Effect of the anionic composition of an electrolyte on the rate of anodic ionization of nonpassivated metals
Abstract We show that a limiting current of diffusion nature is observed on the anodic polarization curves of iron and its analogs in relatively dilute acid solutions. The values of this current do not depend directly on the pH of the solution, but are related to the anion concentration. The last fe...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Tkalenko, D. A. [verfasserIn] |
|---|
| Format: |
Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2006 |
|---|
| Schlagwörter: |
|---|
| Anmerkung: |
© Springer Science+Business Media, Inc. 2006 |
|---|
| Übergeordnetes Werk: |
Enthalten in: Materials science - Kluwer Academic Publishers-Consultants Bureau, 1993, 42(2006), 5 vom: Sept., Seite 579-583 |
|---|---|
| Übergeordnetes Werk: |
volume:42 ; year:2006 ; number:5 ; month:09 ; pages:579-583 |
| Links: |
|---|
| DOI / URN: |
10.1007/s11003-006-0119-0 |
|---|
| Katalog-ID: |
OLC207530792X |
|---|
| LEADER | 01000caa a22002652 4500 | ||
|---|---|---|---|
| 001 | OLC207530792X | ||
| 003 | DE-627 | ||
| 005 | 20230503173617.0 | ||
| 007 | tu | ||
| 008 | 200820s2006 xx ||||| 00| ||eng c | ||
| 024 | 7 | |a 10.1007/s11003-006-0119-0 |2 doi | |
| 035 | |a (DE-627)OLC207530792X | ||
| 035 | |a (DE-He213)s11003-006-0119-0-p | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 082 | 0 | 4 | |a 540 |a 600 |a 670 |q VZ |
| 100 | 1 | |a Tkalenko, D. A. |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Effect of the anionic composition of an electrolyte on the rate of anodic ionization of nonpassivated metals |
| 264 | 1 | |c 2006 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a ohne Hilfsmittel zu benutzen |b n |2 rdamedia | ||
| 338 | |a Band |b nc |2 rdacarrier | ||
| 500 | |a © Springer Science+Business Media, Inc. 2006 | ||
| 520 | |a Abstract We show that a limiting current of diffusion nature is observed on the anodic polarization curves of iron and its analogs in relatively dilute acid solutions. The values of this current do not depend directly on the pH of the solution, but are related to the anion concentration. The last feature formed the basis of the hypothesis that the limiting current is determined by the delivery rate of anions, which take part in the neutralization of positive charge of the formed metal cations, to the surface of the electrode. This hypothesis envisages the formation of such labile particles as ion pairs or cation-anion complexes in the course of anodic dissolution of iron. | ||
| 650 | 4 | |a Polarization Curve | |
| 650 | 4 | |a Anodic Dissolution | |
| 650 | 4 | |a Sulfuric Acid Solution | |
| 650 | 4 | |a Anodic Process | |
| 650 | 4 | |a Anodic Polarization Curve | |
| 700 | 1 | |a Byk, M. V. |4 aut | |
| 700 | 1 | |a Harbuz, V. M. |4 aut | |
| 700 | 1 | |a Vyshnevs’ka, Yu. P. |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Materials science |d Kluwer Academic Publishers-Consultants Bureau, 1993 |g 42(2006), 5 vom: Sept., Seite 579-583 |w (DE-627)171289099 |w (DE-600)1174050-4 |w (DE-576)038733633 |x 1068-820X |7 nnns |
| 773 | 1 | 8 | |g volume:42 |g year:2006 |g number:5 |g month:09 |g pages:579-583 |
| 856 | 4 | 1 | |u https://doi.org/10.1007/s11003-006-0119-0 |z lizenzpflichtig |3 Volltext |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a SYSFLAG_A | ||
| 912 | |a GBV_OLC | ||
| 912 | |a SSG-OLC-TEC | ||
| 912 | |a SSG-OLC-CHE | ||
| 912 | |a GBV_ILN_70 | ||
| 951 | |a AR | ||
| 952 | |d 42 |j 2006 |e 5 |c 09 |h 579-583 | ||
| author_variant |
d a t da dat m v b mv mvb v m h vm vmh y p v yp ypv |
|---|---|
| matchkey_str |
article:1068820X:2006----::fetfhaincopstooaeetoyenhrtoaoiinzt |
| hierarchy_sort_str |
2006 |
| publishDate |
2006 |
| allfields |
10.1007/s11003-006-0119-0 doi (DE-627)OLC207530792X (DE-He213)s11003-006-0119-0-p DE-627 ger DE-627 rakwb eng 540 600 670 VZ Tkalenko, D. A. verfasserin aut Effect of the anionic composition of an electrolyte on the rate of anodic ionization of nonpassivated metals 2006 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, Inc. 2006 Abstract We show that a limiting current of diffusion nature is observed on the anodic polarization curves of iron and its analogs in relatively dilute acid solutions. The values of this current do not depend directly on the pH of the solution, but are related to the anion concentration. The last feature formed the basis of the hypothesis that the limiting current is determined by the delivery rate of anions, which take part in the neutralization of positive charge of the formed metal cations, to the surface of the electrode. This hypothesis envisages the formation of such labile particles as ion pairs or cation-anion complexes in the course of anodic dissolution of iron. Polarization Curve Anodic Dissolution Sulfuric Acid Solution Anodic Process Anodic Polarization Curve Byk, M. V. aut Harbuz, V. M. aut Vyshnevs’ka, Yu. P. aut Enthalten in Materials science Kluwer Academic Publishers-Consultants Bureau, 1993 42(2006), 5 vom: Sept., Seite 579-583 (DE-627)171289099 (DE-600)1174050-4 (DE-576)038733633 1068-820X nnns volume:42 year:2006 number:5 month:09 pages:579-583 https://doi.org/10.1007/s11003-006-0119-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 42 2006 5 09 579-583 |
