Template synthesis, characterization and electrochemical studies of copper(II) macrocyclic complexes derived from 4-methyl-2,6-di(formyl/benzoyl) phenol and diamines
Abstract Copper(II) macrocyclic complexes [Cu(L)Cl2]·2H2O (1,2) have been synthesized from the copper(II)-directed condensation of 4-methyl-2,6-diformylphenol (1) or 4-methyl-2,6-dibenzoylphenol (2) with diamines [1,2-diaminopropane (a), 1,3-diaminopropane (b) and o-phenylenediamine (c)] in EtOH in...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Gupta, Sushil K. [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1997 |
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| Schlagwörter: |
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| Anmerkung: |
© Chapman and Hall 1997 |
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| Übergeordnetes Werk: |
Enthalten in: Transition metal chemistry - Springer Netherlands, 1975, 22(1997), 3 vom: 01. Mai, Seite 225-228 |
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| Übergeordnetes Werk: |
volume:22 ; year:1997 ; number:3 ; day:01 ; month:05 ; pages:225-228 |
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| DOI / URN: |
10.1023/A:1018452105387 |
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OLC2079983849 |
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| 245 | 1 | 0 | |a Template synthesis, characterization and electrochemical studies of copper(II) macrocyclic complexes derived from 4-methyl-2,6-di(formyl/benzoyl) phenol and diamines |
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| 520 | |a Abstract Copper(II) macrocyclic complexes [Cu(L)Cl2]·2H2O (1,2) have been synthesized from the copper(II)-directed condensation of 4-methyl-2,6-diformylphenol (1) or 4-methyl-2,6-dibenzoylphenol (2) with diamines [1,2-diaminopropane (a), 1,3-diaminopropane (b) and o-phenylenediamine (c)] in EtOH in high yields. These complexes are monomeric, non-electrolytes and paramagnetic, indicating a distorted octahedral geometry around copper, which is supported by i.r., electronic, e.s.r. and magnetic susceptibility measurements. Electrochemical studies of (1) and (2) using c.v. indicate an irreversible cathodic peak (ca. –0.65 to –0.76 V) corresponding to reduction of copper(II) to copper(I) and the diffusion-controlled nature of the electrode process. | ||
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10.1023/A:1018452105387 doi (DE-627)OLC2079983849 (DE-He213)A:1018452105387-p DE-627 ger DE-627 rakwb eng 660 VZ Gupta, Sushil K. verfasserin aut Template synthesis, characterization and electrochemical studies of copper(II) macrocyclic complexes derived from 4-methyl-2,6-di(formyl/benzoyl) phenol and diamines 1997 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall 1997 Abstract Copper(II) macrocyclic complexes [Cu(L)Cl2]·2H2O (1,2) have been synthesized from the copper(II)-directed condensation of 4-methyl-2,6-diformylphenol (1) or 4-methyl-2,6-dibenzoylphenol (2) with diamines [1,2-diaminopropane (a), 1,3-diaminopropane (b) and o-phenylenediamine (c)] in EtOH in high yields. These complexes are monomeric, non-electrolytes and paramagnetic, indicating a distorted octahedral geometry around copper, which is supported by i.r., electronic, e.s.r. and magnetic susceptibility measurements. Electrochemical studies of (1) and (2) using c.v. indicate an irreversible cathodic peak (ca. –0.65 to –0.76 V) corresponding to reduction of copper(II) to copper(I) and the diffusion-controlled nature of the electrode process. Copper Physical Chemistry 2H2O Phenol Inorganic Chemistry Raina, Daisy aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 22(1997), 3 vom: 01. Mai, Seite 225-228 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:22 year:1997 number:3 day:01 month:05 pages:225-228 https://doi.org/10.1023/A:1018452105387 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4082 GBV_ILN_4125 AR 22 1997 3 01 05 225-228 |
