Immiscibility in sulfate-bearing fluid systems at high temperatures and pressures
Abstract Fluid equilibria in the $ H_{2} $O-$ Na_{2} $$ SO_{4} $-$ SiO_{2} $ system were experimentally studied at 700 and 800°C and pressures of 1, 2, and 3 kbar using synthetic fluid inclusions in quartz. The obtained results indicated a heterogeneous state of fluid within the whole range of exper...
Ausführliche Beschreibung
Autor*in: |
Kotel’nikova, Z. A. [verfasserIn] |
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Artikel |
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Sprache: |
Englisch |
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2010 |
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Anmerkung: |
© Pleiades Publishing, Ltd. 2010 |
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Übergeordnetes Werk: |
Enthalten in: Geochemistry international - SP MAIK Nauka/Interperiodica, 1964, 48(2010), 4 vom: Apr., Seite 381-389 |
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Übergeordnetes Werk: |
volume:48 ; year:2010 ; number:4 ; month:04 ; pages:381-389 |
Links: |
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DOI / URN: |
10.1134/S0016702910040063 |
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OLC2062979142 |
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520 | |a Abstract Fluid equilibria in the $ H_{2} $O-$ Na_{2} $$ SO_{4} $-$ SiO_{2} $ system were experimentally studied at 700 and 800°C and pressures of 1, 2, and 3 kbar using synthetic fluid inclusions in quartz. The obtained results indicated a heterogeneous state of fluid within the whole range of experimental parameters of this study. Sodium sulfate underwent high-temperature hydrolysis, whose products chemically reacted with quartz. As a result, a noncrystalline phase containing substantial amounts of silica was formed at a temperature of 800°C and a pressure of 3 kbar. This phase was observed in the inclusions as glass. The thermometric investigation of inclusions that trapped fluid phases immiscible under experimental conditions showed that they can, in turn, become heterogeneous at temperatures of approximately 200–400°C. Under such conditions, three or four noncrystalline phases can be in equilibrium. It was concluded that the modeling of natural fluids on the basis of the structure of binary water-salt systems does not account for all variants of fluid equilibria occurring (a) at an increase in the number of components and (b) in the presence of salts of the second type. In natural multicomponent fluid-silicate systems, the possibility of fluid unmixing increases considerably and, this process may result in the equilibration of not only two, but also three, four, or more noncrystalline immiscible phases. Under the conditions of the separation of a $ SiO_{2} $-rich phase, ore components can be transported together with $ SiO_{2} $. | ||
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10.1134/S0016702910040063 doi (DE-627)OLC2062979142 (DE-He213)S0016702910040063-p DE-627 ger DE-627 rakwb eng 550 VZ Kotel’nikova, Z. A. verfasserin aut Immiscibility in sulfate-bearing fluid systems at high temperatures and pressures 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2010 Abstract Fluid equilibria in the $ H_{2} $O-$ Na_{2} $$ SO_{4} $-$ SiO_{2} $ system were experimentally studied at 700 and 800°C and pressures of 1, 2, and 3 kbar using synthetic fluid inclusions in quartz. The obtained results indicated a heterogeneous state of fluid within the whole range of experimental parameters of this study. Sodium sulfate underwent high-temperature hydrolysis, whose products chemically reacted with quartz. As a result, a noncrystalline phase containing substantial amounts of silica was formed at a temperature of 800°C and a pressure of 3 kbar. This phase was observed in the inclusions as glass. The thermometric investigation of inclusions that trapped fluid phases immiscible under experimental conditions showed that they can, in turn, become heterogeneous at temperatures of approximately 200–400°C. Under such conditions, three or four noncrystalline phases can be in equilibrium. It was concluded that the modeling of natural fluids on the basis of the structure of binary water-salt systems does not account for all variants of fluid equilibria occurring (a) at an increase in the number of components and (b) in the presence of salts of the second type. In natural multicomponent fluid-silicate systems, the possibility of fluid unmixing increases considerably and, this process may result in the equilibration of not only two, but also three, four, or more noncrystalline immiscible phases. Under the conditions of the separation of a $ SiO_{2} $-rich phase, ore components can be transported together with $ SiO_{2} $. Fluid Inclusion Geochemistry International Phase Inclusion Natural Fluid Fluid Equilibrium Kotel’nikov, A. R. aut Enthalten in Geochemistry international SP MAIK Nauka/Interperiodica, 1964 48(2010), 4 vom: Apr., Seite 381-389 (DE-627)12960321X (DE-600)241677-3 (DE-576)01509703X 0016-7029 nnns volume:48 year:2010 number:4 month:04 pages:381-389 https://doi.org/10.1134/S0016702910040063 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_70 AR 48 2010 4 04 381-389 |
