Structural, Optical and Magnetic Properties of Diamagnetic $ Cd^{2+} $ Incorporated Cobalt Ferrite Thin Films Deposited by Spray Pyrolysis
Abstract Cadmium ($ Cd^{2+} $)-substituted cobalt ferrite thin films with configuration $ Co_{1−x} $$ Cd_{x} $$ Fe_{2} $$ O_{4} $ (x = 0.0 to 1.0 in steps of 0.2) were grown via spray pyrolysis. The influence of $ Cd^{2+} $ substitution on structural and functional properties was investigated. X-ray...
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| Autor*in: |
Jadhav, Gajanan L. [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2021 |
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| Schlagwörter: |
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| Anmerkung: |
© The Minerals, Metals & Materials Society 2021 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of electronic materials - Springer US, 1972, 50(2021), 11 vom: 13. Sept., Seite 6525-6534 |
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| Übergeordnetes Werk: |
volume:50 ; year:2021 ; number:11 ; day:13 ; month:09 ; pages:6525-6534 |
| Links: |
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| DOI / URN: |
10.1007/s11664-021-09199-7 |
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| Katalog-ID: |
OLC2077056711 |
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| 245 | 1 | 0 | |a Structural, Optical and Magnetic Properties of Diamagnetic $ Cd^{2+} $ Incorporated Cobalt Ferrite Thin Films Deposited by Spray Pyrolysis |
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| 520 | |a Abstract Cadmium ($ Cd^{2+} $)-substituted cobalt ferrite thin films with configuration $ Co_{1−x} $$ Cd_{x} $$ Fe_{2} $$ O_{4} $ (x = 0.0 to 1.0 in steps of 0.2) were grown via spray pyrolysis. The influence of $ Cd^{2+} $ substitution on structural and functional properties was investigated. X-ray diffraction analysis clearly shows a single-phase cubic spinel geometry (Fd3m space group). The ultrafine nanocrystallites with average crystallite dimensions of 11–15 nm were obtained. The surface topography was inspected by scanning electron microscopy. The uniform distribution of the crystallites in nanosize dimensions (10–14 nm) was also supported by transmission electron microscopy. The contact angle measurements of the fabricated thin films demonstrate special affinity towards water molecules. FTIR spectra affirmed the construction of spinel ferrite structure and the band position was influenced by $ Cd^{2+} $-substitution. The optical band gap energy (Eg) can be tuned by $ Cd^{2+} $ -substitution and decreases from 2.98 to 2.10 eV viewing the semiconducting performance. The PL investigation showed the distinguishing near-band-edge emission at about 700 nm, which can be ascribed to the re-grouping of electrons with light-produced holes in oxygen vacancies and creation of intrinsic defects. Magnetic properties, i.e. saturation magnetization (Ms, 412.84–111.47 emu/cc), remanence magnetization (Mr, 44.83–2.18 emu/cc) and coercivity (Hc, 402.12–78.12 Oe), decreased with increasing diamagnetic $ Cd^{2+} $ substitution due to a decrease in net magnetization. | ||
| 650 | 4 | |a Thin film | |
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| 700 | 1 | |a Kale, C. M. |4 aut | |
| 700 | 1 | |a Jadhav, K. M. |4 aut | |
