The mono- and bis-(trichloroacetic acid)-solvates of ferricenium trichloroacetate
Summary Inconsistent literature reports on the preparation of the mono- and bis-(trichloroacetic acid)-solvated ferricenium trichloroacetates, (1) and (2) have prompted a comprehensive investigation of the experimental conditions giving rise to the formation of the two ferricenium salts. In agreemen...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Neuse, Eberhard W. [verfasserIn] |
|---|
| Format: |
Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
1984 |
|---|
| Schlagwörter: |
|---|
| Anmerkung: |
© Verlag Chemie GmbH 1984 |
|---|
| Übergeordnetes Werk: |
Enthalten in: Transition metal chemistry - Kluwer Academic Publishers, 1975, 9(1984), 1 vom: Jan., Seite 12-17 |
|---|---|
| Übergeordnetes Werk: |
volume:9 ; year:1984 ; number:1 ; month:01 ; pages:12-17 |
| Links: |
|---|
| DOI / URN: |
10.1007/BF00620720 |
|---|
| Katalog-ID: |
OLC2083997425 |
|---|
| LEADER | 01000caa a22002652 4500 | ||
|---|---|---|---|
| 001 | OLC2083997425 | ||
| 003 | DE-627 | ||
| 005 | 20230504062936.0 | ||
| 007 | tu | ||
| 008 | 230301s1984 xx ||||| 00| ||eng c | ||
| 024 | 7 | |a 10.1007/BF00620720 |2 doi | |
| 035 | |a (DE-627)OLC2083997425 | ||
| 035 | |a (DE-He213)BF00620720-p | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 082 | 0 | 4 | |a 660 |q VZ |
| 100 | 1 | |a Neuse, Eberhard W. |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a The mono- and bis-(trichloroacetic acid)-solvates of ferricenium trichloroacetate |
| 264 | 1 | |c 1984 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a ohne Hilfsmittel zu benutzen |b n |2 rdamedia | ||
| 338 | |a Band |b nc |2 rdacarrier | ||
| 500 | |a © Verlag Chemie GmbH 1984 | ||
| 520 | |a Summary Inconsistent literature reports on the preparation of the mono- and bis-(trichloroacetic acid)-solvated ferricenium trichloroacetates, (1) and (2) have prompted a comprehensive investigation of the experimental conditions giving rise to the formation of the two ferricenium salts. In agreement with the majority of authors, (2) is reproducibly obtained from trichloroacetic acid and ferrocene in molar ratios of 3 and higher in benzene over a wide range of experimental variables in the presence of air or, preferably, under conditions of oxygen saturation. Treatment of aqueous ferricenium sulfate solutions with trichloroacetic acid in an acid/ferrocene ratio of 3 and above affords the di-solvate, whereas at lower reactant ratios, and under conditions of reduced acidity, formation of the mono-solvate prevails. More efficiently, and in a higher degree of purity, the latter salt is generated from the former by a controlled recrystallization from water. Representative spectroscopic features of the two salts are discussed. | ||
| 650 | 4 | |a Oxygen | |
| 650 | 4 | |a Sulfate | |
| 650 | 4 | |a Physical Chemistry | |
| 650 | 4 | |a Benzene | |
| 650 | 4 | |a Inorganic Chemistry | |
| 700 | 1 | |a Loonat, Rokaya |4 aut | |
| 700 | 1 | |a Boeyens, Jan C. A. |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Transition metal chemistry |d Kluwer Academic Publishers, 1975 |g 9(1984), 1 vom: Jan., Seite 12-17 |w (DE-627)129605417 |w (DE-600)242084-3 |w (DE-576)015099652 |x 0340-4285 |7 nnns |
| 773 | 1 | 8 | |g volume:9 |g year:1984 |g number:1 |g month:01 |g pages:12-17 |
| 856 | 4 | 1 | |u https://doi.org/10.1007/BF00620720 |z lizenzpflichtig |3 Volltext |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a SYSFLAG_A | ||
| 912 | |a GBV_OLC | ||
| 912 | |a SSG-OLC-TEC | ||
| 912 | |a SSG-OLC-CHE | ||
| 912 | |a GBV_ILN_22 | ||
| 912 | |a GBV_ILN_40 | ||
| 912 | |a GBV_ILN_70 | ||
| 912 | |a GBV_ILN_2018 | ||
| 912 | |a GBV_ILN_2021 | ||
| 912 | |a GBV_ILN_4012 | ||
| 912 | |a GBV_ILN_4028 | ||
| 912 | |a GBV_ILN_4046 | ||
| 912 | |a GBV_ILN_4082 | ||
| 912 | |a GBV_ILN_4103 | ||
| 912 | |a GBV_ILN_4125 | ||
| 912 | |a GBV_ILN_4305 | ||
| 912 | |a GBV_ILN_4306 | ||
| 951 | |a AR | ||
| 952 | |d 9 |j 1984 |e 1 |c 01 |h 12-17 | ||
| author_variant |
e w n ew ewn r l rl j c a b jca jcab |
