Some factors affecting hydrogenation of milk fat
Abstract Hydrogenation of milk fat with palladium and nickel as catalysts was studied at various temperatures, pressures, and concentrations of catalyst. Samples were removed from the laboratory hydrogenator at intervals during the reaction, and changes in refractive index, iodine value, Wiley mp, a...
Ausführliche Beschreibung
Autor*in: |
Smith, Lloyd M. [verfasserIn] |
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Artikel |
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Sprache: |
Englisch |
Erschienen: |
1974 |
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Anmerkung: |
© American Oil Chemists’ Society 1974 |
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Übergeordnetes Werk: |
Enthalten in: Journal of the American Oil Chemists’ Society - Springer-Verlag, 1947, 51(1974), 2 vom: Feb., Seite 26-30 |
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Übergeordnetes Werk: |
volume:51 ; year:1974 ; number:2 ; month:02 ; pages:26-30 |
Links: |
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DOI / URN: |
10.1007/BF02545209 |
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OLC2068049899 |
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10.1007/BF02545209 doi (DE-627)OLC2068049899 (DE-He213)BF02545209-p DE-627 ger DE-627 rakwb eng 660 VZ Smith, Lloyd M. verfasserin aut Some factors affecting hydrogenation of milk fat 1974 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © American Oil Chemists’ Society 1974 Abstract Hydrogenation of milk fat with palladium and nickel as catalysts was studied at various temperatures, pressures, and concentrations of catalyst. Samples were removed from the laboratory hydrogenator at intervals during the reaction, and changes in refractive index, iodine value, Wiley mp, and percentages of fatty acids andtrans-isomers were determined. Palladium was several times more active as a catalyst than nickel. Milk fat with an iodine value of 35 and mp of 34 C was hydrogenated with 0.05% palladium to an iodine value of 6 and a mp of 46 C in 30 min at 66 C and 53 psi of hydrogen. Kinetic data for each catalyst yielded two slopes, indicating that a change in reaction rate occurred. Palladium Nickel Catalyst Iodine Value Palladium Catalyst Raney Nickel Vasconcellos, Andres aut Enthalten in Journal of the American Oil Chemists’ Society Springer-Verlag, 1947 51(1974), 2 vom: Feb., Seite 26-30 (DE-627)129595691 (DE-600)240684-6 (DE-576)015088715 0003-021X nnns volume:51 year:1974 number:2 month:02 pages:26-30 https://doi.org/10.1007/BF02545209 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_26 GBV_ILN_40 GBV_ILN_70 GBV_ILN_2360 GBV_ILN_4012 GBV_ILN_4036 GBV_ILN_4046 GBV_ILN_4125 GBV_ILN_4219 GBV_ILN_4306 GBV_ILN_4315 AR 51 1974 2 02 26-30 |
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10.1007/BF02545209 doi (DE-627)OLC2068049899 (DE-He213)BF02545209-p DE-627 ger DE-627 rakwb eng 660 VZ Smith, Lloyd M. verfasserin aut Some factors affecting hydrogenation of milk fat 1974 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © American Oil Chemists’ Society 1974 Abstract Hydrogenation of milk fat with palladium and nickel as catalysts was studied at various temperatures, pressures, and concentrations of catalyst. Samples were removed from the laboratory hydrogenator at intervals during the reaction, and changes in refractive index, iodine value, Wiley mp, and percentages of fatty acids andtrans-isomers were determined. Palladium was several times more active as a catalyst than nickel. Milk fat with an iodine value of 35 and mp of 34 C was hydrogenated with 0.05% palladium to an iodine value of 6 and a mp of 46 C in 30 min at 66 C and 53 psi of hydrogen. Kinetic data for each catalyst yielded two slopes, indicating that a change in reaction rate occurred. Palladium Nickel Catalyst Iodine Value Palladium Catalyst Raney Nickel Vasconcellos, Andres aut Enthalten in Journal of the American Oil Chemists’ Society Springer-Verlag, 1947 51(1974), 2 vom: Feb., Seite 26-30 (DE-627)129595691 (DE-600)240684-6 (DE-576)015088715 0003-021X nnns volume:51 year:1974 number:2 month:02 pages:26-30 https://doi.org/10.1007/BF02545209 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_26 GBV_ILN_40 GBV_ILN_70 GBV_ILN_2360 GBV_ILN_4012 GBV_ILN_4036 GBV_ILN_4046 GBV_ILN_4125 GBV_ILN_4219 GBV_ILN_4306 GBV_ILN_4315 AR 51 1974 2 02 26-30 |
