Trans-bis(dicyanamido)nickel(II) complexes with polyaza macrocyclic ligands
Abstract Two new trans-bis(dicyanamido)nickel(II) macrocyclic complexes, [Ni(II)(L1){N(CN)2}2] · $ H_{2} $O (1) and [Ni(II)-(L3){N(CN)2}2] (2), where L1 is 3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexaazacyclotetradecane and L3 is 3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,$ 0^{1.18} $,$ 0^{7.12} $...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Cho, Jaeheung [verfasserIn] |
|---|
| Format: |
Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2002 |
|---|
| Schlagwörter: |
|---|
| Anmerkung: |
© Kluwer Academic Publishers 2002 |
|---|
| Übergeordnetes Werk: |
Enthalten in: Transition metal chemistry - Kluwer Academic Publishers, 1975, 27(2002), 4 vom: Mai, Seite 429-432 |
|---|---|
| Übergeordnetes Werk: |
volume:27 ; year:2002 ; number:4 ; month:05 ; pages:429-432 |
| Links: |
|---|
| DOI / URN: |
10.1023/A:1015028601350 |
|---|
| Katalog-ID: |
OLC2084023386 |
|---|
| LEADER | 01000caa a22002652 4500 | ||
|---|---|---|---|
| 001 | OLC2084023386 | ||
| 003 | DE-627 | ||
| 005 | 20230504063117.0 | ||
| 007 | tu | ||
| 008 | 230301s2002 xx ||||| 00| ||eng c | ||
| 024 | 7 | |a 10.1023/A:1015028601350 |2 doi | |
| 035 | |a (DE-627)OLC2084023386 | ||
| 035 | |a (DE-He213)A:1015028601350-p | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 082 | 0 | 4 | |a 660 |q VZ |
| 100 | 1 | |a Cho, Jaeheung |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Trans-bis(dicyanamido)nickel(II) complexes with polyaza macrocyclic ligands |
| 264 | 1 | |c 2002 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a ohne Hilfsmittel zu benutzen |b n |2 rdamedia | ||
| 338 | |a Band |b nc |2 rdacarrier | ||
| 500 | |a © Kluwer Academic Publishers 2002 | ||
| 520 | |a Abstract Two new trans-bis(dicyanamido)nickel(II) macrocyclic complexes, [Ni(II)(L1){N(CN)2}2] · $ H_{2} $O (1) and [Ni(II)-(L3){N(CN)2}2] (2), where L1 is 3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexaazacyclotetradecane and L3 is 3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,$ 0^{1.18} $,$ 0^{7.12} $]docosane, have been synthesized and structurally characterized by spectroscopic and X-ray crystallographic methods. In (1) and (2), each central nickel(II) ion possesses a distorted octahedral geometry with four equatorial nitrogen atoms from the macrocycle and two axial nitrogen atoms from dicyanamide anions, which are terminally bonded to the central nickel atom. The solid state electronic spectra of (1) and (2) using the diffuse reflectance method show a characteristic high-spin $ d^{8} $ nickel(II) ion in a distorted octahedral environment. | ||
| 650 | 4 | |a Macrocycle | |
| 650 | 4 | |a Macrocyclic Ligand | |
| 650 | 4 | |a Distorted Octahedral Geometry | |
| 650 | 4 | |a Macrocyclic Complex | |
| 650 | 4 | |a Dicyanamide | |
| 700 | 1 | |a Lee, Uk |4 aut | |
| 700 | 1 | |a Kim, Ju Chang |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Transition metal chemistry |d Kluwer Academic Publishers, 1975 |g 27(2002), 4 vom: Mai, Seite 429-432 |w (DE-627)129605417 |w (DE-600)242084-3 |w (DE-576)015099652 |x 0340-4285 |7 nnns |
| 773 | 1 | 8 | |g volume:27 |g year:2002 |g number:4 |g month:05 |g pages:429-432 |
| 856 | 4 | 1 | |u https://doi.org/10.1023/A:1015028601350 |z lizenzpflichtig |3 Volltext |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a SYSFLAG_A | ||
| 912 | |a GBV_OLC | ||
| 912 | |a SSG-OLC-TEC | ||
| 912 | |a SSG-OLC-CHE | ||
| 912 | |a GBV_ILN_21 | ||
| 912 | |a GBV_ILN_70 | ||
| 912 | |a GBV_ILN_4012 | ||
| 912 | |a GBV_ILN_4125 | ||
| 951 | |a AR | ||
| 952 | |d 27 |j 2002 |e 4 |c 05 |h 429-432 | ||
| author_variant |
j c jc u l ul j c k jc jck |
|---|---|
| matchkey_str |
article:03404285:2002----::rnbsiynmdnceicmlxsihoyzm |
| hierarchy_sort_str |
2002 |
| publishDate |
2002 |
| allfields |