|---|---|
| matchkey_str |
article:03404285:1984----::hmnaditihooctccdovtsfercn |
| hierarchy_sort_str |
1984 |
| publishDate |
1984 |
| allfields |
10.1007/BF00620720 doi (DE-627)OLC2083997425 (DE-He213)BF00620720-p DE-627 ger DE-627 rakwb eng 660 VZ Neuse, Eberhard W. verfasserin aut The mono- and bis-(trichloroacetic acid)-solvates of ferricenium trichloroacetate 1984 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Verlag Chemie GmbH 1984 Summary Inconsistent literature reports on the preparation of the mono- and bis-(trichloroacetic acid)-solvated ferricenium trichloroacetates, (1) and (2) have prompted a comprehensive investigation of the experimental conditions giving rise to the formation of the two ferricenium salts. In agreement with the majority of authors, (2) is reproducibly obtained from trichloroacetic acid and ferrocene in molar ratios of 3 and higher in benzene over a wide range of experimental variables in the presence of air or, preferably, under conditions of oxygen saturation. Treatment of aqueous ferricenium sulfate solutions with trichloroacetic acid in an acid/ferrocene ratio of 3 and above affords the di-solvate, whereas at lower reactant ratios, and under conditions of reduced acidity, formation of the mono-solvate prevails. More efficiently, and in a higher degree of purity, the latter salt is generated from the former by a controlled recrystallization from water. Representative spectroscopic features of the two salts are discussed. Oxygen Sulfate Physical Chemistry Benzene Inorganic Chemistry Loonat, Rokaya aut Boeyens, Jan C. A. aut Enthalten in Transition metal chemistry Kluwer Academic Publishers, 1975 9(1984), 1 vom: Jan., Seite 12-17 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:9 year:1984 number:1 month:01 pages:12-17 https://doi.org/10.1007/BF00620720 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_22 GBV_ILN_40 GBV_ILN_70 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_4012 GBV_ILN_4028 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4103 GBV_ILN_4125 GBV_ILN_4305 GBV_ILN_4306 AR 9 1984 1 01 12-17 |
| spelling |
10.1007/BF00620720 doi (DE-627)OLC2083997425 (DE-He213)BF00620720-p DE-627 ger DE-627 rakwb eng 660 VZ Neuse, Eberhard W. verfasserin aut The mono- and bis-(trichloroacetic acid)-solvates of ferricenium trichloroacetate 1984 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Verlag Chemie GmbH 1984 Summary Inconsistent literature reports on the preparation of the mono- and bis-(trichloroacetic acid)-solvated ferricenium trichloroacetates, (1) and (2) have prompted a comprehensive investigation of the experimental conditions giving rise to the formation of the two ferricenium salts. In agreement with the majority of authors, (2) is reproducibly obtained from trichloroacetic acid and ferrocene in molar ratios of 3 and higher in benzene over a wide range of experimental variables in the presence of air or, preferably, under conditions of oxygen saturation. Treatment of aqueous ferricenium sulfate solutions with trichloroacetic acid in an acid/ferrocene ratio of 3 and above affords the di-solvate, whereas at lower reactant ratios, and under conditions of reduced acidity, formation of the mono-solvate prevails. More efficiently, and in a higher degree of purity, the latter salt is generated from the former by a controlled recrystallization from water. Representative spectroscopic features of the two salts are discussed. Oxygen Sulfate Physical Chemistry Benzene Inorganic Chemistry Loonat, Rokaya aut Boeyens, Jan C. A. aut Enthalten in Transition metal chemistry Kluwer Academic Publishers, 1975 9(1984), 1 vom: Jan., Seite 12-17 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:9 year:1984 number:1 month:01 pages:12-17 https://doi.org/10.1007/BF00620720 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_22 GBV_ILN_40 GBV_ILN_70 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_4012 GBV_ILN_4028 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4103 GBV_ILN_4125 GBV_ILN_4305 GBV_ILN_4306 AR 9 1984 1 01 12-17 |
| allfields_unstemmed |
