Heterobinuclear and heterotrinuclear transition-metal μ-allenyl complexes
Abstract Binuclear and trinuclear transition-metal μ-allenyl complexes—especially mixedmetal complexes—are reviewed. In recent years, a number of such compounds have been prepared by use of several synthetic methods. The most general of these methods, viz. reactions of metal propargyls and of the lo...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Wojcicki, Andrew [verfasserIn] |
|---|
| Format: |
Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
1993 |
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| Anmerkung: |
© Plenum Publishing Corporation 1993 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of cluster science - Kluwer Academic Publishers-Plenum Publishers, 1990, 4(1993), 1 vom: März, Seite 59-75 |
|---|---|
| Übergeordnetes Werk: |
volume:4 ; year:1993 ; number:1 ; month:03 ; pages:59-75 |
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| DOI / URN: |
10.1007/BF01028385 |
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| 520 | |a Abstract Binuclear and trinuclear transition-metal μ-allenyl complexes—especially mixedmetal complexes—are reviewed. In recent years, a number of such compounds have been prepared by use of several synthetic methods. The most general of these methods, viz. reactions of metal propargyls and of the lower nuclearity metal allenyls with low-valent metal complexes such as metal carbonyls and platinum(0) compounds, are considered in some detail. The structures of the binuclear metal μ-$ η^{1} $,$ η^{2} $- and μ-$ η^{3} $,$ η^{2} $-allenyl complexes and of the trinuclear metal $ μ_{3} $-$ η^{1} $,$ η^{2} $,$ η^{2} $-allenyl complexes—both triangular and open—are presented and compared. Trends in $ the^{1} $H $ and^{13} $C NMR spectroscopic properties of these compounds are examined. Some aspects of reaction chemistry of the heteronuclear platinum-ruthenium μ-$ η^{1} $,$ η^{2} $-allenyl complexes are presented. | ||
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10.1007/BF01028385 doi (DE-627)OLC2072647185 (DE-He213)BF01028385-p DE-627 ger DE-627 rakwb eng 500 VZ 11 ssgn Wojcicki, Andrew verfasserin aut Heterobinuclear and heterotrinuclear transition-metal μ-allenyl complexes 1993 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Plenum Publishing Corporation 1993 Abstract Binuclear and trinuclear transition-metal μ-allenyl complexes—especially mixedmetal complexes—are reviewed. In recent years, a number of such compounds have been prepared by use of several synthetic methods. The most general of these methods, viz. reactions of metal propargyls and of the lower nuclearity metal allenyls with low-valent metal complexes such as metal carbonyls and platinum(0) compounds, are considered in some detail. The structures of the binuclear metal μ-$ η^{1} $,$ η^{2} $- and μ-$ η^{3} $,$ η^{2} $-allenyl complexes and of the trinuclear metal $ μ_{3} $-$ η^{1} $,$ η^{2} $,$ η^{2} $-allenyl complexes—both triangular and open—are presented and compared. Trends in $ the^{1} $H $ and^{13} $C NMR spectroscopic properties of these compounds are examined. Some aspects of reaction chemistry of the heteronuclear platinum-ruthenium μ-$ η^{1} $,$ η^{2} $-allenyl complexes are presented. Enthalten in Journal of cluster science Kluwer Academic Publishers-Plenum Publishers, 1990 4(1993), 1 vom: März, Seite 59-75 (DE-627)130895687 (DE-600)1042216-X (DE-576)023130083 1040-7278 nnns volume:4 year:1993 number:1 month:03 pages:59-75 https://doi.org/10.1007/BF01028385 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-MAT GBV_ILN_40 GBV_ILN_70 GBV_ILN_4012 AR 4 1993 1 03 59-75 |
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10.1007/BF01028385 doi (DE-627)OLC2072647185 (DE-He213)BF01028385-p DE-627 ger DE-627 rakwb eng 500 VZ 11 ssgn Wojcicki, Andrew verfasserin aut Heterobinuclear and heterotrinuclear transition-metal μ-allenyl complexes 1993 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Plenum Publishing Corporation 1993 Abstract Binuclear and trinuclear transition-metal μ-allenyl complexes—especially mixedmetal complexes—are reviewed. In recent years, a number of such compounds have been prepared by use of several synthetic methods. The most general of these methods, viz. reactions of metal propargyls and of the lower nuclearity metal allenyls with low-valent metal complexes such as metal carbonyls and platinum(0) compounds, are considered in some