Mixed-Metal Cluster Complexes from the Reactions of $ M_{3} $(CO)12 (M = Fe, Ru, Os) with the Unsaturated Complex Pt(IPr)($ SnBu^{t} $3)(H)
Abstract The reaction of $ Ru_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at 68 °C yielded the trigonal bipyramidal cluster $ Ru_{3} $$ Pt_{2} $(IPr)2(CO)12, 1, in 32% yield. The reaction of $ Os_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at 68 °C furnished the triosmium–monoplatinum cluster complex...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Zollo, Vincent [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2019 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer Science+Business Media, LLC, part of Springer Nature 2019 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of cluster science - Springer US, 1990, 30(2019), 5 vom: Sept., Seite 1355-1361 |
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| Übergeordnetes Werk: |
volume:30 ; year:2019 ; number:5 ; month:09 ; pages:1355-1361 |
| Links: |
|---|
| DOI / URN: |
10.1007/s10876-019-01665-x |
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OLC2072666805 |
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| 520 | |a Abstract The reaction of $ Ru_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at 68 °C yielded the trigonal bipyramidal cluster $ Ru_{3} $$ Pt_{2} $(IPr)2(CO)12, 1, in 32% yield. The reaction of $ Os_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at 68 °C furnished the triosmium–monoplatinum cluster complex $ Os_{3} $Pt(IPr)(CO)12, 2, in 51% yield and the triosmium–diplatinum cluster complex $ Os_{3} $$ Pt_{2} $(IPr)2(CO)12, 3, in 19% yield. The reaction of $ Fe_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at room temperature resulted in cluster fragmentation to afford the diiron–monoplatinum cluster complex $ Fe_{2} $Pt(IPr)(CO)9, 4, in 44% yield. All four compounds were structurally characterized by single-crystal X-ray diffraction analyses. Graphic Abstract | ||
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10.1007/s10876-019-01665-x doi (DE-627)OLC2072666805 (DE-He213)s10876-019-01665-x-p DE-627 ger DE-627 rakwb eng 500 VZ 11 ssgn Zollo, Vincent verfasserin aut Mixed-Metal Cluster Complexes from the Reactions of $ M_{3} $(CO)12 (M = Fe, Ru, Os) with the Unsaturated Complex Pt(IPr)($ SnBu^{t} $3)(H) 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2019 Abstract The reaction of $ Ru_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at 68 °C yielded the trigonal bipyramidal cluster $ Ru_{3} $$ Pt_{2} $(IPr)2(CO)12, 1, in 32% yield. The reaction of $ Os_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at 68 °C furnished the triosmium–monoplatinum cluster complex $ Os_{3} $Pt(IPr)(CO)12, 2, in 51% yield and the triosmium–diplatinum cluster complex $ Os_{3} $$ Pt_{2} $(IPr)2(CO)12, 3, in 19% yield. The reaction of $ Fe_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at room temperature resulted in cluster fragmentation to afford the diiron–monoplatinum cluster complex $ Fe_{2} $Pt(IPr)(CO)9, 4, in 44% yield. All four compounds were structurally characterized by single-crystal X-ray diffraction analyses. Graphic Abstract Platinum Cluster Bimetallic -heterocyclic carbene Etezadi, Sedigheh aut Gamage, Mohan M. aut Captain, Burjor aut Enthalten in Journal of cluster science Springer US, 1990 30(2019), 5 vom: Sept., Seite 1355-1361 (DE-627)130895687 (DE-600)1042216-X (DE-576)023130083 1040-7278 nnns volume:30 year:2019 number:5 month:09 pages:1355-1361 https://doi.org/10.1007/s10876-019-01665-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-MAT AR 30 2019 5 09 1355-1361 |