10.1007/BF00620720 doi (DE-627)OLC2083997425 (DE-He213)BF00620720-p DE-627 ger DE-627 rakwb eng 660 VZ Neuse, Eberhard W. verfasserin aut The mono- and bis-(trichloroacetic acid)-solvates of ferricenium trichloroacetate 1984 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Verlag Chemie GmbH 1984 Summary Inconsistent literature reports on the preparation of the mono- and bis-(trichloroacetic acid)-solvated ferricenium trichloroacetates, (1) and (2) have prompted a comprehensive investigation of the experimental conditions giving rise to the formation of the two ferricenium salts. In agreement with the majority of authors, (2) is reproducibly obtained from trichloroacetic acid and ferrocene in molar ratios of 3 and higher in benzene over a wide range of experimental variables in the presence of air or, preferably, under conditions of oxygen saturation. Treatment of aqueous ferricenium sulfate solutions with trichloroacetic acid in an acid/ferrocene ratio of 3 and above affords the di-solvate, whereas at lower reactant ratios, and under conditions of reduced acidity, formation of the mono-solvate prevails. More efficiently, and in a higher degree of purity, the latter salt is generated from the former by a controlled recrystallization from water. Representative spectroscopic features of the two salts are discussed. Oxygen Sulfate Physical Chemistry Benzene Inorganic Chemistry Loonat, Rokaya aut Boeyens, Jan C. A. aut Enthalten in Transition metal chemistry Kluwer Academic Publishers, 1975 9(1984), 1 vom: Jan., Seite 12-17 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:9 year:1984 number:1 month:01 pages:12-17 https://doi.org/10.1007/BF00620720 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_22 GBV_ILN_40 GBV_ILN_70 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_4012 GBV_ILN_4028 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4103 GBV_ILN_4125 GBV_ILN_4305 GBV_ILN_4306 AR 9 1984 1 01 12-17 |
| allfieldsGer |
10.1007/BF00620720 doi (DE-627)OLC2083997425 (DE-He213)BF00620720-p DE-627 ger DE-627 rakwb eng 660 VZ Neuse, Eberhard W. verfasserin aut The mono- and bis-(trichloroacetic acid)-solvates of ferricenium trichloroacetate 1984 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Verlag Chemie GmbH 1984 Summary Inconsistent literature reports on the preparation of the mono- and bis-(trichloroacetic acid)-solvated ferricenium trichloroacetates, (1) and (2) have prompted a comprehensive investigation of the experimental conditions giving rise to the formation of the two ferricenium salts. In agreement with the majority of authors, (2) is reproducibly obtained from trichloroacetic acid and ferrocene in molar ratios of 3 and higher in benzene over a wide range of experimental variables in the presence of air or, preferably, under conditions of oxygen saturation. Treatment of aqueous ferricenium sulfate solutions with trichloroacetic acid in an acid/ferrocene ratio of 3 and above affords the di-solvate, whereas at lower reactant ratios, and under conditions of reduced acidity, formation of the mono-solvate prevails. More efficiently, and in a higher degree of purity, the latter salt is generated from the former by a controlled recrystallization from water. Representative spectroscopic features of the two salts are discussed. Oxygen Sulfate Physical Chemistry Benzene Inorganic Chemistry Loonat, Rokaya aut Boeyens, Jan C. A. aut Enthalten in Transition metal chemistry Kluwer Academic Publishers, 1975 9(1984), 1 vom: Jan., Seite 12-17 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:9 year:1984 number:1 month:01 pages:12-17 https://doi.org/10.1007/BF00620720 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_22 GBV_ILN_40 GBV_ILN_70 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_4012 GBV_ILN_4028 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4103 GBV_ILN_4125 GBV_ILN_4305 GBV_ILN_4306 AR 9 1984 1 01 12-17 |
| allfieldsSound |