| spelling |
10.1007/s11003-006-0119-0 doi (DE-627)OLC207530792X (DE-He213)s11003-006-0119-0-p DE-627 ger DE-627 rakwb eng 540 600 670 VZ Tkalenko, D. A. verfasserin aut Effect of the anionic composition of an electrolyte on the rate of anodic ionization of nonpassivated metals 2006 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, Inc. 2006 Abstract We show that a limiting current of diffusion nature is observed on the anodic polarization curves of iron and its analogs in relatively dilute acid solutions. The values of this current do not depend directly on the pH of the solution, but are related to the anion concentration. The last feature formed the basis of the hypothesis that the limiting current is determined by the delivery rate of anions, which take part in the neutralization of positive charge of the formed metal cations, to the surface of the electrode. This hypothesis envisages the formation of such labile particles as ion pairs or cation-anion complexes in the course of anodic dissolution of iron. Polarization Curve Anodic Dissolution Sulfuric Acid Solution Anodic Process Anodic Polarization Curve Byk, M. V. aut Harbuz, V. M. aut Vyshnevs’ka, Yu. P. aut Enthalten in Materials science Kluwer Academic Publishers-Consultants Bureau, 1993 42(2006), 5 vom: Sept., Seite 579-583 (DE-627)171289099 (DE-600)1174050-4 (DE-576)038733633 1068-820X nnns volume:42 year:2006 number:5 month:09 pages:579-583 https://doi.org/10.1007/s11003-006-0119-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 42 2006 5 09 579-583 |
| allfields_unstemmed |
10.1007/s11003-006-0119-0 doi (DE-627)OLC207530792X (DE-He213)s11003-006-0119-0-p DE-627 ger DE-627 rakwb eng 540 600 670 VZ Tkalenko, D. A. verfasserin aut Effect of the anionic composition of an electrolyte on the rate of anodic ionization of nonpassivated metals 2006 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, Inc. 2006 Abstract We show that a limiting current of diffusion nature is observed on the anodic polarization curves of iron and its analogs in relatively dilute acid solutions. The values of this current do not depend directly on the pH of the solution, but are related to the anion concentration. The last feature formed the basis of the hypothesis that the limiting current is determined by the delivery rate of anions, which take part in the neutralization of positive charge of the formed metal cations, to the surface of the electrode. This hypothesis envisages the formation of such labile particles as ion pairs or cation-anion complexes in the course of anodic dissolution of iron. Polarization Curve Anodic Dissolution Sulfuric Acid Solution Anodic Process Anodic Polarization Curve Byk, M. V. aut Harbuz, V. M. aut Vyshnevs’ka, Yu. P. aut Enthalten in Materials science Kluwer Academic Publishers-Consultants Bureau, 1993 42(2006), 5 vom: Sept., Seite 579-583 (DE-627)171289099 (DE-600)1174050-4 (DE-576)038733633 1068-820X nnns volume:42 year:2006 number:5 month:09 pages:579-583 https://doi.org/10.1007/s11003-006-0119-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 42 2006 5 09 579-583 |
| allfieldsGer |
10.1007/s11003-006-0119-0 doi (DE-627)OLC207530792X (DE-He213)s11003-006-0119-0-p DE-627 ger DE-627 rakwb eng 540 600 670 VZ Tkalenko, D. A. verfasserin aut Effect of the anionic composition of an electrolyte on the rate of anodic ionization of nonpassivated metals 2006 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, Inc. 2006 Abstract We show that a limiting current of diffusion nature is observed on the anodic polarization curves of iron and its analogs in relatively dilute acid solutions. The values of this current do not depend directly on the pH of the solution, but are related to the anion concentration. The last feature formed the basis of the hypothesis that the limiting current is determined by the delivery rate of anions, which take part in the neutralization of positive charge of the formed metal cations, to the surface of the electrode. This hypothesis envisages the formation of such labile particles as ion pairs or cation-anion complexes in the course of anodic dissolution of iron. Polarization Curve Anodic Dissolution Sulfuric Acid Solution Anodic Process Anodic Polarization Curve Byk, M. V. aut Harbuz, V. M. aut Vyshnevs’ka, Yu. P. aut Enthalten in Materials science Kluwer Academic Publishers-Consultants Bureau, 1993 42(2006), 5 vom: Sept., Seite 579-583 (DE-627)171289099 (DE-600)1174050-4 (DE-576)038733633 1068-820X nnns volume:42 year:2006 number:5 month:09 pages:579-583 https://doi.org/10.1007/s11003-006-0119-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 42 2006 5 09 579-583 |
