Hole doping effects in ($ Sr_{2-x} $$ Na_{x} $)$ FeMoO_{6} $ double perovskite
Abstract Hole-doped double perovskite compounds (Sr,Na)2$ FeMoO_{6} $ with the Na content of x=0,0.02,0.03,0.07 and 0.17 have been synthesized by sol–gel method. Effects of hole doping on the crystal structure and magnetic properties of $ Sr_{2} $$ FeMoO_{6} $ have been investigated by means of X-ra...
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Autor*in: |
Zhang, Q. [verfasserIn] |
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Englisch |
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2006 |
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© Springer-Verlag 2006 |
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Übergeordnetes Werk: |
Enthalten in: Applied physics. A, Materials science & processing - Springer-Verlag, 1981, 84(2006), 4 vom: 04. Juli, Seite 459-463 |
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Übergeordnetes Werk: |
volume:84 ; year:2006 ; number:4 ; day:04 ; month:07 ; pages:459-463 |
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DOI / URN: |
10.1007/s00339-006-3646-5 |
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OLC207417764X |
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520 | |a Abstract Hole-doped double perovskite compounds (Sr,Na)2$ FeMoO_{6} $ with the Na content of x=0,0.02,0.03,0.07 and 0.17 have been synthesized by sol–gel method. Effects of hole doping on the crystal structure and magnetic properties of $ Sr_{2} $$ FeMoO_{6} $ have been investigated by means of X-ray powder diffraction (XRD) and magnetic measurements. The XRD pattern indicates that all the samples are of single phase and belong to the space group I4/m. Due to the smaller ionic radius of $ Na^{+} $ than that of $ Sr^{2+} $ ions, the lattice constants and unit cell volume of the compound decrease slightly with x. The degree of cation ordering in the Na-doped $ Sr_{2} $$ FeMoO_{6} $ compounds shows a non-monotonic variation with the doping level, increasing from x=0 to x=0.03 and decreasing slightly with further increase of the doping. In contrast to the composition dependence of the degree of ordering, the Curie temperature of the compound decreases at low doping level and increases at high doping level. The saturation magnetization of the compound increases with x for x<0.17. Similar to the electron-doped $ Sr_{2} $$ FeMoO_{6} $, provided that the doped hole enters selectively the spin-down band, the variation of the saturation magnetization can be explained in light of the ferrimagnetic model (FIM). | ||
650 | 4 | |a Saturation Magnetization | |
650 | 4 | |a Doping Level | |
650 | 4 | |a Unit Cell Volume | |
650 | 4 | |a High Doping Level | |
650 | 4 | |a Hole Doping | |
700 | 1 | |a Rao, G.H. |4 aut | |
700 | 1 | |a Xiao, Y.G. |4 aut | |
700 | 1 | |a Liu, G.Y. |4 aut | |
700 | 1 | |a Zhang, Y. |4 aut | |
700 | 1 | |a Liang, J.K. |4 aut | |
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10.1007/s00339-006-3646-5 doi (DE-627)OLC207417764X (DE-He213)s00339-006-3646-5-p DE-627 ger DE-627 rakwb eng 530 620 VZ 530 VZ UA 9001.A VZ rvk Zhang, Q. verfasserin aut Hole doping effects in ($ Sr_{2-x} $$ Na_{x} $)$ FeMoO_{6} $ double perovskite 2006 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 2006 Abstract Hole-doped double perovskite compounds (Sr,Na)2$ FeMoO_{6} $ with the Na content of x=0,0.02,0.03,0.07 and 0.17 have been synthesized by sol–gel method. Effects of hole doping on the crystal structure and magnetic properties of $ Sr_{2} $$ FeMoO_{6} $ have been investigated by means of X-ray powder diffraction (XRD) and magnetic measurements. The XRD pattern indicates that all the samples are of single phase and belong to the space group I4/m. Due to the smaller ionic radius of $ Na^{+} $ than that of $ Sr^{2+} $ ions, the lattice constants and unit cell volume of the compound decrease slightly with x. The degree of cation ordering in the Na-doped $ Sr_{2} $$ FeMoO_{6} $ compounds shows a non-monotonic variation with the doping level, increasing from x=0 to x=0.03 and decreasing slightly with further increase of the doping. In contrast to the composition dependence of the degree of ordering, the Curie temperature of the compound decreases at low