10.1007/BF00620720 doi (DE-627)OLC2083997425 (DE-He213)BF00620720-p DE-627 ger DE-627 rakwb eng 660 VZ Neuse, Eberhard W. verfasserin aut The mono- and bis-(trichloroacetic acid)-solvates of ferricenium trichloroacetate 1984 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Verlag Chemie GmbH 1984 Summary Inconsistent literature reports on the preparation of the mono- and bis-(trichloroacetic acid)-solvated ferricenium trichloroacetates, (1) and (2) have prompted a comprehensive investigation of the experimental conditions giving rise to the formation of the two ferricenium salts. In agreement with the majority of authors, (2) is reproducibly obtained from trichloroacetic acid and ferrocene in molar ratios of 3 and higher in benzene over a wide range of experimental variables in the presence of air or, preferably, under conditions of oxygen saturation. Treatment of aqueous ferricenium sulfate solutions with trichloroacetic acid in an acid/ferrocene ratio of 3 and above affords the di-solvate, whereas at lower reactant ratios, and under conditions of reduced acidity, formation of the mono-solvate prevails. More efficiently, and in a higher degree of purity, the latter salt is generated from the former by a controlled recrystallization from water. Representative spectroscopic features of the two salts are discussed. Oxygen Sulfate Physical Chemistry Benzene Inorganic Chemistry Loonat, Rokaya aut Boeyens, Jan C. A. aut Enthalten in Transition metal chemistry Kluwer Academic Publishers, 1975 9(1984), 1 vom: Jan., Seite 12-17 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:9 year:1984 number:1 month:01 pages:12-17 https://doi.org/10.1007/BF00620720 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_22 GBV_ILN_40 GBV_ILN_70 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_4012 GBV_ILN_4028 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4103 GBV_ILN_4125 GBV_ILN_4305 GBV_ILN_4306 AR 9 1984 1 01 12-17 |
| language |
English |
| source |
Enthalten in Transition metal chemistry 9(1984), 1 vom: Jan., Seite 12-17 volume:9 year:1984 number:1 month:01 pages:12-17 |
| sourceStr |
Enthalten in Transition metal chemistry 9(1984), 1 vom: Jan., Seite 12-17 volume:9 year:1984 number:1 month:01 pages:12-17 |
| format_phy_str_mv |
Article |
| institution |
findex.gbv.de |
| topic_facet |
Oxygen Sulfate Physical Chemistry Benzene Inorganic Chemistry |
| dewey-raw |
660 |
| isfreeaccess_bool |
false |
| container_title |
Transition metal chemistry |
| authorswithroles_txt_mv |
Neuse, Eberhard W. @@aut@@ Loonat, Rokaya @@aut@@ Boeyens, Jan C. A. @@aut@@ |
| publishDateDaySort_date |
1984-01-01T00:00:00Z |
| hierarchy_top_id |
129605417 |
| dewey-sort |
3660 |
| id |
OLC2083997425 |
| language_de |
englisch |
| fullrecord |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC2083997425</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230504062936.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">230301s1984 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/BF00620720</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2083997425</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)BF00620720-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Neuse, Eberhard W.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">The mono- and bis-(trichloroacetic acid)-solvates of ferricenium trichloroacetate</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">1984</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Verlag Chemie GmbH 1984</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Summary Inconsistent literature reports on the preparation of the mono- and bis-(trichloroacetic acid)-solvated ferricenium trichloroacetates, (1) and (2) have prompted a comprehensive investigation of the experimental conditions giving rise to the formation of the two ferricenium salts. In agreement with the majority of authors, (2) is reproducibly obtained from trichloroacetic acid and ferrocene in molar ratios of 3 and higher in benzene over a wide range of experimental variables in the presence of air or, preferably, under conditions of oxygen saturation. Treatment of aqueous ferricenium sulfate solutions with trichloroacetic acid in an acid/ferrocene ratio of 3 and above affords the di-solvate, whereas at lower reactant ratios, and under conditions of reduced acidity, formation of the mono-solvate prevails. More efficiently, and in a higher degree of purity, the latter salt is generated from the former by a controlled recrystallization from water. Representative spectroscopic features of the two salts are discussed.