Entropy Flow of Chemical Oscillating Reactions Involving Amino Acids
Abstract Variations of $ H^{+} $, $ Mn^{2+} $, and $${{\rm BrO}_3^-}$$ during chemical oscillating reactions involving amino acids were investigated using $ H_{2} $$ SO_{4} $–$${{\rm BrO}_3^{-}}$$ –$ Mn^{2+} $–acetone as an oscillator, and the thermodynamic functions (ΔS, ΔH, and ΔG) were calculated...
Ausführliche Beschreibung
Gespeichert in:
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Pu, X. H. [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2012 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer Science+Business Media, LLC 2012 |
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| Übergeordnetes Werk: |
Enthalten in: International journal of thermophysics - Springer US, 1980, 33(2012), 3 vom: 12. Feb., Seite 505-512 |
|---|---|
| Übergeordnetes Werk: |
volume:33 ; year:2012 ; number:3 ; day:12 ; month:02 ; pages:505-512 |
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| DOI / URN: |
10.1007/s10765-012-1155-7 |
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| 520 | |a Abstract Variations of $ H^{+} $, $ Mn^{2+} $, and $${{\rm BrO}_3^-}$$ during chemical oscillating reactions involving amino acids were investigated using $ H_{2} $$ SO_{4} $–$${{\rm BrO}_3^{-}}$$ –$ Mn^{2+} $–acetone as an oscillator, and the thermodynamic functions (ΔS, ΔH, and ΔG) were calculated. The results indicated that the oscillating reaction is a process from disorder to order. In the oscillating system, the heat provided by the environment is used to increase the internal energy and entropy. When external positive entropy flow could make the system reach negative entropy flow, the system starts to oscillate and to maintain oscillations by a stable entropy. | ||
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10.1007/s10765-012-1155-7 doi (DE-627)OLC2076475524 (DE-He213)s10765-012-1155-7-p DE-627 ger DE-627 rakwb eng 530 VZ Pu, X. H. verfasserin aut Entropy Flow of Chemical Oscillating Reactions Involving Amino Acids 2012 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2012 Abstract Variations of $ H^{+} $, $ Mn^{2+} $, and $${{\rm BrO}_3^-}$$ during chemical oscillating reactions involving amino acids were investigated using $ H_{2} $$ SO_{4} $–$${{\rm BrO}_3^{-}}$$ –$ Mn^{2+} $–acetone as an oscillator, and the thermodynamic functions (ΔS, ΔH, and ΔG) were calculated. The results indicated that the oscillating reaction is a process from disorder to order. In the oscillating system, the heat provided by the environment is used to increase the internal energy and entropy. When external positive entropy flow could make the system reach negative entropy flow, the system starts to oscillate and to maintain oscillations by a stable entropy. Activation Chemical oscillation Entropy flow Open system Thermodynamic function Li, Z. X. aut Enthalten in International journal of thermophysics Springer US, 1980 33(2012), 3 vom: 12. Feb., Seite 505-512 (DE-627)130512540 (DE-600)764389-5 (DE-576)016085965 0195-928X nnns volume:33 year:2012 number:3 day:12 month:02 pages:505-512 https://doi.org/10.1007/s10765-012-1155-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_170 GBV_ILN_4012 GBV_ILN_4700 AR 33 2012 3 12 02 505-512 |
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10.1007/s10765-012-1155-7 doi (DE-627)OLC2076475524 (DE-He213)s10765-012-1155-7-p DE-627 ger DE-627 rakwb eng 530 VZ Pu, X. H. verfasserin aut Entropy Flow of Chemical Oscillating Reactions Involving Amino Acids 2012 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2012 Abstract Variations of $ H^{+} $, $ Mn^{2+} $, and $${{\rm BrO}_3^-}$$ during chemical oscillating reactions involving amino acids were investigated using $ H_{2} $$ SO_{4} $–$${{\rm BrO}_3^{-}}$$ –$ Mn^{2+} $–acetone as an oscillator, and the thermodynamic functions (ΔS, ΔH, and ΔG) were calculated. The results indicated that the oscillating reaction is a process from disorder to order. In the oscillating system, the heat provided by the environment is used to increase the internal energy and entropy. When external positive entropy flow could make the system reach negative entropy flow, the system starts to oscillate and to maintain oscillations by a stable entropy. Activation Chemical oscillation Entropy flow Open system Thermodynamic function Li, Z. X. aut Enthalten in International journal of thermophysics Springer US, 1980 33(2012), 3 vom: 12. Feb., Seite 505-512 (DE-627)130512540 (DE-600)764389-5 (DE-576)016085965 0195-928X nnns volume:33 year:2012 number:3 day:12 month:02 pages:505-512 https://doi.org/10.1007/s10765-012-1155-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_170 GBV_ILN_4012 GBV_ILN_4700 AR 33 2012 3 12 02 505-512 |