detail. The structures of the binuclear metal μ-$ η^{1} $,$ η^{2} $- and μ-$ η^{3} $,$ η^{2} $-allenyl complexes and of the trinuclear metal $ μ_{3} $-$ η^{1} $,$ η^{2} $,$ η^{2} $-allenyl complexes—both triangular and open—are presented and compared. Trends in $ the^{1} $H $ and^{13} $C NMR spectroscopic properties of these compounds are examined. Some aspects of reaction chemistry of the heteronuclear platinum-ruthenium μ-$ η^{1} $,$ η^{2} $-allenyl complexes are presented. Enthalten in Journal of cluster science Kluwer Academic Publishers-Plenum Publishers, 1990 4(1993), 1 vom: März, Seite 59-75 (DE-627)130895687 (DE-600)1042216-X (DE-576)023130083 1040-7278 nnns volume:4 year:1993 number:1 month:03 pages:59-75 https://doi.org/10.1007/BF01028385 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-MAT GBV_ILN_40 GBV_ILN_70 GBV_ILN_4012 AR 4 1993 1 03 59-75 |
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10.1007/BF01028385 doi (DE-627)OLC2072647185 (DE-He213)BF01028385-p DE-627 ger DE-627 rakwb eng 500 VZ 11 ssgn Wojcicki, Andrew verfasserin aut Heterobinuclear and heterotrinuclear transition-metal μ-allenyl complexes 1993 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Plenum Publishing Corporation 1993 Abstract Binuclear and trinuclear transition-metal μ-allenyl complexes—especially mixedmetal complexes—are reviewed. In recent years, a number of such compounds have been prepared by use of several synthetic methods. The most general of these methods, viz. reactions of metal propargyls and of the lower nuclearity metal allenyls with low-valent metal complexes such as metal carbonyls and platinum(0) compounds, are considered in some detail. The structures of the binuclear metal μ-$ η^{1} $,$ η^{2} $- and μ-$ η^{3} $,$ η^{2} $-allenyl complexes and of the trinuclear metal $ μ_{3} $-$ η^{1} $,$ η^{2} $,$ η^{2} $-allenyl complexes—both triangular and open—are presented and compared. Trends in $ the^{1} $H $ and^{13} $C NMR spectroscopic properties of these compounds are examined. Some aspects of reaction chemistry of the heteronuclear platinum-ruthenium μ-$ η^{1} $,$ η^{2} $-allenyl complexes are presented. Enthalten in Journal of cluster science Kluwer Academic Publishers-Plenum Publishers, 1990 4(1993), 1 vom: März, Seite 59-75 (DE-627)130895687 (DE-600)1042216-X (DE-576)023130083 1040-7278 nnns volume:4 year:1993 number:1 month:03 pages:59-75 https://doi.org/10.1007/BF01028385 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-MAT GBV_ILN_40 GBV_ILN_70 GBV_ILN_4012 AR 4 1993 1 03 59-75 |
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10.1007/BF01028385 doi (DE-627)OLC2072647185 (DE-He213)BF01028385-p DE-627 ger DE-627 rakwb eng 500 VZ 11 ssgn Wojcicki, Andrew verfasserin aut Heterobinuclear and heterotrinuclear transition-metal μ-allenyl complexes 1993 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Plenum Publishing Corporation 1993 Abstract Binuclear and trinuclear transition-metal μ-allenyl complexes—especially mixedmetal complexes—are reviewed. In recent years, a number of such compounds have been prepared by use of several synthetic methods. The most general of these methods, viz. reactions of metal propargyls and of the lower nuclearity metal allenyls with low-valent metal complexes such as metal carbonyls and platinum(0) compounds, are considered in some detail. The structures of the binuclear metal μ-$ η^{1} $,$ η^{2} $- and μ-$ η^{3} $,$ η^{2} $-allenyl complexes and of the trinuclear metal $ μ_{3} $-$ η^{1} $,$ η^{2} $,$ η^{2} $-allenyl complexes—both triangular and open—are presented and compared. Trends in $ the^{1} $H $ and^{13} $C NMR spectroscopic properties of these compounds are examined. Some aspects of reaction chemistry of the heteronuclear platinum-ruthenium μ-$ η^{1} $,$ η^{2} $-allenyl complexes are presented. Enthalten in Journal of cluster science Kluwer Academic Publishers-Plenum Publishers, 1990 4(1993), 1 vom: März, Seite 59-75 (DE-627)130895687 (DE-600)1042216-X (DE-576)023130083 1040-7278 nnns volume:4 year:1993 number:1 month:03 pages:59-75 https://doi.org/10.1007/BF01028385 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-MAT GBV_ILN_40 GBV_ILN_70 GBV_ILN_4012 AR 4 1993 1 03 59-75 |
