Acceptor-acceptor-type Organoboron Conjugated Polymers: Effect of Backbone Configuration on Thermoelectric Performance
Abstract The development of n-type polymer thermoelectrics lags far behind that of p-type ones in view of material diversity and performance. New structural insights into the thermoelectric performance are needed for efficient n-type polymer thermoelectric materials. Herein, we developed three accep...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Dong, Chang-Shuai [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2022 |
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| Schlagwörter: |
Acceptor-acceptor type conjugated polymers |
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| Anmerkung: |
© Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2022 |
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| Übergeordnetes Werk: |
Enthalten in: Chinese journal of polymer science - Springer Nature Singapore, 1985, 41(2022), 1 vom: 05. Sept., Seite 108-116 |
|---|---|
| Übergeordnetes Werk: |
volume:41 ; year:2022 ; number:1 ; day:05 ; month:09 ; pages:108-116 |
| Links: |
|---|
| DOI / URN: |
10.1007/s10118-022-2815-0 |
|---|
| Katalog-ID: |
OLC2080192957 |
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| 520 | |a Abstract The development of n-type polymer thermoelectrics lags far behind that of p-type ones in view of material diversity and performance. New structural insights into the thermoelectric performance are needed for efficient n-type polymer thermoelectric materials. Herein, we developed three acceptor-acceptor type organoboron polymers and investigated the effect of backbone configuration on thermoelectric performance. The three polymers are designed based on double B←N bridged bipyridine (BNBP) unit with monomeric thieno[3,4-c]pyrrole-4,6-dione (TPD), TPD dimer and TPD trimer as the copolymerizing units, respectively. The three polymers show similar low LUMO energy levels but different backbone configuration. Compared with the wavy backbone configuration, the pseudo-straight backbone configuration imparts the polymer with much enhanced crystallinity and electron mobility. As a result, after n-doping, the polymer with pseudo-straight configuration shows much higher electronic conductivity and power factor. We think these findings could serve as important guidelines for molecular design toward efficient n-type polymer thermoelectric materials. | ||
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10.1007/s10118-022-2815-0 doi (DE-627)OLC2080192957 (DE-He213)s10118-022-2815-0-p DE-627 ger DE-627 rakwb eng 540 660 VZ 660 670 VZ Dong, Chang-Shuai verfasserin aut Acceptor-acceptor-type Organoboron Conjugated Polymers: Effect of Backbone Configuration on Thermoelectric Performance 2022 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2022 Abstract The development of n-type polymer thermoelectrics lags far behind that of p-type ones in view of material diversity and performance. New structural insights into the thermoelectric performance are needed for efficient n-type polymer thermoelectric materials. Herein, we developed three acceptor-acceptor type organoboron polymers and investigated the effect of backbone configuration on thermoelectric performance. The three polymers are designed based on double B←N bridged bipyridine (BNBP) unit with monomeric thieno[3,4-c]pyrrole-4,6-dione (TPD), TPD dimer and TPD trimer as the copolymerizing units, respectively. The three polymers show similar low LUMO energy levels but different backbone configuration. Compared with the wavy backbone configuration, the pseudo-straight backbone configuration imparts the polymer with much enhanced crystallinity and electron mobility. As a result, after n-doping, the polymer with pseudo-straight configuration shows much higher electronic conductivity and power factor. We think these findings could serve as important guidelines for molecular design toward efficient n-type polymer thermoelectric materials. Organoboron polymers Acceptor-acceptor type conjugated polymers n-Type polymer thermoelectrics n-Doping Meng, Bin aut Liu, Jun aut Wang, Li-Xiang aut Enthalten in Chinese journal of polymer science Springer Nature Singapore, 1985 41(2022), 1 vom: 05. Sept., Seite 108-116 (DE-627)130996939 (DE-600)1082856-4 (DE-576)026374684 0256-7679 nnns volume:41 year:2022 number:1 day:05 month:09 pages:108-116 https://doi.org/10.1007/s10118-022-2815-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_4277 AR 41 2022 1 05 09 108-116 |