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10.1007/s10876-019-01665-x doi (DE-627)OLC2072666805 (DE-He213)s10876-019-01665-x-p DE-627 ger DE-627 rakwb eng 500 VZ 11 ssgn Zollo, Vincent verfasserin aut Mixed-Metal Cluster Complexes from the Reactions of $ M_{3} $(CO)12 (M = Fe, Ru, Os) with the Unsaturated Complex Pt(IPr)($ SnBu^{t} $3)(H) 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2019 Abstract The reaction of $ Ru_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at 68 °C yielded the trigonal bipyramidal cluster $ Ru_{3} $$ Pt_{2} $(IPr)2(CO)12, 1, in 32% yield. The reaction of $ Os_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at 68 °C furnished the triosmium–monoplatinum cluster complex $ Os_{3} $Pt(IPr)(CO)12, 2, in 51% yield and the triosmium–diplatinum cluster complex $ Os_{3} $$ Pt_{2} $(IPr)2(CO)12, 3, in 19% yield. The reaction of $ Fe_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at room temperature resulted in cluster fragmentation to afford the diiron–monoplatinum cluster complex $ Fe_{2} $Pt(IPr)(CO)9, 4, in 44% yield. All four compounds were structurally characterized by single-crystal X-ray diffraction analyses. Graphic Abstract Platinum Cluster Bimetallic -heterocyclic carbene Etezadi, Sedigheh aut Gamage, Mohan M. aut Captain, Burjor aut Enthalten in Journal of cluster science Springer US, 1990 30(2019), 5 vom: Sept., Seite 1355-1361 (DE-627)130895687 (DE-600)1042216-X (DE-576)023130083 1040-7278 nnns volume:30 year:2019 number:5 month:09 pages:1355-1361 https://doi.org/10.1007/s10876-019-01665-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-MAT AR 30 2019 5 09 1355-1361 |
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10.1007/s10876-019-01665-x doi (DE-627)OLC2072666805 (DE-He213)s10876-019-01665-x-p DE-627 ger DE-627 rakwb eng 500 VZ 11 ssgn Zollo, Vincent verfasserin aut Mixed-Metal Cluster Complexes from the Reactions of $ M_{3} $(CO)12 (M = Fe, Ru, Os) with the Unsaturated Complex Pt(IPr)($ SnBu^{t} $3)(H) 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2019 Abstract The reaction of $ Ru_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at 68 °C yielded the trigonal bipyramidal cluster $ Ru_{3} $$ Pt_{2} $(IPr)2(CO)12, 1, in 32% yield. The reaction of $ Os_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at 68 °C furnished the triosmium–monoplatinum cluster complex $ Os_{3} $Pt(IPr)(CO)12, 2, in 51% yield and the triosmium–diplatinum cluster complex $ Os_{3} $$ Pt_{2} $(IPr)2(CO)12, 3, in 19% yield. The reaction of $ Fe_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at room temperature resulted in cluster fragmentation to afford the diiron–monoplatinum cluster complex $ Fe_{2} $Pt(IPr)(CO)9, 4, in 44% yield. All four compounds were structurally characterized by single-crystal X-ray diffraction analyses. Graphic Abstract Platinum Cluster Bimetallic -heterocyclic carbene Etezadi, Sedigheh aut Gamage, Mohan M. aut Captain, Burjor aut Enthalten in Journal of cluster science Springer US, 1990 30(2019), 5 vom: Sept., Seite 1355-1361 (DE-627)130895687 (DE-600)1042216-X (DE-576)023130083 1040-7278 nnns volume:30 year:2019 number:5 month:09 pages:1355-1361 https://doi.org/10.1007/s10876-019-01665-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-MAT AR 30 2019 5 09 1355-1361 |
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10.1007/s10876-019-01665-x doi (DE-627)OLC2072666805 (DE-He213)s10876-019-01665-x-p DE-627 ger DE-627 rakwb eng 500 VZ 11 ssgn Zollo, Vincent verfasserin aut Mixed-Metal Cluster Complexes from the Reactions of $ M_{3} $(CO)12 (M = Fe, Ru, Os) with the Unsaturated Complex Pt(IPr)($ SnBu^{t} $3)(H) 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2019 Abstract The reaction of $ Ru_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at 68 °C yielded the trigonal bipyramidal cluster $ Ru_{3} $$ Pt_{2} $(IPr)2(CO)12, 