Fluid-driven destabilization of REE-bearing accessory minerals in the granitic orthogneisses of North Veporic basement (Western Carpathians, Slovakia)
Abstract A variety of rare earth elements-bearing (REE) accessory mineral breakdowns were identified in granitic orthogneisses from the pre-Alpine basement in the Veporic Unit, Central Western Carpathians, Slovakia. The Ordovician granitic rocks were subjected to Variscan metamorphic-anatectic overp...
Ausführliche Beschreibung
Autor*in: |
Ondrejka, M. [verfasserIn] |
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Englisch |
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2016 |
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Anmerkung: |
© Springer-Verlag Wien 2016 |
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Übergeordnetes Werk: |
Enthalten in: Mineralogy and petrology - Springer Vienna, 1987, 110(2016), 5 vom: 12. Feb., Seite 561-580 |
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Übergeordnetes Werk: |
volume:110 ; year:2016 ; number:5 ; day:12 ; month:02 ; pages:561-580 |
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DOI / URN: |
10.1007/s00710-016-0432-8 |
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Katalog-ID: |
OLC2062489587 |
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520 | |a Abstract A variety of rare earth elements-bearing (REE) accessory mineral breakdowns were identified in granitic orthogneisses from the pre-Alpine basement in the Veporic Unit, Central Western Carpathians, Slovakia. The Ordovician granitic rocks were subjected to Variscan metamorphic-anatectic overprint in amphibolite facies. Chemical U-Th-Pb dating of monazite-(Ce) and xenotime-(Y) reveal their primary magmatic Lower to Middle Ordovician age (monazite: 472 ± 4 to 468 ± 6 Ma and xenotime: 471 ± 13 Ma) and/or metamorphic-anatectic Variscan (Carboniferous, Visean) age (monazite: 345 ± 3 Ma). Younger fluid-rock interactions caused breakdown of primary magmatic and/or metamorphic-anatectic monazite-(Ce), xenotime-(Y), fluorapatite and allanite-(Ce). Fluid-induced breakdown of xenotime-(Y) produced numerous tiny uraninite inclusions within the altered xenotime-(Y) domains. The monazite-(Ce) breakdown produced secondary egg-shaped coronal structures of different stages with well-developed concentric mineral zones. Secondary sulphatian monazite-(Ce) (up to 0.15 apfu S) occasionally formed along fluorapatite fissures. Localized fluorapatite and monazite-(Ce) recrystallization resulted in a very fine-grained, non-stoichiometric mixture of REE-Y-Fe-Th-Ca-P-Si phases. Finally, allanite-(Ce) decomposed to secondary REE carbonate minerals (members of the bastnäsite and synchysite groups) and calcite in some places. Although the xenotime alteration and formation of uraninite inclusions is believed to be the result of dissolution-reprecipitation between early magmatic xenotime and late-magmatic granitic fluids, the monazite, apatite and allanite breakdowns were driven by metamorphic hydrothermal fluids. While earlier impact of post-magmatic fluids originated probably from Permian acidic volcanic and microgranitic veins crosscutting the orthogneisses, another fluid-rock interaction event most likely occurred during Late Cretaceous metamorphism in the Veporic basement and covering rocks. This stage indicates carbon-bearing fluids precipitating the carbonate minerals. | ||
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700 | 1 | |a Konečný, P. |4 aut | |