10.1023/A:1015028601350 doi (DE-627)OLC2084023386 (DE-He213)A:1015028601350-p DE-627 ger DE-627 rakwb eng 660 VZ Cho, Jaeheung verfasserin aut Trans-bis(dicyanamido)nickel(II) complexes with polyaza macrocyclic ligands 2002 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Kluwer Academic Publishers 2002 Abstract Two new trans-bis(dicyanamido)nickel(II) macrocyclic complexes, [Ni(II)(L1){N(CN)2}2] · $ H_{2} $O (1) and [Ni(II)-(L3){N(CN)2}2] (2), where L1 is 3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexaazacyclotetradecane and L3 is 3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,$ 0^{1.18} $,$ 0^{7.12} $]docosane, have been synthesized and structurally characterized by spectroscopic and X-ray crystallographic methods. In (1) and (2), each central nickel(II) ion possesses a distorted octahedral geometry with four equatorial nitrogen atoms from the macrocycle and two axial nitrogen atoms from dicyanamide anions, which are terminally bonded to the central nickel atom. The solid state electronic spectra of (1) and (2) using the diffuse reflectance method show a characteristic high-spin $ d^{8} $ nickel(II) ion in a distorted octahedral environment. Macrocycle Macrocyclic Ligand Distorted Octahedral Geometry Macrocyclic Complex Dicyanamide Lee, Uk aut Kim, Ju Chang aut Enthalten in Transition metal chemistry Kluwer Academic Publishers, 1975 27(2002), 4 vom: Mai, Seite 429-432 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:27 year:2002 number:4 month:05 pages:429-432 https://doi.org/10.1023/A:1015028601350 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 27 2002 4 05 429-432 |
| spelling |
10.1023/A:1015028601350 doi (DE-627)OLC2084023386 (DE-He213)A:1015028601350-p DE-627 ger DE-627 rakwb eng 660 VZ Cho, Jaeheung verfasserin aut Trans-bis(dicyanamido)nickel(II) complexes with polyaza macrocyclic ligands 2002 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Kluwer Academic Publishers 2002 Abstract Two new trans-bis(dicyanamido)nickel(II) macrocyclic complexes, [Ni(II)(L1){N(CN)2}2] · $ H_{2} $O (1) and [Ni(II)-(L3){N(CN)2}2] (2), where L1 is 3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexaazacyclotetradecane and L3 is 3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,$ 0^{1.18} $,$ 0^{7.12} $]docosane, have been synthesized and structurally characterized by spectroscopic and X-ray crystallographic methods. In (1) and (2), each central nickel(II) ion possesses a distorted octahedral geometry with four equatorial nitrogen atoms from the macrocycle and two axial nitrogen atoms from dicyanamide anions, which are terminally bonded to the central nickel atom. The solid state electronic spectra of (1) and (2) using the diffuse reflectance method show a characteristic high-spin $ d^{8} $ nickel(II) ion in a distorted octahedral environment. Macrocycle Macrocyclic Ligand Distorted Octahedral Geometry Macrocyclic Complex Dicyanamide Lee, Uk aut Kim, Ju Chang aut Enthalten in Transition metal chemistry Kluwer Academic Publishers, 1975 27(2002), 4 vom: Mai, Seite 429-432 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:27 year:2002 number:4 month:05 pages:429-432 https://doi.org/10.1023/A:1015028601350 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 27 2002 4 05 429-432 |
| allfields_unstemmed |
10.1023/A:1015028601350 doi (DE-627)OLC2084023386 (DE-He213)A:1015028601350-p DE-627 ger DE-627 rakwb eng 660 VZ Cho, Jaeheung verfasserin aut Trans-bis(dicyanamido)nickel(II) complexes with polyaza macrocyclic ligands 2002 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Kluwer Academic Publishers 2002 Abstract Two new trans-bis(dicyanamido)nickel(II) macrocyclic complexes, [Ni(II)(L1){N(CN)2}2] · $ H_{2} $O (1) and [Ni(II)-(L3){N(CN)2}2] (2), where L1 is 3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexaazacyclotetradecane and L3 is 3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,$ 0^{1.18} $,$ 0^{7.12} $]docosane, have been synthesized and structurally characterized by spectroscopic and X-ray crystallographic methods. In (1) and (2), each central nickel(II) ion possesses a distorted octahedral geometry with four equatorial nitrogen atoms from the macrocycle and two axial nitrogen atoms from dicyanamide anions, which are terminally bonded to the central nickel atom. The solid state electronic spectra of (1) and (2) using the diffuse reflectance method show a characteristic high-spin $ d^{8} $ nickel(II) ion in a distorted octahedral environment. Macrocycle Macrocyclic Ligand Distorted Octahedral Geometry Macrocyclic Complex Dicyanamide Lee, Uk aut Kim, Ju Chang aut Enthalten in Transition metal chemistry Kluwer Academic Publishers, 1975 27(2002), 4 vom: Mai, Seite 429-432 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:27 year:2002 number:4 month:05 pages:429-432 https://doi.org/10.1023/A:1015028601350 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 27 2002 4 05 429-432 |