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10.1007/s11664-021-09199-7 doi (DE-627)OLC2077056711 (DE-He213)s11664-021-09199-7-p DE-627 ger DE-627 rakwb eng 670 VZ Jadhav, Gajanan L. verfasserin aut Structural, Optical and Magnetic Properties of Diamagnetic $ Cd^{2+} $ Incorporated Cobalt Ferrite Thin Films Deposited by Spray Pyrolysis 2021 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Minerals, Metals & Materials Society 2021 Abstract Cadmium ($ Cd^{2+} $)-substituted cobalt ferrite thin films with configuration $ Co_{1−x} $$ Cd_{x} $$ Fe_{2} $$ O_{4} $ (x = 0.0 to 1.0 in steps of 0.2) were grown via spray pyrolysis. The influence of $ Cd^{2+} $ substitution on structural and functional properties was investigated. X-ray diffraction analysis clearly shows a single-phase cubic spinel geometry (Fd3m space group). The ultrafine nanocrystallites with average crystallite dimensions of 11–15 nm were obtained. The surface topography was inspected by scanning electron microscopy. The uniform distribution of the crystallites in nanosize dimensions (10–14 nm) was also supported by transmission electron microscopy. The contact angle measurements of the fabricated thin films demonstrate special affinity towards water molecules. FTIR spectra affirmed the construction of spinel ferrite structure and the band position was influenced by $ Cd^{2+} $-substitution. The optical band gap energy (Eg) can be tuned by $ Cd^{2+} $ -substitution and decreases from 2.98 to 2.10 eV viewing the semiconducting performance. The PL investigation showed the distinguishing near-band-edge emission at about 700 nm, which can be ascribed to the re-grouping of electrons with light-produced holes in oxygen vacancies and creation of intrinsic defects. Magnetic properties, i.e. saturation magnetization (Ms, 412.84–111.47 emu/cc), remanence magnetization (Mr, 44.83–2.18 emu/cc) and coercivity (Hc, 402.12–78.12 Oe), decreased with increasing diamagnetic $ Cd^{2+} $ substitution due to a decrease in net magnetization. Thin film spray pyrolysis spinel ferrite photoluminescence magnetic properties Khirade, Pankaj P. (orcid)0000-0002-4187-2820 aut Chavan, Apparao R. aut Kale, C. M. aut Jadhav, K. M. aut Enthalten in Journal of electronic materials Springer US, 1972 50(2021), 11 vom: 13. Sept., Seite 6525-6534 (DE-627)129398233 (DE-600)186069-0 (DE-576)014781387 0361-5235 nnns volume:50 year:2021 number:11 day:13 month:09 pages:6525-6534 https://doi.org/10.1007/s11664-021-09199-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY AR 50 2021 11 13 09 6525-6534 |
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10.1007/s11664-021-09199-7 doi (DE-627)OLC2077056711 (DE-He213)s11664-021-09199-7-p DE-627 ger DE-627 rakwb eng 670 VZ Jadhav, Gajanan L. verfasserin aut Structural, Optical and Magnetic Properties of Diamagnetic $ Cd^{2+} $ Incorporated Cobalt Ferrite Thin Films Deposited by Spray Pyrolysis 2021 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Minerals, Metals & Materials Society 2021 Abstract Cadmium ($ Cd^{2+} $)-substituted cobalt ferrite thin films with configuration $ Co_{1−x} $$ Cd_{x} $$ Fe_{2} $$ O_{4} $ (x = 0.0 to 1.0 in steps of 0.2) were grown via spray pyrolysis. The influence of $ Cd^{2+} $ substitution on structural and functional properties was investigated. X-ray diffraction analysis clearly shows a single-phase cubic spinel geometry (Fd3m space group). The ultrafine nanocrystallites with average crystallite dimensions of 11–15 nm were obtained. The surface topography was inspected by scanning electron microscopy. The uniform distribution of the crystallites in nanosize dimensions (10–14 nm) was also supported by transmission electron microscopy. The contact angle measurements of the fabricated thin films demonstrate special affinity towards water molecules. FTIR spectra affirmed the construction of spinel ferrite structure and the band position was influenced by $ Cd^{2+} $-substitution. The optical band gap energy (Eg) can be tuned by $ Cd^{2+} $ -substitution and decreases from 2.98 to 2.10 eV viewing the semiconducting performance. The PL investigation showed the distinguishing