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10.1007/BF02545209 doi (DE-627)OLC2068049899 (DE-He213)BF02545209-p DE-627 ger DE-627 rakwb eng 660 VZ Smith, Lloyd M. verfasserin aut Some factors affecting hydrogenation of milk fat 1974 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © American Oil Chemists’ Society 1974 Abstract Hydrogenation of milk fat with palladium and nickel as catalysts was studied at various temperatures, pressures, and concentrations of catalyst. Samples were removed from the laboratory hydrogenator at intervals during the reaction, and changes in refractive index, iodine value, Wiley mp, and percentages of fatty acids andtrans-isomers were determined. Palladium was several times more active as a catalyst than nickel. Milk fat with an iodine value of 35 and mp of 34 C was hydrogenated with 0.05% palladium to an iodine value of 6 and a mp of 46 C in 30 min at 66 C and 53 psi of hydrogen. Kinetic data for each catalyst yielded two slopes, indicating that a change in reaction rate occurred. Palladium Nickel Catalyst Iodine Value Palladium Catalyst Raney Nickel Vasconcellos, Andres aut Enthalten in Journal of the American Oil Chemists’ Society Springer-Verlag, 1947 51(1974), 2 vom: Feb., Seite 26-30 (DE-627)129595691 (DE-600)240684-6 (DE-576)015088715 0003-021X nnns volume:51 year:1974 number:2 month:02 pages:26-30 https://doi.org/10.1007/BF02545209 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_26 GBV_ILN_40 GBV_ILN_70 GBV_ILN_2360 GBV_ILN_4012 GBV_ILN_4036 GBV_ILN_4046 GBV_ILN_4125 GBV_ILN_4219 GBV_ILN_4306 GBV_ILN_4315 AR 51 1974 2 02 26-30 |
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10.1007/BF02545209 doi (DE-627)OLC2068049899 (DE-He213)BF02545209-p DE-627 ger DE-627 rakwb eng 660 VZ Smith, Lloyd M. verfasserin aut Some factors affecting hydrogenation of milk fat 1974 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © American Oil Chemists’ Society 1974 Abstract Hydrogenation of milk fat with palladium and nickel as catalysts was studied at various temperatures, pressures, and concentrations of catalyst. Samples were removed from the laboratory hydrogenator at intervals during the reaction, and changes in refractive index, iodine value, Wiley mp, and percentages of fatty acids andtrans-isomers were determined. Palladium was several times more active as a catalyst than nickel. Milk fat with an iodine value of 35 and mp of 34 C was hydrogenated with 0.05% palladium to an iodine value of 6 and a mp of 46 C in 30 min at 66 C and 53 psi of hydrogen. Kinetic data for each catalyst yielded two slopes, indicating that a change in reaction rate occurred. Palladium Nickel Catalyst Iodine Value Palladium Catalyst Raney Nickel Vasconcellos, Andres aut Enthalten in Journal of the American Oil Chemists’ Society Springer-Verlag, 1947 51(1974), 2 vom: Feb., Seite 26-30 (DE-627)129595691 (DE-600)240684-6 (DE-576)015088715 0003-021X nnns volume:51 year:1974 number:2 month:02 pages:26-30 https://doi.org/10.1007/BF02545209 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_26 GBV_ILN_40 GBV_ILN_70 GBV_ILN_2360 GBV_ILN_4012 GBV_ILN_4036 GBV_ILN_4046 GBV_ILN_4125 GBV_ILN_4219 GBV_ILN_4306 GBV_ILN_4315 AR 51 1974 2 02 26-30 |