doping level and increases at high doping level. The saturation magnetization of the compound increases with x for x<0.17. Similar to the electron-doped $ Sr_{2} $$ FeMoO_{6} $, provided that the doped hole enters selectively the spin-down band, the variation of the saturation magnetization can be explained in light of the ferrimagnetic model (FIM). Saturation Magnetization Doping Level Unit Cell Volume High Doping Level Hole Doping Rao, G.H. aut Xiao, Y.G. aut Liu, G.Y. aut Zhang, Y. aut Liang, J.K. aut Enthalten in Applied physics. A, Materials science & processing Springer-Verlag, 1981 84(2006), 4 vom: 04. Juli, Seite 459-463 (DE-627)129861340 (DE-600)283365-7 (DE-576)015171930 0947-8396 nnns volume:84 year:2006 number:4 day:04 month:07 pages:459-463 https://doi.org/10.1007/s00339-006-3646-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_21 GBV_ILN_22 GBV_ILN_30 GBV_ILN_31 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_70 GBV_ILN_130 GBV_ILN_150 GBV_ILN_170 GBV_ILN_2002 GBV_ILN_2010 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_4036 GBV_ILN_4116 GBV_ILN_4126 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4318 GBV_ILN_4319 GBV_ILN_4700 UA 9001.A AR 84 2006 4 04 07 459-463 |
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10.1007/s00339-006-3646-5 doi (DE-627)OLC207417764X (DE-He213)s00339-006-3646-5-p DE-627 ger DE-627 rakwb eng 530 620 VZ 530 VZ UA 9001.A VZ rvk Zhang, Q. verfasserin aut Hole doping effects in ($ Sr_{2-x} $$ Na_{x} $)$ FeMoO_{6} $ double perovskite 2006 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 2006 Abstract Hole-doped double perovskite compounds (Sr,Na)2$ FeMoO_{6} $ with the Na content of x=0,0.02,0.03,0.07 and 0.17 have been synthesized by sol–gel method. Effects of hole doping on the crystal structure and magnetic properties of $ Sr_{2} $$ FeMoO_{6} $ have been investigated by means of X-ray powder diffraction (XRD) and magnetic measurements. The XRD pattern indicates that all the samples are of single phase and belong to the space group I4/m. Due to the smaller ionic radius of $ Na^{+} $ than that of $ Sr^{2+} $ ions, the lattice constants and unit cell volume of the compound decrease slightly with x. The degree of cation ordering in the Na-doped $ Sr_{2} $$ FeMoO_{6} $ compounds shows a non-monotonic variation with the doping level, increasing from x=0 to x=0.03 and decreasing slightly with further increase of the doping. In contrast to the composition dependence of the degree of ordering, the Curie temperature of the compound decreases at low doping level and increases at high doping level. The saturation magnetization of the compound increases with x for x<0.17. Similar to the electron-doped $ Sr_{2} $$ FeMoO_{6} $, provided that the doped hole enters selectively the spin-down band, the variation of the saturation magnetization can be explained in light of the ferrimagnetic model (FIM). Saturation Magnetization Doping Level Unit Cell Volume High Doping Level Hole Doping Rao, G.H. aut Xiao, Y.G. aut Liu, G.Y. aut Zhang, Y. aut Liang, J.K. aut Enthalten in Applied physics. A, Materials science & processing Springer-Verlag, 1981 84(2006), 4 vom: 04. Juli, Seite 459-463 (DE-627)129861340 (DE-600)283365-7 (DE-576)015171930 0947-8396 nnns volume:84 year:2006 number:4 day:04 month:07 pages:459-463 https://doi.org/10.1007/s00339-006-3646-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_21 GBV_ILN_22 GBV_ILN_30 GBV_ILN_31 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_70 GBV_ILN_130 GBV_ILN_150 GBV_ILN_170 GBV_ILN_2002 GBV_ILN_2010 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_4036 GBV_ILN_4116 GBV_ILN_4126 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4318 GBV_ILN_4319 GBV_ILN_4700 UA 9001.A AR 84 2006 4 04 07 459-463 |
