrations of OH point defects corresponding to $ H_{2} $O concentrations of about 35 wt ppm. Unlike other olivine spectra, the dominating bands are strongly polarised parallel to the b-axis. The unusual spectra type, excludes the presence of planar defects. This finding is supported by transmission electron microscopy. The 3,613 $ cm^{−1} $ band is related to vacant Si sites, the slightly lower energetic bands preferentially to vacant M2 sites. The exclusive presence of these bands is not only a characteristic feature of olivines treated under high P,T conditions equivalent to mantle environment, the presence of these bands in untreated natural olivine also indicates formation conditions equivalent to crustal rocks. © Springer-Verlag 2009 |
| abstractGer |
Abstract The infrared (IR) spectra of gem-quality olivine crystals from Pakistan, formed in serpentinised dunitic rocks, are characterised by strongly pleochroic absorption bands at 3,613, 3,597, 3,580 and 3,566 $ cm^{−1} $. These bands are assigned to O-H stretching vibrations of OH point defects corresponding to $ H_{2} $O concentrations of about 35 wt ppm. Unlike other olivine spectra, the dominating bands are strongly polarised parallel to the b-axis. The unusual spectra type, excludes the presence of planar defects. This finding is supported by transmission electron microscopy. The 3,613 $ cm^{−1} $ band is related to vacant Si sites, the slightly lower energetic bands preferentially to vacant M2 sites. The exclusive presence of these bands is not only a characteristic feature of olivines treated under high P,T conditions equivalent to mantle environment, the presence of these bands in untreated natural olivine also indicates formation conditions equivalent to crustal rocks. © Springer-Verlag 2009 |
| abstract_unstemmed |
Abstract The infrared (IR) spectra of gem-quality olivine crystals from Pakistan, formed in serpentinised dunitic rocks, are characterised by strongly pleochroic absorption bands at 3,613, 3,597, 3,580 and 3,566 $ cm^{−1} $. These bands are assigned to O-H stretching vibrations of OH point defects corresponding to $ H_{2} $O concentrations of about 35 wt ppm. Unlike other olivine spectra, the dominating bands are strongly polarised parallel to the b-axis. The unusual spectra type, excludes the presence of planar defects. This finding is supported by transmission electron microscopy. The 3,613 $ cm^{−1} $ band is related to vacant Si sites, the slightly lower energetic bands preferentially to vacant M2 sites. The exclusive presence of these bands is not only a characteristic feature of olivines treated under high P,T conditions equivalent to mantle environment, the presence of these bands in untreated natural olivine also indicates formation conditions equivalent to crustal rocks. © Springer-Verlag 2009 |
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OH point defects in olivine from Pakistan |
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