| allfieldsGer |
10.1023/A:1015028601350 doi (DE-627)OLC2084023386 (DE-He213)A:1015028601350-p DE-627 ger DE-627 rakwb eng 660 VZ Cho, Jaeheung verfasserin aut Trans-bis(dicyanamido)nickel(II) complexes with polyaza macrocyclic ligands 2002 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Kluwer Academic Publishers 2002 Abstract Two new trans-bis(dicyanamido)nickel(II) macrocyclic complexes, [Ni(II)(L1){N(CN)2}2] · $ H_{2} $O (1) and [Ni(II)-(L3){N(CN)2}2] (2), where L1 is 3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexaazacyclotetradecane and L3 is 3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,$ 0^{1.18} $,$ 0^{7.12} $]docosane, have been synthesized and structurally characterized by spectroscopic and X-ray crystallographic methods. In (1) and (2), each central nickel(II) ion possesses a distorted octahedral geometry with four equatorial nitrogen atoms from the macrocycle and two axial nitrogen atoms from dicyanamide anions, which are terminally bonded to the central nickel atom. The solid state electronic spectra of (1) and (2) using the diffuse reflectance method show a characteristic high-spin $ d^{8} $ nickel(II) ion in a distorted octahedral environment. Macrocycle Macrocyclic Ligand Distorted Octahedral Geometry Macrocyclic Complex Dicyanamide Lee, Uk aut Kim, Ju Chang aut Enthalten in Transition metal chemistry Kluwer Academic Publishers, 1975 27(2002), 4 vom: Mai, Seite 429-432 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:27 year:2002 number:4 month:05 pages:429-432 https://doi.org/10.1023/A:1015028601350 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 27 2002 4 05 429-432 |
| allfieldsSound |
10.1023/A:1015028601350 doi (DE-627)OLC2084023386 (DE-He213)A:1015028601350-p DE-627 ger DE-627 rakwb eng 660 VZ Cho, Jaeheung verfasserin aut Trans-bis(dicyanamido)nickel(II) complexes with polyaza macrocyclic ligands 2002 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Kluwer Academic Publishers 2002 Abstract Two new trans-bis(dicyanamido)nickel(II) macrocyclic complexes, [Ni(II)(L1){N(CN)2}2] · $ H_{2} $O (1) and [Ni(II)-(L3){N(CN)2}2] (2), where L1 is 3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexaazacyclotetradecane and L3 is 3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,$ 0^{1.18} $,$ 0^{7.12} $]docosane, have been synthesized and structurally characterized by spectroscopic and X-ray crystallographic methods. In (1) and (2), each central nickel(II) ion possesses a distorted octahedral geometry with four equatorial nitrogen atoms from the macrocycle and two axial nitrogen atoms from dicyanamide anions, which are terminally bonded to the central nickel atom. The solid state electronic spectra of (1) and (2) using the diffuse reflectance method show a characteristic high-spin $ d^{8} $ nickel(II) ion in a distorted octahedral environment. Macrocycle Macrocyclic Ligand Distorted Octahedral Geometry Macrocyclic Complex Dicyanamide Lee, Uk aut Kim, Ju Chang aut Enthalten in Transition metal chemistry Kluwer Academic Publishers, 1975 27(2002), 4 vom: Mai, Seite 429-432 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:27 year:2002 number:4 month:05 pages:429-432 https://doi.org/10.1023/A:1015028601350 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 27 2002 4 05 429-432 |
| language |
English |
| source |
Enthalten in Transition metal chemistry 27(2002), 4 vom: Mai, Seite 429-432 volume:27 year:2002 number:4 month:05 pages:429-432 |
| sourceStr |
Enthalten in Transition metal chemistry 27(2002), 4 vom: Mai, Seite 429-432 volume:27 year:2002 number:4 month:05 pages:429-432 |
| format_phy_str_mv |
Article |
| institution |
findex.gbv.de |
| topic_facet |
Macrocycle Macrocyclic Ligand Distorted Octahedral Geometry Macrocyclic Complex Dicyanamide |
| dewey-raw |
660 |
| isfreeaccess_bool |
false |
| container_title |
