Vapor-phase oxidation of β-picoline to nicotinic acid on $ V_{2} $$ O_{5} $ and modified vanadium oxide catalysts
Abstract Modification of $ V_{2} $$ O_{5} $ with Ti, Sn, Zr, Nb, and Al oxides improves the activity and selectivity of the vanadium oxide catalyst in vapor-phase oxidation of β-picoline to give nicotinic acid. It is shown that the conversion of β-picoline and the yield of nicotinic acid on two-comp...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Vorobyev, P. B. [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2014 |
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| Schlagwörter: |
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| Anmerkung: |
© Pleiades Publishing, Ltd. 2014 |
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| Übergeordnetes Werk: |
Enthalten in: Russian journal of applied chemistry - Pleiades Publishing, 1993, 87(2014), 7 vom: Juli, Seite 887-894 |
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| Übergeordnetes Werk: |
volume:87 ; year:2014 ; number:7 ; month:07 ; pages:887-894 |
| Links: |
|---|
| DOI / URN: |
10.1134/S1070427214070076 |
|---|
| Katalog-ID: |
OLC2063646996 |
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| 520 | |a Abstract Modification of $ V_{2} $$ O_{5} $ with Ti, Sn, Zr, Nb, and Al oxides improves the activity and selectivity of the vanadium oxide catalyst in vapor-phase oxidation of β-picoline to give nicotinic acid. It is shown that the conversion of β-picoline and the yield of nicotinic acid on two-component $ V_{2} $$ O_{5} $-$ TiO_{2} $, $ V_{2} $$ O_{5} $-$ SnO_{2} $, $ V_{2} $$ O_{5} $-$ ZtrO_{2} $, $ V_{2} $$ O_{5} $-$ Nb_{2} $$ O_{5} $, and $ V_{2} $$ O_{5} $-$ Al_{2} $$ O_{3} $ catalysts may be several times those on the $ V_{2} $$ O_{5} $ catalyst. It was found that, on passing from $ V_{2} $$ O_{5} $ to double-component vanadium-containing catalysts, the proton affinity of active oxygen bonded to vanadium, calculated by the quantum-chemical method, grows simultaneously with the increase in the activity of the catalysts in the oxidation reaction. | ||
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| 700 | 1 | |a Serebryanskaya, A. P. |4 aut | |
| 700 | 1 | |a Shlygina, I. A. |4 aut | |
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10.1134/S1070427214070076 doi (DE-627)OLC2063646996 (DE-He213)S1070427214070076-p DE-627 ger DE-627 rakwb eng 540 VZ Vorobyev, P. B. verfasserin aut Vapor-phase oxidation of β-picoline to nicotinic acid on $ V_{2} $$ O_{5} $ and modified vanadium oxide catalysts 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2014 Abstract Modification of $ V_{2} $$ O_{5} $ with Ti, Sn, Zr, Nb, and Al oxides improves the activity and selectivity of the vanadium oxide catalyst in vapor-phase oxidation of β-picoline to give nicotinic acid. It is shown that the conversion of β-picoline and the yield of nicotinic acid on two-component $ V_{2} $$ O_{5} $-$ TiO_{2} $, $ V_{2} $$ O_{5} $-$ SnO_{2} $, $ V_{2} $$ O_{5} $-$ ZtrO_{2} $, $ V_{2} $$ O_{5} $-$ Nb_{2} $$ O_{5} $, and $ V_{2} $$ O_{5} $-$ Al_{2} $$ O_{3} $ catalysts may be several times those on the $ V_{2} $$ O_{5} $ catalyst. It was found that, on passing from $ V_{2} $$ O_{5} $ to double-component vanadium-containing catalysts, the proton affinity of active oxygen bonded to vanadium, calculated by the quantum-chemical method, grows simultaneously with the increase in the activity of the catalysts in the oxidation reaction. Vanadium Nicotinic Acid Vanadium Oxide Vanadium Oxide Catalyst Vanadyl Oxygen Saurambaeva, L. I. aut Mikhailovskaya, T. P. aut Yugay, O. K. aut Serebryanskaya, A. P. aut Shlygina, I. A. aut Enthalten in Russian journal of applied chemistry Pleiades Publishing, 1993 87(2014), 7 vom: Juli, Seite 887-894 (DE-627)181999927 (DE-600)1181520-6 (DE-576)038881543 1070-4272 nnns volume:87 year:2014 number:7 month:07 pages:887-894 https://doi.org/10.1134/S1070427214070076 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 87 2014 7 07 887-894 |
