Decarboxylation syntheses of transition metal organometallics, II.trans-carbonyl(polyhalogenophenyl)bis(triphenylphosphine)rhodium(I) compounds
Summary The rhodium(I) carboxylates,trans-$ RhO_{2} $CR(CO)($ PPh_{3} $)2 (R = $ C_{6} $$ F_{5} $, $ C_{6} $$ Cl_{5} $,p-$ HC_{6} $$ F_{4} $,m-$ HC_{6} $$ F_{4} $,o-$ HC_{6} $$ F_{4} $,p-$ McOC_{6} $$ F_{4} $, 4,5-$ H_{2} $$ C_{6} $$ F_{3} $, 3,5-$ H_{2} $$ C_{6} $$ F_{3} $, or 2,6-$ F_{2} $$ C_{6}...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Deacon, Glen B. [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1980 |
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| Schlagwörter: |
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| Anmerkung: |
© Verlag Chemie, GmbH 1980 |
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| Übergeordnetes Werk: |
Enthalten in: Transition metal chemistry - Kluwer Academic Publishers, 1975, 5(1980), 1 vom: Dez., Seite 305-313 |
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| Übergeordnetes Werk: |
volume:5 ; year:1980 ; number:1 ; month:12 ; pages:305-313 |
| Links: |
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| DOI / URN: |
10.1007/BF01396945 |
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| Katalog-ID: |
OLC2083993594 |
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| 024 | 7 | |a 10.1007/BF01396945 |2 doi | |
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| 100 | 1 | |a Deacon, Glen B. |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Decarboxylation syntheses of transition metal organometallics, II.trans-carbonyl(polyhalogenophenyl)bis(triphenylphosphine)rhodium(I) compounds |
| 264 | 1 | |c 1980 | |
| 336 | |a Text |b txt |2 rdacontent | ||
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| 500 | |a © Verlag Chemie, GmbH 1980 | ||
| 520 | |a Summary The rhodium(I) carboxylates,trans-$ RhO_{2} $CR(CO)($ PPh_{3} $)2 (R = $ C_{6} $$ F_{5} $, $ C_{6} $$ Cl_{5} $,p-$ HC_{6} $$ F_{4} $,m-$ HC_{6} $$ F_{4} $,o-$ HC_{6} $$ F_{4} $,p-$ McOC_{6} $$ F_{4} $, 4,5-$ H_{2} $$ C_{6} $$ F_{3} $, 3,5-$ H_{2} $$ C_{6} $$ F_{3} $, or 2,6-$ F_{2} $$ C_{6} $$ H_{3} $, have been prepared by reaction of RhH(CO)($ PPh_{3} $)3 with the appropriate polyhalogenobenzoic acids in ethanol and/or by reaction oftrans-RhCl(CO)($ PPh_{3} $)2 with the appropriate thallous carboxylates in benzene. Decarboxylations with formation of polyhalogenoarylrhodium(I) compounds,trans-RhR(CO)($ PPh_{3} $)2 (R = $ C_{6} $$ F_{5} $, $ C_{6} $$ Cl_{5} $,p-$ HC_{6} $$ F_{4} $,m-$ HC_{6} $$ F_{4} $,p-$ MeOC_{6} $$ F_{4} $, 4,5-$ H_{2} $$ C_{6} $$ F_{3} $ or 3,5-$ H_{2} $$ C_{6} $$ F_{3} $), have been achieved either by decomposition of the corresponding rhodium(I) carboxylates in pyridine or by reaction oftrans-RhCl(CO)($ PPh_{3} $)2 and the thallous carboxylates in pyridine, but the derivatives R =o-$ HC_{6} $$ F_{4} $ or 2,6-$ F_{2} $$ C_{6} $$ H_{3} $ could not be obtained by this method. The rate of decarboxylation decreased in the sequence R = $ C_{6} $$ F_{5} $ >p-$ MeOC_{6} $$ F_{4} $ >p-$ HC_{6} $$ F_{4} $ >m-$ HC_{6} $$ F_{4} $ > 4,5-$ H_{2} $$ C_{6} $$ F_{3} $ > 3,5-$ H_{2} $$ C_{6} $$ F_{3} $. | ||
| 650 | 4 | |a Physical Chemistry | |
| 650 | 4 | |a Benzene | |
| 650 | 4 | |a Inorganic Chemistry | |
| 650 | 4 | |a Catalysis | |
| 650 | 4 | |a Carboxylate | |
