Three Iodobismuthates Hybrids Displaying Mono-nuclear, Dimer and 1-D Arrangements Templated by 1,4-diazabicyclo[2.2.2]octane Derivatives: Semiconductor and Photocurrent Response Properties
Abstract The structures, semiconductor and photocurrent response properties of three 1,4-diazabicyclo[2.2.2]octane derivative-templated iodobismuthates, ($ Et_{2} $DABCO)3($ BiI_{6} $)2 (1), (i-$ Pr_{2} $DABCO)2($ Bi_{2} $$ I_{10} $) (2), [($ Me_{2} $DABCO)2($ Bi_{2} $$ I_{10} $)2]n (3) ($ Et_{2} $$...
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| Autor*in: |
Zhang, Zhao-Pei [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2018 |
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| Anmerkung: |
© Springer Science+Business Media, LLC, part of Springer Nature 2018 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of cluster science - Springer US, 1990, 29(2018), 4 vom: 18. Mai, Seite 725-735 |
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| Übergeordnetes Werk: |
volume:29 ; year:2018 ; number:4 ; day:18 ; month:05 ; pages:725-735 |
| Links: |
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| DOI / URN: |
10.1007/s10876-018-1397-z |
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| Katalog-ID: |
OLC2072664799 |
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| 245 | 1 | 0 | |a Three Iodobismuthates Hybrids Displaying Mono-nuclear, Dimer and 1-D Arrangements Templated by 1,4-diazabicyclo[2.2.2]octane Derivatives: Semiconductor and Photocurrent Response Properties |
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| 520 | |a Abstract The structures, semiconductor and photocurrent response properties of three 1,4-diazabicyclo[2.2.2]octane derivative-templated iodobismuthates, ($ Et_{2} $DABCO)3($ BiI_{6} $)2 (1), (i-$ Pr_{2} $DABCO)2($ Bi_{2} $$ I_{10} $) (2), [($ Me_{2} $DABCO)2($ Bi_{2} $$ I_{10} $)2]n (3) ($ Et_{2} $$ DABCO^{2+} $ = N,N′-diethyl-1,4-diazabicyclo[2.2.2] octane, i-$ Pr_{2} $$ DABCO^{2+} $ = N,N′-diisoproyl-1,4-diazabicyclo[2.2.2] octane, $ Me_{2} $$ DABCO^{2+} $ = N,N′-dimethyl-1,4-diazabicyclo[2.2.2] octane), are reported. Based on the templates with different substitutents on 1,4-diazabicyclo[2.2.2]octane, mono-nuclear (($ BiI_{6} $)3− for 1), dimer (($ Bi_{2} $$ I_{10} $)4− for 2) and 1-D chain (($ BiI_{5} $)n2n− for 3) can be obtained. C-H···I hydrogen bonds contribute to the structural extension to 2-D layer (for 2) and 3-D network (for 3). Their absorption spectra were investigated, and energy band gaps of 2.24/1.73/1.44 eV indicate their narrow-gap semiconductor natures. Their photocurrent response properties were also discussed. Finally, theoretical calculation was executed to give structure-properties correlation. | ||
| 650 | 4 | |a Organic–inorganic hybrid | |
| 650 | 4 | |a Iodobismuthates | |
| 650 | 4 | |a Photocurrent response | |
| 700 | 1 | |a Feng, Qi-Yan |4 aut | |
| 700 | 1 | |a Wei, Yan-Li |4 aut | |
| 700 | 1 | |a Gao, Zhi-Ying |4 aut | |
| 700 | 1 | |a Wang, Zhi-Wei |4 aut | |
| 700 | 1 | |a Wang, Ying-Mei |4 aut | |
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10.1007/s10876-018-1397-z doi (DE-627)OLC2072664799 (DE-He213)s10876-018-1397-z-p DE-627 ger DE-627 rakwb eng 500 VZ 11 ssgn Zhang, Zhao-Pei verfasserin aut Three Iodobismuthates Hybrids Displaying Mono-nuclear, Dimer and 1-D Arrangements Templated by 1,4-diazabicyclo[2.2.2]octane Derivatives: Semiconductor and Photocurrent Response Properties 2018 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2018 Abstract The structures, semiconductor and photocurrent response properties of three 1,4-diazabicyclo[2.2.2]octane derivative-templated iodobismuthates, ($ Et_{2} $DABCO)3($ BiI_{6} $)2 (1), (i-$ Pr_{2} $DABCO)2($ Bi_{2} $$ I_{10} $) (2), [($ Me_{2} $DABCO)2($ Bi_{2} $$ I_{10} $)2]n (3) ($ Et_{2} $$ DABCO^{2+} $ = N,N′-diethyl-1,4-diazabicyclo[2.2.2] octane, i-$ Pr_{2} $$ DABCO^{2+} $ = N,N′-diisoproyl-1,4-diazabicyclo[2.2.2] octane, $ Me_{2} $$ DABCO^{2+} $ = N,N′-dimethyl-1,4-diazabicyclo[2.2.2] octane), are reported. Based on the templates with different substitutents on 1,4-diazabicyclo[2.2.2]octane, mono-nuclear (($ BiI_{6} $)3− for 1), dimer (($ Bi_{2} $$ I_{10} $)4− for 2) and 1-D chain (($ BiI_{5} $)n2n− for 3) can be obtained. C-H···I hydrogen bonds contribute to the structural extension to 2-D layer (for 2) and 3-D network (for 3). Their absorption spectra were investigated, and energy band gaps of 2.24/1.73/1.44 eV indicate their narrow-gap semiconductor natures. Their photocurrent response properties were also discussed. Finally, theoretical calculation was executed to give structure-properties correlation. Organic–inorganic hybrid Iodobismuthates Photocurrent response Feng, Qi-Yan aut Wei, Yan-Li aut Gao, Zhi-Ying aut Wang, Zhi-Wei aut Wang, Ying-Mei aut Enthalten in Journal of cluster science Springer US, 1990 29(2018), 4 vom: 18. Mai, Seite 725-735 (DE-627)130895687 (DE-600)1042216-X (DE-576)023130083 1040-7278 nnns volume:29 year:2018 number:4 day:18 month:05 pages:725-735 https://doi.org/10.1007/s10876-018-1397-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-MAT AR 29 2018 4 18 05 725-735 |
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10.1007/s10876-018-1397-z doi (DE-627)OLC2072664799 (DE-He213)s10876-018-1397-z-p DE-627 ger DE-627 rakwb eng 500 VZ 11 ssgn Zhang, Zhao-Pei verfasserin aut Three Iodobismuthates Hybrids Displaying Mono-nuclear, Dimer and 1-D Arrangements Templated by 1,4-diazabicyclo[2.2.2]octane Derivatives: Semiconductor and Photocurrent Response Properties 2018 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2018 Abstract The structures, semiconductor and photocurrent response properties of three 1,4-diazabicyclo[2.2.2]octane derivative-templated iodobismuthates, ($ Et_{2} $DABCO)3($ BiI_{6} $)2 (1), (i-$ Pr_{2} $DABCO)2($ Bi_{2} $$ I_{10} $) (2), [($ Me_{2} $DABCO)2($ Bi_{2} $$ I_{10} $)2]n (3) ($ Et_{2} $$ DABCO^{2+} $ = N,N′-diethyl-1,4-diazabicyclo[2.2.2] octane, i-$ Pr_{2} $$ DABCO^{2+} $ = N,N′-diisoproyl-1,4-diazabicyclo[2.2.2] octane, $ Me_{2} $$ DABCO^{2+} $ = N,N′-dimethyl-1,4-diazabicyclo[2.2.2] octane), are reported. Based on the templates with different substitutents on 1,4-diazabicyclo[2.2.2]octane, mono-nuclear (($ BiI_{6} $)3− for 1), dimer (($ Bi_{2} $$ I_{10} $)4− for 2) and 1-D chain (($ BiI_{5} $)n2n− for 3) can be obtained. C-H···I hydrogen bonds contribute to the structural extension to 2-D layer (for 2) and 3-D network (for 3). Their absorption spectra were investigated, and energy band gaps of 2.24/1.73/1.44 eV indicate their narrow-gap semiconductor natures. Their photocurrent response properties were also discussed. Finally, theoretical calculation was executed to give structure-properties correlation. Organic–inorganic hybrid Iodobismuthates Photocurrent response Feng, Qi-Yan aut Wei, Yan-Li aut Gao, Zhi-Ying aut Wang, Zhi-Wei aut Wang, Ying-Mei aut Enthalten in Journal of cluster science Springer US, 1990 29(2018), 4 vom: 18. Mai, Seite 725-735 (DE-627)130895687 (DE-600)1042216-X (DE-576)023130083 1040-7278 nnns volume:29 year:2018 number:4 day:18 month:05 pages:725-735 https://doi.org/10.1007/s10876-018-1397-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-MAT AR 29 2018 4 18 05 725-735 |