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10.1007/s10118-022-2815-0 doi (DE-627)OLC2080192957 (DE-He213)s10118-022-2815-0-p DE-627 ger DE-627 rakwb eng 540 660 VZ 660 670 VZ Dong, Chang-Shuai verfasserin aut Acceptor-acceptor-type Organoboron Conjugated Polymers: Effect of Backbone Configuration on Thermoelectric Performance 2022 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2022 Abstract The development of n-type polymer thermoelectrics lags far behind that of p-type ones in view of material diversity and performance. New structural insights into the thermoelectric performance are needed for efficient n-type polymer thermoelectric materials. Herein, we developed three acceptor-acceptor type organoboron polymers and investigated the effect of backbone configuration on thermoelectric performance. The three polymers are designed based on double B←N bridged bipyridine (BNBP) unit with monomeric thieno[3,4-c]pyrrole-4,6-dione (TPD), TPD dimer and TPD trimer as the copolymerizing units, respectively. The three polymers show similar low LUMO energy levels but different backbone configuration. Compared with the wavy backbone configuration, the pseudo-straight backbone configuration imparts the polymer with much enhanced crystallinity and electron mobility. As a result, after n-doping, the polymer with pseudo-straight configuration shows much higher electronic conductivity and power factor. We think these findings could serve as important guidelines for molecular design toward efficient n-type polymer thermoelectric materials. Organoboron polymers Acceptor-acceptor type conjugated polymers n-Type polymer thermoelectrics n-Doping Meng, Bin aut Liu, Jun aut Wang, Li-Xiang aut Enthalten in Chinese journal of polymer science Springer Nature Singapore, 1985 41(2022), 1 vom: 05. Sept., Seite 108-116 (DE-627)130996939 (DE-600)1082856-4 (DE-576)026374684 0256-7679 nnns volume:41 year:2022 number:1 day:05 month:09 pages:108-116 https://doi.org/10.1007/s10118-022-2815-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_4277 AR 41 2022 1 05 09 108-116 |
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10.1007/s10118-022-2815-0 doi (DE-627)OLC2080192957 (DE-He213)s10118-022-2815-0-p DE-627 ger DE-627 rakwb eng 540 660 VZ 660 670 VZ Dong, Chang-Shuai verfasserin aut Acceptor-acceptor-type Organoboron Conjugated Polymers: Effect of Backbone Configuration on Thermoelectric Performance 2022 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2022 Abstract The development of n-type polymer thermoelectrics lags far behind that of p-type ones in view of material diversity and performance. New structural insights into the thermoelectric performance are needed for efficient n-type polymer thermoelectric materials. Herein, we developed three acceptor-acceptor type organoboron polymers and investigated the effect of backbone configuration on thermoelectric performance. The three polymers are designed based on double B←N bridged bipyridine (BNBP) unit with monomeric thieno[3,4-c]pyrrole-4,6-dione (TPD), TPD dimer and TPD trimer as the copolymerizing units, respectively. The three polymers show similar low LUMO energy levels but different backbone configuration. Compared with the wavy backbone configuration, the pseudo-straight backbone configuration imparts the polymer with much enhanced crystallinity and electron mobility. As a result, after n-doping, the polymer with pseudo-straight configuration shows much higher electronic conductivity and power factor. We think these findings could serve as important guidelines for molecular design toward efficient n-type polymer thermoelectric materials. Organoboron polymers Acceptor-acceptor type conjugated polymers n-Type polymer thermoelectrics n-Doping Meng, Bin aut Liu, Jun aut Wang, Li-Xiang aut Enthalten in Chinese journal of polymer science Springer Nature Singapore, 1985 41(2022), 1 vom: 05. Sept., Seite 108-116 (DE-627)130996939 (DE-600)1082856-4 (DE-576)026374684 0256-7679 nnns volume:41 year:2022 number:1 day:05 month:09 pages:108-116 https://doi.org/10.1007/s10118-022-2815-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_4277 AR 41 2022 1 05 09 108-116 |