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10.1023/A:1018452105387 doi (DE-627)OLC2079983849 (DE-He213)A:1018452105387-p DE-627 ger DE-627 rakwb eng 660 VZ Gupta, Sushil K. verfasserin aut Template synthesis, characterization and electrochemical studies of copper(II) macrocyclic complexes derived from 4-methyl-2,6-di(formyl/benzoyl) phenol and diamines 1997 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall 1997 Abstract Copper(II) macrocyclic complexes [Cu(L)Cl2]·2H2O (1,2) have been synthesized from the copper(II)-directed condensation of 4-methyl-2,6-diformylphenol (1) or 4-methyl-2,6-dibenzoylphenol (2) with diamines [1,2-diaminopropane (a), 1,3-diaminopropane (b) and o-phenylenediamine (c)] in EtOH in high yields. These complexes are monomeric, non-electrolytes and paramagnetic, indicating a distorted octahedral geometry around copper, which is supported by i.r., electronic, e.s.r. and magnetic susceptibility measurements. Electrochemical studies of (1) and (2) using c.v. indicate an irreversible cathodic peak (ca. –0.65 to –0.76 V) corresponding to reduction of copper(II) to copper(I) and the diffusion-controlled nature of the electrode process. Copper Physical Chemistry 2H2O Phenol Inorganic Chemistry Raina, Daisy aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 22(1997), 3 vom: 01. Mai, Seite 225-228 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:22 year:1997 number:3 day:01 month:05 pages:225-228 https://doi.org/10.1023/A:1018452105387 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4082 GBV_ILN_4125 AR 22 1997 3 01 05 225-228 |
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10.1023/A:1018452105387 doi (DE-627)OLC2079983849 (DE-He213)A:1018452105387-p DE-627 ger DE-627 rakwb eng 660 VZ Gupta, Sushil K. verfasserin aut Template synthesis, characterization and electrochemical studies of copper(II) macrocyclic complexes derived from 4-methyl-2,6-di(formyl/benzoyl) phenol and diamines 1997 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall 1997 Abstract Copper(II) macrocyclic complexes [Cu(L)Cl2]·2H2O (1,2) have been synthesized from the copper(II)-directed condensation of 4-methyl-2,6-diformylphenol (1) or 4-methyl-2,6-dibenzoylphenol (2) with diamines [1,2-diaminopropane (a), 1,3-diaminopropane (b) and o-phenylenediamine (c)] in EtOH in high yields. These complexes are monomeric, non-electrolytes and paramagnetic, indicating a distorted octahedral geometry around copper, which is supported by i.r., electronic, e.s.r. and magnetic susceptibility measurements. Electrochemical studies of (1) and (2) using c.v. indicate an irreversible cathodic peak (ca. –0.65 to –0.76 V) corresponding to reduction of copper(II) to copper(I) and the diffusion-controlled nature of the electrode process. Copper Physical Chemistry 2H2O Phenol Inorganic Chemistry Raina, Daisy aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 22(1997), 3 vom: 01. Mai, Seite 225-228 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:22 year:1997 number:3 day:01 month:05 pages:225-228 https://doi.org/10.1023/A:1018452105387 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4082 GBV_ILN_4125 AR 22 1997 3 01 05 225-228 |
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10.1023/A:1018452105387 doi (DE-627)OLC2079983849 (DE-He213)A:1018452105387-p DE-627 ger DE-627 rakwb eng 660 VZ Gupta, Sushil K. verfasserin aut Template synthesis, characterization and electrochemical studies of copper(II) macrocyclic complexes derived from 4-methyl-2,6-di(formyl/benzoyl) phenol and diamines 1997 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall 1997 Abstract Copper(II) macrocyclic complexes [Cu(L)Cl2]·2H2O (1,2) have been synthesized from the copper(II)-directed condensation of 4-methyl-2,6-diformylphenol (1) or 4-methyl-2,6-dibenzoylphenol (2) with diamines [1,2-diaminopropane (a), 1,3-diaminopropane (b) and o-phenylenediamine (c)] in EtOH in high yields. These complexes are monomeric, non-electrolytes and paramagnetic, indicating a distorted octahedral geometry around copper, which is supported by i.r., electronic, e.s.r. and magnetic susceptibility measurements. Electrochemical studies of (1) and (2) using c.v. indicate an irreversible cathodic peak (ca. –0.65 to –0.76 V) corresponding to reduction of copper(II) to copper(I) and the diffusion-controlled nature of the electrode process. Copper Physical Chemistry 2H2O Phenol Inorganic Chemistry Raina, Daisy aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 22(1997), 3 vom: 01. Mai, Seite 225-228 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:22 year:1997 number:3 day:01 month:05 pages:225-228 https://doi.org/10.1023/A:1018452105387 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4082 GBV_ILN_4125 AR 22 1997 3 01 05 225-228 |