| 700 | 1 | |a Faulks, Suellen J. |4 aut | |
| 700 | 1 | |a Miller, Jack M. |4 aut | |
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10.1007/BF01396945 doi (DE-627)OLC2083993594 (DE-He213)BF01396945-p DE-627 ger DE-627 rakwb eng 660 VZ Deacon, Glen B. verfasserin aut Decarboxylation syntheses of transition metal organometallics, II.trans-carbonyl(polyhalogenophenyl)bis(triphenylphosphine)rhodium(I) compounds 1980 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Verlag Chemie, GmbH 1980 Summary The rhodium(I) carboxylates,trans-$ RhO_{2} $CR(CO)($ PPh_{3} $)2 (R = $ C_{6} $$ F_{5} $, $ C_{6} $$ Cl_{5} $,p-$ HC_{6} $$ F_{4} $,m-$ HC_{6} $$ F_{4} $,o-$ HC_{6} $$ F_{4} $,p-$ McOC_{6} $$ F_{4} $, 4,5-$ H_{2} $$ C_{6} $$ F_{3} $, 3,5-$ H_{2} $$ C_{6} $$ F_{3} $, or 2,6-$ F_{2} $$ C_{6} $$ H_{3} $, have been prepared by reaction of RhH(CO)($ PPh_{3} $)3 with the appropriate polyhalogenobenzoic acids in ethanol and/or by reaction oftrans-RhCl(CO)($ PPh_{3} $)2 with the appropriate thallous carboxylates in benzene. Decarboxylations with formation of polyhalogenoarylrhodium(I) compounds,trans-RhR(CO)($ PPh_{3} $)2 (R = $ C_{6} $$ F_{5} $, $ C_{6} $$ Cl_{5} $,p-$ HC_{6} $$ F_{4} $,m-$ HC_{6} $$ F_{4} $,p-$ MeOC_{6} $$ F_{4} $, 4,5-$ H_{2} $$ C_{6} $$ F_{3} $ or 3,5-$ H_{2} $$ C_{6} $$ F_{3} $), have been achieved either by decomposition of the corresponding rhodium(I) carboxylates in pyridine or by reaction oftrans-RhCl(CO)($ PPh_{3} $)2 and the thallous carboxylates in pyridine, but the derivatives R =o-$ HC_{6} $$ F_{4} $ or 2,6-$ F_{2} $$ C_{6} $$ H_{3} $ could not be obtained by this method. The rate of decarboxylation decreased in the sequence R = $ C_{6} $$ F_{5} $ >p-$ MeOC_{6} $$ F_{4} $ >p-$ HC_{6} $$ F_{4} $ >m-$ HC_{6} $$ F_{4} $ > 4,5-$ H_{2} $$ C_{6} $$ F_{3} $ > 3,5-$ H_{2} $$ C_{6} $$ F_{3} $. Physical Chemistry Benzene Inorganic Chemistry Catalysis Carboxylate Faulks, Suellen J. aut Miller, Jack M. aut Enthalten in Transition metal chemistry Kluwer Academic Publishers, 1975 5(1980), 1 vom: Dez., Seite 305-313 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:5 year:1980 number:1 month:12 pages:305-313 https://doi.org/10.1007/BF01396945 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_22 GBV_ILN_40 GBV_ILN_70 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_4012 GBV_ILN_4028 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4103 GBV_ILN_4125 GBV_ILN_4305 AR 5 1980 1 12 305-313 |
| spelling |
10.1007/BF01396945 doi (DE-627)OLC2083993594 (DE-He213)BF01396945-p DE-627 ger DE-627 rakwb eng 660 VZ Deacon, Glen B. verfasserin aut Decarboxylation syntheses of transition metal organometallics, II.trans-carbonyl(polyhalogenophenyl)bis(triphenylphosphine)rhodium(I) compounds 1980 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Verlag Chemie, GmbH 1980 Summary The rhodium(I) carboxylates,trans-$ RhO_{2} $CR(CO)($ PPh_{3} $)2 (R = $ C_{6} $$ F_{5} $, $ C_{6} $$ Cl_{5} $,p-$ HC_{6} $$ F_{4} $,m-$ HC_{6} $$ F_{4} $,o-$ HC_{6} $$ F_{4} $,p-$ McOC_{6} $$ F_{4} $, 4,5-$ H_{2} $$ C_{6} $$ F_{3} $, 3,5-$ H_{2} $$ C_{6} $$ F_{3} $, or 2,6-$ F_{2} $$ C_{6} $$ H_{3} $, have been prepared by reaction of RhH(CO)($ PPh_{3} $)3 with the appropriate polyhalogenobenzoic acids in ethanol and/or by reaction oftrans-RhCl(CO)($ PPh_{3} $)2 with the appropriate thallous carboxylates in benzene. Decarboxylations with formation of polyhalogenoarylrhodium(I) compounds,trans-RhR(CO)($ PPh_{3} $)2 (R = $ C_{6} $$ F_{5} $, $ C_{6} $$ Cl_{5} $,p-$ HC_{6} $$ F_{4} $,m-$ HC_{6} $$ F_{4} $,p-$ MeOC_{6} $$ F_{4} $, 4,5-$ H_{2} $$ C_{6} $$ F_{3} $ or 3,5-$ H_{2} $$ C_{6} $$ F_{3} $), have been achieved either by decomposition of the corresponding rhodium(I) carboxylates in pyridine or by reaction oftrans-RhCl(CO)($ PPh_{3} $)2 and the thallous carboxylates in pyridine, but the derivatives R =o-$ HC_{6} $$ F_{4} $ or 2,6-$ F_{2} $$ C_{6} $$ H_{3} $ could not be obtained by this method. The rate of decarboxylation decreased in the sequence R = $ C_{6} $$ F_{5} $ >p-$ MeOC_{6} $$ F_{4} $ >p-$ HC_{6} $$ F_{4} $ >m-$ HC_{6} $$ F_{4} $ > 4,5-$ H_{2} $$ C_{6} $$ F_{3} $ > 3,5-$ H_{2} $$ C_{6} $$ F_{3} $. Physical Chemistry Benzene Inorganic Chemistry Catalysis Carboxylate Faulks, Suellen J. aut Miller, Jack M. aut Enthalten in Transition metal chemistry Kluwer Academic Publishers, 1975 5(1980), 1 vom: Dez., Seite 305-313 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:5 year:1980 number:1 month:12 pages:305-313 https://doi.org/10.1007/BF01396945 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_22 GBV_ILN_40 GBV_ILN_70 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_4012 GBV_ILN_4028 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4103 GBV_ILN_4125 GBV_ILN_4305 AR 5 1980 1 12 305-313 |
| allfields_unstemmed |
10.1007/BF01396945 doi (DE-627)OLC2083993594 (DE-He213)BF01396945-p DE-627 ger DE-627 rakwb eng 660 VZ Deacon, Glen B. verfasserin aut Decarboxylation syntheses of transition metal organometallics, II.trans-carbonyl(polyhalogenophenyl)bis(triphenylphosphine)rhodium(I) compounds 1980 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Verlag Chemie, GmbH 1980 Summary The rhodium(I) carboxylates,trans-$ RhO_{2} $CR(CO)($ PPh_{3} $)2 (R = $ C_{6} $$ F_{5} $, $ C_{6} $$ Cl_{5} $,p-$ HC_{6} $$ F_{4} $,m-$ HC_{6} $$ F_{4} $,o-$ HC_{6} $$ F_{4} $,p-$ McOC_{6} $$ F_{4} $, 4,5-$ H_{2} $$ C_{6} $$ F_{3} $, 3,5-$ H_{2} $$ C_{6} $$ F_{3} $, or 2,6-$ F_{2} $$ C_{6} $$ H_{3} $, have been prepared by reaction of RhH(CO)($ PPh_{3} $)3 with the appropriate polyhalogenobenzoic acids in ethanol and/or by reaction oftrans-RhCl(CO)($ PPh_{3} $)2 with the appropriate thallous carboxylates in benzene. Decarboxylations with formation of polyhalogenoarylrhodium(I) compounds,trans-RhR(CO)($ PPh_{3} $)2 (R = $ C_{6} $$ F_{5} $, $ C_{6} $$ Cl_{5} $,p-$ HC_{6} $$ F_{4} $,m-$ HC_{6} $$ F_{4} $,p-$ MeOC_{6} $$ F_{4} $, 4,5-$ H_{2} $$ C_{6} $$ F_{3} $ or 3,5-$ H_{2} $$ C_{6} $$ F_{3} $), have been achieved either by decomposition of the corresponding rhodium(I) carboxylates in pyridine or by reaction oftrans-RhCl(CO)($ PPh_{3} $)2 and the thallous carboxylates in pyridine, but the derivatives R =o-$ HC_{6} $$ F_{4} $ or 2,6-$ F_{2} $$ C_{6} $$ H_{3} $ could not be obtained by this method. The rate of decarboxylation decreased in the sequence R = $ C_{6} $$ F_{5} $ >p-$ MeOC_{6} $$ F_{4} $ >p-$ HC_{6} $$ F_{4} $ >m-$ HC_{6} $$ F_{4} $ > 4,5-$ H_{2} $$ C_{6} $$ F_{3} $ > 3,5-$ H_{2} $$ C_{6} $$ F_{3} $. Physical Chemistry Benzene Inorganic Chemistry Catalysis Carboxylate Faulks, Suellen J. aut