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10.1007/s10118-022-2815-0 doi (DE-627)OLC2080192957 (DE-He213)s10118-022-2815-0-p DE-627 ger DE-627 rakwb eng 540 660 VZ 660 670 VZ Dong, Chang-Shuai verfasserin aut Acceptor-acceptor-type Organoboron Conjugated Polymers: Effect of Backbone Configuration on Thermoelectric Performance 2022 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2022 Abstract The development of n-type polymer thermoelectrics lags far behind that of p-type ones in view of material diversity and performance. New structural insights into the thermoelectric performance are needed for efficient n-type polymer thermoelectric materials. Herein, we developed three acceptor-acceptor type organoboron polymers and investigated the effect of backbone configuration on thermoelectric performance. The three polymers are designed based on double B←N bridged bipyridine (BNBP) unit with monomeric thieno[3,4-c]pyrrole-4,6-dione (TPD), TPD dimer and TPD trimer as the copolymerizing units, respectively. The three polymers show similar low LUMO energy levels but different backbone configuration. Compared with the wavy backbone configuration, the pseudo-straight backbone configuration imparts the polymer with much enhanced crystallinity and electron mobility. As a result, after n-doping, the polymer with pseudo-straight configuration shows much higher electronic conductivity and power factor. We think these findings could serve as important guidelines for molecular design toward efficient n-type polymer thermoelectric materials. Organoboron polymers Acceptor-acceptor type conjugated polymers n-Type polymer thermoelectrics n-Doping Meng, Bin aut Liu, Jun aut Wang, Li-Xiang aut Enthalten in Chinese journal of polymer science Springer Nature Singapore, 1985 41(2022), 1 vom: 05. Sept., Seite 108-116 (DE-627)130996939 (DE-600)1082856-4 (DE-576)026374684 0256-7679 nnns volume:41 year:2022 number:1 day:05 month:09 pages:108-116 https://doi.org/10.1007/s10118-022-2815-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_4277 AR 41 2022 1 05 09 108-116 |
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10.1007/s10118-022-2815-0 doi (DE-627)OLC2080192957 (DE-He213)s10118-022-2815-0-p DE-627 ger DE-627 rakwb eng 540 660 VZ 660 670 VZ Dong, Chang-Shuai verfasserin aut Acceptor-acceptor-type Organoboron Conjugated Polymers: Effect of Backbone Configuration on Thermoelectric Performance 2022 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2022 Abstract The development of n-type polymer thermoelectrics lags far behind that of p-type ones in view of material diversity and performance. New structural insights into the thermoelectric performance are needed for efficient n-type polymer thermoelectric materials. Herein, we developed three acceptor-acceptor type organoboron polymers and investigated the effect of backbone configuration on thermoelectric performance. The three polymers are designed based on double B←N bridged bipyridine (BNBP) unit with monomeric thieno[3,4-c]pyrrole-4,6-dione (TPD), TPD dimer and TPD trimer as the copolymerizing units, respectively. The three polymers show similar low LUMO energy levels but different backbone configuration. Compared with the wavy backbone configuration, the pseudo-straight backbone configuration imparts the polymer with much enhanced crystallinity and electron mobility. As a result, after n-doping, the polymer with pseudo-straight configuration shows much higher electronic conductivity and power factor. We think these findings could serve as important guidelines for molecular design toward efficient n-type polymer thermoelectric materials. Organoboron polymers Acceptor-acceptor type conjugated polymers n-Type polymer thermoelectrics n-Doping Meng, Bin aut Liu, Jun aut Wang, Li-Xiang aut Enthalten in Chinese journal of polymer science Springer Nature Singapore, 1985 41(2022), 1 vom: 05. Sept., Seite 108-116 (DE-627)130996939 (DE-600)1082856-4 (DE-576)026374684 0256-7679 nnns volume:41 year:2022 number:1 day:05 month:09 pages:108-116 https://doi.org/10.1007/s10118-022-2815-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_4277 AR 41 2022 1 05 09 108-116 |
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Dong, Chang-Shuai Meng, Bin Liu, Jun Wang, Li-Xiang |
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Dong, Chang-Shuai |
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10.1007/s10118-022-2815-0 |