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10.1007/BF02545209 doi (DE-627)OLC2068049899 (DE-He213)BF02545209-p DE-627 ger DE-627 rakwb eng 660 VZ Smith, Lloyd M. verfasserin aut Some factors affecting hydrogenation of milk fat 1974 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © American Oil Chemists’ Society 1974 Abstract Hydrogenation of milk fat with palladium and nickel as catalysts was studied at various temperatures, pressures, and concentrations of catalyst. Samples were removed from the laboratory hydrogenator at intervals during the reaction, and changes in refractive index, iodine value, Wiley mp, and percentages of fatty acids andtrans-isomers were determined. Palladium was several times more active as a catalyst than nickel. Milk fat with an iodine value of 35 and mp of 34 C was hydrogenated with 0.05% palladium to an iodine value of 6 and a mp of 46 C in 30 min at 66 C and 53 psi of hydrogen. Kinetic data for each catalyst yielded two slopes, indicating that a change in reaction rate occurred. Palladium Nickel Catalyst Iodine Value Palladium Catalyst Raney Nickel Vasconcellos, Andres aut Enthalten in Journal of the American Oil Chemists’ Society Springer-Verlag, 1947 51(1974), 2 vom: Feb., Seite 26-30 (DE-627)129595691 (DE-600)240684-6 (DE-576)015088715 0003-021X nnns volume:51 year:1974 number:2 month:02 pages:26-30 https://doi.org/10.1007/BF02545209 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_26 GBV_ILN_40 GBV_ILN_70 GBV_ILN_2360 GBV_ILN_4012 GBV_ILN_4036 GBV_ILN_4046 GBV_ILN_4125 GBV_ILN_4219 GBV_ILN_4306 GBV_ILN_4315 AR 51 1974 2 02 26-30 |
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Abstract Hydrogenation of milk fat with palladium and nickel as catalysts was studied at various temperatures, pressures, and concentrations of catalyst. Samples were removed from the laboratory hydrogenator at intervals during the reaction, and changes in refractive index, iodine value, Wiley mp, and percentages of fatty acids andtrans-isomers were determined. Palladium was several times more active as a catalyst than nickel. Milk fat with an iodine value of 35 and mp of 34 C was hydrogenated with 0.05% palladium to an iodine value of 6 and a mp of 46 C in 30 min at 66 C and 53 psi of hydrogen. Kinetic data for each catalyst yielded two slopes, indicating that a change in reaction rate occurred. © American Oil Chemists’ Society 1974 |
abstractGer |
Abstract Hydrogenation of milk fat with palladium and nickel as catalysts was studied at various temperatures, pressures, and concentrations of catalyst. Samples were removed from the laboratory hydrogenator at intervals during the reaction, and changes in refractive index, iodine value, Wiley mp, and percentages of fatty acids andtrans-isomers were determined. Palladium was several times more active as a catalyst than nickel. Milk fat with an iodine value of 35 and mp of 34 C was hydrogenated with 0.05% palladium to an iodine value of 6 and a mp of 46 C in 30 min at 66 C and 53 psi of hydrogen. Kinetic data for each catalyst yielded two slopes, indicating that a change in reaction rate occurred. © American Oil Chemists’ Society 1974 |
abstract_unstemmed |
Abstract Hydrogenation of milk fat with palladium and nickel as catalysts was studied at various temperatures, pressures, and concentrations of catalyst. Samples were removed from the laboratory hydrogenator at intervals during the reaction, and changes in refractive index, iodine value, Wiley mp, and percentages of fatty acids andtrans-isomers were determined. Palladium was several times more active as a catalyst than nickel. Milk fat with an iodine value of 35 and mp of 34 C was hydrogenated with 0.05% palladium to an iodine value of 6 and a mp of 46 C in 30 min at 66 C and 53 psi of hydrogen. Kinetic data for each catalyst yielded two slopes, indicating that a change in reaction rate occurred. © American Oil Chemists’ Society 1974 |
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title_short |
Some factors affecting hydrogenation of milk fat |
url |
https://doi.org/10.1007/BF02545209 |
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Vasconcellos, Andres |
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