Miller, Jack M. aut Enthalten in Transition metal chemistry Kluwer Academic Publishers, 1975 5(1980), 1 vom: Dez., Seite 305-313 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:5 year:1980 number:1 month:12 pages:305-313 https://doi.org/10.1007/BF01396945 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_22 GBV_ILN_40 GBV_ILN_70 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_4012 GBV_ILN_4028 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4103 GBV_ILN_4125 GBV_ILN_4305 AR 5 1980 1 12 305-313 |
| allfieldsGer |
10.1007/BF01396945 doi (DE-627)OLC2083993594 (DE-He213)BF01396945-p DE-627 ger DE-627 rakwb eng 660 VZ Deacon, Glen B. verfasserin aut Decarboxylation syntheses of transition metal organometallics, II.trans-carbonyl(polyhalogenophenyl)bis(triphenylphosphine)rhodium(I) compounds 1980 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Verlag Chemie, GmbH 1980 Summary The rhodium(I) carboxylates,trans-$ RhO_{2} $CR(CO)($ PPh_{3} $)2 (R = $ C_{6} $$ F_{5} $, $ C_{6} $$ Cl_{5} $,p-$ HC_{6} $$ F_{4} $,m-$ HC_{6} $$ F_{4} $,o-$ HC_{6} $$ F_{4} $,p-$ McOC_{6} $$ F_{4} $, 4,5-$ H_{2} $$ C_{6} $$ F_{3} $, 3,5-$ H_{2} $$ C_{6} $$ F_{3} $, or 2,6-$ F_{2} $$ C_{6} $$ H_{3} $, have been prepared by reaction of RhH(CO)($ PPh_{3} $)3 with the appropriate polyhalogenobenzoic acids in ethanol and/or by reaction oftrans-RhCl(CO)($ PPh_{3} $)2 with the appropriate thallous carboxylates in benzene. Decarboxylations with formation of polyhalogenoarylrhodium(I) compounds,trans-RhR(CO)($ PPh_{3} $)2 (R = $ C_{6} $$ F_{5} $, $ C_{6} $$ Cl_{5} $,p-$ HC_{6} $$ F_{4} $,m-$ HC_{6} $$ F_{4} $,p-$ MeOC_{6} $$ F_{4} $, 4,5-$ H_{2} $$ C_{6} $$ F_{3} $ or 3,5-$ H_{2} $$ C_{6} $$ F_{3} $), have been achieved either by decomposition of the corresponding rhodium(I) carboxylates in pyridine or by reaction oftrans-RhCl(CO)($ PPh_{3} $)2 and the thallous carboxylates in pyridine, but the derivatives R =o-$ HC_{6} $$ F_{4} $ or 2,6-$ F_{2} $$ C_{6} $$ H_{3} $ could not be obtained by this method. The rate of decarboxylation decreased in the sequence R = $ C_{6} $$ F_{5} $ >p-$ MeOC_{6} $$ F_{4} $ >p-$ HC_{6} $$ F_{4} $ >m-$ HC_{6} $$ F_{4} $ > 4,5-$ H_{2} $$ C_{6} $$ F_{3} $ > 3,5-$ H_{2} $$ C_{6} $$ F_{3} $. Physical Chemistry Benzene Inorganic Chemistry Catalysis Carboxylate Faulks, Suellen J. aut Miller, Jack M. aut Enthalten in Transition metal chemistry Kluwer Academic Publishers, 1975 5(1980), 1 vom: Dez., Seite 305-313 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:5 year:1980 number:1 month:12 pages:305-313 https://doi.org/10.1007/BF01396945 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_22 GBV_ILN_40 GBV_ILN_70 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_4012 GBV_ILN_4028 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4103 GBV_ILN_4125 GBV_ILN_4305 AR 5 1980 1 12 305-313 |
| allfieldsSound |
