Development of the Chemical Oxygen-Iodine Laser (COIL) with chemical generation of atomic iodine

Abstract. This article addresses the development of a Chemical Oxygen-Iodine Laser (COIL) with alternative chemical ways of generating atomic iodine. Injection of atomic iodine as opposed to molecular iodine has the potential to improve the COIL efficiency. This paper describes two chemical methods...
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Autor*in:	Kodymová, J. [verfasserIn] Špalek, O. Jirásek, V. Čenský, M. Hager, G.D.

Format:	Artikel
Sprache:	Englisch

Erschienen:	2003

Systematik:	UA 9001.A

Anmerkung:	© Springer-Verlag 2003

Übergeordnetes Werk:	Enthalten in: Applied physics. A, Materials science & processing - Springer-Verlag, 1981, 77(2003), 2 vom: Juli, Seite 331-336
Übergeordnetes Werk:	volume:77 ; year:2003 ; number:2 ; month:07 ; pages:331-336

Links:	Volltext

DOI / URN:	10.1007/s00339-003-2136-2

Katalog-ID:	OLC2074161220

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allfields	10.1007/s00339-003-2136-2 doi (DE-627)OLC2074161220 (DE-He213)s00339-003-2136-2-p DE-627 ger DE-627 rakwb eng 530 620 VZ 530 VZ UA 9001.A VZ rvk Kodymová, J. verfasserin aut Development of the Chemical Oxygen-Iodine Laser (COIL) with chemical generation of atomic iodine 2003 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 2003 Abstract. This article addresses the development of a Chemical Oxygen-Iodine Laser (COIL) with alternative chemical ways of generating atomic iodine. Injection of atomic iodine as opposed to molecular iodine has the potential to improve the COIL efficiency. This paper describes two chemical methods for generating iodine atoms based on the gas phase reactions of hydrogen/deuterium iodide with fluorine or chlorine atoms, which are also produced chemically. Simplified one-dimensional gas dynamic modeling that describes the stream-wise profiles of species concentrations within both reaction systems is used to gain a theoretical understanding of both reaction systems under COIL conditions. The modeling results are used for the design of an experimental device and the interpretation of experimental data. The first experimental investigation studies the production of iodine atoms produced from reactions of Cl with HI. Atomic iodine yields of 70–100% in nitrogen are obtained, and the gain on the I(2P1/2)–I(2P3/2) transition in a flow of singlet oxygen is measured. Špalek, O. aut Jirásek, V. aut Čenský, M. aut Hager, G.D. aut Enthalten in Applied physics. A, Materials science & processing Springer-Verlag, 1981 77(2003), 2 vom: Juli, Seite 331-336 (DE-627)129861340 (DE-600)283365-7 (DE-576)015171930 0947-8396 nnns volume:77 year:2003 number:2 month:07 pages:331-336 https://doi.org/10.1007/s00339-003-2136-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_20 GBV_ILN_21 GBV_ILN_22 GBV_ILN_30 GBV_ILN_31 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_70 GBV_ILN_130 GBV_ILN_150 GBV_ILN_170 GBV_ILN_2002 GBV_ILN_2005 GBV_ILN_2010 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_4012 GBV_ILN_4036 GBV_ILN_4116 GBV_ILN_4126 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4318 GBV_ILN_4319 GBV_ILN_4700 UA 9001.A AR 77 2003 2 07 331-336
spelling	10.1007/s00339-003-2136-2 doi (DE-627)OLC2074161220 (DE-He213)s00339-003-2136-2-p DE-627 ger DE-627 rakwb eng 530 620 VZ 530 VZ UA 9001.A VZ rvk Kodymová, J. verfasserin aut Development of the Chemical Oxygen-Iodine Laser (COIL) with chemical generation of atomic iodine 2003 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 2003 Abstract. This article addresses the development of a Chemical Oxygen-Iodine Laser (COIL) with alternative chemical ways of generating atomic iodine. Injection of atomic iodine as opposed to molecular iodine has the potential to improve the COIL efficiency. This paper describes two chemical methods for generating iodine atoms based on the gas phase reactions of hydrogen/deuterium iodide with fluorine or chlorine atoms, which are also produced chemically. Simplified one-dimensional gas dynamic modeling that describes the stream-wise profiles of species concentrations within both reaction systems is used to gain a theoretical understanding of both reaction systems under COIL conditions. The modeling results are used for the design of an experimental device and the interpretation of experimental data. The first experimental investigation studies the production of iodine atoms produced from reactions of Cl with HI. Atomic iodine yields of 70–100% in nitrogen are obtained, and the gain on the I(2P1/2)–I(2P3/2) transition in a flow of singlet oxygen is measured. Špalek, O. aut Jirásek, V. aut Čenský, M. aut Hager, G.D. aut Enthalten in Applied physics. A, Materials science & processing Springer-Verlag, 1981 77(2003), 2 vom: Juli, Seite 331-336 (DE-627)129861340 (DE-600)283365-7 (DE-576)015171930 0947-8396 nnns volume:77 year:2003 number:2 month:07 pages:331-336 https://doi.org/10.1007/s00339-003-2136-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_20 GBV_ILN_21 GBV_ILN_22 GBV_ILN_30 GBV_ILN_31 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_70 GBV_ILN_130 GBV_ILN_150 GBV_ILN_170 GBV_ILN_2002 GBV_ILN_2005 GBV_ILN_2010 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_4012 GBV_ILN_4036 GBV_ILN_4116 GBV_ILN_4126 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4318 GBV_ILN_4319 GBV_ILN_4700 UA 9001.A AR 77 2003 2 07 331-336