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10.1007/s00710-016-0432-8 doi (DE-627)OLC2062489587 (DE-He213)s00710-016-0432-8-p DE-627 ger DE-627 rakwb eng 550 VZ 13 ssgn TE 1000 VZ rvk Ondrejka, M. verfasserin aut Fluid-driven destabilization of REE-bearing accessory minerals in the granitic orthogneisses of North Veporic basement (Western Carpathians, Slovakia) 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag Wien 2016 Abstract A variety of rare earth elements-bearing (REE) accessory mineral breakdowns were identified in granitic orthogneisses from the pre-Alpine basement in the Veporic Unit, Central Western Carpathians, Slovakia. The Ordovician granitic rocks were subjected to Variscan metamorphic-anatectic overprint in amphibolite facies. Chemical U-Th-Pb dating of monazite-(Ce) and xenotime-(Y) reveal their primary magmatic Lower to Middle Ordovician age (monazite: 472 ± 4 to 468 ± 6 Ma and xenotime: 471 ± 13 Ma) and/or metamorphic-anatectic Variscan (Carboniferous, Visean) age (monazite: 345 ± 3 Ma). Younger fluid-rock interactions caused breakdown of primary magmatic and/or metamorphic-anatectic monazite-(Ce), xenotime-(Y), fluorapatite and allanite-(Ce). Fluid-induced breakdown of xenotime-(Y) produced numerous tiny uraninite inclusions within the altered xenotime-(Y) domains. The monazite-(Ce) breakdown produced secondary egg-shaped coronal structures of different stages with well-developed concentric mineral zones. Secondary sulphatian monazite-(Ce) (up to 0.15 apfu S) occasionally formed along fluorapatite fissures. Localized fluorapatite and monazite-(Ce) recrystallization resulted in a very fine-grained, non-stoichiometric mixture of REE-Y-Fe-Th-Ca-P-Si phases. Finally, allanite-(Ce) decomposed to secondary REE carbonate minerals (members of the bastnäsite and synchysite groups) and calcite in some places. Although the xenotime alteration and formation of uraninite inclusions is believed to be the result of dissolution-reprecipitation between early magmatic xenotime and late-magmatic granitic fluids, the monazite, apatite and allanite breakdowns were driven by metamorphic hydrothermal fluids. While earlier impact of post-magmatic fluids originated probably from Permian acidic volcanic and microgranitic veins crosscutting the orthogneisses, another fluid-rock interaction event most likely occurred during Late Cretaceous metamorphism in the Veporic basement and covering rocks. This stage indicates carbon-bearing fluids precipitating the carbonate minerals. Apatite ThO2 Fluorapatite Light Rare Earth Element Heavy Rare Earth Element Putiš, M. aut Uher, P. aut Schmiedt, I. aut Pukančík, L. aut Konečný, P. aut Enthalten in Mineralogy and petrology Springer Vienna, 1987 110(2016), 5 vom: 12. Feb., Seite 561-580 (DE-627)129383856 (DE-600)166036-6 (DE-576)014770881 0930-0708 nnns volume:110 year:2016 number:5 day:12 month:02 pages:561-580 https://doi.org/10.1007/s00710-016-0432-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2399 GBV_ILN_4306 TE 1000 AR 110 2016 5 12 02 561-580 |
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10.1007/s00710-016-0432-8 doi (DE-627)OLC2062489587 (DE-He213)s00710-016-0432-8-p DE-627 ger DE-627 rakwb eng 550 VZ 13 ssgn TE 1000 VZ rvk Ondrejka, M. verfasserin aut Fluid-driven destabilization of REE-bearing accessory minerals in the granitic orthogneisses of North Veporic basement (Western Carpathians, Slovakia) 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag Wien 2016 Abstract A variety of rare earth elements-bearing (REE) accessory mineral breakdowns were identified in granitic orthogneisses from the pre-Alpine basement in the Veporic Unit, Central Western Carpathians, Slovakia. The Ordovician granitic rocks were subjected to Variscan metamorphic-anatectic overprint in amphibolite facies. Chemical U-Th-Pb dating of monazite-(Ce) and xenotime-(Y) reveal their primary magmatic Lower to Middle Ordovician age (monazite: 472 ± 4 to 468 ± 6 Ma and xenotime: 471 ± 13 Ma) and/or metamorphic-anatectic Variscan (Carboniferous, Visean) age (monazite: 345 ± 3 Ma). Younger fluid-rock interactions caused breakdown of primary magmatic and/or metamorphic-anatectic monazite-(Ce), xenotime-(Y), fluorapatite and allanite-(Ce). Fluid-induced breakdown of xenotime-(Y) produced