near-band-edge emission at about 700 nm, which can be ascribed to the re-grouping of electrons with light-produced holes in oxygen vacancies and creation of intrinsic defects. Magnetic properties, i.e. saturation magnetization (Ms, 412.84–111.47 emu/cc), remanence magnetization (Mr, 44.83–2.18 emu/cc) and coercivity (Hc, 402.12–78.12 Oe), decreased with increasing diamagnetic $ Cd^{2+} $ substitution due to a decrease in net magnetization. Thin film spray pyrolysis spinel ferrite photoluminescence magnetic properties Khirade, Pankaj P. (orcid)0000-0002-4187-2820 aut Chavan, Apparao R. aut Kale, C. M. aut Jadhav, K. M. aut Enthalten in Journal of electronic materials Springer US, 1972 50(2021), 11 vom: 13. Sept., Seite 6525-6534 (DE-627)129398233 (DE-600)186069-0 (DE-576)014781387 0361-5235 nnns volume:50 year:2021 number:11 day:13 month:09 pages:6525-6534 https://doi.org/10.1007/s11664-021-09199-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY AR 50 2021 11 13 09 6525-6534 |
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10.1007/s11664-021-09199-7 doi (DE-627)OLC2077056711 (DE-He213)s11664-021-09199-7-p DE-627 ger DE-627 rakwb eng 670 VZ Jadhav, Gajanan L. verfasserin aut Structural, Optical and Magnetic Properties of Diamagnetic $ Cd^{2+} $ Incorporated Cobalt Ferrite Thin Films Deposited by Spray Pyrolysis 2021 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Minerals, Metals & Materials Society 2021 Abstract Cadmium ($ Cd^{2+} $)-substituted cobalt ferrite thin films with configuration $ Co_{1−x} $$ Cd_{x} $$ Fe_{2} $$ O_{4} $ (x = 0.0 to 1.0 in steps of 0.2) were grown via spray pyrolysis. The influence of $ Cd^{2+} $ substitution on structural and functional properties was investigated. X-ray diffraction analysis clearly shows a single-phase cubic spinel geometry (Fd3m space group). The ultrafine nanocrystallites with average crystallite dimensions of 11–15 nm were obtained. The surface topography was inspected by scanning electron microscopy. The uniform distribution of the crystallites in nanosize dimensions (10–14 nm) was also supported by transmission electron microscopy. The contact angle measurements of the fabricated thin films demonstrate special affinity towards water molecules. FTIR spectra affirmed the construction of spinel ferrite structure and the band position was influenced by $ Cd^{2+} $-substitution. The optical band gap energy (Eg) can be tuned by $ Cd^{2+} $ -substitution and decreases from 2.98 to 2.10 eV viewing the semiconducting performance. The PL investigation showed the distinguishing near-band-edge emission at about 700 nm, which can be ascribed to the re-grouping of electrons with light-produced holes in oxygen vacancies and creation of intrinsic defects. Magnetic properties, i.e. saturation magnetization (Ms, 412.84–111.47 emu/cc), remanence magnetization (Mr, 44.83–2.18 emu/cc) and coercivity (Hc, 402.12–78.12 Oe), decreased with increasing diamagnetic $ Cd^{2+} $ substitution due to a decrease in net magnetization. Thin film spray pyrolysis spinel ferrite photoluminescence magnetic properties Khirade, Pankaj P. (orcid)0000-0002-4187-2820 aut Chavan, Apparao R. aut Kale, C. M. aut Jadhav, K. M. aut Enthalten in Journal of electronic materials Springer US, 1972 50(2021), 11 vom: 13. Sept., Seite 6525-6534 (DE-627)129398233 (DE-600)186069-0 (DE-576)014781387 0361-5235 nnns volume:50 year:2021 number:11 day:13 month:09 pages:6525-6534 https://doi.org/10.1007/s11664-021-09199-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY AR 50 2021 11 13 09 6525-6534 |
| allfieldsGer |