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10.1134/S1070427214070076 doi (DE-627)OLC2063646996 (DE-He213)S1070427214070076-p DE-627 ger DE-627 rakwb eng 540 VZ Vorobyev, P. B. verfasserin aut Vapor-phase oxidation of β-picoline to nicotinic acid on $ V_{2} $$ O_{5} $ and modified vanadium oxide catalysts 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2014 Abstract Modification of $ V_{2} $$ O_{5} $ with Ti, Sn, Zr, Nb, and Al oxides improves the activity and selectivity of the vanadium oxide catalyst in vapor-phase oxidation of β-picoline to give nicotinic acid. It is shown that the conversion of β-picoline and the yield of nicotinic acid on two-component $ V_{2} $$ O_{5} $-$ TiO_{2} $, $ V_{2} $$ O_{5} $-$ SnO_{2} $, $ V_{2} $$ O_{5} $-$ ZtrO_{2} $, $ V_{2} $$ O_{5} $-$ Nb_{2} $$ O_{5} $, and $ V_{2} $$ O_{5} $-$ Al_{2} $$ O_{3} $ catalysts may be several times those on the $ V_{2} $$ O_{5} $ catalyst. It was found that, on passing from $ V_{2} $$ O_{5} $ to double-component vanadium-containing catalysts, the proton affinity of active oxygen bonded to vanadium, calculated by the quantum-chemical method, grows simultaneously with the increase in the activity of the catalysts in the oxidation reaction. Vanadium Nicotinic Acid Vanadium Oxide Vanadium Oxide Catalyst Vanadyl Oxygen Saurambaeva, L. I. aut Mikhailovskaya, T. P. aut Yugay, O. K. aut Serebryanskaya, A. P. aut Shlygina, I. A. aut Enthalten in Russian journal of applied chemistry Pleiades Publishing, 1993 87(2014), 7 vom: Juli, Seite 887-894 (DE-627)181999927 (DE-600)1181520-6 (DE-576)038881543 1070-4272 nnns volume:87 year:2014 number:7 month:07 pages:887-894 https://doi.org/10.1134/S1070427214070076 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 87 2014 7 07 887-894 |
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10.1134/S1070427214070076 doi (DE-627)OLC2063646996 (DE-He213)S1070427214070076-p DE-627 ger DE-627 rakwb eng 540 VZ Vorobyev, P. B. verfasserin aut Vapor-phase oxidation of β-picoline to nicotinic acid on $ V_{2} $$ O_{5} $ and modified vanadium oxide catalysts 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2014 Abstract Modification of $ V_{2} $$ O_{5} $ with Ti, Sn, Zr, Nb, and Al oxides improves the activity and selectivity of the vanadium oxide catalyst in vapor-phase oxidation of β-picoline to give nicotinic acid. It is shown that the conversion of β-picoline and the yield of nicotinic acid on two-component $ V_{2} $$ O_{5} $-$ TiO_{2} $, $ V_{2} $$ O_{5} $-$ SnO_{2} $, $ V_{2} $$ O_{5} $-$ ZtrO_{2} $, $ V_{2} $$ O_{5} $-$ Nb_{2} $$ O_{5} $, and $ V_{2} $$ O_{5} $-$ Al_{2} $$ O_{3} $ catalysts may be several times those on the $ V_{2} $$ O_{5} $ catalyst. It was found that, on passing from $ V_{2} $$ O_{5} $ to double-component vanadium-containing catalysts, the proton affinity of active oxygen bonded to vanadium, calculated by the quantum-chemical method, grows simultaneously with the increase in the activity of the catalysts in the oxidation reaction. Vanadium Nicotinic Acid Vanadium Oxide Vanadium Oxide Catalyst Vanadyl Oxygen Saurambaeva, L. I. aut Mikhailovskaya, T. P. aut Yugay, O. K. aut Serebryanskaya, A. P. aut Shlygina, I. A. aut Enthalten in Russian journal of applied chemistry Pleiades Publishing, 1993 87(2014), 7 vom: Juli, Seite 887-894 (DE-627)181999927 (DE-600)1181520-6 (DE-576)038881543 1070-4272 nnns volume:87 year:2014 number:7 month:07 pages:887-894 https://doi.org/10.1134/S1070427214070076 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 87 2014 7 07 887-894 |