Transition metal chemistry |
| authorswithroles_txt_mv |
Cho, Jaeheung @@aut@@ Lee, Uk @@aut@@ Kim, Ju Chang @@aut@@ |
| publishDateDaySort_date |
2002-05-01T00:00:00Z |
| hierarchy_top_id |
129605417 |
| dewey-sort |
3660 |
| id |
OLC2084023386 |
| language_de |
englisch |
| fullrecord |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC2084023386</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230504063117.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">230301s2002 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1023/A:1015028601350</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2084023386</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)A:1015028601350-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Cho, Jaeheung</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Trans-bis(dicyanamido)nickel(II) complexes with polyaza macrocyclic ligands</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2002</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Kluwer Academic Publishers 2002</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Two new trans-bis(dicyanamido)nickel(II) macrocyclic complexes, [Ni(II)(L1){N(CN)2}2] · $ H_{2} $O (1) and [Ni(II)-(L3){N(CN)2}2] (2), where L1 is 3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexaazacyclotetradecane and L3 is 3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,$ 0^{1.18} $,$ 0^{7.12} $]docosane, have been synthesized and structurally characterized by spectroscopic and X-ray crystallographic methods. In (1) and (2), each central nickel(II) ion possesses a distorted octahedral geometry with four equatorial nitrogen atoms from the macrocycle and two axial nitrogen atoms from dicyanamide anions, which are terminally bonded to the central nickel atom. The solid state electronic spectra of (1) and (2) using the diffuse reflectance method show a characteristic high-spin $ d^{8} $ nickel(II) ion in a distorted octahedral environment.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Macrocycle</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Macrocyclic Ligand</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Distorted Octahedral Geometry</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Macrocyclic Complex</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Dicyanamide</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Lee, Uk</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Kim, Ju Chang</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Transition metal chemistry</subfield><subfield code="d">Kluwer Academic Publishers, 1975</subfield><subfield code="g">27(2002), 4 vom: Mai, Seite 429-432</subfield><subfield code="w">(DE-627)129605417</subfield><subfield code="w">(DE-600)242084-3</subfield><subfield code="w">(DE-576)015099652</subfield><subfield code="x">0340-4285</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:27</subfield><subfield code="g">year:2002</subfield><subfield code="g">number:4</subfield><subfield code="g">month:05</subfield><subfield code="g">pages:429-432</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1023/A:1015028601350</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_21</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4012</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">27</subfield><subfield code="j">2002</subfield><subfield code="e">4</subfield><subfield code="c">05</subfield><subfield code="h">429-432</subfield></datafield></record></collection>
|
| author |
Cho, Jaeheung |
| spellingShingle |
Cho, Jaeheung ddc 660 misc Macrocycle misc Macrocyclic Ligand misc Distorted Octahedral Geometry misc Macrocyclic Complex misc Dicyanamide Trans-bis(dicyanamido)nickel(II) complexes with polyaza macrocyclic ligands |
| authorStr |
Cho, Jaeheung |
| ppnlink_with_tag_str_mv |
@@773@@(DE-627)129605417 |
| format |
Article |
| dewey-ones |
660 - Chemical engineering |
| delete_txt_mv |
keep |
| author_role |
aut aut aut |
| collection |
OLC |
| remote_str |
false |
| illustrated |
Not Illustrated |
| issn |
0340-4285 |
| topic_title |
660 VZ Trans-bis(dicyanamido)nickel(II) complexes with polyaza macrocyclic ligands Macrocycle Macrocyclic Ligand Distorted Octahedral Geometry Macrocyclic Complex Dicyanamide |
