Measurement and correlation of excess molar volumes for mixtures of 1-propanol and aromatic hydrocarbons
Abstract Excess molar volumes ($ V_{m} $E) have been measured at 303.15 K for 1-propanol+benzene or toluene or o- or m- or p-xylene mixtures using V-shape dilatometer. The $ V_{m} $E values, for an equimolar composition, vary in the order: benzene>toluene∼m-xylene>o-xylene>p-xylene. The $ V...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Gahlyan, Suman [verfasserIn] |
|---|
| Format: |
Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2014 |
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| Schlagwörter: |
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| Anmerkung: |
© Korean Institute of Chemical Engineers, Seoul, Korea 2014 |
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| Übergeordnetes Werk: |
Enthalten in: The Korean journal of chemical engineering - Springer US, 1984, 32(2014), 1 vom: 12. Nov., Seite 168-177 |
|---|---|
| Übergeordnetes Werk: |
volume:32 ; year:2014 ; number:1 ; day:12 ; month:11 ; pages:168-177 |
| Links: |
|---|
| DOI / URN: |
10.1007/s11814-014-0200-6 |
|---|
| Katalog-ID: |
OLC2063030219 |
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| 520 | |a Abstract Excess molar volumes ($ V_{m} $E) have been measured at 303.15 K for 1-propanol+benzene or toluene or o- or m- or p-xylene mixtures using V-shape dilatometer. The $ V_{m} $E values, for an equimolar composition, vary in the order: benzene>toluene∼m-xylene>o-xylene>p-xylene. The $ V_{m} $E data have been used to calculate partial molar volumes, excess partial molar volumes, and apparent molar volumes of 1-propanol and aromatic hydrocarbons over the entire range of composition. The excess volume data have also been interpreted in terms of graph-theoretical approach and Prigogine-Flory-Patterson theory (PFP). While PFP theory fails to predict the $ V_{m} $E values for systems with s-shaped $ V_{m} $E versus $ x_{1} $ graph, the $ V_{m} $E values calculated by graph theory compare reasonably well with the corresponding experimental values. This graph theory analysis has further yielded information about the state of aggregation of pure components as well as of the mixtures. | ||
| 650 | 4 | |a Molar Excess Volume | |
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| 650 | 4 | |a 1-Propanol | |
| 650 | 4 | |a Aromatic Hydrocarbon | |
| 650 | 4 | |a Graph Theoretical Approach | |
| 650 | 4 | |a Prigogine-Flory-Patterson Theory | |
| 700 | 1 | |a Rani, Manju |4 aut | |
| 700 | 1 | |a Lee, Inkyu |4 aut | |
| 700 | 1 | |a Moon, Il |4 aut | |
| 700 | 1 | |a Maken, Sanjeev Kumar |4 aut | |
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10.1007/s11814-014-0200-6 doi (DE-627)OLC2063030219 (DE-He213)s11814-014-0200-6-p DE-627 ger DE-627 rakwb eng 660 VZ 58.00 bkl Gahlyan, Suman verfasserin aut Measurement and correlation of excess molar volumes for mixtures of 1-propanol and aromatic hydrocarbons 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Korean Institute of Chemical Engineers, Seoul, Korea 2014 Abstract Excess molar volumes ($ V_{m} $E) have been measured at 303.15 K for 1-propanol+benzene or toluene or o- or m- or p-xylene mixtures using V-shape dilatometer. The $ V_{m} $E values, for an equimolar composition, vary in the order: benzene>toluene∼m-xylene>o-xylene>p-xylene. The $ V_{m} $E data have been used to calculate partial molar volumes, excess partial molar volumes, and apparent molar volumes of 1-propanol and aromatic hydrocarbons over the entire range of composition. The excess volume data have also been interpreted in terms of graph-theoretical approach and Prigogine-Flory-Patterson theory (PFP). While PFP theory fails to predict the $ V_{m} $E values for systems with s-shaped $ V_{m} $E versus $ x_{1} $ graph, the $ V_{m} $E values calculated by graph theory compare reasonably well with the corresponding experimental values. This graph theory analysis has further yielded information about the state of aggregation of pure components as well as of the mixtures. Molar Excess Volume Partial Molar Volume 1-Propanol Aromatic Hydrocarbon Graph Theoretical Approach Prigogine-Flory-Patterson Theory Rani, Manju aut Lee, Inkyu aut Moon, Il aut Maken, Sanjeev Kumar aut Enthalten in The Korean journal of chemical engineering Springer US, 1984 32(2014), 1 vom: 12. Nov., Seite 168-177 (DE-627)129165409 (DE-600)50398-8 (DE-576)099445263 0256-1115 nnns volume:32 year:2014 number:1 day:12 month:11 pages:168-177 https://doi.org/10.1007/s11814-014-0200-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 58.00 VZ AR 32 2014 1 12 11 168-177 |