| allfieldsSound |
10.1007/s11003-006-0119-0 doi (DE-627)OLC207530792X (DE-He213)s11003-006-0119-0-p DE-627 ger DE-627 rakwb eng 540 600 670 VZ Tkalenko, D. A. verfasserin aut Effect of the anionic composition of an electrolyte on the rate of anodic ionization of nonpassivated metals 2006 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, Inc. 2006 Abstract We show that a limiting current of diffusion nature is observed on the anodic polarization curves of iron and its analogs in relatively dilute acid solutions. The values of this current do not depend directly on the pH of the solution, but are related to the anion concentration. The last feature formed the basis of the hypothesis that the limiting current is determined by the delivery rate of anions, which take part in the neutralization of positive charge of the formed metal cations, to the surface of the electrode. This hypothesis envisages the formation of such labile particles as ion pairs or cation-anion complexes in the course of anodic dissolution of iron. Polarization Curve Anodic Dissolution Sulfuric Acid Solution Anodic Process Anodic Polarization Curve Byk, M. V. aut Harbuz, V. M. aut Vyshnevs’ka, Yu. P. aut Enthalten in Materials science Kluwer Academic Publishers-Consultants Bureau, 1993 42(2006), 5 vom: Sept., Seite 579-583 (DE-627)171289099 (DE-600)1174050-4 (DE-576)038733633 1068-820X nnns volume:42 year:2006 number:5 month:09 pages:579-583 https://doi.org/10.1007/s11003-006-0119-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 42 2006 5 09 579-583 |
| language |
English |
| source |
Enthalten in Materials science 42(2006), 5 vom: Sept., Seite 579-583 volume:42 year:2006 number:5 month:09 pages:579-583 |
| sourceStr |
Enthalten in Materials science 42(2006), 5 vom: Sept., Seite 579-583 volume:42 year:2006 number:5 month:09 pages:579-583 |
| format_phy_str_mv |
Article |
| institution |
findex.gbv.de |
| topic_facet |
Polarization Curve Anodic Dissolution Sulfuric Acid Solution Anodic Process Anodic Polarization Curve |
| dewey-raw |
540 |
| isfreeaccess_bool |
false |
| container_title |
Materials science |
| authorswithroles_txt_mv |
Tkalenko, D. A. @@aut@@ Byk, M. V. @@aut@@ Harbuz, V. M. @@aut@@ Vyshnevs’ka, Yu. P. @@aut@@ |
| publishDateDaySort_date |
2006-09-01T00:00:00Z |
| hierarchy_top_id |
171289099 |
| dewey-sort |
3540 |
| id |
OLC207530792X |
| language_de |
englisch |
| fullrecord |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC207530792X</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230503173617.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">200820s2006 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s11003-006-0119-0</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC207530792X</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)s11003-006-0119-0-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="a">600</subfield><subfield code="a">670</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Tkalenko, D. A.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Effect of the anionic composition of an electrolyte on the rate of anodic ionization of nonpassivated metals</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2006</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Springer Science+Business Media, Inc. 2006</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract We show that a limiting current of diffusion nature is observed on the anodic polarization curves of iron and its analogs in relatively dilute acid solutions. The values of this current do not depend directly on the pH of the solution, but are related to the anion concentration. The last feature formed the basis of the hypothesis that the limiting current is determined by the delivery rate of anions, which take part in the neutralization of positive charge of the formed metal cations, to the surface of the electrode. This hypothesis envisages the formation of such labile particles as ion pairs or cation-anion complexes in the course of anodic dissolution of iron.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Polarization Curve</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Anodic Dissolution</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Sulfuric Acid Solution</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Anodic Process</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Anodic Polarization Curve</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Byk, M. V.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Harbuz, V. M.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Vyshnevs’ka, Yu. P.