| topic |
ddc 660 misc Macrocycle misc Macrocyclic Ligand misc Distorted Octahedral Geometry misc Macrocyclic Complex misc Dicyanamide |
| topic_unstemmed |
ddc 660 misc Macrocycle misc Macrocyclic Ligand misc Distorted Octahedral Geometry misc Macrocyclic Complex misc Dicyanamide |
| topic_browse |
ddc 660 misc Macrocycle misc Macrocyclic Ligand misc Distorted Octahedral Geometry misc Macrocyclic Complex misc Dicyanamide |
| format_facet |
Aufsätze Gedruckte Aufsätze |
| format_main_str_mv |
Text Zeitschrift/Artikel |
| carriertype_str_mv |
nc |
| hierarchy_parent_title |
Transition metal chemistry |
| hierarchy_parent_id |
129605417 |
| dewey-tens |
660 - Chemical engineering |
| hierarchy_top_title |
Transition metal chemistry |
| isfreeaccess_txt |
false |
| familylinks_str_mv |
(DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 |
| title |
Trans-bis(dicyanamido)nickel(II) complexes with polyaza macrocyclic ligands |
| ctrlnum |
(DE-627)OLC2084023386 (DE-He213)A:1015028601350-p |
| title_full |
Trans-bis(dicyanamido)nickel(II) complexes with polyaza macrocyclic ligands |
| author_sort |
Cho, Jaeheung |
| journal |
Transition metal chemistry |
| journalStr |
Transition metal chemistry |
| lang_code |
eng |
| isOA_bool |
false |
| dewey-hundreds |
600 - Technology |
| recordtype |
marc |
| publishDateSort |
2002 |
| contenttype_str_mv |
txt |
| container_start_page |
429 |
| author_browse |
Cho, Jaeheung Lee, Uk Kim, Ju Chang |
| container_volume |
27 |
| class |
660 VZ |
| format_se |
Aufsätze |
| author-letter |
Cho, Jaeheung |
| doi_str_mv |
10.1023/A:1015028601350 |
| dewey-full |
660 |
| title_sort |
trans-bis(dicyanamido)nickel(ii) complexes with polyaza macrocyclic ligands |
| title_auth |
Trans-bis(dicyanamido)nickel(II) complexes with polyaza macrocyclic ligands |
| abstract |
Abstract Two new trans-bis(dicyanamido)nickel(II) macrocyclic complexes, [Ni(II)(L1){N(CN)2}2] · $ H_{2} $O (1) and [Ni(II)-(L3){N(CN)2}2] (2), where L1 is 3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexaazacyclotetradecane and L3 is 3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,$ 0^{1.18} $,$ 0^{7.12} $]docosane, have been synthesized and structurally characterized by spectroscopic and X-ray crystallographic methods. In (1) and (2), each central nickel(II) ion possesses a distorted octahedral geometry with four equatorial nitrogen atoms from the macrocycle and two axial nitrogen atoms from dicyanamide anions, which are terminally bonded to the central nickel atom. The solid state electronic spectra of (1) and (2) using the diffuse reflectance method show a characteristic high-spin $ d^{8} $ nickel(II) ion in a distorted octahedral environment. © Kluwer Academic Publishers 2002 |
| abstractGer |
Abstract Two new trans-bis(dicyanamido)nickel(II) macrocyclic complexes, [Ni(II)(L1){N(CN)2}2] · $ H_{2} $O (1) and [Ni(II)-(L3){N(CN)2}2] (2), where L1 is 3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexaazacyclotetradecane and L3 is 3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,$ 0^{1.18} $,$ 0^{7.12} $]docosane, have been synthesized and structurally characterized by spectroscopic and X-ray crystallographic methods. In (1) and (2), each central nickel(II) ion possesses a distorted octahedral geometry with four equatorial nitrogen atoms from the macrocycle and two axial nitrogen atoms from dicyanamide anions, which are terminally bonded to the central nickel atom. The solid state electronic spectra of (1) and (2) using the diffuse reflectance method show a characteristic high-spin $ d^{8} $ nickel(II) ion in a distorted octahedral environment. © Kluwer Academic Publishers 2002 |
| abstract_unstemmed |
Abstract Two new trans-bis(dicyanamido)nickel(II) macrocyclic complexes, [Ni(II)(L1){N(CN)2}2] · $ H_{2} $O (1) and [Ni(II)-(L3){N(CN)2}2] (2), where L1 is 3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexaazacyclotetradecane and L3 is 3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,$ 0^{1.18} $,$ 0^{7.12} $]docosane, have been synthesized and structurally characterized by spectroscopic and X-ray crystallographic methods. In (1) and (2), each central nickel(II) ion possesses a distorted octahedral geometry with four equatorial nitrogen atoms from the macrocycle and two axial nitrogen atoms from dicyanamide anions, which are terminally bonded to the central nickel atom. The solid state electronic spectra of (1) and (2) using the diffuse reflectance method show a characteristic high-spin $ d^{8} $ nickel(II) ion in a distorted octahedral environment. © Kluwer Academic Publishers 2002 |