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Oxygen</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Sulfate</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Physical Chemistry</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Benzene</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Inorganic Chemistry</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Loonat, Rokaya</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Boeyens, Jan C. A.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Transition metal chemistry</subfield><subfield code="d">Kluwer Academic Publishers, 1975</subfield><subfield code="g">9(1984), 1 vom: Jan., Seite 12-17</subfield><subfield code="w">(DE-627)129605417</subfield><subfield code="w">(DE-600)242084-3</subfield><subfield code="w">(DE-576)015099652</subfield><subfield code="x">0340-4285</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:9</subfield><subfield code="g">year:1984</subfield><subfield code="g">number:1</subfield><subfield code="g">month:01</subfield><subfield code="g">pages:12-17</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/BF00620720</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2018</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4012</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4028</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4046</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4082</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4103</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">9</subfield><subfield code="j">1984</subfield><subfield code="e">1</subfield><subfield code="c">01</subfield><subfield code="h">12-17</subfield></datafield></record></collection>
|
| author |
Neuse, Eberhard W. |
| spellingShingle |
Neuse, Eberhard W. ddc 660 misc Oxygen misc Sulfate misc Physical Chemistry misc Benzene misc Inorganic Chemistry The mono- and bis-(trichloroacetic acid)-solvates of ferricenium trichloroacetate |
| authorStr |
Neuse, Eberhard W. |
| ppnlink_with_tag_str_mv |
@@773@@(DE-627)129605417 |
| format |
Article |
| dewey-ones |
660 - Chemical engineering |
| delete_txt_mv |
keep |
| author_role |
aut aut aut |
| collection |
OLC |
| remote_str |
false |
| illustrated |
Not Illustrated |
| issn |
0340-4285 |
| topic_title |
660 VZ The mono- and bis-(trichloroacetic acid)-solvates of ferricenium trichloroacetate Oxygen Sulfate Physical Chemistry Benzene Inorganic Chemistry |
| topic |
ddc 660 misc Oxygen misc Sulfate misc Physical Chemistry misc Benzene misc Inorganic Chemistry |
| topic_unstemmed |
ddc 660 misc Oxygen misc Sulfate misc Physical Chemistry misc Benzene misc Inorganic Chemistry |
| topic_browse |
ddc 660 misc Oxygen misc Sulfate misc Physical Chemistry misc Benzene misc Inorganic Chemistry |
| format_facet |
Aufsätze Gedruckte Aufsätze |
| format_main_str_mv |
Text Zeitschrift/Artikel |
| carriertype_str_mv |
nc |
| hierarchy_parent_title |
Transition metal chemistry |
| hierarchy_parent_id |
129605417 |
| dewey-tens |
660 - Chemical engineering |
| hierarchy_top_title |
Transition metal chemistry |
| isfreeaccess_txt |
false |
| familylinks_str_mv |
(DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 |
| title |
The mono- and bis-(trichloroacetic acid)-solvates of ferricenium trichloroacetate |
| ctrlnum |
(DE-627)OLC2083997425 (DE-He213)BF00620720-p |
| title_full |
The mono- and bis-(trichloroacetic acid)-solvates of ferricenium trichloroacetate |
| author_sort |
Neuse, Eberhard W. |
| journal |
Transition metal chemistry |
| journalStr |
Transition metal chemistry |
| lang_code |
eng |
| isOA_bool |
false |
| dewey-hundreds |
600 - Technology |
| recordtype |