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Materials science</subfield><subfield code="d">Kluwer Academic Publishers-Consultants Bureau, 1993</subfield><subfield code="g">42(2006), 5 vom: Sept., Seite 579-583</subfield><subfield code="w">(DE-627)171289099</subfield><subfield code="w">(DE-600)1174050-4</subfield><subfield code="w">(DE-576)038733633</subfield><subfield code="x">1068-820X</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:42</subfield><subfield code="g">year:2006</subfield><subfield code="g">number:5</subfield><subfield code="g">month:09</subfield><subfield code="g">pages:579-583</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/s11003-006-0119-0</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">42</subfield><subfield code="j">2006</subfield><subfield code="e">5</subfield><subfield code="c">09</subfield><subfield code="h">579-583</subfield></datafield></record></collection>
|
| author |
Tkalenko, D. A. |
| spellingShingle |
Tkalenko, D. A. ddc 540 misc Polarization Curve misc Anodic Dissolution misc Sulfuric Acid Solution misc Anodic Process misc Anodic Polarization Curve Effect of the anionic composition of an electrolyte on the rate of anodic ionization of nonpassivated metals |
| authorStr |
Tkalenko, D. A. |
| ppnlink_with_tag_str_mv |
@@773@@(DE-627)171289099 |
| format |
Article |
| dewey-ones |
540 - Chemistry & allied sciences 600 - Technology 670 - Manufacturing |
| delete_txt_mv |
keep |
| author_role |
aut aut aut aut |
| collection |
OLC |
| remote_str |
false |
| illustrated |
Not Illustrated |
| issn |
1068-820X |
| topic_title |
540 600 670 VZ Effect of the anionic composition of an electrolyte on the rate of anodic ionization of nonpassivated metals Polarization Curve Anodic Dissolution Sulfuric Acid Solution Anodic Process Anodic Polarization Curve |
| topic |
ddc 540 misc Polarization Curve misc Anodic Dissolution misc Sulfuric Acid Solution misc Anodic Process misc Anodic Polarization Curve |
| topic_unstemmed |
ddc 540 misc Polarization Curve misc Anodic Dissolution misc Sulfuric Acid Solution misc Anodic Process misc Anodic Polarization Curve |
| topic_browse |
ddc 540 misc Polarization Curve misc Anodic Dissolution misc Sulfuric Acid Solution misc Anodic Process misc Anodic Polarization Curve |
| format_facet |
Aufsätze Gedruckte Aufsätze |
| format_main_str_mv |
Text Zeitschrift/Artikel |
| carriertype_str_mv |
nc |
| hierarchy_parent_title |
Materials science |
| hierarchy_parent_id |
171289099 |
| dewey-tens |
540 - Chemistry 600 - Technology 670 - Manufacturing |
| hierarchy_top_title |
Materials science |
| isfreeaccess_txt |
false |
| familylinks_str_mv |
(DE-627)171289099 (DE-600)1174050-4 (DE-576)038733633 |
| title |
Effect of the anionic composition of an electrolyte on the rate of anodic ionization of nonpassivated metals |
| ctrlnum |
(DE-627)OLC207530792X (DE-He213)s11003-006-0119-0-p |
| title_full |
Effect of the anionic composition of an electrolyte on the rate of anodic ionization of nonpassivated metals |
| author_sort |
Tkalenko, D. A. |
| journal |
Materials science |
| journalStr |
Materials science |
| lang_code |
eng |
| isOA_bool |
false |
| dewey-hundreds |
500 - Science 600 - Technology |
| recordtype |
marc |
| publishDateSort |
2006 |
| contenttype_str_mv |
txt |
| container_start_page |
579 |
| author_browse |
Tkalenko, D. A. Byk, M. V. Harbuz, V. M. Vyshnevs’ka, Yu. P. |
| container_volume |
42 |
| class |
540 600 670 VZ |
| format_se |
Aufsätze |
| author-letter |
Tkalenko, D. A. |
| doi_str_mv |
10.1007/s11003-006-0119-0 |
| dewey-full |
540 600 670 |
| title_sort |
effect of the anionic composition of an electrolyte on the rate of anodic ionization of nonpassivated metals |
| title_auth |
Effect of the anionic composition of an electrolyte on the rate of anodic ionization of nonpassivated metals |
| abstract |
Abstract We show that a limiting current of diffusion nature is observed on the anodic polarization curves of iron and its analogs in relatively dilute acid solutions. The values of this current do not depend directly on the pH of the solution, but are related to the anion concentration. The last feature formed the basis of the hypothesis that the limiting current is determined by the delivery rate of anions, which take part in the neutralization of positive charge of the formed metal cations, to the surface of the electrode. This hypothesis envisages the formation of such labile particles as ion pairs or cation-anion complexes in the course of anodic dissolution of iron. © Springer Science+Business Media, Inc. 2006 |
| abstractGer |
Abstract We show that a limiting current of diffusion nature is observed on the anodic polarization curves of iron and its analogs in relatively dilute acid solutions. The values of this current do not depend directly on the pH of the solution, but are related to the anion concentration. The last feature formed the basis of the hypothesis that the limiting current is determined by the delivery rate of anions, which take part in the neutralization of positive charge of the formed metal cations, to the surface of the electrode. This hypothesis envisages the formation of such labile particles as ion pairs or cation-anion complexes in the course of anodic dissolution of iron. © Springer Science+Business Media, Inc. 2006 |