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10.1007/s10876-018-1397-z doi (DE-627)OLC2072664799 (DE-He213)s10876-018-1397-z-p DE-627 ger DE-627 rakwb eng 500 VZ 11 ssgn Zhang, Zhao-Pei verfasserin aut Three Iodobismuthates Hybrids Displaying Mono-nuclear, Dimer and 1-D Arrangements Templated by 1,4-diazabicyclo[2.2.2]octane Derivatives: Semiconductor and Photocurrent Response Properties 2018 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2018 Abstract The structures, semiconductor and photocurrent response properties of three 1,4-diazabicyclo[2.2.2]octane derivative-templated iodobismuthates, ($ Et_{2} $DABCO)3($ BiI_{6} $)2 (1), (i-$ Pr_{2} $DABCO)2($ Bi_{2} $$ I_{10} $) (2), [($ Me_{2} $DABCO)2($ Bi_{2} $$ I_{10} $)2]n (3) ($ Et_{2} $$ DABCO^{2+} $ = N,N′-diethyl-1,4-diazabicyclo[2.2.2] octane, i-$ Pr_{2} $$ DABCO^{2+} $ = N,N′-diisoproyl-1,4-diazabicyclo[2.2.2] octane, $ Me_{2} $$ DABCO^{2+} $ = N,N′-dimethyl-1,4-diazabicyclo[2.2.2] octane), are reported. Based on the templates with different substitutents on 1,4-diazabicyclo[2.2.2]octane, mono-nuclear (($ BiI_{6} $)3− for 1), dimer (($ Bi_{2} $$ I_{10} $)4− for 2) and 1-D chain (($ BiI_{5} $)n2n− for 3) can be obtained. C-H···I hydrogen bonds contribute to the structural extension to 2-D layer (for 2) and 3-D network (for 3). Their absorption spectra were investigated, and energy band gaps of 2.24/1.73/1.44 eV indicate their narrow-gap semiconductor natures. Their photocurrent response properties were also discussed. Finally, theoretical calculation was executed to give structure-properties correlation. Organic–inorganic hybrid Iodobismuthates Photocurrent response Feng, Qi-Yan aut Wei, Yan-Li aut Gao, Zhi-Ying aut Wang, Zhi-Wei aut Wang, Ying-Mei aut Enthalten in Journal of cluster science Springer US, 1990 29(2018), 4 vom: 18. Mai, Seite 725-735 (DE-627)130895687 (DE-600)1042216-X (DE-576)023130083 1040-7278 nnns volume:29 year:2018 number:4 day:18 month:05 pages:725-735 https://doi.org/10.1007/s10876-018-1397-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-MAT AR 29 2018 4 18 05 725-735 |
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10.1007/s10876-018-1397-z doi (DE-627)OLC2072664799 (DE-He213)s10876-018-1397-z-p DE-627 ger DE-627 rakwb eng 500 VZ 11 ssgn Zhang, Zhao-Pei verfasserin aut Three Iodobismuthates Hybrids Displaying Mono-nuclear, Dimer and 1-D Arrangements Templated by 1,4-diazabicyclo[2.2.2]octane Derivatives: Semiconductor and Photocurrent Response Properties 2018 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2018 Abstract The structures, semiconductor and photocurrent response properties of three 1,4-diazabicyclo[2.2.2]octane derivative-templated iodobismuthates, ($ Et_{2} $DABCO)3($ BiI_{6} $)2 (1), (i-$ Pr_{2} $DABCO)2($ Bi_{2} $$ I_{10} $) (2), [($ Me_{2} $DABCO)2($ Bi_{2} $$ I_{10} $)2]n (3) ($ Et_{2} $$ DABCO^{2+} $ = N,N′-diethyl-1,4-diazabicyclo[2.2.2] octane, i-$ Pr_{2} $$ DABCO^{2+} $ = N,N′-diisoproyl-1,4-diazabicyclo[2.2.2] octane, $ Me_{2} $$ DABCO^{2+} $ = N,N′-dimethyl-1,4-diazabicyclo[2.2.2] octane), are reported. Based on the templates with different substitutents on 1,4-diazabicyclo[2.2.2]octane, mono-nuclear (($ BiI_{6} $)3− for 1), dimer (($ Bi_{2} $$ I_{10} $)4− for 2) and 1-D chain (($ BiI_{5} $)n2n− for 3) can be obtained. C-H···I hydrogen bonds contribute to the structural extension to 2-D layer (for 2) and 3-D network (for 3). Their absorption spectra were investigated, and energy band gaps of 2.24/1.73/1.44 eV indicate their narrow-gap semiconductor natures. Their photocurrent response properties were also discussed. Finally, theoretical calculation was executed to give structure-properties correlation. Organic–inorganic hybrid Iodobismuthates Photocurrent response Feng, Qi-Yan aut Wei, Yan-Li aut Gao, Zhi-Ying aut Wang, Zhi-Wei aut Wang, Ying-Mei aut Enthalten in Journal of cluster science Springer US, 1990 29(2018), 4 vom: 18. Mai, Seite 725-735 (DE-627)130895687 (DE-600)1042216-X (DE-576)023130083 1040-7278 nnns volume:29 year:2018 number:4 day:18 month:05 pages:725-735 https://doi.org/10.1007/s10876-018-1397-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-MAT AR 29 2018 4 18 05 725-735 |