allfields_unstemmed	10.1007/s00339-003-2136-2 doi (DE-627)OLC2074161220 (DE-He213)s00339-003-2136-2-p DE-627 ger DE-627 rakwb eng 530 620 VZ 530 VZ UA 9001.A VZ rvk Kodymová, J. verfasserin aut Development of the Chemical Oxygen-Iodine Laser (COIL) with chemical generation of atomic iodine 2003 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 2003 Abstract. This article addresses the development of a Chemical Oxygen-Iodine Laser (COIL) with alternative chemical ways of generating atomic iodine. Injection of atomic iodine as opposed to molecular iodine has the potential to improve the COIL efficiency. This paper describes two chemical methods for generating iodine atoms based on the gas phase reactions of hydrogen/deuterium iodide with fluorine or chlorine atoms, which are also produced chemically. Simplified one-dimensional gas dynamic modeling that describes the stream-wise profiles of species concentrations within both reaction systems is used to gain a theoretical understanding of both reaction systems under COIL conditions. The modeling results are used for the design of an experimental device and the interpretation of experimental data. The first experimental investigation studies the production of iodine atoms produced from reactions of Cl with HI. Atomic iodine yields of 70–100% in nitrogen are obtained, and the gain on the I(2P1/2)–I(2P3/2) transition in a flow of singlet oxygen is measured. Špalek, O. aut Jirásek, V. aut Čenský, M. aut Hager, G.D. aut Enthalten in Applied physics. A, Materials science & processing Springer-Verlag, 1981 77(2003), 2 vom: Juli, Seite 331-336 (DE-627)129861340 (DE-600)283365-7 (DE-576)015171930 0947-8396 nnns volume:77 year:2003 number:2 month:07 pages:331-336 https://doi.org/10.1007/s00339-003-2136-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_20 GBV_ILN_21 GBV_ILN_22 GBV_ILN_30 GBV_ILN_31 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_70 GBV_ILN_130 GBV_ILN_150 GBV_ILN_170 GBV_ILN_2002 GBV_ILN_2005 GBV_ILN_2010 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_4012 GBV_ILN_4036 GBV_ILN_4116 GBV_ILN_4126 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4318 GBV_ILN_4319 GBV_ILN_4700 UA 9001.A AR 77 2003 2 07 331-336
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author	Kodymová, J.
spellingShingle	Kodymová, J. ddc 530 rvk UA 9001.A Development of the Chemical Oxygen-Iodine Laser (COIL) with chemical generation of atomic iodine
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title_full	Development of the Chemical Oxygen-Iodine Laser (COIL) with chemical generation of atomic iodine
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title_sort	development of the chemical oxygen-iodine laser (coil) with chemical generation of atomic iodine
title_auth	Development of the Chemical Oxygen-Iodine Laser (COIL) with chemical generation of atomic iodine
abstract	Abstract. This article addresses the development of a Chemical Oxygen-Iodine Laser (COIL) with alternative chemical ways of generating atomic iodine. Injection of atomic iodine as opposed to molecular iodine has the potential to improve the COIL efficiency. This paper describes two chemical methods for generating iodine atoms based on the gas phase reactions of hydrogen/deuterium iodide with fluorine or chlorine atoms, which are also produced chemically. Simplified one-dimensional gas dynamic modeling that describes the stream-wise profiles of species concentrations within both reaction systems is used to gain a theoretical understanding of both reaction systems under COIL conditions. The modeling results are used for the design of an experimental device and the interpretation of experimental data. The first experimental investigation studies the production of iodine atoms produced from reactions of Cl with HI. Atomic iodine yields of 70–100% in nitrogen are obtained, and the gain on the I(2P1/2)–I(2P3/2) transition in a flow of singlet oxygen is measured. © Springer-Verlag 2003
abstractGer	Abstract. This article addresses the development of a Chemical Oxygen-Iodine Laser (COIL) with alternative chemical ways of generating atomic iodine. Injection of atomic iodine as opposed to molecular iodine has the potential to improve the COIL efficiency. This paper describes two chemical methods for generating iodine atoms based on the gas phase reactions of hydrogen/deuterium iodide with fluorine or chlorine atoms, which are also produced chemically. Simplified one-dimensional gas dynamic modeling that describes the stream-wise profiles of species concentrations within both reaction systems is used to gain a theoretical understanding of both reaction systems under COIL conditions. The modeling results are used for the design of an experimental device and the interpretation of experimental data. The first experimental investigation studies the production of iodine atoms produced from reactions of Cl with HI. Atomic iodine yields of 70–100% in nitrogen are obtained, and the gain on the I(2P1/2)–I(2P3/2) transition in a flow of singlet oxygen is measured. © Springer-Verlag 2003
abstract_unstemmed	Abstract. This article addresses the development of a Chemical Oxygen-Iodine Laser (COIL) with alternative chemical ways of generating atomic iodine. Injection of atomic iodine as opposed to molecular iodine has the potential to improve the COIL efficiency. This paper describes two chemical methods for generating iodine atoms based on the gas phase reactions of hydrogen/deuterium iodide with fluorine or chlorine atoms, which are also produced chemically. Simplified one-dimensional gas dynamic modeling that describes the stream-wise profiles of species concentrations within both reaction systems is used to gain a theoretical understanding of both reaction systems under COIL conditions. The modeling results are used for the design of an experimental device and the interpretation of experimental data. The first experimental investigation studies the production of iodine atoms produced from reactions of Cl with HI. Atomic iodine yields of 70–100% in nitrogen are obtained, and the gain on the I(2P1/2)–I(2P3/2) transition in a flow of singlet oxygen is measured. © Springer-Verlag 2003
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title_short	Development of the Chemical Oxygen-Iodine Laser (COIL) with chemical generation of atomic iodine
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