marc |
| publishDateSort |
1984 |
| contenttype_str_mv |
txt |
| container_start_page |
12 |
| author_browse |
Neuse, Eberhard W. Loonat, Rokaya Boeyens, Jan C. A. |
| container_volume |
9 |
| class |
660 VZ |
| format_se |
Aufsätze |
| author-letter |
Neuse, Eberhard W. |
| doi_str_mv |
10.1007/BF00620720 |
| dewey-full |
660 |
| title_sort |
the mono- and bis-(trichloroacetic acid)-solvates of ferricenium trichloroacetate |
| title_auth |
The mono- and bis-(trichloroacetic acid)-solvates of ferricenium trichloroacetate |
| abstract |
Summary Inconsistent literature reports on the preparation of the mono- and bis-(trichloroacetic acid)-solvated ferricenium trichloroacetates, (1) and (2) have prompted a comprehensive investigation of the experimental conditions giving rise to the formation of the two ferricenium salts. In agreement with the majority of authors, (2) is reproducibly obtained from trichloroacetic acid and ferrocene in molar ratios of 3 and higher in benzene over a wide range of experimental variables in the presence of air or, preferably, under conditions of oxygen saturation. Treatment of aqueous ferricenium sulfate solutions with trichloroacetic acid in an acid/ferrocene ratio of 3 and above affords the di-solvate, whereas at lower reactant ratios, and under conditions of reduced acidity, formation of the mono-solvate prevails. More efficiently, and in a higher degree of purity, the latter salt is generated from the former by a controlled recrystallization from water. Representative spectroscopic features of the two salts are discussed. © Verlag Chemie GmbH 1984 |
| abstractGer |
Summary Inconsistent literature reports on the preparation of the mono- and bis-(trichloroacetic acid)-solvated ferricenium trichloroacetates, (1) and (2) have prompted a comprehensive investigation of the experimental conditions giving rise to the formation of the two ferricenium salts. In agreement with the majority of authors, (2) is reproducibly obtained from trichloroacetic acid and ferrocene in molar ratios of 3 and higher in benzene over a wide range of experimental variables in the presence of air or, preferably, under conditions of oxygen saturation. Treatment of aqueous ferricenium sulfate solutions with trichloroacetic acid in an acid/ferrocene ratio of 3 and above affords the di-solvate, whereas at lower reactant ratios, and under conditions of reduced acidity, formation of the mono-solvate prevails. More efficiently, and in a higher degree of purity, the latter salt is generated from the former by a controlled recrystallization from water. Representative spectroscopic features of the two salts are discussed. © Verlag Chemie GmbH 1984 |
| abstract_unstemmed |
Summary Inconsistent literature reports on the preparation of the mono- and bis-(trichloroacetic acid)-solvated ferricenium trichloroacetates, (1) and (2) have prompted a comprehensive investigation of the experimental conditions giving rise to the formation of the two ferricenium salts. In agreement with the majority of authors, (2) is reproducibly obtained from trichloroacetic acid and ferrocene in molar ratios of 3 and higher in benzene over a wide range of experimental variables in the presence of air or, preferably, under conditions of oxygen saturation. Treatment of aqueous ferricenium sulfate solutions with trichloroacetic acid in an acid/ferrocene ratio of 3 and above affords the di-solvate, whereas at lower reactant ratios, and under conditions of reduced acidity, formation of the mono-solvate prevails. More efficiently, and in a higher degree of purity, the latter salt is generated from the former by a controlled recrystallization from water. Representative spectroscopic features of the two salts are discussed. © Verlag Chemie GmbH 1984 |
| collection_details |
GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_22 GBV_ILN_40 GBV_ILN_70 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_4012 GBV_ILN_4028 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4103 GBV_ILN_4125 GBV_ILN_4305 GBV_ILN_4306 |
| container_issue |
1 |
