Cluster self-organization of silicate and germanate systems: Invariant suprapolyhedral cluster precursors and self-assembly of the crystal structures of Li,TR silicates (germanates)

Abstract The initial stages of formation of suprapolyhedral clusters (containing polyhedra of different types) in an evolving chemical system are considered. The suprapolyhedral clusters of the chain and cyclic types are used for modeling two-dimensional periodic structures. The developed model is u...
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Autor*in:	Ilyushin, G. D. [verfasserIn] Dem’yanets, L. N.

Format:	Artikel
Sprache:	Englisch

Erschienen:	2008

Anmerkung:	© Pleiades Publishing, Ltd. 2008

Übergeordnetes Werk:	Enthalten in: Crystallography reports - SP MAIK Nauka/Interperiodica, 1993, 53(2008), 3 vom: Mai, Seite 365-378
Übergeordnetes Werk:	volume:53 ; year:2008 ; number:3 ; month:05 ; pages:365-378

Links:	Volltext

DOI / URN:	10.1134/S1063774508030024

Katalog-ID:	OLC2070252612

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allfields	10.1134/S1063774508030024 doi (DE-627)OLC2070252612 (DE-He213)S1063774508030024-p DE-627 ger DE-627 rakwb eng 540 530 VZ Ilyushin, G. D. verfasserin aut Cluster self-organization of silicate and germanate systems: Invariant suprapolyhedral cluster precursors and self-assembly of the crystal structures of Li,TR silicates (germanates) 2008 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2008 Abstract The initial stages of formation of suprapolyhedral clusters (containing polyhedra of different types) in an evolving chemical system are considered. The suprapolyhedral clusters of the chain and cyclic types are used for modeling two-dimensional periodic structures. The developed model is used to search for cluster precursors in the structures of Li,TR silicates (germanates) of the known structure types. The complete threedimensional reconstruction of the self-assembly of Li,TR silicates (germanates) is performed using computer methods (with the TOPOS program package) according to the following scheme: cluster precursor → primary chain → microlayer → microframework (supraprecursor) → … framework. Two types of invariant cyclic cluster precursors composed of the TR polyhedra linked by tetrahedra and the TR polyhedra joined by diorthotetrahedra are identified in five and two structures, respectively. It is revealed that the lithium atoms are located at the centers of all clusters. New types of two-dimensional nets with a hierarchical structure formed as a result of the packing of cyclic four-, six-, and eight-node clusters are described. Dem’yanets, L. N. aut Enthalten in Crystallography reports SP MAIK Nauka/Interperiodica, 1993 53(2008), 3 vom: Mai, Seite 365-378 (DE-627)171187822 (DE-600)1162973-3 (DE-576)038500337 1063-7745 nnns volume:53 year:2008 number:3 month:05 pages:365-378 https://doi.org/10.1134/S1063774508030024 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_21 GBV_ILN_22 GBV_ILN_30 GBV_ILN_40 GBV_ILN_70 AR 53 2008 3 05 365-378
spelling	10.1134/S1063774508030024 doi (DE-627)OLC2070252612 (DE-He213)S1063774508030024-p DE-627 ger DE-627 rakwb eng 540 530 VZ Ilyushin, G. D. verfasserin aut Cluster self-organization of silicate and germanate systems: Invariant suprapolyhedral cluster precursors and self-assembly of the crystal structures of Li,TR silicates (germanates) 2008 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2008 Abstract The initial stages of formation of suprapolyhedral clusters (containing polyhedra of different types) in an evolving chemical system are considered. The suprapolyhedral clusters of the chain and cyclic types are used for modeling two-dimensional periodic structures. The developed model is used to search for cluster precursors in the structures of Li,TR silicates (germanates) of the known structure types. The complete threedimensional reconstruction of the self-assembly of Li,TR silicates (germanates) is performed using computer methods (with the TOPOS program package) according to the following scheme: cluster precursor → primary chain → microlayer → microframework (supraprecursor) → … framework. Two types of invariant cyclic cluster precursors composed of the TR polyhedra linked by tetrahedra and the TR polyhedra joined by diorthotetrahedra are identified in five and two structures, respectively. It is revealed that the lithium atoms are located at the centers of all clusters. New types of two-dimensional nets with a hierarchical structure formed as a result of the packing of cyclic four-, six-, and eight-node clusters are described. Dem’yanets, L. N. aut Enthalten in Crystallography reports SP MAIK Nauka/Interperiodica, 1993 53(2008), 3 vom: Mai, Seite 365-378 (DE-627)171187822 (DE-600)1162973-3 (DE-576)038500337 1063-7745 nnns volume:53 year:2008 number:3 month:05 pages:365-378 https://doi.org/10.1134/S1063774508030024 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_21 GBV_ILN_22 GBV_ILN_30 GBV_ILN_40 GBV_ILN_70 AR 53 2008 3 05 365-378
allfields_unstemmed	10.1134/S1063774508030024 doi (DE-627)OLC2070252612 (DE-He213)S1063774508030024-p DE-627 ger DE-627 rakwb eng 540 530 VZ Ilyushin, G. D. verfasserin aut Cluster self-organization of silicate and germanate systems: Invariant suprapolyhedral cluster precursors and self-assembly of the crystal structures of Li,TR silicates (germanates) 2008 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2008 Abstract The initial stages of formation of suprapolyhedral clusters (containing polyhedra of different types) in an evolving chemical system are considered. The suprapolyhedral clusters of the chain and cyclic types are used for modeling two-dimensional periodic structures. The developed model is used to search for cluster precursors in the structures of Li,TR silicates (germanates) of the known structure types. The complete threedimensional reconstruction of the self-assembly of Li,TR silicates (germanates) is performed using computer methods (with the TOPOS program package) according to the following scheme: cluster