Swelling and shrinking of a polyelectrolyte gel induced by a salt solution
Abstract The stability of a polyelectrolyte gel in solution results from a delicate balance between several competing thermodynamic forces, viz. osmotic pressure of free ions in the gel,molecular interaction of solvent and polymer molecules,network elasticity,Debye-Htickel interaction of ions. That...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Rydzewski, R. [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1990 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer-Verlag 1990 |
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| Übergeordnetes Werk: |
Enthalten in: Continuum mechanics and thermodynamics - Springer-Verlag, 1989, 2(1990), 2 vom: Mai, Seite 77-97 |
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| Übergeordnetes Werk: |
volume:2 ; year:1990 ; number:2 ; month:05 ; pages:77-97 |
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| DOI / URN: |
10.1007/BF01126716 |
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| 520 | |a Abstract The stability of a polyelectrolyte gel in solution results from a delicate balance between several competing thermodynamic forces, viz. osmotic pressure of free ions in the gel,molecular interaction of solvent and polymer molecules,network elasticity,Debye-Htickel interaction of ions. That balance may be upset by a decrease of temperature and by the addition of salt to the solvent. This results in a decrease of osmotic pressure and collapse of the gel to a small fraction of the initial volume. The effect can be reversed by increasing temperature and by removing salt from the solution. This paper presents an attempt to describe swelling and shrinking quantitatively and to understand the nature of the opposing forces. The volume of a particular polyacrylamide gel in a water acetone solution is represented as a function of the salt content and of temperature. | ||
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10.1007/BF01126716 doi (DE-627)OLC2073823289 (DE-He213)BF01126716-p DE-627 ger DE-627 rakwb eng 530 VZ Rydzewski, R. verfasserin aut Swelling and shrinking of a polyelectrolyte gel induced by a salt solution 1990 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 1990 Abstract The stability of a polyelectrolyte gel in solution results from a delicate balance between several competing thermodynamic forces, viz. osmotic pressure of free ions in the gel,molecular interaction of solvent and polymer molecules,network elasticity,Debye-Htickel interaction of ions. That balance may be upset by a decrease of temperature and by the addition of salt to the solvent. This results in a decrease of osmotic pressure and collapse of the gel to a small fraction of the initial volume. The effect can be reversed by increasing temperature and by removing salt from the solution. This paper presents an attempt to describe swelling and shrinking quantitatively and to understand the nature of the opposing forces. The volume of a particular polyacrylamide gel in a water acetone solution is represented as a function of the salt content and of temperature. Polymer Acetone Polyacrylamide Salt Solution Osmotic Pressure Enthalten in Continuum mechanics and thermodynamics Springer-Verlag, 1989 2(1990), 2 vom: Mai, Seite 77-97 (DE-627)130799327 (DE-600)1007878-2 (DE-576)023042303 0935-1175 nnns volume:2 year:1990 number:2 month:05 pages:77-97 https://doi.org/10.1007/BF01126716 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_11 GBV_ILN_30 GBV_ILN_40 GBV_ILN_65 GBV_ILN_70 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2409 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4103 GBV_ILN_4313 GBV_ILN_4314 GBV_ILN_4319 GBV_ILN_4700 AR 2 1990 2 05 77-97 |
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10.1007/BF01126716 doi (DE-627)OLC2073823289 (DE-He213)BF01126716-p DE-627 ger DE-627 rakwb eng 530 VZ Rydzewski, R. verfasserin aut Swelling and shrinking of a polyelectrolyte gel induced by a salt solution 1990 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 1990 Abstract The stability of a polyelectrolyte gel in solution results from a delicate balance between several competing thermodynamic forces, viz. osmotic pressure of free ions in the gel,molecular interaction of solvent and polymer molecules,network elasticity,Debye-Htickel interaction of ions. That balance may be upset by a decrease of temperature and by the addition of salt to the solvent. This results in a decrease of osmotic pressure and collapse of the gel to a small fraction of the initial volume. The effect can be reversed by increasing temperature and by removing salt from the solution. This paper presents an attempt to describe swelling and shrinking quantitatively and to understand the nature of the opposing forces. The volume of a particular polyacrylamide gel in a water acetone solution is represented as a function of the salt content and of temperature. Polymer Acetone Polyacrylamide Salt Solution Osmotic Pressure Enthalten in Continuum mechanics and thermodynamics Springer-Verlag, 1989 2(1990), 2 vom: Mai, Seite 77-97 (DE-627)130799327 (DE-600)1007878-2 (DE-576)023042303 0935-1175 nnns volume:2 year:1990 number:2 month:05 pages:77-97 https://doi.org/10.1007/BF01126716 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_11 GBV_ILN_30 GBV_ILN_40 GBV_ILN_65 GBV_ILN_70 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2409 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4103 GBV_ILN_4313 GBV_ILN_4314 GBV_ILN_4319 GBV_ILN_4700 AR 2 1990 2 05 77-97 |