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10.1134/S1070427214070076 doi (DE-627)OLC2063646996 (DE-He213)S1070427214070076-p DE-627 ger DE-627 rakwb eng 540 VZ Vorobyev, P. B. verfasserin aut Vapor-phase oxidation of β-picoline to nicotinic acid on $ V_{2} $$ O_{5} $ and modified vanadium oxide catalysts 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2014 Abstract Modification of $ V_{2} $$ O_{5} $ with Ti, Sn, Zr, Nb, and Al oxides improves the activity and selectivity of the vanadium oxide catalyst in vapor-phase oxidation of β-picoline to give nicotinic acid. It is shown that the conversion of β-picoline and the yield of nicotinic acid on two-component $ V_{2} $$ O_{5} $-$ TiO_{2} $, $ V_{2} $$ O_{5} $-$ SnO_{2} $, $ V_{2} $$ O_{5} $-$ ZtrO_{2} $, $ V_{2} $$ O_{5} $-$ Nb_{2} $$ O_{5} $, and $ V_{2} $$ O_{5} $-$ Al_{2} $$ O_{3} $ catalysts may be several times those on the $ V_{2} $$ O_{5} $ catalyst. It was found that, on passing from $ V_{2} $$ O_{5} $ to double-component vanadium-containing catalysts, the proton affinity of active oxygen bonded to vanadium, calculated by the quantum-chemical method, grows simultaneously with the increase in the activity of the catalysts in the oxidation reaction. Vanadium Nicotinic Acid Vanadium Oxide Vanadium Oxide Catalyst Vanadyl Oxygen Saurambaeva, L. I. aut Mikhailovskaya, T. P. aut Yugay, O. K. aut Serebryanskaya, A. P. aut Shlygina, I. A. aut Enthalten in Russian journal of applied chemistry Pleiades Publishing, 1993 87(2014), 7 vom: Juli, Seite 887-894 (DE-627)181999927 (DE-600)1181520-6 (DE-576)038881543 1070-4272 nnns volume:87 year:2014 number:7 month:07 pages:887-894 https://doi.org/10.1134/S1070427214070076 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 87 2014 7 07 887-894 |
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10.1134/S1070427214070076 doi (DE-627)OLC2063646996 (DE-He213)S1070427214070076-p DE-627 ger DE-627 rakwb eng 540 VZ Vorobyev, P. B. verfasserin aut Vapor-phase oxidation of β-picoline to nicotinic acid on $ V_{2} $$ O_{5} $ and modified vanadium oxide catalysts 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2014 Abstract Modification of $ V_{2} $$ O_{5} $ with Ti, Sn, Zr, Nb, and Al oxides improves the activity and selectivity of the vanadium oxide catalyst in vapor-phase oxidation of β-picoline to give nicotinic acid. It is shown that the conversion of β-picoline and the yield of nicotinic acid on two-component $ V_{2} $$ O_{5} $-$ TiO_{2} $, $ V_{2} $$ O_{5} $-$ SnO_{2} $, $ V_{2} $$ O_{5} $-$ ZtrO_{2} $, $ V_{2} $$ O_{5} $-$ Nb_{2} $$ O_{5} $, and $ V_{2} $$ O_{5} $-$ Al_{2} $$ O_{3} $ catalysts may be several times those on the $ V_{2} $$ O_{5} $ catalyst. It was found that, on passing from $ V_{2} $$ O_{5} $ to double-component vanadium-containing catalysts, the proton affinity of active oxygen bonded to vanadium, calculated by the quantum-chemical method, grows simultaneously with the increase in the activity of the catalysts in the oxidation reaction. Vanadium Nicotinic Acid Vanadium Oxide Vanadium Oxide Catalyst Vanadyl Oxygen Saurambaeva, L. I. aut Mikhailovskaya, T. P. aut Yugay, O. K. aut Serebryanskaya, A. P. aut Shlygina, I. A. aut Enthalten in Russian journal of applied chemistry Pleiades Publishing, 1993 87(2014), 7 vom: Juli, Seite 887-894 (DE-627)181999927 (DE-600)1181520-6 (DE-576)038881543 1070-4272 nnns volume:87 year:2014 number:7 month:07 pages:887-894 https://doi.org/10.1134/S1070427214070076 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 87 2014 7 07 887-894 |
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Vapor-phase oxidation of β-picoline to nicotinic acid on $ V_{2} $$ O_{5} $ and modified vanadium oxide catalysts |
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(DE-627)OLC2063646996 (DE-He213)S1070427214070076-p |
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Vapor-phase oxidation of β-picoline to nicotinic acid on $ V_{2} $$ O_{5} $ and modified vanadium oxide catalysts |
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Vorobyev, P. B. |
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Russian journal of applied chemistry |