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10.1007/s11814-014-0200-6 doi (DE-627)OLC2063030219 (DE-He213)s11814-014-0200-6-p DE-627 ger DE-627 rakwb eng 660 VZ 58.00 bkl Gahlyan, Suman verfasserin aut Measurement and correlation of excess molar volumes for mixtures of 1-propanol and aromatic hydrocarbons 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Korean Institute of Chemical Engineers, Seoul, Korea 2014 Abstract Excess molar volumes ($ V_{m} $E) have been measured at 303.15 K for 1-propanol+benzene or toluene or o- or m- or p-xylene mixtures using V-shape dilatometer. The $ V_{m} $E values, for an equimolar composition, vary in the order: benzene>toluene∼m-xylene>o-xylene>p-xylene. The $ V_{m} $E data have been used to calculate partial molar volumes, excess partial molar volumes, and apparent molar volumes of 1-propanol and aromatic hydrocarbons over the entire range of composition. The excess volume data have also been interpreted in terms of graph-theoretical approach and Prigogine-Flory-Patterson theory (PFP). While PFP theory fails to predict the $ V_{m} $E values for systems with s-shaped $ V_{m} $E versus $ x_{1} $ graph, the $ V_{m} $E values calculated by graph theory compare reasonably well with the corresponding experimental values. This graph theory analysis has further yielded information about the state of aggregation of pure components as well as of the mixtures. Molar Excess Volume Partial Molar Volume 1-Propanol Aromatic Hydrocarbon Graph Theoretical Approach Prigogine-Flory-Patterson Theory Rani, Manju aut Lee, Inkyu aut Moon, Il aut Maken, Sanjeev Kumar aut Enthalten in The Korean journal of chemical engineering Springer US, 1984 32(2014), 1 vom: 12. Nov., Seite 168-177 (DE-627)129165409 (DE-600)50398-8 (DE-576)099445263 0256-1115 nnns volume:32 year:2014 number:1 day:12 month:11 pages:168-177 https://doi.org/10.1007/s11814-014-0200-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 58.00 VZ AR 32 2014 1 12 11 168-177 |
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10.1007/s11814-014-0200-6 doi (DE-627)OLC2063030219 (DE-He213)s11814-014-0200-6-p DE-627 ger DE-627 rakwb eng 660 VZ 58.00 bkl Gahlyan, Suman verfasserin aut Measurement and correlation of excess molar volumes for mixtures of 1-propanol and aromatic hydrocarbons 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Korean Institute of Chemical Engineers, Seoul, Korea 2014 Abstract Excess molar volumes ($ V_{m} $E) have been measured at 303.15 K for 1-propanol+benzene or toluene or o- or m- or p-xylene mixtures using V-shape dilatometer. The $ V_{m} $E values, for an equimolar composition, vary in the order: benzene>toluene∼m-xylene>o-xylene>p-xylene. The $ V_{m} $E data have been used to calculate partial molar volumes, excess partial molar volumes, and apparent molar volumes of 1-propanol and aromatic hydrocarbons over the entire range of composition. The excess volume data have also been interpreted in terms of graph-theoretical approach and Prigogine-Flory-Patterson theory (PFP). While PFP theory fails to predict the $ V_{m} $E values for systems with s-shaped $ V_{m} $E versus $ x_{1} $ graph, the $ V_{m} $E values calculated by graph theory compare reasonably well with the corresponding experimental values. This graph theory analysis has further yielded information about the state of aggregation of pure components as well as of the mixtures. Molar Excess Volume Partial Molar Volume 1-Propanol Aromatic Hydrocarbon Graph Theoretical Approach Prigogine-Flory-Patterson Theory Rani, Manju aut Lee, Inkyu aut Moon, Il aut Maken, Sanjeev Kumar aut Enthalten in The Korean journal of chemical engineering Springer US, 1984 32(2014), 1 vom: 12. Nov., Seite 168-177 (DE-627)129165409 (DE-600)50398-8 (DE-576)099445263 0256-1115 nnns volume:32 year:2014 number:1 day:12 month:11 pages:168-177 https://doi.org/10.1007/s11814-014-0200-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 58.00 VZ AR 32 2014 1 12 11 168-177 |