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10.1007/BF01126716 doi (DE-627)OLC2073823289 (DE-He213)BF01126716-p DE-627 ger DE-627 rakwb eng 530 VZ Rydzewski, R. verfasserin aut Swelling and shrinking of a polyelectrolyte gel induced by a salt solution 1990 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 1990 Abstract The stability of a polyelectrolyte gel in solution results from a delicate balance between several competing thermodynamic forces, viz. osmotic pressure of free ions in the gel,molecular interaction of solvent and polymer molecules,network elasticity,Debye-Htickel interaction of ions. That balance may be upset by a decrease of temperature and by the addition of salt to the solvent. This results in a decrease of osmotic pressure and collapse of the gel to a small fraction of the initial volume. The effect can be reversed by increasing temperature and by removing salt from the solution. This paper presents an attempt to describe swelling and shrinking quantitatively and to understand the nature of the opposing forces. The volume of a particular polyacrylamide gel in a water acetone solution is represented as a function of the salt content and of temperature. Polymer Acetone Polyacrylamide Salt Solution Osmotic Pressure Enthalten in Continuum mechanics and thermodynamics Springer-Verlag, 1989 2(1990), 2 vom: Mai, Seite 77-97 (DE-627)130799327 (DE-600)1007878-2 (DE-576)023042303 0935-1175 nnns volume:2 year:1990 number:2 month:05 pages:77-97 https://doi.org/10.1007/BF01126716 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_11 GBV_ILN_30 GBV_ILN_40 GBV_ILN_65 GBV_ILN_70 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2409 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4103 GBV_ILN_4313 GBV_ILN_4314 GBV_ILN_4319 GBV_ILN_4700 AR 2 1990 2 05 77-97 |
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10.1007/BF01126716 doi (DE-627)OLC2073823289 (DE-He213)BF01126716-p DE-627 ger DE-627 rakwb eng 530 VZ Rydzewski, R. verfasserin aut Swelling and shrinking of a polyelectrolyte gel induced by a salt solution 1990 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 1990 Abstract The stability of a polyelectrolyte gel in solution results from a delicate balance between several competing thermodynamic forces, viz. osmotic pressure of free ions in the gel,molecular interaction of solvent and polymer molecules,network elasticity,Debye-Htickel interaction of ions. That balance may be upset by a decrease of temperature and by the addition of salt to the solvent. This results in a decrease of osmotic pressure and collapse of the gel to a small fraction of the initial volume. The effect can be reversed by increasing temperature and by removing salt from the solution. This paper presents an attempt to describe swelling and shrinking quantitatively and to understand the nature of the opposing forces. The volume of a particular polyacrylamide gel in a water acetone solution is represented as a function of the salt content and of temperature. Polymer Acetone Polyacrylamide Salt Solution Osmotic Pressure Enthalten in Continuum mechanics and thermodynamics Springer-Verlag, 1989 2(1990), 2 vom: Mai, Seite 77-97 (DE-627)130799327 (DE-600)1007878-2 (DE-576)023042303 0935-1175 nnns volume:2 year:1990 number:2 month:05 pages:77-97 https://doi.org/10.1007/BF01126716 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_11 GBV_ILN_30 GBV_ILN_40 GBV_ILN_65 GBV_ILN_70 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2409 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4103 GBV_ILN_4313 GBV_ILN_4314 GBV_ILN_4319 GBV_ILN_4700 AR 2 1990 2 05 77-97 |
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Swelling and shrinking of a polyelectrolyte gel induced by a salt solution |
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Abstract The stability of a polyelectrolyte gel in solution results from a delicate balance between several competing thermodynamic forces, viz. osmotic pressure of free ions in the gel,molecular interaction of solvent and polymer molecules,network elasticity,Debye-Htickel interaction of ions. That balance may be upset by a decrease of temperature and by the addition of salt to the solvent. This results in a decrease of osmotic pressure and collapse of the gel to a small fraction of the initial volume. The effect can be reversed by increasing temperature and by removing salt from the solution. This paper presents an attempt to describe swelling and shrinking quantitatively and to understand the nature of the opposing forces. The volume of a particular polyacrylamide gel in a water acetone solution is represented as a function of the salt content and of temperature. © Springer-Verlag 1990 |
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Abstract The stability of a polyelectrolyte gel in solution results from a delicate balance between several competing thermodynamic forces, viz. osmotic pressure of free ions in the gel,molecular interaction of solvent and polymer molecules,network elasticity,Debye-Htickel interaction of ions. That balance may be upset by a decrease of temperature and by the addition of salt to the solvent. This results in a decrease of osmotic pressure and collapse of the gel to a small fraction of the initial volume. The effect can be reversed by increasing temperature and by removing salt from the solution. This paper presents an attempt to describe swelling and shrinking quantitatively and to understand the nature of the opposing forces. The volume of a particular polyacrylamide gel in a water acetone solution is represented as a function of the salt content and of temperature. © Springer-Verlag 1990 |
| abstract_unstemmed |
Abstract The stability of a polyelectrolyte gel in solution results from a delicate balance between several competing thermodynamic forces, viz. osmotic pressure of free ions in the gel,molecular interaction of solvent and polymer molecules,network elasticity,Debye-Htickel interaction of ions. That balance may be upset by a decrease of temperature and by the addition of salt to the solvent. This results in a decrease of osmotic pressure and collapse of the gel to a small fraction of the initial volume. The effect can be reversed by increasing temperature and by removing salt from the solution. This paper presents an attempt to describe swelling and shrinking quantitatively and to understand the nature of the opposing forces. The volume of a particular polyacrylamide gel in a water acetone solution is represented as a function of the salt content and of temperature. © Springer-Verlag 1990 |
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Swelling and shrinking of a polyelectrolyte gel induced by a salt solution |
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