10.1007/BF01396945 doi (DE-627)OLC2083993594 (DE-He213)BF01396945-p DE-627 ger DE-627 rakwb eng 660 VZ Deacon, Glen B. verfasserin aut Decarboxylation syntheses of transition metal organometallics, II.trans-carbonyl(polyhalogenophenyl)bis(triphenylphosphine)rhodium(I) compounds 1980 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Verlag Chemie, GmbH 1980 Summary The rhodium(I) carboxylates,trans-$ RhO_{2} $CR(CO)($ PPh_{3} $)2 (R = $ C_{6} $$ F_{5} $, $ C_{6} $$ Cl_{5} $,p-$ HC_{6} $$ F_{4} $,m-$ HC_{6} $$ F_{4} $,o-$ HC_{6} $$ F_{4} $,p-$ McOC_{6} $$ F_{4} $, 4,5-$ H_{2} $$ C_{6} $$ F_{3} $, 3,5-$ H_{2} $$ C_{6} $$ F_{3} $, or 2,6-$ F_{2} $$ C_{6} $$ H_{3} $, have been prepared by reaction of RhH(CO)($ PPh_{3} $)3 with the appropriate polyhalogenobenzoic acids in ethanol and/or by reaction oftrans-RhCl(CO)($ PPh_{3} $)2 with the appropriate thallous carboxylates in benzene. Decarboxylations with formation of polyhalogenoarylrhodium(I) compounds,trans-RhR(CO)($ PPh_{3} $)2 (R = $ C_{6} $$ F_{5} $, $ C_{6} $$ Cl_{5} $,p-$ HC_{6} $$ F_{4} $,m-$ HC_{6} $$ F_{4} $,p-$ MeOC_{6} $$ F_{4} $, 4,5-$ H_{2} $$ C_{6} $$ F_{3} $ or 3,5-$ H_{2} $$ C_{6} $$ F_{3} $), have been achieved either by decomposition of the corresponding rhodium(I) carboxylates in pyridine or by reaction oftrans-RhCl(CO)($ PPh_{3} $)2 and the thallous carboxylates in pyridine, but the derivatives R =o-$ HC_{6} $$ F_{4} $ or 2,6-$ F_{2} $$ C_{6} $$ H_{3} $ could not be obtained by this method. The rate of decarboxylation decreased in the sequence R = $ C_{6} $$ F_{5} $ >p-$ MeOC_{6} $$ F_{4} $ >p-$ HC_{6} $$ F_{4} $ >m-$ HC_{6} $$ F_{4} $ > 4,5-$ H_{2} $$ C_{6} $$ F_{3} $ > 3,5-$ H_{2} $$ C_{6} $$ F_{3} $. Physical Chemistry Benzene Inorganic Chemistry Catalysis Carboxylate Faulks, Suellen J. aut Miller, Jack M. aut Enthalten in Transition metal chemistry Kluwer Academic Publishers, 1975 5(1980), 1 vom: Dez., Seite 305-313 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:5 year:1980 number:1 month:12 pages:305-313 https://doi.org/10.1007/BF01396945 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_22 GBV_ILN_40 GBV_ILN_70 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_4012 GBV_ILN_4028 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4103 GBV_ILN_4125 GBV_ILN_4305 AR 5 1980 1 12 305-313 |
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Enthalten in Transition metal chemistry 5(1980), 1 vom: Dez., Seite 305-313 volume:5 year:1980 number:1 month:12 pages:305-313 |
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Decarboxylations with formation of polyhalogenoarylrhodium(I) compounds,trans-RhR(CO)($ PPh_{3} $)2 (R = $ C_{6} $$ F_{5} $, $ C_{6} $$ Cl_{5} $,p-$ HC_{6} $$ F_{4} $,m-$ HC_{6} $$ F_{4} $,p-$ MeOC_{6} $$ F_{4} $, 4,5-$ H_{2} $$ C_{6} $$ F_{3} $ or 3,5-$ H_{2} $$ C_{6} $$ F_{3} $), have been achieved either by decomposition of the corresponding rhodium(I) carboxylates in pyridine or by reaction oftrans-RhCl(CO)($ PPh_{3} $)2 and the thallous carboxylates in pyridine, but the derivatives R =o-$ HC_{6} $$ F_{4} $ or 2,6-$ F_{2} $$ C_{6} $$ H_{3} $ could not be obtained by this method. 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Deacon, Glen B. |
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Deacon, Glen B. ddc 660 misc Physical Chemistry misc Benzene misc Inorganic Chemistry misc Catalysis misc Carboxylate Decarboxylation syntheses of transition metal organometallics, II.trans-carbonyl(polyhalogenophenyl)bis(triphenylphosphine)rhodium(I) compounds |
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660 VZ Decarboxylation syntheses of transition metal organometallics, II.trans-carbonyl(polyhalogenophenyl)bis(triphenylphosphine)rhodium(I) compounds Physical Chemistry Benzene Inorganic Chemistry Catalysis Carboxylate |