10.1007/s11664-021-09199-7 doi (DE-627)OLC2077056711 (DE-He213)s11664-021-09199-7-p DE-627 ger DE-627 rakwb eng 670 VZ Jadhav, Gajanan L. verfasserin aut Structural, Optical and Magnetic Properties of Diamagnetic $ Cd^{2+} $ Incorporated Cobalt Ferrite Thin Films Deposited by Spray Pyrolysis 2021 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Minerals, Metals & Materials Society 2021 Abstract Cadmium ($ Cd^{2+} $)-substituted cobalt ferrite thin films with configuration $ Co_{1−x} $$ Cd_{x} $$ Fe_{2} $$ O_{4} $ (x = 0.0 to 1.0 in steps of 0.2) were grown via spray pyrolysis. The influence of $ Cd^{2+} $ substitution on structural and functional properties was investigated. X-ray diffraction analysis clearly shows a single-phase cubic spinel geometry (Fd3m space group). The ultrafine nanocrystallites with average crystallite dimensions of 11–15 nm were obtained. The surface topography was inspected by scanning electron microscopy. The uniform distribution of the crystallites in nanosize dimensions (10–14 nm) was also supported by transmission electron microscopy. The contact angle measurements of the fabricated thin films demonstrate special affinity towards water molecules. FTIR spectra affirmed the construction of spinel ferrite structure and the band position was influenced by $ Cd^{2+} $-substitution. The optical band gap energy (Eg) can be tuned by $ Cd^{2+} $ -substitution and decreases from 2.98 to 2.10 eV viewing the semiconducting performance. The PL investigation showed the distinguishing near-band-edge emission at about 700 nm, which can be ascribed to the re-grouping of electrons with light-produced holes in oxygen vacancies and creation of intrinsic defects. Magnetic properties, i.e. saturation magnetization (Ms, 412.84–111.47 emu/cc), remanence magnetization (Mr, 44.83–2.18 emu/cc) and coercivity (Hc, 402.12–78.12 Oe), decreased with increasing diamagnetic $ Cd^{2+} $ substitution due to a decrease in net magnetization. Thin film spray pyrolysis spinel ferrite photoluminescence magnetic properties Khirade, Pankaj P. (orcid)0000-0002-4187-2820 aut Chavan, Apparao R. aut Kale, C. M. aut Jadhav, K. M. aut Enthalten in Journal of electronic materials Springer US, 1972 50(2021), 11 vom: 13. Sept., Seite 6525-6534 (DE-627)129398233 (DE-600)186069-0 (DE-576)014781387 0361-5235 nnns volume:50 year:2021 number:11 day:13 month:09 pages:6525-6534 https://doi.org/10.1007/s11664-021-09199-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY AR 50 2021 11 13 09 6525-6534 |
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10.1007/s11664-021-09199-7 doi (DE-627)OLC2077056711 (DE-He213)s11664-021-09199-7-p DE-627 ger DE-627 rakwb eng 670 VZ Jadhav, Gajanan L. verfasserin aut Structural, Optical and Magnetic Properties of Diamagnetic $ Cd^{2+} $ Incorporated Cobalt Ferrite Thin Films Deposited by Spray Pyrolysis 2021 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Minerals, Metals & Materials Society 2021 Abstract Cadmium ($ Cd^{2+} $)-substituted cobalt ferrite thin films with configuration $ Co_{1−x} $$ Cd_{x} $$ Fe_{2} $$ O_{4} $ (x = 0.0 to 1.0 in steps of 0.2) were grown via spray pyrolysis. The influence of $ Cd^{2+} $ substitution on structural and functional properties was investigated. X-ray diffraction analysis clearly shows a single-phase cubic spinel geometry (Fd3m space group). The ultrafine nanocrystallites with average crystallite dimensions of 11–15 nm were obtained. The surface topography was inspected by scanning electron microscopy. The uniform distribution of the crystallites in nanosize dimensions (10–14 nm) was also supported by transmission electron microscopy. The contact angle measurements of the fabricated thin films demonstrate special affinity towards water molecules. FTIR spectra affirmed the construction of spinel ferrite structure