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10.1134/S0016702910040063 doi (DE-627)OLC2062979142 (DE-He213)S0016702910040063-p DE-627 ger DE-627 rakwb eng 550 VZ Kotel’nikova, Z. A. verfasserin aut Immiscibility in sulfate-bearing fluid systems at high temperatures and pressures 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2010 Abstract Fluid equilibria in the $ H_{2} $O-$ Na_{2} $$ SO_{4} $-$ SiO_{2} $ system were experimentally studied at 700 and 800°C and pressures of 1, 2, and 3 kbar using synthetic fluid inclusions in quartz. The obtained results indicated a heterogeneous state of fluid within the whole range of experimental parameters of this study. Sodium sulfate underwent high-temperature hydrolysis, whose products chemically reacted with quartz. As a result, a noncrystalline phase containing substantial amounts of silica was formed at a temperature of 800°C and a pressure of 3 kbar. This phase was observed in the inclusions as glass. The thermometric investigation of inclusions that trapped fluid phases immiscible under experimental conditions showed that they can, in turn, become heterogeneous at temperatures of approximately 200–400°C. Under such conditions, three or four noncrystalline phases can be in equilibrium. It was concluded that the modeling of natural fluids on the basis of the structure of binary water-salt systems does not account for all variants of fluid equilibria occurring (a) at an increase in the number of components and (b) in the presence of salts of the second type. In natural multicomponent fluid-silicate systems, the possibility of fluid unmixing increases considerably and, this process may result in the equilibration of not only two, but also three, four, or more noncrystalline immiscible phases. Under the conditions of the separation of a $ SiO_{2} $-rich phase, ore components can be transported together with $ SiO_{2} $. Fluid Inclusion Geochemistry International Phase Inclusion Natural Fluid Fluid Equilibrium Kotel’nikov, A. R. aut Enthalten in Geochemistry international SP MAIK Nauka/Interperiodica, 1964 48(2010), 4 vom: Apr., Seite 381-389 (DE-627)12960321X (DE-600)241677-3 (DE-576)01509703X 0016-7029 nnns volume:48 year:2010 number:4 month:04 pages:381-389 https://doi.org/10.1134/S0016702910040063 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_70 AR 48 2010 4 04 381-389 |
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10.1134/S0016702910040063 doi (DE-627)OLC2062979142 (DE-He213)S0016702910040063-p DE-627 ger DE-627 rakwb eng 550 VZ Kotel’nikova, Z. A. verfasserin aut Immiscibility in sulfate-bearing fluid systems at high temperatures and pressures 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2010 Abstract Fluid equilibria in the $ H_{2} $O-$ Na_{2} $$ SO_{4} $-$ SiO_{2} $ system were experimentally studied at 700 and 800°C and pressures of 1, 2, and 3 kbar using synthetic fluid inclusions in quartz. The obtained results indicated a heterogeneous state of fluid within the whole range of experimental parameters of this study. Sodium sulfate underwent high-temperature hydrolysis, whose products chemically reacted with quartz. As a result, a noncrystalline phase containing substantial amounts of silica was formed at a temperature of 800°C and a pressure of 3 kbar. This phase was observed in the inclusions as glass. The thermometric investigation of inclusions that trapped fluid phases immiscible under experimental conditions showed that they can, in turn, become heterogeneous at temperatures of approximately 200–400°C. Under such conditions, three or four noncrystalline phases can be in equilibrium. It was concluded that the modeling of natural fluids on the basis of the structure of binary water-salt systems does not account for all variants of fluid equilibria occurring (a) at an increase in the number of components and (b) in the presence of salts of the second type. In natural multicomponent fluid-silicate systems, the possibility of fluid unmixing increases considerably and, this process may result in the equilibration of not only two, but also three, four, or more noncrystalline immiscible phases. Under the conditions of the separation of a $ SiO_{2} $-rich phase, ore components can be transported together with $ SiO_{2} $. Fluid Inclusion Geochemistry International Phase Inclusion Natural Fluid Fluid Equilibrium Kotel’nikov, A. R. aut Enthalten in Geochemistry international SP MAIK Nauka/Interperiodica, 1964 48(2010), 4 vom: Apr., Seite 381-389 (DE-627)12960321X (DE-600)241677-3 (DE-576)01509703X 0016-7029 nnns volume:48 year:2010 number:4 month:04 pages:381-389 https://doi.org/10.1134/S0016702910040063 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_70 AR 48 2010 4 04 381-389 |