1, in 32% yield. The reaction of $ Os_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at 68 °C furnished the triosmium–monoplatinum cluster complex $ Os_{3} $Pt(IPr)(CO)12, 2, in 51% yield and the triosmium–diplatinum cluster complex $ Os_{3} $$ Pt_{2} $(IPr)2(CO)12, 3, in 19% yield. The reaction of $ Fe_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at room temperature resulted in cluster fragmentation to afford the diiron–monoplatinum cluster complex $ Fe_{2} $Pt(IPr)(CO)9, 4, in 44% yield. All four compounds were structurally characterized by single-crystal X-ray diffraction analyses. Graphic Abstract Platinum Cluster Bimetallic -heterocyclic carbene Etezadi, Sedigheh aut Gamage, Mohan M. aut Captain, Burjor aut Enthalten in Journal of cluster science Springer US, 1990 30(2019), 5 vom: Sept., Seite 1355-1361 (DE-627)130895687 (DE-600)1042216-X (DE-576)023130083 1040-7278 nnns volume:30 year:2019 number:5 month:09 pages:1355-1361 https://doi.org/10.1007/s10876-019-01665-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-MAT AR 30 2019 5 09 1355-1361 |
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10.1007/s10876-019-01665-x doi (DE-627)OLC2072666805 (DE-He213)s10876-019-01665-x-p DE-627 ger DE-627 rakwb eng 500 VZ 11 ssgn Zollo, Vincent verfasserin aut Mixed-Metal Cluster Complexes from the Reactions of $ M_{3} $(CO)12 (M = Fe, Ru, Os) with the Unsaturated Complex Pt(IPr)($ SnBu^{t} $3)(H) 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2019 Abstract The reaction of $ Ru_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at 68 °C yielded the trigonal bipyramidal cluster $ Ru_{3} $$ Pt_{2} $(IPr)2(CO)12, 1, in 32% yield. The reaction of $ Os_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at 68 °C furnished the triosmium–monoplatinum cluster complex $ Os_{3} $Pt(IPr)(CO)12, 2, in 51% yield and the triosmium–diplatinum cluster complex $ Os_{3} $$ Pt_{2} $(IPr)2(CO)12, 3, in 19% yield. The reaction of $ Fe_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at room temperature resulted in cluster fragmentation to afford the diiron–monoplatinum cluster complex $ Fe_{2} $Pt(IPr)(CO)9, 4, in 44% yield. All four compounds were structurally characterized by single-crystal X-ray diffraction analyses. Graphic Abstract Platinum Cluster Bimetallic -heterocyclic carbene Etezadi, Sedigheh aut Gamage, Mohan M. aut Captain, Burjor aut Enthalten in Journal of cluster science Springer US, 1990 30(2019), 5 vom: Sept., Seite 1355-1361 (DE-627)130895687 (DE-600)1042216-X (DE-576)023130083 1040-7278 nnns volume:30 year:2019 number:5 month:09 pages:1355-1361 https://doi.org/10.1007/s10876-019-01665-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-MAT AR 30 2019 5 09 1355-1361 |
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Mixed-Metal Cluster Complexes from the Reactions of $ M_{3} $(CO)12 (M = Fe, Ru, Os) with the Unsaturated Complex Pt(IPr)($ SnBu^{t} $3)(H) |
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Zollo, Vincent |
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Journal of cluster science |
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Journal of cluster science |
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eng |
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500 - Science |
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marc |
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2019 |
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1355 |
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Zollo, Vincent Etezadi, Sedigheh Gamage, Mohan M. Captain, Burjor |
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30 |
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Aufsätze |