and the band position was influenced by $ Cd^{2+} $-substitution. The optical band gap energy (Eg) can be tuned by $ Cd^{2+} $ -substitution and decreases from 2.98 to 2.10 eV viewing the semiconducting performance. The PL investigation showed the distinguishing near-band-edge emission at about 700 nm, which can be ascribed to the re-grouping of electrons with light-produced holes in oxygen vacancies and creation of intrinsic defects. Magnetic properties, i.e. saturation magnetization (Ms, 412.84–111.47 emu/cc), remanence magnetization (Mr, 44.83–2.18 emu/cc) and coercivity (Hc, 402.12–78.12 Oe), decreased with increasing diamagnetic $ Cd^{2+} $ substitution due to a decrease in net magnetization. Thin film spray pyrolysis spinel ferrite photoluminescence magnetic properties Khirade, Pankaj P. (orcid)0000-0002-4187-2820 aut Chavan, Apparao R. aut Kale, C. M. aut Jadhav, K. M. aut Enthalten in Journal of electronic materials Springer US, 1972 50(2021), 11 vom: 13. Sept., Seite 6525-6534 (DE-627)129398233 (DE-600)186069-0 (DE-576)014781387 0361-5235 nnns volume:50 year:2021 number:11 day:13 month:09 pages:6525-6534 https://doi.org/10.1007/s11664-021-09199-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY AR 50 2021 11 13 09 6525-6534 |
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Jadhav, Gajanan L. ddc 670 misc Thin film misc spray pyrolysis misc spinel ferrite misc photoluminescence misc magnetic properties Structural, Optical and Magnetic Properties of Diamagnetic $ Cd^{2+} $ Incorporated Cobalt Ferrite Thin Films Deposited by Spray Pyrolysis |
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670 VZ Structural, Optical and Magnetic Properties of Diamagnetic $ Cd^{2+} $ Incorporated Cobalt Ferrite Thin Films Deposited by Spray Pyrolysis Thin film spray pyrolysis spinel ferrite photoluminescence magnetic properties |
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Structural, Optical and Magnetic Properties of Diamagnetic $ Cd^{2+} $ Incorporated Cobalt Ferrite Thin Films Deposited by Spray Pyrolysis |
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structural, optical and magnetic properties of diamagnetic $ cd^{2+} $ incorporated cobalt ferrite thin films deposited by spray pyrolysis |
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Structural, Optical and Magnetic Properties of Diamagnetic $ Cd^{2+} $ Incorporated Cobalt Ferrite Thin Films Deposited by Spray Pyrolysis |
| abstract |
Abstract Cadmium ($ Cd^{2+} $)-substituted cobalt ferrite thin films with configuration $ Co_{1−x} $$ Cd_{x} $$ Fe_{2} $$ O_{4} $ (x = 0.0 to 1.0 in steps of 0.2) were grown via spray pyrolysis. The influence of $ Cd^{2+} $ substitution on structural and functional properties was investigated. X-ray diffraction analysis clearly shows a single-phase cubic spinel geometry (Fd3m space group). The ultrafine nanocrystallites with average crystallite dimensions of 11–15 nm were obtained. The surface topography was inspected by scanning electron microscopy. The uniform distribution of the crystallites in nanosize dimensions (10–14 nm) was also supported by transmission electron microscopy. The contact angle measurements of the fabricated thin films demonstrate special affinity towards water molecules. FTIR spectra affirmed the construction of spinel ferrite structure and the band position was influenced by $ Cd^{2+} $-substitution. The optical band gap energy (Eg) can be tuned by $ Cd^{2+} $ -substitution and decreases from 2.98 to 2.10 eV viewing the semiconducting performance. The PL investigation showed the distinguishing near-band-edge emission at about 700 nm, which can be ascribed to the re-grouping of electrons with light-produced holes in oxygen vacancies and creation of intrinsic defects. Magnetic properties, i.e. saturation magnetization (Ms, 412.84–111.47 emu/cc), remanence magnetization (Mr, 44.83–2.18 emu/cc) and coercivity (Hc, 402.12–78.12 Oe), decreased with increasing diamagnetic $ Cd^{2+} $ substitution due to a decrease in net magnetization. © The Minerals, Metals & Materials Society 2021 |