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10.1134/S0016702910040063 doi (DE-627)OLC2062979142 (DE-He213)S0016702910040063-p DE-627 ger DE-627 rakwb eng 550 VZ Kotel’nikova, Z. A. verfasserin aut Immiscibility in sulfate-bearing fluid systems at high temperatures and pressures 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2010 Abstract Fluid equilibria in the $ H_{2} $O-$ Na_{2} $$ SO_{4} $-$ SiO_{2} $ system were experimentally studied at 700 and 800°C and pressures of 1, 2, and 3 kbar using synthetic fluid inclusions in quartz. The obtained results indicated a heterogeneous state of fluid within the whole range of experimental parameters of this study. Sodium sulfate underwent high-temperature hydrolysis, whose products chemically reacted with quartz. As a result, a noncrystalline phase containing substantial amounts of silica was formed at a temperature of 800°C and a pressure of 3 kbar. This phase was observed in the inclusions as glass. The thermometric investigation of inclusions that trapped fluid phases immiscible under experimental conditions showed that they can, in turn, become heterogeneous at temperatures of approximately 200–400°C. Under such conditions, three or four noncrystalline phases can be in equilibrium. It was concluded that the modeling of natural fluids on the basis of the structure of binary water-salt systems does not account for all variants of fluid equilibria occurring (a) at an increase in the number of components and (b) in the presence of salts of the second type. In natural multicomponent fluid-silicate systems, the possibility of fluid unmixing increases considerably and, this process may result in the equilibration of not only two, but also three, four, or more noncrystalline immiscible phases. Under the conditions of the separation of a $ SiO_{2} $-rich phase, ore components can be transported together with $ SiO_{2} $. Fluid Inclusion Geochemistry International Phase Inclusion Natural Fluid Fluid Equilibrium Kotel’nikov, A. R. aut Enthalten in Geochemistry international SP MAIK Nauka/Interperiodica, 1964 48(2010), 4 vom: Apr., Seite 381-389 (DE-627)12960321X (DE-600)241677-3 (DE-576)01509703X 0016-7029 nnns volume:48 year:2010 number:4 month:04 pages:381-389 https://doi.org/10.1134/S0016702910040063 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_70 AR 48 2010 4 04 381-389 |
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10.1134/S0016702910040063 doi (DE-627)OLC2062979142 (DE-He213)S0016702910040063-p DE-627 ger DE-627 rakwb eng 550 VZ Kotel’nikova, Z. A. verfasserin aut Immiscibility in sulfate-bearing fluid systems at high temperatures and pressures 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2010 Abstract Fluid equilibria in the $ H_{2} $O-$ Na_{2} $$ SO_{4} $-$ SiO_{2} $ system were experimentally studied at 700 and 800°C and pressures of 1, 2, and 3 kbar using synthetic fluid inclusions in quartz. The obtained results indicated a heterogeneous state of fluid within the whole range of experimental parameters of this study. Sodium sulfate underwent high-temperature hydrolysis, whose products chemically reacted with quartz. As a result, a noncrystalline phase containing substantial amounts of silica was formed at a temperature of 800°C and a pressure of 3 kbar. This phase was observed in the inclusions as glass. The thermometric investigation of inclusions that trapped fluid phases immiscible under experimental conditions showed that they can, in turn, become heterogeneous at temperatures of approximately 200–400°C. Under such conditions, three or four noncrystalline phases can be in equilibrium. It was concluded that the modeling of natural fluids on the basis of the structure of binary water-salt systems does not account for all variants of fluid equilibria occurring (a) at an increase in the number of components and (b) in the presence of salts of the second type. In natural multicomponent fluid-silicate systems, the possibility of fluid unmixing increases considerably and, this process may result in the equilibration of not only two, but also three, four, or more noncrystalline immiscible phases. Under the conditions of the separation of a $ SiO_{2} $-rich phase, ore components can be transported together with $ SiO_{2} $. Fluid Inclusion Geochemistry International Phase Inclusion Natural Fluid Fluid Equilibrium Kotel’nikov, A. R. aut Enthalten in Geochemistry international SP MAIK Nauka/Interperiodica, 1964 48(2010), 4 vom: Apr., Seite 381-389 (DE-627)12960321X (DE-600)241677-3 (DE-576)01509703X 0016-7029 nnns volume:48 year:2010 number:4 month:04 pages:381-389 https://doi.org/10.1134/S0016702910040063 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_70 AR 48 2010 4 04 381-389 |
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Immiscibility in sulfate-bearing fluid systems at high temperatures and pressures |
abstract |