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10.1007/s10876-018-1397-z doi (DE-627)OLC2072664799 (DE-He213)s10876-018-1397-z-p DE-627 ger DE-627 rakwb eng 500 VZ 11 ssgn Zhang, Zhao-Pei verfasserin aut Three Iodobismuthates Hybrids Displaying Mono-nuclear, Dimer and 1-D Arrangements Templated by 1,4-diazabicyclo[2.2.2]octane Derivatives: Semiconductor and Photocurrent Response Properties 2018 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2018 Abstract The structures, semiconductor and photocurrent response properties of three 1,4-diazabicyclo[2.2.2]octane derivative-templated iodobismuthates, ($ Et_{2} $DABCO)3($ BiI_{6} $)2 (1), (i-$ Pr_{2} $DABCO)2($ Bi_{2} $$ I_{10} $) (2), [($ Me_{2} $DABCO)2($ Bi_{2} $$ I_{10} $)2]n (3) ($ Et_{2} $$ DABCO^{2+} $ = N,N′-diethyl-1,4-diazabicyclo[2.2.2] octane, i-$ Pr_{2} $$ DABCO^{2+} $ = N,N′-diisoproyl-1,4-diazabicyclo[2.2.2] octane, $ Me_{2} $$ DABCO^{2+} $ = N,N′-dimethyl-1,4-diazabicyclo[2.2.2] octane), are reported. Based on the templates with different substitutents on 1,4-diazabicyclo[2.2.2]octane, mono-nuclear (($ BiI_{6} $)3− for 1), dimer (($ Bi_{2} $$ I_{10} $)4− for 2) and 1-D chain (($ BiI_{5} $)n2n− for 3) can be obtained. C-H···I hydrogen bonds contribute to the structural extension to 2-D layer (for 2) and 3-D network (for 3). Their absorption spectra were investigated, and energy band gaps of 2.24/1.73/1.44 eV indicate their narrow-gap semiconductor natures. Their photocurrent response properties were also discussed. Finally, theoretical calculation was executed to give structure-properties correlation. Organic–inorganic hybrid Iodobismuthates Photocurrent response Feng, Qi-Yan aut Wei, Yan-Li aut Gao, Zhi-Ying aut Wang, Zhi-Wei aut Wang, Ying-Mei aut Enthalten in Journal of cluster science Springer US, 1990 29(2018), 4 vom: 18. Mai, Seite 725-735 (DE-627)130895687 (DE-600)1042216-X (DE-576)023130083 1040-7278 nnns volume:29 year:2018 number:4 day:18 month:05 pages:725-735 https://doi.org/10.1007/s10876-018-1397-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-MAT AR 29 2018 4 18 05 725-735 |
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Three Iodobismuthates Hybrids Displaying Mono-nuclear, Dimer and 1-D Arrangements Templated by 1,4-diazabicyclo[2.2.2]octane Derivatives: Semiconductor and Photocurrent Response Properties |
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Three Iodobismuthates Hybrids Displaying Mono-nuclear, Dimer and 1-D Arrangements Templated by 1,4-diazabicyclo[2.2.2]octane Derivatives: Semiconductor and Photocurrent Response Properties |
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three iodobismuthates hybrids displaying mono-nuclear, dimer and 1-d arrangements templated by 1,4-diazabicyclo[2.2.2]octane derivatives: semiconductor and photocurrent response properties |
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Three Iodobismuthates Hybrids Displaying Mono-nuclear, Dimer and 1-D Arrangements Templated by 1,4-diazabicyclo[2.2.2]octane Derivatives: Semiconductor and Photocurrent Response Properties |
| abstract |