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10.1007/s10765-012-1155-7 doi (DE-627)OLC2076475524 (DE-He213)s10765-012-1155-7-p DE-627 ger DE-627 rakwb eng 530 VZ Pu, X. H. verfasserin aut Entropy Flow of Chemical Oscillating Reactions Involving Amino Acids 2012 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2012 Abstract Variations of $ H^{+} $, $ Mn^{2+} $, and $${{\rm BrO}_3^-}$$ during chemical oscillating reactions involving amino acids were investigated using $ H_{2} $$ SO_{4} $–$${{\rm BrO}_3^{-}}$$ –$ Mn^{2+} $–acetone as an oscillator, and the thermodynamic functions (ΔS, ΔH, and ΔG) were calculated. The results indicated that the oscillating reaction is a process from disorder to order. In the oscillating system, the heat provided by the environment is used to increase the internal energy and entropy. When external positive entropy flow could make the system reach negative entropy flow, the system starts to oscillate and to maintain oscillations by a stable entropy. Activation Chemical oscillation Entropy flow Open system Thermodynamic function Li, Z. X. aut Enthalten in International journal of thermophysics Springer US, 1980 33(2012), 3 vom: 12. Feb., Seite 505-512 (DE-627)130512540 (DE-600)764389-5 (DE-576)016085965 0195-928X nnns volume:33 year:2012 number:3 day:12 month:02 pages:505-512 https://doi.org/10.1007/s10765-012-1155-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_170 GBV_ILN_4012 GBV_ILN_4700 AR 33 2012 3 12 02 505-512 |
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10.1007/s10765-012-1155-7 doi (DE-627)OLC2076475524 (DE-He213)s10765-012-1155-7-p DE-627 ger DE-627 rakwb eng 530 VZ Pu, X. H. verfasserin aut Entropy Flow of Chemical Oscillating Reactions Involving Amino Acids 2012 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2012 Abstract Variations of $ H^{+} $, $ Mn^{2+} $, and $${{\rm BrO}_3^-}$$ during chemical oscillating reactions involving amino acids were investigated using $ H_{2} $$ SO_{4} $–$${{\rm BrO}_3^{-}}$$ –$ Mn^{2+} $–acetone as an oscillator, and the thermodynamic functions (ΔS, ΔH, and ΔG) were calculated. The results indicated that the oscillating reaction is a process from disorder to order. In the oscillating system, the heat provided by the environment is used to increase the internal energy and entropy. When external positive entropy flow could make the system reach negative entropy flow, the system starts to oscillate and to maintain oscillations by a stable entropy. Activation Chemical oscillation Entropy flow Open system Thermodynamic function Li, Z. X. aut Enthalten in International journal of thermophysics Springer US, 1980 33(2012), 3 vom: 12. Feb., Seite 505-512 (DE-627)130512540 (DE-600)764389-5 (DE-576)016085965 0195-928X nnns volume:33 year:2012 number:3 day:12 month:02 pages:505-512 https://doi.org/10.1007/s10765-012-1155-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_170 GBV_ILN_4012 GBV_ILN_4700 AR 33 2012 3 12 02 505-512 |
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Abstract Variations of $ H^{+} $, $ Mn^{2+} $, and $${{\rm BrO}_3^-}$$ during chemical oscillating reactions involving amino acids were investigated using $ H_{2} $$ SO_{4} $–$${{\rm BrO}_3^{-}}$$ –$ Mn^{2+} $–acetone as an oscillator, and the thermodynamic functions (ΔS, ΔH, and ΔG) were calculated. The results indicated that the oscillating reaction is a process from disorder to order. In the oscillating system, the heat provided by the environment is used to increase the internal energy and entropy. When external positive entropy flow could make the system reach negative entropy flow, the system starts to oscillate and to maintain oscillations by a stable entropy. © Springer Science+Business Media, LLC 2012 |
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Abstract Variations of $ H^{+} $, $ Mn^{2+} $, and $${{\rm BrO}_3^-}$$ during chemical oscillating reactions involving amino acids were investigated using $ H_{2} $$ SO_{4} $–$${{\rm BrO}_3^{-}}$$ –$ Mn^{2+} $–acetone as an oscillator, and the thermodynamic functions (ΔS, ΔH, and ΔG) were calculated. The results indicated that the oscillating reaction is a process from disorder to order. In the oscillating system, the heat provided by the environment is used to increase the internal energy and entropy. When external positive entropy flow could make the system reach negative entropy flow, the system starts to oscillate and to maintain oscillations by a stable entropy. © Springer Science+Business Media, LLC 2012 |
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Abstract Variations of $ H^{+} $, $ Mn^{2+} $, and $${{\rm BrO}_3^-}$$ during chemical oscillating reactions involving amino acids were investigated using $ H_{2} $$ SO_{4} $–$${{\rm BrO}_3^{-}}$$ –$ Mn^{2+} $–acetone as an oscillator, and the thermodynamic functions (ΔS, ΔH, and ΔG) were calculated. The results indicated that the oscillating reaction is a process from disorder to order. In the oscillating system, the heat provided by the environment is used to increase the internal energy and entropy. When external positive entropy flow could make the system reach negative entropy flow, the system starts to oscillate and to maintain oscillations by a stable entropy. © Springer Science+Business Media, LLC 2012 |
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H.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Entropy Flow of Chemical Oscillating Reactions Involving Amino Acids</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2012</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Springer Science+Business Media, LLC 2012</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Variations of $ H^{+} $, $ Mn^{2+} $, and $${{\rm BrO}_3^-}$$ during chemical oscillating reactions involving amino acids were investigated using $ H_{2} $$ SO_{4} $–$${{\rm BrO}_3^{-}}$$ –$ Mn^{2+} $–acetone as an oscillator, and the thermodynamic functions (ΔS, ΔH, and ΔG) were calculated. 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