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10.1007/s00339-006-3646-5 doi (DE-627)OLC207417764X (DE-He213)s00339-006-3646-5-p DE-627 ger DE-627 rakwb eng 530 620 VZ 530 VZ UA 9001.A VZ rvk Zhang, Q. verfasserin aut Hole doping effects in ($ Sr_{2-x} $$ Na_{x} $)$ FeMoO_{6} $ double perovskite 2006 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 2006 Abstract Hole-doped double perovskite compounds (Sr,Na)2$ FeMoO_{6} $ with the Na content of x=0,0.02,0.03,0.07 and 0.17 have been synthesized by sol–gel method. Effects of hole doping on the crystal structure and magnetic properties of $ Sr_{2} $$ FeMoO_{6} $ have been investigated by means of X-ray powder diffraction (XRD) and magnetic measurements. The XRD pattern indicates that all the samples are of single phase and belong to the space group I4/m. Due to the smaller ionic radius of $ Na^{+} $ than that of $ Sr^{2+} $ ions, the lattice constants and unit cell volume of the compound decrease slightly with x. The degree of cation ordering in the Na-doped $ Sr_{2} $$ FeMoO_{6} $ compounds shows a non-monotonic variation with the doping level, increasing from x=0 to x=0.03 and decreasing slightly with further increase of the doping. In contrast to the composition dependence of the degree of ordering, the Curie temperature of the compound decreases at low doping level and increases at high doping level. The saturation magnetization of the compound increases with x for x<0.17. Similar to the electron-doped $ Sr_{2} $$ FeMoO_{6} $, provided that the doped hole enters selectively the spin-down band, the variation of the saturation magnetization can be explained in light of the ferrimagnetic model (FIM). Saturation Magnetization Doping Level Unit Cell Volume High Doping Level Hole Doping Rao, G.H. aut Xiao, Y.G. aut Liu, G.Y. aut Zhang, Y. aut Liang, J.K. aut Enthalten in Applied physics. A, Materials science & processing Springer-Verlag, 1981 84(2006), 4 vom: 04. Juli, Seite 459-463 (DE-627)129861340 (DE-600)283365-7 (DE-576)015171930 0947-8396 nnns volume:84 year:2006 number:4 day:04 month:07 pages:459-463 https://doi.org/10.1007/s00339-006-3646-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_21 GBV_ILN_22 GBV_ILN_30 GBV_ILN_31 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_70 GBV_ILN_130 GBV_ILN_150 GBV_ILN_170 GBV_ILN_2002 GBV_ILN_2010 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_4036 GBV_ILN_4116 GBV_ILN_4126 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4318 GBV_ILN_4319 GBV_ILN_4700 UA 9001.A AR 84 2006 4 04 07 459-463 |
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10.1007/s00339-006-3646-5 doi (DE-627)OLC207417764X (DE-He213)s00339-006-3646-5-p DE-627 ger DE-627 rakwb eng 530 620 VZ 530 VZ UA 9001.A VZ rvk Zhang, Q. verfasserin aut Hole doping effects in ($ Sr_{2-x} $$ Na_{x} $)$ FeMoO_{6} $ double perovskite 2006 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 2006 Abstract Hole-doped double perovskite compounds (Sr,Na)2$ FeMoO_{6} $ with the Na content of x=0,0.02,0.03,0.07 and 0.17 have been synthesized by sol–gel method. Effects of hole doping on the crystal structure and magnetic properties of $ Sr_{2} $$ FeMoO_{6} $ have been investigated by means of X-ray powder diffraction (XRD) and magnetic measurements. The XRD pattern indicates that all the samples are of single phase and belong to the space group I4/m. Due to the smaller ionic radius of $ Na^{+} $ than that of $ Sr^{2+} $ ions, the lattice constants and unit cell volume of the compound decrease slightly with x. The degree of cation ordering in the Na-doped $ Sr_{2} $$ FeMoO_{6} $ compounds shows a non-monotonic variation with the doping level, increasing from x=0 to x=0.03 and decreasing slightly with further increase of the doping. In contrast to the composition dependence of the degree of ordering, the Curie temperature of the compound decreases at low doping level and increases at high doping level. The saturation magnetization of the compound increases with x for x<0.17. Similar to the electron-doped $ Sr_{2} $$ FeMoO_{6} $, provided that the doped hole enters selectively the spin-down band, the variation of the saturation magnetization can be explained in light of the ferrimagnetic model (FIM). Saturation Magnetization Doping Level Unit Cell Volume High Doping Level Hole Doping Rao, G.H. aut Xiao, Y.G. aut Liu, G.Y. aut Zhang, Y. aut Liang, J.K. aut Enthalten in Applied physics. A, Materials science & processing Springer-Verlag, 1981 84(2006), 4 vom: 04. Juli, Seite 459-463 (DE-627)129861340 (DE-600)283365-7 (DE-576)015171930 0947-8396 nnns volume:84 year:2006 number:4 day:04 month:07 pages:459-463 https://doi.org/10.1007/s00339-006-3646-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_21 GBV_ILN_22 GBV_ILN_30 GBV_ILN_31 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_70 GBV_ILN_130 GBV_ILN_150 GBV_ILN_170 GBV_ILN_2002 GBV_ILN_2010 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_4036 GBV_ILN_4116 GBV_ILN_4126 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4318 GBV_ILN_4319 GBV_ILN_4700 UA 9001.A AR 84 2006 4 04 07 459-463 |