Abstract The structures, semiconductor and photocurrent response properties of three 1,4-diazabicyclo[2.2.2]octane derivative-templated iodobismuthates, ($ Et_{2} $DABCO)3($ BiI_{6} $)2 (1), (i-$ Pr_{2} $DABCO)2($ Bi_{2} $$ I_{10} $) (2), [($ Me_{2} $DABCO)2($ Bi_{2} $$ I_{10} $)2]n (3) ($ Et_{2} $$ DABCO^{2+} $ = N,N′-diethyl-1,4-diazabicyclo[2.2.2] octane, i-$ Pr_{2} $$ DABCO^{2+} $ = N,N′-diisoproyl-1,4-diazabicyclo[2.2.2] octane, $ Me_{2} $$ DABCO^{2+} $ = N,N′-dimethyl-1,4-diazabicyclo[2.2.2] octane), are reported. Based on the templates with different substitutents on 1,4-diazabicyclo[2.2.2]octane, mono-nuclear (($ BiI_{6} $)3− for 1), dimer (($ Bi_{2} $$ I_{10} $)4− for 2) and 1-D chain (($ BiI_{5} $)n2n− for 3) can be obtained. C-H···I hydrogen bonds contribute to the structural extension to 2-D layer (for 2) and 3-D network (for 3). Their absorption spectra were investigated, and energy band gaps of 2.24/1.73/1.44 eV indicate their narrow-gap semiconductor natures. Their photocurrent response properties were also discussed. Finally, theoretical calculation was executed to give structure-properties correlation. © Springer Science+Business Media, LLC, part of Springer Nature 2018 |
| abstractGer |
Abstract The structures, semiconductor and photocurrent response properties of three 1,4-diazabicyclo[2.2.2]octane derivative-templated iodobismuthates, ($ Et_{2} $DABCO)3($ BiI_{6} $)2 (1), (i-$ Pr_{2} $DABCO)2($ Bi_{2} $$ I_{10} $) (2), [($ Me_{2} $DABCO)2($ Bi_{2} $$ I_{10} $)2]n (3) ($ Et_{2} $$ DABCO^{2+} $ = N,N′-diethyl-1,4-diazabicyclo[2.2.2] octane, i-$ Pr_{2} $$ DABCO^{2+} $ = N,N′-diisoproyl-1,4-diazabicyclo[2.2.2] octane, $ Me_{2} $$ DABCO^{2+} $ = N,N′-dimethyl-1,4-diazabicyclo[2.2.2] octane), are reported. Based on the templates with different substitutents on 1,4-diazabicyclo[2.2.2]octane, mono-nuclear (($ BiI_{6} $)3− for 1), dimer (($ Bi_{2} $$ I_{10} $)4− for 2) and 1-D chain (($ BiI_{5} $)n2n− for 3) can be obtained. C-H···I hydrogen bonds contribute to the structural extension to 2-D layer (for 2) and 3-D network (for 3). Their absorption spectra were investigated, and energy band gaps of 2.24/1.73/1.44 eV indicate their narrow-gap semiconductor natures. Their photocurrent response properties were also discussed. Finally, theoretical calculation was executed to give structure-properties correlation. © Springer Science+Business Media, LLC, part of Springer Nature 2018 |
| abstract_unstemmed |
Abstract The structures, semiconductor and photocurrent response properties of three 1,4-diazabicyclo[2.2.2]octane derivative-templated iodobismuthates, ($ Et_{2} $DABCO)3($ BiI_{6} $)2 (1), (i-$ Pr_{2} $DABCO)2($ Bi_{2} $$ I_{10} $) (2), [($ Me_{2} $DABCO)2($ Bi_{2} $$ I_{10} $)2]n (3) ($ Et_{2} $$ DABCO^{2+} $ = N,N′-diethyl-1,4-diazabicyclo[2.2.2] octane, i-$ Pr_{2} $$ DABCO^{2+} $ = N,N′-diisoproyl-1,4-diazabicyclo[2.2.2] octane, $ Me_{2} $$ DABCO^{2+} $ = N,N′-dimethyl-1,4-diazabicyclo[2.2.2] octane), are reported. Based on the templates with different substitutents on 1,4-diazabicyclo[2.2.2]octane, mono-nuclear (($ BiI_{6} $)3− for 1), dimer (($ Bi_{2} $$ I_{10} $)4− for 2) and 1-D chain (($ BiI_{5} $)n2n− for 3) can be obtained. C-H···I hydrogen bonds contribute to the structural extension to 2-D layer (for 2) and 3-D network (for 3). Their absorption spectra were investigated, and energy band gaps of 2.24/1.73/1.44 eV indicate their narrow-gap semiconductor natures. Their photocurrent response properties were also discussed. Finally, theoretical calculation was executed to give structure-properties correlation. © Springer Science+Business Media, LLC, part of Springer Nature 2018 |
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Three Iodobismuthates Hybrids Displaying Mono-nuclear, Dimer and 1-D Arrangements Templated by 1,4-diazabicyclo[2.2.2]octane Derivatives: Semiconductor and Photocurrent Response Properties |
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