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10.1007/s11814-014-0200-6 doi (DE-627)OLC2063030219 (DE-He213)s11814-014-0200-6-p DE-627 ger DE-627 rakwb eng 660 VZ 58.00 bkl Gahlyan, Suman verfasserin aut Measurement and correlation of excess molar volumes for mixtures of 1-propanol and aromatic hydrocarbons 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Korean Institute of Chemical Engineers, Seoul, Korea 2014 Abstract Excess molar volumes ($ V_{m} $E) have been measured at 303.15 K for 1-propanol+benzene or toluene or o- or m- or p-xylene mixtures using V-shape dilatometer. The $ V_{m} $E values, for an equimolar composition, vary in the order: benzene>toluene∼m-xylene>o-xylene>p-xylene. The $ V_{m} $E data have been used to calculate partial molar volumes, excess partial molar volumes, and apparent molar volumes of 1-propanol and aromatic hydrocarbons over the entire range of composition. The excess volume data have also been interpreted in terms of graph-theoretical approach and Prigogine-Flory-Patterson theory (PFP). While PFP theory fails to predict the $ V_{m} $E values for systems with s-shaped $ V_{m} $E versus $ x_{1} $ graph, the $ V_{m} $E values calculated by graph theory compare reasonably well with the corresponding experimental values. This graph theory analysis has further yielded information about the state of aggregation of pure components as well as of the mixtures. Molar Excess Volume Partial Molar Volume 1-Propanol Aromatic Hydrocarbon Graph Theoretical Approach Prigogine-Flory-Patterson Theory Rani, Manju aut Lee, Inkyu aut Moon, Il aut Maken, Sanjeev Kumar aut Enthalten in The Korean journal of chemical engineering Springer US, 1984 32(2014), 1 vom: 12. Nov., Seite 168-177 (DE-627)129165409 (DE-600)50398-8 (DE-576)099445263 0256-1115 nnns volume:32 year:2014 number:1 day:12 month:11 pages:168-177 https://doi.org/10.1007/s11814-014-0200-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 58.00 VZ AR 32 2014 1 12 11 168-177 |
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10.1007/s11814-014-0200-6 doi (DE-627)OLC2063030219 (DE-He213)s11814-014-0200-6-p DE-627 ger DE-627 rakwb eng 660 VZ 58.00 bkl Gahlyan, Suman verfasserin aut Measurement and correlation of excess molar volumes for mixtures of 1-propanol and aromatic hydrocarbons 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Korean Institute of Chemical Engineers, Seoul, Korea 2014 Abstract Excess molar volumes ($ V_{m} $E) have been measured at 303.15 K for 1-propanol+benzene or toluene or o- or m- or p-xylene mixtures using V-shape dilatometer. The $ V_{m} $E values, for an equimolar composition, vary in the order: benzene>toluene∼m-xylene>o-xylene>p-xylene. The $ V_{m} $E data have been used to calculate partial molar volumes, excess partial molar volumes, and apparent molar volumes of 1-propanol and aromatic hydrocarbons over the entire range of composition. The excess volume data have also been interpreted in terms of graph-theoretical approach and Prigogine-Flory-Patterson theory (PFP). While PFP theory fails to predict the $ V_{m} $E values for systems with s-shaped $ V_{m} $E versus $ x_{1} $ graph, the $ V_{m} $E values calculated by graph theory compare reasonably well with the corresponding experimental values. This graph theory analysis has further yielded information about the state of aggregation of pure components as well as of the mixtures. Molar Excess Volume Partial Molar Volume 1-Propanol Aromatic Hydrocarbon Graph Theoretical Approach Prigogine-Flory-Patterson Theory Rani, Manju aut Lee, Inkyu aut Moon, Il aut Maken, Sanjeev Kumar aut Enthalten in The Korean journal of chemical engineering Springer US, 1984 32(2014), 1 vom: 12. Nov., Seite 168-177 (DE-627)129165409 (DE-600)50398-8 (DE-576)099445263 0256-1115 nnns volume:32 year:2014 number:1 day:12 month:11 pages:168-177 https://doi.org/10.1007/s11814-014-0200-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 58.00 VZ AR 32 2014 1 12 11 168-177 |
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Measurement and correlation of excess molar volumes for mixtures of 1-propanol and aromatic hydrocarbons |