| collection_details |
GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 |
| container_issue |
4 |
| title_short |
Trans-bis(dicyanamido)nickel(II) complexes with polyaza macrocyclic ligands |
| url |
https://doi.org/10.1023/A:1015028601350 |
| remote_bool |
false |
| author2 |
Lee, Uk Kim, Ju Chang |
| author2Str |
Lee, Uk Kim, Ju Chang |
| ppnlink |
129605417 |
| mediatype_str_mv |
n |
| isOA_txt |
false |
| hochschulschrift_bool |
false |
| doi_str |
10.1023/A:1015028601350 |
| up_date |
2024-07-04T01:14:31.561Z |
| _version_ |
1803609095879524352 |
| fullrecord_marcxml |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC2084023386</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230504063117.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">230301s2002 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1023/A:1015028601350</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2084023386</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)A:1015028601350-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Cho, Jaeheung</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Trans-bis(dicyanamido)nickel(II) complexes with polyaza macrocyclic ligands</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2002</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Kluwer Academic Publishers 2002</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Two new trans-bis(dicyanamido)nickel(II) macrocyclic complexes, [Ni(II)(L1){N(CN)2}2] · $ H_{2} $O (1) and [Ni(II)-(L3){N(CN)2}2] (2), where L1 is 3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexaazacyclotetradecane and L3 is 3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,$ 0^{1.18} $,$ 0^{7.12} $]docosane, have been synthesized and structurally characterized by spectroscopic and X-ray crystallographic methods. In (1) and (2), each central nickel(II) ion possesses a distorted octahedral geometry with four equatorial nitrogen atoms from the macrocycle and two axial nitrogen atoms from dicyanamide anions, which are terminally bonded to the central nickel atom. The solid state electronic spectra of (1) and (2) using the diffuse reflectance method show a characteristic high-spin $ d^{8} $ nickel(II) ion in a distorted octahedral environment.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Macrocycle</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Macrocyclic Ligand</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Distorted Octahedral Geometry</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Macrocyclic Complex</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Dicyanamide</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Lee, Uk</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Kim, Ju Chang</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Transition metal chemistry</subfield><subfield code="d">Kluwer Academic Publishers, 1975</subfield><subfield code="g">27(2002), 4 vom: Mai, Seite 429-432</subfield><subfield code="w">(DE-627)129605417</subfield><subfield code="w">(DE-600)242084-3</subfield><subfield code="w">(DE-576)015099652</subfield><subfield code="x">0340-4285</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:27</subfield><subfield code="g">year:2002</subfield><subfield code="g">number:4</subfield><subfield code="g">month:05</subfield><subfield code="g">pages:429-432</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1023/A:1015028601350</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_21</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4012</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">27</subfield><subfield code="j">2002</subfield><subfield code="e">4</subfield><subfield code="c">05</subfield><subfield code="h">429-432</subfield></datafield></record></collection>
|
| score |
7.3983355 |