numerous tiny uraninite inclusions within the altered xenotime-(Y) domains. The monazite-(Ce) breakdown produced secondary egg-shaped coronal structures of different stages with well-developed concentric mineral zones. Secondary sulphatian monazite-(Ce) (up to 0.15 apfu S) occasionally formed along fluorapatite fissures. Localized fluorapatite and monazite-(Ce) recrystallization resulted in a very fine-grained, non-stoichiometric mixture of REE-Y-Fe-Th-Ca-P-Si phases. Finally, allanite-(Ce) decomposed to secondary REE carbonate minerals (members of the bastnäsite and synchysite groups) and calcite in some places. Although the xenotime alteration and formation of uraninite inclusions is believed to be the result of dissolution-reprecipitation between early magmatic xenotime and late-magmatic granitic fluids, the monazite, apatite and allanite breakdowns were driven by metamorphic hydrothermal fluids. While earlier impact of post-magmatic fluids originated probably from Permian acidic volcanic and microgranitic veins crosscutting the orthogneisses, another fluid-rock interaction event most likely occurred during Late Cretaceous metamorphism in the Veporic basement and covering rocks. This stage indicates carbon-bearing fluids precipitating the carbonate minerals. Apatite ThO2 Fluorapatite Light Rare Earth Element Heavy Rare Earth Element Putiš, M. aut Uher, P. aut Schmiedt, I. aut Pukančík, L. aut Konečný, P. aut Enthalten in Mineralogy and petrology Springer Vienna, 1987 110(2016), 5 vom: 12. Feb., Seite 561-580 (DE-627)129383856 (DE-600)166036-6 (DE-576)014770881 0930-0708 nnns volume:110 year:2016 number:5 day:12 month:02 pages:561-580 https://doi.org/10.1007/s00710-016-0432-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2399 GBV_ILN_4306 TE 1000 AR 110 2016 5 12 02 561-580 |
allfields_unstemmed |
10.1007/s00710-016-0432-8 doi (DE-627)OLC2062489587 (DE-He213)s00710-016-0432-8-p DE-627 ger DE-627 rakwb eng 550 VZ 13 ssgn TE 1000 VZ rvk Ondrejka, M. verfasserin aut Fluid-driven destabilization of REE-bearing accessory minerals in the granitic orthogneisses of North Veporic basement (Western Carpathians, Slovakia) 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag Wien 2016 Abstract A variety of rare earth elements-bearing (REE) accessory mineral breakdowns were identified in granitic orthogneisses from the pre-Alpine basement in the Veporic Unit, Central Western Carpathians, Slovakia. The Ordovician granitic rocks were subjected to Variscan metamorphic-anatectic overprint in amphibolite facies. Chemical U-Th-Pb dating of monazite-(Ce) and xenotime-(Y) reveal their primary magmatic Lower to Middle Ordovician age (monazite: 472 ± 4 to 468 ± 6 Ma and xenotime: 471 ± 13 Ma) and/or metamorphic-anatectic Variscan (Carboniferous, Visean) age (monazite: 345 ± 3 Ma). Younger fluid-rock interactions caused breakdown of primary magmatic and/or metamorphic-anatectic monazite-(Ce), xenotime-(Y), fluorapatite and allanite-(Ce). Fluid-induced breakdown of xenotime-(Y) produced numerous tiny uraninite inclusions within the altered xenotime-(Y) domains. The monazite-(Ce) breakdown produced secondary egg-shaped coronal structures of different stages with well-developed concentric mineral zones. Secondary sulphatian monazite-(Ce) (up to 0.15 apfu S) occasionally formed along fluorapatite fissures. Localized fluorapatite and monazite-(Ce) recrystallization resulted in a very fine-grained, non-stoichiometric mixture of REE-Y-Fe-Th-Ca-P-Si phases. Finally, allanite-(Ce) decomposed to secondary REE carbonate minerals (members of the bastnäsite and synchysite groups) and calcite in some places. Although the xenotime alteration and formation of uraninite inclusions is believed to be the result of dissolution-reprecipitation between early magmatic xenotime and late-magmatic granitic fluids, the monazite, apatite and allanite breakdowns were