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ddc 660 misc Physical Chemistry misc Benzene misc Inorganic Chemistry misc Catalysis misc Carboxylate |
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ddc 660 misc Physical Chemistry misc Benzene misc Inorganic Chemistry misc Catalysis misc Carboxylate |
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Decarboxylation syntheses of transition metal organometallics, II.trans-carbonyl(polyhalogenophenyl)bis(triphenylphosphine)rhodium(I) compounds |
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Decarboxylation syntheses of transition metal organometallics, II.trans-carbonyl(polyhalogenophenyl)bis(triphenylphosphine)rhodium(I) compounds |
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Deacon, Glen B. |
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Transition metal chemistry |
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1980 |
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Deacon, Glen B. Faulks, Suellen J. Miller, Jack M. |
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Deacon, Glen B. |
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10.1007/BF01396945 |
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decarboxylation syntheses of transition metal organometallics, ii.trans-carbonyl(polyhalogenophenyl)bis(triphenylphosphine)rhodium(i) compounds |
| title_auth |
Decarboxylation syntheses of transition metal organometallics, II.trans-carbonyl(polyhalogenophenyl)bis(triphenylphosphine)rhodium(I) compounds |
| abstract |
Summary The rhodium(I) carboxylates,trans-$ RhO_{2} $CR(CO)($ PPh_{3} $)2 (R = $ C_{6} $$ F_{5} $, $ C_{6} $$ Cl_{5} $,p-$ HC_{6} $$ F_{4} $,m-$ HC_{6} $$ F_{4} $,o-$ HC_{6} $$ F_{4} $,p-$ McOC_{6} $$ F_{4} $, 4,5-$ H_{2} $$ C_{6} $$ F_{3} $, 3,5-$ H_{2} $$ C_{6} $$ F_{3} $, or 2,6-$ F_{2} $$ C_{6} $$ H_{3} $, have been prepared by reaction of RhH(CO)($ PPh_{3} $)3 with the appropriate polyhalogenobenzoic acids in ethanol and/or by reaction oftrans-RhCl(CO)($ PPh_{3} $)2 with the appropriate thallous carboxylates in benzene. Decarboxylations with formation of polyhalogenoarylrhodium(I) compounds,trans-RhR(CO)($ PPh_{3} $)2 (R = $ C_{6} $$ F_{5} $, $ C_{6} $$ Cl_{5} $,p-$ HC_{6} $$ F_{4} $,m-$ HC_{6} $$ F_{4} $,p-$ MeOC_{6} $$ F_{4} $, 4,5-$ H_{2} $$ C_{6} $$ F_{3} $ or 3,5-$ H_{2} $$ C_{6} $$ F_{3} $), have been achieved either by decomposition of the corresponding rhodium(I) carboxylates in pyridine or by reaction oftrans-RhCl(CO)($ PPh_{3} $)2 and the thallous carboxylates in pyridine, but the derivatives R =o-$ HC_{6} $$ F_{4} $ or 2,6-$ F_{2} $$ C_{6} $$ H_{3} $ could not be obtained by this method. The rate of decarboxylation decreased in the sequence R = $ C_{6} $$ F_{5} $ >p-$ MeOC_{6} $$ F_{4} $ >p-$ HC_{6} $$ F_{4} $ >m-$ HC_{6} $$ F_{4} $ > 4,5-$ H_{2} $$ C_{6} $$ F_{3} $ > 3,5-$ H_{2} $$ C_{6} $$ F_{3} $. © Verlag Chemie, GmbH 1980 |
| abstractGer |