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10.1007/s00339-006-3646-5 doi (DE-627)OLC207417764X (DE-He213)s00339-006-3646-5-p DE-627 ger DE-627 rakwb eng 530 620 VZ 530 VZ UA 9001.A VZ rvk Zhang, Q. verfasserin aut Hole doping effects in ($ Sr_{2-x} $$ Na_{x} $)$ FeMoO_{6} $ double perovskite 2006 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 2006 Abstract Hole-doped double perovskite compounds (Sr,Na)2$ FeMoO_{6} $ with the Na content of x=0,0.02,0.03,0.07 and 0.17 have been synthesized by sol–gel method. Effects of hole doping on the crystal structure and magnetic properties of $ Sr_{2} $$ FeMoO_{6} $ have been investigated by means of X-ray powder diffraction (XRD) and magnetic measurements. The XRD pattern indicates that all the samples are of single phase and belong to the space group I4/m. Due to the smaller ionic radius of $ Na^{+} $ than that of $ Sr^{2+} $ ions, the lattice constants and unit cell volume of the compound decrease slightly with x. The degree of cation ordering in the Na-doped $ Sr_{2} $$ FeMoO_{6} $ compounds shows a non-monotonic variation with the doping level, increasing from x=0 to x=0.03 and decreasing slightly with further increase of the doping. In contrast to the composition dependence of the degree of ordering, the Curie temperature of the compound decreases at low doping level and increases at high doping level. The saturation magnetization of the compound increases with x for x<0.17. Similar to the electron-doped $ Sr_{2} $$ FeMoO_{6} $, provided that the doped hole enters selectively the spin-down band, the variation of the saturation magnetization can be explained in light of the ferrimagnetic model (FIM). Saturation Magnetization Doping Level Unit Cell Volume High Doping Level Hole Doping Rao, G.H. aut Xiao, Y.G. aut Liu, G.Y. aut Zhang, Y. aut Liang, J.K. aut Enthalten in Applied physics. A, Materials science & processing Springer-Verlag, 1981 84(2006), 4 vom: 04. Juli, Seite 459-463 (DE-627)129861340 (DE-600)283365-7 (DE-576)015171930 0947-8396 nnns volume:84 year:2006 number:4 day:04 month:07 pages:459-463 https://doi.org/10.1007/s00339-006-3646-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_21 GBV_ILN_22 GBV_ILN_30 GBV_ILN_31 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_70 GBV_ILN_130 GBV_ILN_150 GBV_ILN_170 GBV_ILN_2002 GBV_ILN_2010 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_4036 GBV_ILN_4116 GBV_ILN_4126 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4318 GBV_ILN_4319 GBV_ILN_4700 UA 9001.A AR 84 2006 4 04 07 459-463 |
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Enthalten in Applied physics. A, Materials science & processing 84(2006), 4 vom: 04. Juli, Seite 459-463 volume:84 year:2006 number:4 day:04 month:07 pages:459-463 |
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Effects of hole doping on the crystal structure and magnetic properties of $ Sr_{2} $$ FeMoO_{6} $ have been investigated by means of X-ray powder diffraction (XRD) and magnetic measurements. The XRD pattern indicates that all the samples are of single phase and belong to the space group I4/m. Due to the smaller ionic radius of $ Na^{+} $ than that of $ Sr^{2+} $ ions, the lattice constants and unit cell volume of the compound decrease slightly with x. The degree of cation ordering in the Na-doped $ Sr_{2} $$ FeMoO_{6} $ compounds shows a non-monotonic variation with the doping level, increasing from x=0 to x=0.03 and decreasing slightly with further increase of the doping. In contrast to the composition dependence of the degree of ordering, the Curie temperature of the compound decreases at low doping level and increases at high doping level. The saturation magnetization of the compound increases with x for x<0.17. 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Hole doping effects in ($ Sr_{2-x} $$ Na_{x} $)$ FeMoO_{6} $ double perovskite |
abstract |