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Zollo, Vincent |
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10.1007/s10876-019-01665-x |
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500 |
| title_sort |
mixed-metal cluster complexes from the reactions of $ m_{3} $(co)12 (m = fe, ru, os) with the unsaturated complex pt(ipr)($ snbu^{t} $3)(h) |
| title_auth |
Mixed-Metal Cluster Complexes from the Reactions of $ M_{3} $(CO)12 (M = Fe, Ru, Os) with the Unsaturated Complex Pt(IPr)($ SnBu^{t} $3)(H) |
| abstract |
Abstract The reaction of $ Ru_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at 68 °C yielded the trigonal bipyramidal cluster $ Ru_{3} $$ Pt_{2} $(IPr)2(CO)12, 1, in 32% yield. The reaction of $ Os_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at 68 °C furnished the triosmium–monoplatinum cluster complex $ Os_{3} $Pt(IPr)(CO)12, 2, in 51% yield and the triosmium–diplatinum cluster complex $ Os_{3} $$ Pt_{2} $(IPr)2(CO)12, 3, in 19% yield. The reaction of $ Fe_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at room temperature resulted in cluster fragmentation to afford the diiron–monoplatinum cluster complex $ Fe_{2} $Pt(IPr)(CO)9, 4, in 44% yield. All four compounds were structurally characterized by single-crystal X-ray diffraction analyses. Graphic Abstract © Springer Science+Business Media, LLC, part of Springer Nature 2019 |
| abstractGer |
Abstract The reaction of $ Ru_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at 68 °C yielded the trigonal bipyramidal cluster $ Ru_{3} $$ Pt_{2} $(IPr)2(CO)12, 1, in 32% yield. The reaction of $ Os_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at 68 °C furnished the triosmium–monoplatinum cluster complex $ Os_{3} $Pt(IPr)(CO)12, 2, in 51% yield and the triosmium–diplatinum cluster complex $ Os_{3} $$ Pt_{2} $(IPr)2(CO)12, 3, in 19% yield. The reaction of $ Fe_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at room temperature resulted in cluster fragmentation to afford the diiron–monoplatinum cluster complex $ Fe_{2} $Pt(IPr)(CO)9, 4, in 44% yield. All four compounds were structurally characterized by single-crystal X-ray diffraction analyses. Graphic Abstract © Springer Science+Business Media, LLC, part of Springer Nature 2019 |
| abstract_unstemmed |
Abstract The reaction of $ Ru_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at 68 °C yielded the trigonal bipyramidal cluster $ Ru_{3} $$ Pt_{2} $(IPr)2(CO)12, 1, in 32% yield. The reaction of $ Os_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at 68 °C furnished the triosmium–monoplatinum cluster complex $ Os_{3} $Pt(IPr)(CO)12, 2, in 51% yield and the triosmium–diplatinum cluster complex $ Os_{3} $$ Pt_{2} $(IPr)2(CO)12, 3, in 19% yield. The reaction of $ Fe_{3} $(CO)12 with Pt(IPr)($ SnBu^{t} $3)(H) at room temperature resulted in cluster fragmentation to afford the diiron–monoplatinum cluster complex $ Fe_{2} $Pt(IPr)(CO)9, 4, in 44% yield. All four compounds were structurally characterized by single-crystal X-ray diffraction analyses. Graphic Abstract © Springer Science+Business Media, LLC, part of Springer Nature 2019 |
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GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-MAT |
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5 |
| title_short |
Mixed-Metal Cluster Complexes from the Reactions of $ M_{3} $(CO)12 (M = Fe, Ru, Os) with the Unsaturated Complex Pt(IPr)($ SnBu^{t} $3)(H) |
| url |
https://doi.org/10.1007/s10876-019-01665-x |
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| author2 |
Etezadi, Sedigheh Gamage, Mohan M. Captain, Burjor |
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| up_date |
2024-07-03T15:45:43.054Z |
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