| title_short |
The mono- and bis-(trichloroacetic acid)-solvates of ferricenium trichloroacetate |
| url |
https://doi.org/10.1007/BF00620720 |
| remote_bool |
false |
| author2 |
Loonat, Rokaya Boeyens, Jan C. A. |
| author2Str |
Loonat, Rokaya Boeyens, Jan C. A. |
| ppnlink |
129605417 |
| mediatype_str_mv |
n |
| isOA_txt |
false |
| hochschulschrift_bool |
false |
| doi_str |
10.1007/BF00620720 |
| up_date |
2024-07-04T01:10:22.246Z |
| _version_ |
1803608834439118848 |
| fullrecord_marcxml |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC2083997425</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230504062936.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">230301s1984 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/BF00620720</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2083997425</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)BF00620720-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Neuse, Eberhard W.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">The mono- and bis-(trichloroacetic acid)-solvates of ferricenium trichloroacetate</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">1984</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Verlag Chemie GmbH 1984</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Summary Inconsistent literature reports on the preparation of the mono- and bis-(trichloroacetic acid)-solvated ferricenium trichloroacetates, (1) and (2) have prompted a comprehensive investigation of the experimental conditions giving rise to the formation of the two ferricenium salts. In agreement with the majority of authors, (2) is reproducibly obtained from trichloroacetic acid and ferrocene in molar ratios of 3 and higher in benzene over a wide range of experimental variables in the presence of air or, preferably, under conditions of oxygen saturation. Treatment of aqueous ferricenium sulfate solutions with trichloroacetic acid in an acid/ferrocene ratio of 3 and above affords the di-solvate, whereas at lower reactant ratios, and under conditions of reduced acidity, formation of the mono-solvate prevails. More efficiently, and in a higher degree of purity, the latter salt is generated from the former by a controlled recrystallization from water. Representative spectroscopic features of the two salts are discussed.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Oxygen</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Sulfate</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Physical Chemistry</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Benzene</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Inorganic Chemistry</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Loonat, Rokaya</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Boeyens, Jan C. A.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Transition metal chemistry</subfield><subfield code="d">Kluwer Academic Publishers, 1975</subfield><subfield code="g">9(1984), 1 vom: Jan., Seite 12-17</subfield><subfield code="w">(DE-627)129605417</subfield><subfield code="w">(DE-600)242084-3</subfield><subfield code="w">(DE-576)015099652</subfield><subfield code="x">0340-4285</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:9</subfield><subfield code="g">year:1984</subfield><subfield code="g">number:1</subfield><subfield code="g">month:01</subfield><subfield code="g">pages:12-17</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/BF00620720</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2018</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4012</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4028</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4046</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4082</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4103</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">9</subfield><subfield code="j">1984</subfield><subfield code="e">1</subfield><subfield code="c">01</subfield><subfield code="h">12-17</subfield></datafield></record></collection>
|
| score |
7.3998413 |