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Russian journal of applied chemistry |
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2014 |
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Vorobyev, P. B. Saurambaeva, L. I. Mikhailovskaya, T. P. Yugay, O. K. Serebryanskaya, A. P. Shlygina, I. A. |
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Vorobyev, P. B. |
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10.1134/S1070427214070076 |
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540 |
| title_sort |
vapor-phase oxidation of β-picoline to nicotinic acid on $ v_{2} $$ o_{5} $ and modified vanadium oxide catalysts |
| title_auth |
Vapor-phase oxidation of β-picoline to nicotinic acid on $ V_{2} $$ O_{5} $ and modified vanadium oxide catalysts |
| abstract |
Abstract Modification of $ V_{2} $$ O_{5} $ with Ti, Sn, Zr, Nb, and Al oxides improves the activity and selectivity of the vanadium oxide catalyst in vapor-phase oxidation of β-picoline to give nicotinic acid. It is shown that the conversion of β-picoline and the yield of nicotinic acid on two-component $ V_{2} $$ O_{5} $-$ TiO_{2} $, $ V_{2} $$ O_{5} $-$ SnO_{2} $, $ V_{2} $$ O_{5} $-$ ZtrO_{2} $, $ V_{2} $$ O_{5} $-$ Nb_{2} $$ O_{5} $, and $ V_{2} $$ O_{5} $-$ Al_{2} $$ O_{3} $ catalysts may be several times those on the $ V_{2} $$ O_{5} $ catalyst. It was found that, on passing from $ V_{2} $$ O_{5} $ to double-component vanadium-containing catalysts, the proton affinity of active oxygen bonded to vanadium, calculated by the quantum-chemical method, grows simultaneously with the increase in the activity of the catalysts in the oxidation reaction. © Pleiades Publishing, Ltd. 2014 |
| abstractGer |
Abstract Modification of $ V_{2} $$ O_{5} $ with Ti, Sn, Zr, Nb, and Al oxides improves the activity and selectivity of the vanadium oxide catalyst in vapor-phase oxidation of β-picoline to give nicotinic acid. It is shown that the conversion of β-picoline and the yield of nicotinic acid on two-component $ V_{2} $$ O_{5} $-$ TiO_{2} $, $ V_{2} $$ O_{5} $-$ SnO_{2} $, $ V_{2} $$ O_{5} $-$ ZtrO_{2} $, $ V_{2} $$ O_{5} $-$ Nb_{2} $$ O_{5} $, and $ V_{2} $$ O_{5} $-$ Al_{2} $$ O_{3} $ catalysts may be several times those on the $ V_{2} $$ O_{5} $ catalyst. It was found that, on passing from $ V_{2} $$ O_{5} $ to double-component vanadium-containing catalysts, the proton affinity of active oxygen bonded to vanadium, calculated by the quantum-chemical method, grows simultaneously with the increase in the activity of the catalysts in the oxidation reaction. © Pleiades Publishing, Ltd. 2014 |
| abstract_unstemmed |
Abstract Modification of $ V_{2} $$ O_{5} $ with Ti, Sn, Zr, Nb, and Al oxides improves the activity and selectivity of the vanadium oxide catalyst in vapor-phase oxidation of β-picoline to give nicotinic acid. It is shown that the conversion of β-picoline and the yield of nicotinic acid on two-component $ V_{2} $$ O_{5} $-$ TiO_{2} $, $ V_{2} $$ O_{5} $-$ SnO_{2} $, $ V_{2} $$ O_{5} $-$ ZtrO_{2} $, $ V_{2} $$ O_{5} $-$ Nb_{2} $$ O_{5} $, and $ V_{2} $$ O_{5} $-$ Al_{2} $$ O_{3} $ catalysts may be several times those on the $ V_{2} $$ O_{5} $ catalyst. It was found that, on passing from $ V_{2} $$ O_{5} $ to double-component vanadium-containing catalysts, the proton affinity of active oxygen bonded to vanadium, calculated by the quantum-chemical method, grows simultaneously with the increase in the activity of the catalysts in the oxidation reaction. © Pleiades Publishing, Ltd. 2014 |
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Vapor-phase oxidation of β-picoline to nicotinic acid on $ V_{2} $$ O_{5} $ and modified vanadium oxide catalysts |
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Saurambaeva, L. I. Mikhailovskaya, T. P. Yugay, O. K. Serebryanskaya, A. P. Shlygina, I. A. |
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