Summary The rhodium(I) carboxylates,trans-$ RhO_{2} $CR(CO)($ PPh_{3} $)2 (R = $ C_{6} $$ F_{5} $, $ C_{6} $$ Cl_{5} $,p-$ HC_{6} $$ F_{4} $,m-$ HC_{6} $$ F_{4} $,o-$ HC_{6} $$ F_{4} $,p-$ McOC_{6} $$ F_{4} $, 4,5-$ H_{2} $$ C_{6} $$ F_{3} $, 3,5-$ H_{2} $$ C_{6} $$ F_{3} $, or 2,6-$ F_{2} $$ C_{6} $$ H_{3} $, have been prepared by reaction of RhH(CO)($ PPh_{3} $)3 with the appropriate polyhalogenobenzoic acids in ethanol and/or by reaction oftrans-RhCl(CO)($ PPh_{3} $)2 with the appropriate thallous carboxylates in benzene. Decarboxylations with formation of polyhalogenoarylrhodium(I) compounds,trans-RhR(CO)($ PPh_{3} $)2 (R = $ C_{6} $$ F_{5} $, $ C_{6} $$ Cl_{5} $,p-$ HC_{6} $$ F_{4} $,m-$ HC_{6} $$ F_{4} $,p-$ MeOC_{6} $$ F_{4} $, 4,5-$ H_{2} $$ C_{6} $$ F_{3} $ or 3,5-$ H_{2} $$ C_{6} $$ F_{3} $), have been achieved either by decomposition of the corresponding rhodium(I) carboxylates in pyridine or by reaction oftrans-RhCl(CO)($ PPh_{3} $)2 and the thallous carboxylates in pyridine, but the derivatives R =o-$ HC_{6} $$ F_{4} $ or 2,6-$ F_{2} $$ C_{6} $$ H_{3} $ could not be obtained by this method. The rate of decarboxylation decreased in the sequence R = $ C_{6} $$ F_{5} $ >p-$ MeOC_{6} $$ F_{4} $ >p-$ HC_{6} $$ F_{4} $ >m-$ HC_{6} $$ F_{4} $ > 4,5-$ H_{2} $$ C_{6} $$ F_{3} $ > 3,5-$ H_{2} $$ C_{6} $$ F_{3} $. © Verlag Chemie, GmbH 1980 |
| abstract_unstemmed |
Summary The rhodium(I) carboxylates,trans-$ RhO_{2} $CR(CO)($ PPh_{3} $)2 (R = $ C_{6} $$ F_{5} $, $ C_{6} $$ Cl_{5} $,p-$ HC_{6} $$ F_{4} $,m-$ HC_{6} $$ F_{4} $,o-$ HC_{6} $$ F_{4} $,p-$ McOC_{6} $$ F_{4} $, 4,5-$ H_{2} $$ C_{6} $$ F_{3} $, 3,5-$ H_{2} $$ C_{6} $$ F_{3} $, or 2,6-$ F_{2} $$ C_{6} $$ H_{3} $, have been prepared by reaction of RhH(CO)($ PPh_{3} $)3 with the appropriate polyhalogenobenzoic acids in ethanol and/or by reaction oftrans-RhCl(CO)($ PPh_{3} $)2 with the appropriate thallous carboxylates in benzene. Decarboxylations with formation of polyhalogenoarylrhodium(I) compounds,trans-RhR(CO)($ PPh_{3} $)2 (R = $ C_{6} $$ F_{5} $, $ C_{6} $$ Cl_{5} $,p-$ HC_{6} $$ F_{4} $,m-$ HC_{6} $$ F_{4} $,p-$ MeOC_{6} $$ F_{4} $, 4,5-$ H_{2} $$ C_{6} $$ F_{3} $ or 3,5-$ H_{2} $$ C_{6} $$ F_{3} $), have been achieved either by decomposition of the corresponding rhodium(I) carboxylates in pyridine or by reaction oftrans-RhCl(CO)($ PPh_{3} $)2 and the thallous carboxylates in pyridine, but the derivatives R =o-$ HC_{6} $$ F_{4} $ or 2,6-$ F_{2} $$ C_{6} $$ H_{3} $ could not be obtained by this method. The rate of decarboxylation decreased in the sequence R = $ C_{6} $$ F_{5} $ >p-$ MeOC_{6} $$ F_{4} $ >p-$ HC_{6} $$ F_{4} $ >m-$ HC_{6} $$ F_{4} $ > 4,5-$ H_{2} $$ C_{6} $$ F_{3} $ > 3,5-$ H_{2} $$ C_{6} $$ F_{3} $. © Verlag Chemie, GmbH 1980 |
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Decarboxylation syntheses of transition metal organometallics, II.trans-carbonyl(polyhalogenophenyl)bis(triphenylphosphine)rhodium(I) compounds |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC2083993594</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230504062922.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">230301s1980 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/BF01396945</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2083993594</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)BF01396945-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Deacon, Glen B.