Abstract Fluid equilibria in the $ H_{2} $O-$ Na_{2} $$ SO_{4} $-$ SiO_{2} $ system were experimentally studied at 700 and 800°C and pressures of 1, 2, and 3 kbar using synthetic fluid inclusions in quartz. The obtained results indicated a heterogeneous state of fluid within the whole range of experimental parameters of this study. Sodium sulfate underwent high-temperature hydrolysis, whose products chemically reacted with quartz. As a result, a noncrystalline phase containing substantial amounts of silica was formed at a temperature of 800°C and a pressure of 3 kbar. This phase was observed in the inclusions as glass. The thermometric investigation of inclusions that trapped fluid phases immiscible under experimental conditions showed that they can, in turn, become heterogeneous at temperatures of approximately 200–400°C. Under such conditions, three or four noncrystalline phases can be in equilibrium. It was concluded that the modeling of natural fluids on the basis of the structure of binary water-salt systems does not account for all variants of fluid equilibria occurring (a) at an increase in the number of components and (b) in the presence of salts of the second type. In natural multicomponent fluid-silicate systems, the possibility of fluid unmixing increases considerably and, this process may result in the equilibration of not only two, but also three, four, or more noncrystalline immiscible phases. Under the conditions of the separation of a $ SiO_{2} $-rich phase, ore components can be transported together with $ SiO_{2} $. © Pleiades Publishing, Ltd. 2010 |
abstractGer |
Abstract Fluid equilibria in the $ H_{2} $O-$ Na_{2} $$ SO_{4} $-$ SiO_{2} $ system were experimentally studied at 700 and 800°C and pressures of 1, 2, and 3 kbar using synthetic fluid inclusions in quartz. The obtained results indicated a heterogeneous state of fluid within the whole range of experimental parameters of this study. Sodium sulfate underwent high-temperature hydrolysis, whose products chemically reacted with quartz. As a result, a noncrystalline phase containing substantial amounts of silica was formed at a temperature of 800°C and a pressure of 3 kbar. This phase was observed in the inclusions as glass. The thermometric investigation of inclusions that trapped fluid phases immiscible under experimental conditions showed that they can, in turn, become heterogeneous at temperatures of approximately 200–400°C. Under such conditions, three or four noncrystalline phases can be in equilibrium. It was concluded that the modeling of natural fluids on the basis of the structure of binary water-salt systems does not account for all variants of fluid equilibria occurring (a) at an increase in the number of components and (b) in the presence of salts of the second type. In natural multicomponent fluid-silicate systems, the possibility of fluid unmixing increases considerably and, this process may result in the equilibration of not only two, but also three, four, or more noncrystalline immiscible phases. Under the conditions of the separation of a $ SiO_{2} $-rich phase, ore components can be transported together with $ SiO_{2} $. © Pleiades Publishing, Ltd. 2010 |
abstract_unstemmed |
Abstract Fluid equilibria in the $ H_{2} $O-$ Na_{2} $$ SO_{4} $-$ SiO_{2} $ system were experimentally studied at 700 and 800°C and pressures of 1, 2, and 3 kbar using synthetic fluid inclusions in quartz. The obtained results indicated a heterogeneous state of fluid within the whole range of experimental parameters of this study. Sodium sulfate underwent high-temperature hydrolysis, whose products chemically reacted with quartz. As a result, a noncrystalline phase containing substantial amounts of silica was formed at a temperature of 800°C and a pressure of 3 kbar. This phase was observed in the inclusions as glass. The thermometric investigation of inclusions that trapped fluid phases immiscible under experimental conditions showed that they can, in turn, become heterogeneous at temperatures of approximately 200–400°C. Under such conditions, three or four noncrystalline phases can be in equilibrium. It was concluded that the modeling of natural fluids on the basis of the structure of binary water-salt systems does not account for all variants of fluid equilibria occurring (a) at an increase in the number of components and (b) in the presence of salts of the second type. In natural multicomponent fluid-silicate systems, the possibility of fluid unmixing increases considerably and, this process may result in the equilibration of not only two, but also three, four, or more noncrystalline immiscible phases. Under the conditions of the separation of a $ SiO_{2} $-rich phase, ore components can be transported together with $ SiO_{2} $. © Pleiades Publishing, Ltd. 2010 |
collection_details |
GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_70 |
container_issue |
4 |
title_short |
Immiscibility in sulfate-bearing fluid systems at high temperatures and pressures |
url |
https://doi.org/10.1134/S0016702910040063 |
remote_bool |
false |
author2 |
Kotel’nikov, A. R. |
author2Str |
Kotel’nikov, A. R. |
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doi_str |
10.1134/S0016702910040063 |
up_date |
2024-07-03T17:12:27.644Z |
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