Abstract Hole-doped double perovskite compounds (Sr,Na)2$ FeMoO_{6} $ with the Na content of x=0,0.02,0.03,0.07 and 0.17 have been synthesized by sol–gel method. Effects of hole doping on the crystal structure and magnetic properties of $ Sr_{2} $$ FeMoO_{6} $ have been investigated by means of X-ray powder diffraction (XRD) and magnetic measurements. The XRD pattern indicates that all the samples are of single phase and belong to the space group I4/m. Due to the smaller ionic radius of $ Na^{+} $ than that of $ Sr^{2+} $ ions, the lattice constants and unit cell volume of the compound decrease slightly with x. The degree of cation ordering in the Na-doped $ Sr_{2} $$ FeMoO_{6} $ compounds shows a non-monotonic variation with the doping level, increasing from x=0 to x=0.03 and decreasing slightly with further increase of the doping. In contrast to the composition dependence of the degree of ordering, the Curie temperature of the compound decreases at low doping level and increases at high doping level. The saturation magnetization of the compound increases with x for x<0.17. Similar to the electron-doped $ Sr_{2} $$ FeMoO_{6} $, provided that the doped hole enters selectively the spin-down band, the variation of the saturation magnetization can be explained in light of the ferrimagnetic model (FIM). © Springer-Verlag 2006 |
abstractGer |
Abstract Hole-doped double perovskite compounds (Sr,Na)2$ FeMoO_{6} $ with the Na content of x=0,0.02,0.03,0.07 and 0.17 have been synthesized by sol–gel method. Effects of hole doping on the crystal structure and magnetic properties of $ Sr_{2} $$ FeMoO_{6} $ have been investigated by means of X-ray powder diffraction (XRD) and magnetic measurements. The XRD pattern indicates that all the samples are of single phase and belong to the space group I4/m. Due to the smaller ionic radius of $ Na^{+} $ than that of $ Sr^{2+} $ ions, the lattice constants and unit cell volume of the compound decrease slightly with x. The degree of cation ordering in the Na-doped $ Sr_{2} $$ FeMoO_{6} $ compounds shows a non-monotonic variation with the doping level, increasing from x=0 to x=0.03 and decreasing slightly with further increase of the doping. In contrast to the composition dependence of the degree of ordering, the Curie temperature of the compound decreases at low doping level and increases at high doping level. The saturation magnetization of the compound increases with x for x<0.17. Similar to the electron-doped $ Sr_{2} $$ FeMoO_{6} $, provided that the doped hole enters selectively the spin-down band, the variation of the saturation magnetization can be explained in light of the ferrimagnetic model (FIM). © Springer-Verlag 2006 |
abstract_unstemmed |
Abstract Hole-doped double perovskite compounds (Sr,Na)2$ FeMoO_{6} $ with the Na content of x=0,0.02,0.03,0.07 and 0.17 have been synthesized by sol–gel method. Effects of hole doping on the crystal structure and magnetic properties of $ Sr_{2} $$ FeMoO_{6} $ have been investigated by means of X-ray powder diffraction (XRD) and magnetic measurements. The XRD pattern indicates that all the samples are of single phase and belong to the space group I4/m. Due to the smaller ionic radius of $ Na^{+} $ than that of $ Sr^{2+} $ ions, the lattice constants and unit cell volume of the compound decrease slightly with x. The degree of cation ordering in the Na-doped $ Sr_{2} $$ FeMoO_{6} $ compounds shows a non-monotonic variation with the doping level, increasing from x=0 to x=0.03 and decreasing slightly with further increase of the doping. In contrast to the composition dependence of the degree of ordering, the Curie temperature of the compound decreases at low doping level and increases at high doping level. The saturation magnetization of the compound increases with x for x<0.17. Similar to the electron-doped $ Sr_{2} $$ FeMoO_{6} $, provided that the doped hole enters selectively the spin-down band, the variation of the saturation magnetization can be explained in light of the ferrimagnetic model (FIM). © Springer-Verlag 2006 |
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Hole doping effects in ($ Sr_{2-x} $$ Na_{x} $)$ FeMoO_{6} $ double perovskite |
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