driven by metamorphic hydrothermal fluids. While earlier impact of post-magmatic fluids originated probably from Permian acidic volcanic and microgranitic veins crosscutting the orthogneisses, another fluid-rock interaction event most likely occurred during Late Cretaceous metamorphism in the Veporic basement and covering rocks. This stage indicates carbon-bearing fluids precipitating the carbonate minerals. Apatite ThO2 Fluorapatite Light Rare Earth Element Heavy Rare Earth Element Putiš, M. aut Uher, P. aut Schmiedt, I. aut Pukančík, L. aut Konečný, P. aut Enthalten in Mineralogy and petrology Springer Vienna, 1987 110(2016), 5 vom: 12. Feb., Seite 561-580 (DE-627)129383856 (DE-600)166036-6 (DE-576)014770881 0930-0708 nnns volume:110 year:2016 number:5 day:12 month:02 pages:561-580 https://doi.org/10.1007/s00710-016-0432-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2399 GBV_ILN_4306 TE 1000 AR 110 2016 5 12 02 561-580 |
allfieldsGer |
10.1007/s00710-016-0432-8 doi (DE-627)OLC2062489587 (DE-He213)s00710-016-0432-8-p DE-627 ger DE-627 rakwb eng 550 VZ 13 ssgn TE 1000 VZ rvk Ondrejka, M. verfasserin aut Fluid-driven destabilization of REE-bearing accessory minerals in the granitic orthogneisses of North Veporic basement (Western Carpathians, Slovakia) 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag Wien 2016 Abstract A variety of rare earth elements-bearing (REE) accessory mineral breakdowns were identified in granitic orthogneisses from the pre-Alpine basement in the Veporic Unit, Central Western Carpathians, Slovakia. The Ordovician granitic rocks were subjected to Variscan metamorphic-anatectic overprint in amphibolite facies. Chemical U-Th-Pb dating of monazite-(Ce) and xenotime-(Y) reveal their primary magmatic Lower to Middle Ordovician age (monazite: 472 ± 4 to 468 ± 6 Ma and xenotime: 471 ± 13 Ma) and/or metamorphic-anatectic Variscan (Carboniferous, Visean) age (monazite: 345 ± 3 Ma). Younger fluid-rock interactions caused breakdown of primary magmatic and/or metamorphic-anatectic monazite-(Ce), xenotime-(Y), fluorapatite and allanite-(Ce). Fluid-induced breakdown of xenotime-(Y) produced numerous tiny uraninite inclusions within the altered xenotime-(Y) domains. The monazite-(Ce) breakdown produced secondary egg-shaped coronal structures of different stages with well-developed concentric mineral zones. Secondary sulphatian monazite-(Ce) (up to 0.15 apfu S) occasionally formed along fluorapatite fissures. Localized fluorapatite and monazite-(Ce) recrystallization resulted in a very fine-grained, non-stoichiometric mixture of REE-Y-Fe-Th-Ca-P-Si phases. Finally, allanite-(Ce) decomposed to secondary REE carbonate minerals (members of the bastnäsite and synchysite groups) and calcite in some places. Although the xenotime alteration and formation of uraninite inclusions is believed to be the result of dissolution-reprecipitation between early magmatic xenotime and late-magmatic granitic fluids, the monazite, apatite and allanite breakdowns were driven by metamorphic hydrothermal fluids. While earlier impact of post-magmatic fluids originated probably from Permian acidic volcanic and microgranitic veins crosscutting the orthogneisses, another fluid-rock interaction event most likely occurred during Late Cretaceous metamorphism in the Veporic basement and covering rocks. This stage indicates carbon-bearing fluids precipitating the carbonate minerals. Apatite ThO2 Fluorapatite Light Rare Earth Element Heavy Rare Earth Element Putiš, M. aut Uher, P. aut Schmiedt, I. aut Pukančík, L. aut Konečný, P. aut Enthalten in Mineralogy and petrology Springer Vienna, 1987 110(2016), 5 vom: 12. Feb., Seite 561-580 (DE-627)129383856 (DE-600)166036-6 (DE-576)014770881 0930-0708 nnns volume:110 year:2016 number:5 day:12 month:02 pages:561-580 https://doi.org/10.1007/s00710-016-0432-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2399 GBV_ILN_4306 TE 1000 AR 110 2016 5 12 02 561-580 |