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Decarboxylation syntheses of transition metal organometallics, II.trans-carbonyl(polyhalogenophenyl)bis(triphenylphosphine)rhodium(I) compounds</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">1980</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Verlag Chemie, GmbH 1980</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Summary The rhodium(I) carboxylates,trans-$ RhO_{2} $CR(CO)($ PPh_{3} $)2 (R = $ C_{6} $$ F_{5} $, $ C_{6} $$ Cl_{5} $,p-$ HC_{6} $$ F_{4} $,m-$ HC_{6} $$ F_{4} $,o-$ HC_{6} $$ F_{4} $,p-$ McOC_{6} $$ F_{4} $, 4,5-$ H_{2} $$ C_{6} $$ F_{3} $, 3,5-$ H_{2} $$ C_{6} $$ F_{3} $, or 2,6-$ F_{2} $$ C_{6} $$ H_{3} $, have been prepared by reaction of RhH(CO)($ PPh_{3} $)3 with the appropriate polyhalogenobenzoic acids in ethanol and/or by reaction oftrans-RhCl(CO)($ PPh_{3} $)2 with the appropriate thallous carboxylates in benzene. Decarboxylations with formation of polyhalogenoarylrhodium(I) compounds,trans-RhR(CO)($ PPh_{3} $)2 (R = $ C_{6} $$ F_{5} $, $ C_{6} $$ Cl_{5} $,p-$ HC_{6} $$ F_{4} $,m-$ HC_{6} $$ F_{4} $,p-$ MeOC_{6} $$ F_{4} $, 4,5-$ H_{2} $$ C_{6} $$ F_{3} $ or 3,5-$ H_{2} $$ C_{6} $$ F_{3} $), have been achieved either by decomposition of the corresponding rhodium(I) carboxylates in pyridine or by reaction oftrans-RhCl(CO)($ PPh_{3} $)2 and the thallous carboxylates in pyridine, but the derivatives R =o-$ HC_{6} $$ F_{4} $ or 2,6-$ F_{2} $$ C_{6} $$ H_{3} $ could not be obtained by this method. The rate of decarboxylation decreased in the sequence R = $ C_{6} $$ F_{5} $ >p-$ MeOC_{6} $$ F_{4} $ >p-$ HC_{6} $$ F_{4} $ >m-$ HC_{6} $$ F_{4} $ > 4,5-$ H_{2} $$ C_{6} $$ F_{3} $ > 3,5-$ H_{2} $$ C_{6} $$ F_{3} $.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Physical Chemistry</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Benzene</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Inorganic Chemistry</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Catalysis</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Carboxylate</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Faulks, Suellen J.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Miller, Jack M.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Transition metal chemistry</subfield><subfield code="d">Kluwer Academic Publishers, 1975</subfield><subfield code="g">5(1980), 1 vom: Dez., Seite 305-313</subfield><subfield code="w">(DE-627)129605417</subfield><subfield code="w">(DE-600)242084-3</subfield><subfield code="w">(DE-576)015099652</subfield><subfield code="x">0340-4285</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:5</subfield><subfield code="g">year:1980</subfield><subfield code="g">number:1</subfield><subfield code="g">month:12</subfield><subfield code="g">pages:305-313</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/BF01396945</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2018</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4012</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4028</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4046</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4082</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4103</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">5</subfield><subfield code="j">1980</subfield><subfield code="e">1</subfield><subfield code="c">12</subfield><subfield code="h">305-313</subfield></datafield></record></collection>
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