precursor → primary chain → microlayer → microframework (supraprecursor) → … framework. Two types of invariant cyclic cluster precursors composed of the TR polyhedra linked by tetrahedra and the TR polyhedra joined by diorthotetrahedra are identified in five and two structures, respectively. It is revealed that the lithium atoms are located at the centers of all clusters. New types of two-dimensional nets with a hierarchical structure formed as a result of the packing of cyclic four-, six-, and eight-node clusters are described. Dem’yanets, L. N. aut Enthalten in Crystallography reports SP MAIK Nauka/Interperiodica, 1993 53(2008), 3 vom: Mai, Seite 365-378 (DE-627)171187822 (DE-600)1162973-3 (DE-576)038500337 1063-7745 nnns volume:53 year:2008 number:3 month:05 pages:365-378 https://doi.org/10.1134/S1063774508030024 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_21 GBV_ILN_22 GBV_ILN_30 GBV_ILN_40 GBV_ILN_70 AR 53 2008 3 05 365-378
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title	Cluster self-organization of silicate and germanate systems: Invariant suprapolyhedral cluster precursors and self-assembly of the crystal structures of Li,TR silicates (germanates)
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title_sort	cluster self-organization of silicate and germanate systems: invariant suprapolyhedral cluster precursors and self-assembly of the crystal structures of li,tr silicates (germanates)
title_auth	Cluster self-organization of silicate and germanate systems: Invariant suprapolyhedral cluster precursors and self-assembly of the crystal structures of Li,TR silicates (germanates)
abstract	Abstract The initial stages of formation of suprapolyhedral clusters (containing polyhedra of different types) in an evolving chemical system are considered. The suprapolyhedral clusters of the chain and cyclic types are used for modeling two-dimensional periodic structures. The developed model is used to search for cluster precursors in the structures of Li,TR silicates (germanates) of the known structure types. The complete threedimensional reconstruction of the self-assembly of Li,TR silicates (germanates) is performed using computer methods (with the TOPOS program package) according to the following scheme: cluster precursor → primary chain → microlayer → microframework (supraprecursor) → … framework. Two types of invariant cyclic cluster precursors composed of the TR polyhedra linked by tetrahedra and the TR polyhedra joined by diorthotetrahedra are identified in five and two structures, respectively. It is revealed that the lithium atoms are located at the centers of all clusters. New types of two-dimensional nets with a hierarchical structure formed as a result of the packing of cyclic four-, six-, and eight-node clusters are described. © Pleiades Publishing, Ltd. 2008
abstractGer	Abstract The initial stages of formation of suprapolyhedral clusters (containing polyhedra of different types) in an evolving chemical system are considered. The suprapolyhedral clusters of the chain and cyclic types are used for modeling two-dimensional periodic structures. The developed model is used to search for cluster precursors in the structures of Li,TR silicates (germanates) of the known structure types. The complete threedimensional reconstruction of the self-assembly of Li,TR silicates (germanates) is performed using computer methods (with the TOPOS program package) according to the following scheme: cluster precursor → primary chain → microlayer → microframework (supraprecursor) → … framework. Two types of invariant cyclic cluster precursors composed of the TR polyhedra linked by tetrahedra and the TR polyhedra joined by diorthotetrahedra are identified in five and two structures, respectively. It is revealed that the lithium atoms are located at the centers of all clusters. New types of two-dimensional nets with a hierarchical structure formed as a result of the packing of cyclic four-, six-, and eight-node clusters are described. © Pleiades Publishing, Ltd. 2008
abstract_unstemmed	Abstract The initial stages of formation of suprapolyhedral clusters (containing polyhedra of different types) in an evolving chemical system are considered. The suprapolyhedral clusters of the chain and cyclic types are used for modeling two-dimensional periodic structures. The developed model is used to search for cluster precursors in the structures of Li,TR silicates (germanates) of the known structure types. The complete threedimensional reconstruction of the self-assembly of Li,TR silicates (germanates) is performed using computer methods (with the TOPOS program package) according to the following scheme: cluster precursor → primary chain → microlayer → microframework (supraprecursor) → … framework. Two types of invariant cyclic cluster precursors composed of the TR polyhedra linked by tetrahedra and the TR polyhedra joined by diorthotetrahedra are identified in five and two structures, respectively. It is revealed that the lithium atoms are located at the centers of all clusters. New types of two-dimensional nets with a hierarchical structure formed as a result of the packing of cyclic four-, six-, and eight-node clusters are described. © Pleiades Publishing, Ltd. 2008
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title_short	Cluster self-organization of silicate and germanate systems: Invariant suprapolyhedral cluster precursors and self-assembly of the crystal structures of Li,TR silicates (germanates)
url	https://doi.org/10.1134/S1063774508030024
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author2	Dem’yanets, L. N.
author2Str	Dem’yanets, L. N.
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doi_str	10.1134/S1063774508030024
up_date	2024-07-04T00:43:37.998Z
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Cluster self-organization of silicate and germanate systems: Invariant suprapolyhedral cluster precursors and self-assembly of the crystal structures of Li,TR silicates (germanates)

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