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Measurement and correlation of excess molar volumes for mixtures of 1-propanol and aromatic hydrocarbons |
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Gahlyan, Suman |
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The Korean journal of chemical engineering |
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Gahlyan, Suman Rani, Manju Lee, Inkyu Moon, Il Maken, Sanjeev Kumar |
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measurement and correlation of excess molar volumes for mixtures of 1-propanol and aromatic hydrocarbons |
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Measurement and correlation of excess molar volumes for mixtures of 1-propanol and aromatic hydrocarbons |
| abstract |
Abstract Excess molar volumes ($ V_{m} $E) have been measured at 303.15 K for 1-propanol+benzene or toluene or o- or m- or p-xylene mixtures using V-shape dilatometer. The $ V_{m} $E values, for an equimolar composition, vary in the order: benzene>toluene∼m-xylene>o-xylene>p-xylene. The $ V_{m} $E data have been used to calculate partial molar volumes, excess partial molar volumes, and apparent molar volumes of 1-propanol and aromatic hydrocarbons over the entire range of composition. The excess volume data have also been interpreted in terms of graph-theoretical approach and Prigogine-Flory-Patterson theory (PFP). While PFP theory fails to predict the $ V_{m} $E values for systems with s-shaped $ V_{m} $E versus $ x_{1} $ graph, the $ V_{m} $E values calculated by graph theory compare reasonably well with the corresponding experimental values. This graph theory analysis has further yielded information about the state of aggregation of pure components as well as of the mixtures. © Korean Institute of Chemical Engineers, Seoul, Korea 2014 |
| abstractGer |
Abstract Excess molar volumes ($ V_{m} $E) have been measured at 303.15 K for 1-propanol+benzene or toluene or o- or m- or p-xylene mixtures using V-shape dilatometer. The $ V_{m} $E values, for an equimolar composition, vary in the order: benzene>toluene∼m-xylene>o-xylene>p-xylene. The $ V_{m} $E data have been used to calculate partial molar volumes, excess partial molar volumes, and apparent molar volumes of 1-propanol and aromatic hydrocarbons over the entire range of composition. The excess volume data have also been interpreted in terms of graph-theoretical approach and Prigogine-Flory-Patterson theory (PFP). While PFP theory fails to predict the $ V_{m} $E values for systems with s-shaped $ V_{m} $E versus $ x_{1} $ graph, the $ V_{m} $E values calculated by graph theory compare reasonably well with the corresponding experimental values. This graph theory analysis has further yielded information about the state of aggregation of pure components as well as of the mixtures. © Korean Institute of Chemical Engineers, Seoul, Korea 2014 |
| abstract_unstemmed |
Abstract Excess molar volumes ($ V_{m} $E) have been measured at 303.15 K for 1-propanol+benzene or toluene or o- or m- or p-xylene mixtures using V-shape dilatometer. The $ V_{m} $E values, for an equimolar composition, vary in the order: benzene>toluene∼m-xylene>o-xylene>p-xylene. The $ V_{m} $E data have been used to calculate partial molar volumes, excess partial molar volumes, and apparent molar volumes of 1-propanol and aromatic hydrocarbons over the entire range of composition. The excess volume data have also been interpreted in terms of graph-theoretical approach and Prigogine-Flory-Patterson theory (PFP). While PFP theory fails to predict the $ V_{m} $E values for systems with s-shaped $ V_{m} $E versus $ x_{1} $ graph, the $ V_{m} $E values calculated by graph theory compare reasonably well with the corresponding experimental values. This graph theory analysis has further yielded information about the state of aggregation of pure components as well as of the mixtures. © Korean Institute of Chemical Engineers, Seoul, Korea 2014 |
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Measurement and correlation of excess molar volumes for mixtures of 1-propanol and aromatic hydrocarbons |
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