| abstractGer |
Abstract Cadmium ($ Cd^{2+} $)-substituted cobalt ferrite thin films with configuration $ Co_{1−x} $$ Cd_{x} $$ Fe_{2} $$ O_{4} $ (x = 0.0 to 1.0 in steps of 0.2) were grown via spray pyrolysis. The influence of $ Cd^{2+} $ substitution on structural and functional properties was investigated. X-ray diffraction analysis clearly shows a single-phase cubic spinel geometry (Fd3m space group). The ultrafine nanocrystallites with average crystallite dimensions of 11–15 nm were obtained. The surface topography was inspected by scanning electron microscopy. The uniform distribution of the crystallites in nanosize dimensions (10–14 nm) was also supported by transmission electron microscopy. The contact angle measurements of the fabricated thin films demonstrate special affinity towards water molecules. FTIR spectra affirmed the construction of spinel ferrite structure and the band position was influenced by $ Cd^{2+} $-substitution. The optical band gap energy (Eg) can be tuned by $ Cd^{2+} $ -substitution and decreases from 2.98 to 2.10 eV viewing the semiconducting performance. The PL investigation showed the distinguishing near-band-edge emission at about 700 nm, which can be ascribed to the re-grouping of electrons with light-produced holes in oxygen vacancies and creation of intrinsic defects. Magnetic properties, i.e. saturation magnetization (Ms, 412.84–111.47 emu/cc), remanence magnetization (Mr, 44.83–2.18 emu/cc) and coercivity (Hc, 402.12–78.12 Oe), decreased with increasing diamagnetic $ Cd^{2+} $ substitution due to a decrease in net magnetization. © The Minerals, Metals & Materials Society 2021 |
| abstract_unstemmed |
Abstract Cadmium ($ Cd^{2+} $)-substituted cobalt ferrite thin films with configuration $ Co_{1−x} $$ Cd_{x} $$ Fe_{2} $$ O_{4} $ (x = 0.0 to 1.0 in steps of 0.2) were grown via spray pyrolysis. The influence of $ Cd^{2+} $ substitution on structural and functional properties was investigated. X-ray diffraction analysis clearly shows a single-phase cubic spinel geometry (Fd3m space group). The ultrafine nanocrystallites with average crystallite dimensions of 11–15 nm were obtained. The surface topography was inspected by scanning electron microscopy. The uniform distribution of the crystallites in nanosize dimensions (10–14 nm) was also supported by transmission electron microscopy. The contact angle measurements of the fabricated thin films demonstrate special affinity towards water molecules. FTIR spectra affirmed the construction of spinel ferrite structure and the band position was influenced by $ Cd^{2+} $-substitution. The optical band gap energy (Eg) can be tuned by $ Cd^{2+} $ -substitution and decreases from 2.98 to 2.10 eV viewing the semiconducting performance. The PL investigation showed the distinguishing near-band-edge emission at about 700 nm, which can be ascribed to the re-grouping of electrons with light-produced holes in oxygen vacancies and creation of intrinsic defects. Magnetic properties, i.e. saturation magnetization (Ms, 412.84–111.47 emu/cc), remanence magnetization (Mr, 44.83–2.18 emu/cc) and coercivity (Hc, 402.12–78.12 Oe), decreased with increasing diamagnetic $ Cd^{2+} $ substitution due to a decrease in net magnetization. © The Minerals, Metals & Materials Society 2021 |
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