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10.1023/A:1018452105387 doi (DE-627)OLC2079983849 (DE-He213)A:1018452105387-p DE-627 ger DE-627 rakwb eng 660 VZ Gupta, Sushil K. verfasserin aut Template synthesis, characterization and electrochemical studies of copper(II) macrocyclic complexes derived from 4-methyl-2,6-di(formyl/benzoyl) phenol and diamines 1997 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall 1997 Abstract Copper(II) macrocyclic complexes [Cu(L)Cl2]·2H2O (1,2) have been synthesized from the copper(II)-directed condensation of 4-methyl-2,6-diformylphenol (1) or 4-methyl-2,6-dibenzoylphenol (2) with diamines [1,2-diaminopropane (a), 1,3-diaminopropane (b) and o-phenylenediamine (c)] in EtOH in high yields. These complexes are monomeric, non-electrolytes and paramagnetic, indicating a distorted octahedral geometry around copper, which is supported by i.r., electronic, e.s.r. and magnetic susceptibility measurements. Electrochemical studies of (1) and (2) using c.v. indicate an irreversible cathodic peak (ca. –0.65 to –0.76 V) corresponding to reduction of copper(II) to copper(I) and the diffusion-controlled nature of the electrode process. Copper Physical Chemistry 2H2O Phenol Inorganic Chemistry Raina, Daisy aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 22(1997), 3 vom: 01. Mai, Seite 225-228 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:22 year:1997 number:3 day:01 month:05 pages:225-228 https://doi.org/10.1023/A:1018452105387 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4082 GBV_ILN_4125 AR 22 1997 3 01 05 225-228 |
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template synthesis, characterization and electrochemical studies of copper(ii) macrocyclic complexes derived from 4-methyl-2,6-di(formyl/benzoyl) phenol and diamines |
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Template synthesis, characterization and electrochemical studies of copper(II) macrocyclic complexes derived from 4-methyl-2,6-di(formyl/benzoyl) phenol and diamines |
| abstract |
Abstract Copper(II) macrocyclic complexes [Cu(L)Cl2]·2H2O (1,2) have been synthesized from the copper(II)-directed condensation of 4-methyl-2,6-diformylphenol (1) or 4-methyl-2,6-dibenzoylphenol (2) with diamines [1,2-diaminopropane (a), 1,3-diaminopropane (b) and o-phenylenediamine (c)] in EtOH in high yields. These complexes are monomeric, non-electrolytes and paramagnetic, indicating a distorted octahedral geometry around copper, which is supported by i.r., electronic, e.s.r. and magnetic susceptibility measurements. Electrochemical studies of (1) and (2) using c.v. indicate an irreversible cathodic peak (ca. –0.65 to –0.76 V) corresponding to reduction of copper(II) to copper(I) and the diffusion-controlled nature of the electrode process. © Chapman and Hall 1997 |
| abstractGer |
Abstract Copper(II) macrocyclic complexes [Cu(L)Cl2]·2H2O (1,2) have been synthesized from the copper(II)-directed condensation of 4-methyl-2,6-diformylphenol (1) or 4-methyl-2,6-dibenzoylphenol (2) with diamines [1,2-diaminopropane (a), 1,3-diaminopropane (b) and o-phenylenediamine (c)] in EtOH in high yields. These complexes are monomeric, non-electrolytes and paramagnetic, indicating a distorted octahedral geometry around copper, which is supported by i.r., electronic, e.s.r. and magnetic susceptibility measurements. Electrochemical studies of (1) and (2) using c.v. indicate an irreversible cathodic peak (ca. –0.65 to –0.76 V) corresponding to reduction of copper(II) to copper(I) and the diffusion-controlled nature of the electrode process. © Chapman and Hall 1997 |
| abstract_unstemmed |
Abstract Copper(II) macrocyclic complexes [Cu(L)Cl2]·2H2O (1,2) have been synthesized from the copper(II)-directed condensation of 4-methyl-2,6-diformylphenol (1) or 4-methyl-2,6-dibenzoylphenol (2) with diamines [1,2-diaminopropane (a), 1,3-diaminopropane (b) and o-phenylenediamine (c)] in EtOH in high yields. These complexes are monomeric, non-electrolytes and paramagnetic, indicating a distorted octahedral geometry around copper, which is supported by i.r., electronic, e.s.r. and magnetic susceptibility measurements. Electrochemical studies of (1) and (2) using c.v. indicate an irreversible cathodic peak (ca. –0.65 to –0.76 V) corresponding to reduction of copper(II) to copper(I) and the diffusion-controlled nature of the electrode process. © Chapman and Hall 1997 |
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| container_issue |
3 |
| title_short |
Template synthesis, characterization and electrochemical studies of copper(II) macrocyclic complexes derived from 4-methyl-2,6-di(formyl/benzoyl) phenol and diamines |
| url |
https://doi.org/10.1023/A:1018452105387 |
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| author2 |
Raina, Daisy |
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| doi_str |
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| up_date |
2024-07-04T02:36:12.929Z |
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