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10.1007/BF01028385 doi (DE-627)OLC2072647185 (DE-He213)BF01028385-p DE-627 ger DE-627 rakwb eng 500 VZ 11 ssgn Wojcicki, Andrew verfasserin aut Heterobinuclear and heterotrinuclear transition-metal μ-allenyl complexes 1993 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Plenum Publishing Corporation 1993 Abstract Binuclear and trinuclear transition-metal μ-allenyl complexes—especially mixedmetal complexes—are reviewed. In recent years, a number of such compounds have been prepared by use of several synthetic methods. The most general of these methods, viz. reactions of metal propargyls and of the lower nuclearity metal allenyls with low-valent metal complexes such as metal carbonyls and platinum(0) compounds, are considered in some detail. The structures of the binuclear metal μ-$ η^{1} $,$ η^{2} $- and μ-$ η^{3} $,$ η^{2} $-allenyl complexes and of the trinuclear metal $ μ_{3} $-$ η^{1} $,$ η^{2} $,$ η^{2} $-allenyl complexes—both triangular and open—are presented and compared. Trends in $ the^{1} $H $ and^{13} $C NMR spectroscopic properties of these compounds are examined. Some aspects of reaction chemistry of the heteronuclear platinum-ruthenium μ-$ η^{1} $,$ η^{2} $-allenyl complexes are presented. Enthalten in Journal of cluster science Kluwer Academic Publishers-Plenum Publishers, 1990 4(1993), 1 vom: März, Seite 59-75 (DE-627)130895687 (DE-600)1042216-X (DE-576)023130083 1040-7278 nnns volume:4 year:1993 number:1 month:03 pages:59-75 https://doi.org/10.1007/BF01028385 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-MAT GBV_ILN_40 GBV_ILN_70 GBV_ILN_4012 AR 4 1993 1 03 59-75 |
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Abstract Binuclear and trinuclear transition-metal μ-allenyl complexes—especially mixedmetal complexes—are reviewed. In recent years, a number of such compounds have been prepared by use of several synthetic methods. The most general of these methods, viz. reactions of metal propargyls and of the lower nuclearity metal allenyls with low-valent metal complexes such as metal carbonyls and platinum(0) compounds, are considered in some detail. The structures of the binuclear metal μ-$ η^{1} $,$ η^{2} $- and μ-$ η^{3} $,$ η^{2} $-allenyl complexes and of the trinuclear metal $ μ_{3} $-$ η^{1} $,$ η^{2} $,$ η^{2} $-allenyl complexes—both triangular and open—are presented and compared. Trends in $ the^{1} $H $ and^{13} $C NMR spectroscopic properties of these compounds are examined. Some aspects of reaction chemistry of the heteronuclear platinum-ruthenium μ-$ η^{1} $,$ η^{2} $-allenyl complexes are presented. © Plenum Publishing Corporation 1993 |
| abstractGer |
Abstract Binuclear and trinuclear transition-metal μ-allenyl complexes—especially mixedmetal complexes—are reviewed. In recent years, a number of such compounds have been prepared by use of several synthetic methods. The most general of these methods, viz. reactions of metal propargyls and of the lower nuclearity metal allenyls with low-valent metal complexes such as metal carbonyls and platinum(0) compounds, are considered in some detail. The structures of the binuclear metal μ-$ η^{1} $,$ η^{2} $- and μ-$ η^{3} $,$ η^{2} $-allenyl complexes and of the trinuclear metal $ μ_{3} $-$ η^{1} $,$ η^{2} $,$ η^{2} $-allenyl complexes—both triangular and open—are presented and compared. Trends in $ the^{1} $H $ and^{13} $C NMR spectroscopic properties of these compounds are examined. Some aspects of reaction chemistry of the heteronuclear platinum-ruthenium μ-$ η^{1} $,$ η^{2} $-allenyl complexes are presented. © Plenum Publishing Corporation 1993 |
| abstract_unstemmed |
Abstract Binuclear and trinuclear transition-metal μ-allenyl complexes—especially mixedmetal complexes—are reviewed. In recent years, a number of such compounds have been prepared by use of several synthetic methods. The most general of these methods, viz. reactions of metal propargyls and of the lower nuclearity metal allenyls with low-valent metal complexes such as metal carbonyls and platinum(0) compounds, are considered in some detail. The structures of the binuclear metal μ-$ η^{1} $,$ η^{2} $- and μ-$ η^{3} $,$ η^{2} $-allenyl complexes and of the trinuclear metal $ μ_{3} $-$ η^{1} $,$ η^{2} $,$ η^{2} $-allenyl complexes—both triangular and open—are presented and compared. Trends in $ the^{1} $H $ and^{13} $C NMR spectroscopic properties of these compounds are examined. Some aspects of reaction chemistry of the heteronuclear platinum-ruthenium μ-$ η^{1} $,$ η^{2} $-allenyl complexes are presented. © Plenum Publishing Corporation 1993 |
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