allfieldsSound |
10.1007/s00710-016-0432-8 doi (DE-627)OLC2062489587 (DE-He213)s00710-016-0432-8-p DE-627 ger DE-627 rakwb eng 550 VZ 13 ssgn TE 1000 VZ rvk Ondrejka, M. verfasserin aut Fluid-driven destabilization of REE-bearing accessory minerals in the granitic orthogneisses of North Veporic basement (Western Carpathians, Slovakia) 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag Wien 2016 Abstract A variety of rare earth elements-bearing (REE) accessory mineral breakdowns were identified in granitic orthogneisses from the pre-Alpine basement in the Veporic Unit, Central Western Carpathians, Slovakia. The Ordovician granitic rocks were subjected to Variscan metamorphic-anatectic overprint in amphibolite facies. Chemical U-Th-Pb dating of monazite-(Ce) and xenotime-(Y) reveal their primary magmatic Lower to Middle Ordovician age (monazite: 472 ± 4 to 468 ± 6 Ma and xenotime: 471 ± 13 Ma) and/or metamorphic-anatectic Variscan (Carboniferous, Visean) age (monazite: 345 ± 3 Ma). Younger fluid-rock interactions caused breakdown of primary magmatic and/or metamorphic-anatectic monazite-(Ce), xenotime-(Y), fluorapatite and allanite-(Ce). Fluid-induced breakdown of xenotime-(Y) produced numerous tiny uraninite inclusions within the altered xenotime-(Y) domains. The monazite-(Ce) breakdown produced secondary egg-shaped coronal structures of different stages with well-developed concentric mineral zones. Secondary sulphatian monazite-(Ce) (up to 0.15 apfu S) occasionally formed along fluorapatite fissures. Localized fluorapatite and monazite-(Ce) recrystallization resulted in a very fine-grained, non-stoichiometric mixture of REE-Y-Fe-Th-Ca-P-Si phases. Finally, allanite-(Ce) decomposed to secondary REE carbonate minerals (members of the bastnäsite and synchysite groups) and calcite in some places. Although the xenotime alteration and formation of uraninite inclusions is believed to be the result of dissolution-reprecipitation between early magmatic xenotime and late-magmatic granitic fluids, the monazite, apatite and allanite breakdowns were driven by metamorphic hydrothermal fluids. While earlier impact of post-magmatic fluids originated probably from Permian acidic volcanic and microgranitic veins crosscutting the orthogneisses, another fluid-rock interaction event most likely occurred during Late Cretaceous metamorphism in the Veporic basement and covering rocks. This stage indicates carbon-bearing fluids precipitating the carbonate minerals. Apatite ThO2 Fluorapatite Light Rare Earth Element Heavy Rare Earth Element Putiš, M. aut Uher, P. aut Schmiedt, I. aut Pukančík, L. aut Konečný, P. aut Enthalten in Mineralogy and petrology Springer Vienna, 1987 110(2016), 5 vom: 12. Feb., Seite 561-580 (DE-627)129383856 (DE-600)166036-6 (DE-576)014770881 0930-0708 nnns volume:110 year:2016 number:5 day:12 month:02 pages:561-580 https://doi.org/10.1007/s00710-016-0432-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2399 GBV_ILN_4306 TE 1000 AR 110 2016 5 12 02 561-580 |
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Enthalten in Mineralogy and petrology 110(2016), 5 vom: 12. Feb., Seite 561-580 volume:110 year:2016 number:5 day:12 month:02 pages:561-580 |
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Fluid-driven destabilization of REE-bearing accessory minerals in the granitic orthogneisses of North Veporic basement (Western Carpathians, Slovakia) |
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Fluid-driven destabilization of REE-bearing accessory minerals in the granitic orthogneisses of North Veporic basement (Western Carpathians, Slovakia) |
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fluid-driven destabilization of ree-bearing accessory minerals in the granitic orthogneisses of north veporic basement (western carpathians, slovakia) |