| abstract_unstemmed |
Abstract We show that a limiting current of diffusion nature is observed on the anodic polarization curves of iron and its analogs in relatively dilute acid solutions. The values of this current do not depend directly on the pH of the solution, but are related to the anion concentration. The last feature formed the basis of the hypothesis that the limiting current is determined by the delivery rate of anions, which take part in the neutralization of positive charge of the formed metal cations, to the surface of the electrode. This hypothesis envisages the formation of such labile particles as ion pairs or cation-anion complexes in the course of anodic dissolution of iron. © Springer Science+Business Media, Inc. 2006 |
| collection_details |
GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 |
| container_issue |
5 |
| title_short |
Effect of the anionic composition of an electrolyte on the rate of anodic ionization of nonpassivated metals |
| url |
https://doi.org/10.1007/s11003-006-0119-0 |
| remote_bool |
false |
| author2 |
Byk, M. V. Harbuz, V. M. Vyshnevs’ka, Yu. P. |
| author2Str |
Byk, M. V. Harbuz, V. M. Vyshnevs’ka, Yu. P. |
| ppnlink |
171289099 |
| mediatype_str_mv |
n |
| isOA_txt |
false |
| hochschulschrift_bool |
false |
| doi_str |
10.1007/s11003-006-0119-0 |
| up_date |
2024-07-04T00:58:04.715Z |
| _version_ |
1803608061079715840 |
| fullrecord_marcxml |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC207530792X</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230503173617.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">200820s2006 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s11003-006-0119-0</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC207530792X</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)s11003-006-0119-0-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="a">600</subfield><subfield code="a">670</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Tkalenko, D. A.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Effect of the anionic composition of an electrolyte on the rate of anodic ionization of nonpassivated metals</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2006</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Springer Science+Business Media, Inc. 2006</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract We show that a limiting current of diffusion nature is observed on the anodic polarization curves of iron and its analogs in relatively dilute acid solutions. The values of this current do not depend directly on the pH of the solution, but are related to the anion concentration. The last feature formed the basis of the hypothesis that the limiting current is determined by the delivery rate of anions, which take part in the neutralization of positive charge of the formed metal cations, to the surface of the electrode. This hypothesis envisages the formation of such labile particles as ion pairs or cation-anion complexes in the course of anodic dissolution of iron.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Polarization Curve</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Anodic Dissolution</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Sulfuric Acid Solution</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Anodic Process</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Anodic Polarization Curve</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Byk, M. V.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Harbuz, V. M.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Vyshnevs’ka, Yu. P.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Materials science</subfield><subfield code="d">Kluwer Academic Publishers-Consultants Bureau, 1993</subfield><subfield code="g">42(2006), 5 vom: Sept., Seite 579-583</subfield><subfield code="w">(DE-627)171289099</subfield><subfield code="w">(DE-600)1174050-4</subfield><subfield code="w">(DE-576)038733633</subfield><subfield code="x">1068-820X</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:42</subfield><subfield code="g">year:2006</subfield><subfield code="g">number:5</subfield><subfield code="g">month:09</subfield><subfield code="g">pages:579-583</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/s11003-006-0119-0</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">42</subfield><subfield code="j">2006</subfield><subfield code="e">5</subfield><subfield code="c">09</subfield><subfield code="h">579-583</subfield></datafield></record></collection>
|
| score |
7.398406 |