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540 660 670 |
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acceptor-acceptor-type organoboron conjugated polymers: effect of backbone configuration on thermoelectric performance |
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Acceptor-acceptor-type Organoboron Conjugated Polymers: Effect of Backbone Configuration on Thermoelectric Performance |
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Abstract The development of n-type polymer thermoelectrics lags far behind that of p-type ones in view of material diversity and performance. New structural insights into the thermoelectric performance are needed for efficient n-type polymer thermoelectric materials. Herein, we developed three acceptor-acceptor type organoboron polymers and investigated the effect of backbone configuration on thermoelectric performance. The three polymers are designed based on double B←N bridged bipyridine (BNBP) unit with monomeric thieno[3,4-c]pyrrole-4,6-dione (TPD), TPD dimer and TPD trimer as the copolymerizing units, respectively. The three polymers show similar low LUMO energy levels but different backbone configuration. Compared with the wavy backbone configuration, the pseudo-straight backbone configuration imparts the polymer with much enhanced crystallinity and electron mobility. As a result, after n-doping, the polymer with pseudo-straight configuration shows much higher electronic conductivity and power factor. We think these findings could serve as important guidelines for molecular design toward efficient n-type polymer thermoelectric materials. © Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2022 |
| abstractGer |
Abstract The development of n-type polymer thermoelectrics lags far behind that of p-type ones in view of material diversity and performance. New structural insights into the thermoelectric performance are needed for efficient n-type polymer thermoelectric materials. Herein, we developed three acceptor-acceptor type organoboron polymers and investigated the effect of backbone configuration on thermoelectric performance. The three polymers are designed based on double B←N bridged bipyridine (BNBP) unit with monomeric thieno[3,4-c]pyrrole-4,6-dione (TPD), TPD dimer and TPD trimer as the copolymerizing units, respectively. The three polymers show similar low LUMO energy levels but different backbone configuration. Compared with the wavy backbone configuration, the pseudo-straight backbone configuration imparts the polymer with much enhanced crystallinity and electron mobility. As a result, after n-doping, the polymer with pseudo-straight configuration shows much higher electronic conductivity and power factor. We think these findings could serve as important guidelines for molecular design toward efficient n-type polymer thermoelectric materials. © Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2022 |
| abstract_unstemmed |
Abstract The development of n-type polymer thermoelectrics lags far behind that of p-type ones in view of material diversity and performance. New structural insights into the thermoelectric performance are needed for efficient n-type polymer thermoelectric materials. Herein, we developed three acceptor-acceptor type organoboron polymers and investigated the effect of backbone configuration on thermoelectric performance. The three polymers are designed based on double B←N bridged bipyridine (BNBP) unit with monomeric thieno[3,4-c]pyrrole-4,6-dione (TPD), TPD dimer and TPD trimer as the copolymerizing units, respectively. The three polymers show similar low LUMO energy levels but different backbone configuration. Compared with the wavy backbone configuration, the pseudo-straight backbone configuration imparts the polymer with much enhanced crystallinity and electron mobility. As a result, after n-doping, the polymer with pseudo-straight configuration shows much higher electronic conductivity and power factor. We think these findings could serve as important guidelines for molecular design toward efficient n-type polymer thermoelectric materials. © Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2022 |
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Acceptor-acceptor-type Organoboron Conjugated Polymers: Effect of Backbone Configuration on Thermoelectric Performance |
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