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Fluid-driven destabilization of REE-bearing accessory minerals in the granitic orthogneisses of North Veporic basement (Western Carpathians, Slovakia) |
abstract |
Abstract A variety of rare earth elements-bearing (REE) accessory mineral breakdowns were identified in granitic orthogneisses from the pre-Alpine basement in the Veporic Unit, Central Western Carpathians, Slovakia. The Ordovician granitic rocks were subjected to Variscan metamorphic-anatectic overprint in amphibolite facies. Chemical U-Th-Pb dating of monazite-(Ce) and xenotime-(Y) reveal their primary magmatic Lower to Middle Ordovician age (monazite: 472 ± 4 to 468 ± 6 Ma and xenotime: 471 ± 13 Ma) and/or metamorphic-anatectic Variscan (Carboniferous, Visean) age (monazite: 345 ± 3 Ma). Younger fluid-rock interactions caused breakdown of primary magmatic and/or metamorphic-anatectic monazite-(Ce), xenotime-(Y), fluorapatite and allanite-(Ce). Fluid-induced breakdown of xenotime-(Y) produced numerous tiny uraninite inclusions within the altered xenotime-(Y) domains. The monazite-(Ce) breakdown produced secondary egg-shaped coronal structures of different stages with well-developed concentric mineral zones. Secondary sulphatian monazite-(Ce) (up to 0.15 apfu S) occasionally formed along fluorapatite fissures. Localized fluorapatite and monazite-(Ce) recrystallization resulted in a very fine-grained, non-stoichiometric mixture of REE-Y-Fe-Th-Ca-P-Si phases. Finally, allanite-(Ce) decomposed to secondary REE carbonate minerals (members of the bastnäsite and synchysite groups) and calcite in some places. Although the xenotime alteration and formation of uraninite inclusions is believed to be the result of dissolution-reprecipitation between early magmatic xenotime and late-magmatic granitic fluids, the monazite, apatite and allanite breakdowns were driven by metamorphic hydrothermal fluids. While earlier impact of post-magmatic fluids originated probably from Permian acidic volcanic and microgranitic veins crosscutting the orthogneisses, another fluid-rock interaction event most likely occurred during Late Cretaceous metamorphism in the Veporic basement and covering rocks. This stage indicates carbon-bearing fluids precipitating the carbonate minerals. © Springer-Verlag Wien 2016 |
abstractGer |
Abstract A variety of rare earth elements-bearing (REE) accessory mineral breakdowns were identified in granitic orthogneisses from the pre-Alpine basement in the Veporic Unit, Central Western Carpathians, Slovakia. The Ordovician granitic rocks were subjected to Variscan metamorphic-anatectic overprint in amphibolite facies. Chemical U-Th-Pb dating of monazite-(Ce) and xenotime-(Y) reveal their primary magmatic Lower to Middle Ordovician age (monazite: 472 ± 4 to 468 ± 6 Ma and xenotime: 471 ± 13 Ma) and/or metamorphic-anatectic Variscan (Carboniferous, Visean) age (monazite: 345 ± 3 Ma). Younger fluid-rock interactions caused breakdown of primary magmatic and/or metamorphic-anatectic monazite-(Ce), xenotime-(Y), fluorapatite and allanite-(Ce). Fluid-induced breakdown of xenotime-(Y) produced numerous tiny uraninite inclusions within the altered xenotime-(Y) domains. The monazite-(Ce) breakdown produced secondary egg-shaped coronal structures of different stages with well-developed concentric mineral zones. Secondary sulphatian monazite-(Ce) (up to 0.15 apfu S) occasionally formed along fluorapatite fissures. Localized fluorapatite and monazite-(Ce) recrystallization resulted in a very fine-grained, non-stoichiometric mixture of REE-Y-Fe-Th-Ca-P-Si phases. Finally, allanite-(Ce) decomposed to secondary REE carbonate minerals (members of the bastnäsite and synchysite groups) and calcite in some places. Although the xenotime alteration and formation of uraninite inclusions is believed to be the result of dissolution-reprecipitation between early magmatic xenotime and late-magmatic granitic fluids, the monazite, apatite and allanite breakdowns were driven by metamorphic hydrothermal fluids. While earlier impact of post-magmatic fluids originated probably from Permian acidic volcanic and microgranitic veins crosscutting the orthogneisses, another fluid-rock interaction event most likely occurred during Late Cretaceous metamorphism in the Veporic basement and covering rocks. This stage indicates carbon-bearing fluids precipitating the carbonate minerals. © Springer-Verlag Wien 2016 |
abstract_unstemmed |
Abstract A variety of rare earth elements-bearing (REE) accessory mineral breakdowns were identified in granitic orthogneisses from the pre-Alpine basement in the Veporic Unit, Central Western Carpathians, Slovakia. The Ordovician granitic rocks were subjected to Variscan metamorphic-anatectic overprint in amphibolite facies. Chemical U-Th-Pb dating of monazite-(Ce) and xenotime-(Y) reveal their primary magmatic Lower to Middle Ordovician age (monazite: 472 ± 4 to 468 ± 6 Ma and xenotime: 471 ± 13 Ma) and/or metamorphic-anatectic Variscan (Carboniferous, Visean) age (monazite: 345 ± 3 Ma). Younger fluid-rock interactions caused breakdown of primary magmatic and/or metamorphic-anatectic monazite-(Ce), xenotime-(Y), fluorapatite and allanite-(Ce). Fluid-induced breakdown of xenotime-(Y) produced numerous tiny uraninite inclusions within the altered xenotime-(Y) domains. The monazite-(Ce) breakdown produced secondary egg-shaped coronal structures of different stages with well-developed concentric mineral zones. Secondary sulphatian monazite-(Ce) (up to 0.15 apfu S) occasionally formed along fluorapatite fissures. Localized fluorapatite and monazite-(Ce) recrystallization resulted in a very fine-grained, non-stoichiometric mixture of REE-Y-Fe-Th-Ca-P-Si phases. Finally, allanite-(Ce) decomposed to secondary REE carbonate minerals (members of the bastnäsite and synchysite groups) and calcite in some places. Although the xenotime alteration and formation of uraninite inclusions is believed to be the result of dissolution-reprecipitation between early magmatic xenotime and late-magmatic granitic fluids, the monazite, apatite and allanite breakdowns were driven by metamorphic hydrothermal fluids. While earlier impact of post-magmatic fluids originated probably from Permian acidic volcanic and microgranitic veins crosscutting the orthogneisses, another fluid-rock interaction event most likely occurred during Late Cretaceous metamorphism in the Veporic basement and covering rocks. This stage indicates carbon-bearing fluids precipitating the carbonate minerals. © Springer-Verlag Wien 2016 |
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Fluid-driven destabilization of REE-bearing accessory minerals in the granitic orthogneisses of North Veporic basement (Western Carpathians, Slovakia) |
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Localized fluorapatite and monazite-(Ce) recrystallization resulted in a very fine-grained, non-stoichiometric mixture of REE-Y-Fe-Th-Ca-P-Si phases. Finally, allanite-(Ce) decomposed to secondary REE carbonate minerals (members of the bastnäsite and synchysite groups) and calcite in some places. Although the xenotime alteration and formation of uraninite inclusions is believed to be the result of dissolution-reprecipitation between early magmatic xenotime and late-magmatic granitic fluids, the monazite, apatite and allanite breakdowns were driven by metamorphic hydrothermal fluids. While earlier impact of post-magmatic fluids originated probably from Permian acidic volcanic and microgranitic veins crosscutting the orthogneisses, another fluid-rock interaction event most likely occurred during Late Cretaceous metamorphism in the Veporic basement and covering rocks. 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