Synthesis, characterization, structure and magnetic properties of azido-bridged nickel(II) and copper(II) complexes with a pyridylpyrazole-based ligand
Abstract A new pyridylpyrazole-containing tetradentate ligand, namely N,N-bis(3,5-dimethylpyrazol-1-ylmethyl)aminomethylpyridine (L), and two of its binuclear azido-bridged complexes, [$ Ni_{2} $(L)2($ N_{3} $)2]($ ClO_{4} $)2·2EtOH (1) and [$ Cu_{2} $(L)2($ N_{3} $)2]($ ClO_{4} $)2 (2), have been s...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Mahendrasinh, Zala [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2010 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer Science+Business Media B.V. 2010 |
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| Übergeordnetes Werk: |
Enthalten in: Transition metal chemistry - Springer Netherlands, 1975, 35(2010), 6 vom: 14. Juli, Seite 757-763 |
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| Übergeordnetes Werk: |
volume:35 ; year:2010 ; number:6 ; day:14 ; month:07 ; pages:757-763 |
| Links: |
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| DOI / URN: |
10.1007/s11243-010-9390-x |
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OLC2084042054 |
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| 520 | |a Abstract A new pyridylpyrazole-containing tetradentate ligand, namely N,N-bis(3,5-dimethylpyrazol-1-ylmethyl)aminomethylpyridine (L), and two of its binuclear azido-bridged complexes, [$ Ni_{2} $(L)2($ N_{3} $)2]($ ClO_{4} $)2·2EtOH (1) and [$ Cu_{2} $(L)2($ N_{3} $)2]($ ClO_{4} $)2 (2), have been synthesized and characterized by physico-chemical and spectroscopic methods. The crystal structures of both complexes are reported. Each metal atom in the complexes has a $ MN_{6} $ coordination environment with distorted octahedral geometry. Variable-temperature magnetic susceptibility measurements for complex (1) show typical antiferromagnetic behavior with J value −84.5 ± 1.3 $ cm^{−1} $, whereas complex (2) has no magnetic interactions. | ||
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| 700 | 1 | |a Suresh, E. |4 aut | |
| 700 | 1 | |a Ribas, Joan |4 aut | |
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10.1007/s11243-010-9390-x doi (DE-627)OLC2084042054 (DE-He213)s11243-010-9390-x-p DE-627 ger DE-627 rakwb eng 660 VZ Mahendrasinh, Zala verfasserin aut Synthesis, characterization, structure and magnetic properties of azido-bridged nickel(II) and copper(II) complexes with a pyridylpyrazole-based ligand 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media B.V. 2010 Abstract A new pyridylpyrazole-containing tetradentate ligand, namely N,N-bis(3,5-dimethylpyrazol-1-ylmethyl)aminomethylpyridine (L), and two of its binuclear azido-bridged complexes, [$ Ni_{2} $(L)2($ N_{3} $)2]($ ClO_{4} $)2·2EtOH (1) and [$ Cu_{2} $(L)2($ N_{3} $)2]($ ClO_{4} $)2 (2), have been synthesized and characterized by physico-chemical and spectroscopic methods. The crystal structures of both complexes are reported. Each metal atom in the complexes has a $ MN_{6} $ coordination environment with distorted octahedral geometry. Variable-temperature magnetic susceptibility measurements for complex (1) show typical antiferromagnetic behavior with J value −84.5 ± 1.3 $ cm^{−1} $, whereas complex (2) has no magnetic interactions. Pyrazole Azido Binuclear Complex Pyrazole Ring Dimethylpyrazole Kumar, Sujit B. aut Suresh, E. aut Ribas, Joan aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 35(2010), 6 vom: 14. Juli, Seite 757-763 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:35 year:2010 number:6 day:14 month:07 pages:757-763 https://doi.org/10.1007/s11243-010-9390-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 35 2010 6 14 07 757-763 |
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10.1007/s11243-010-9390-x doi (DE-627)OLC2084042054 (DE-He213)s11243-010-9390-x-p DE-627 ger DE-627 rakwb eng 660 VZ Mahendrasinh, Zala verfasserin aut Synthesis, characterization, structure and magnetic properties of azido-bridged nickel(II) and copper(II) complexes with a pyridylpyrazole-based ligand 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media B.V. 2010 Abstract A new pyridylpyrazole-containing tetradentate ligand, namely N,N-bis(3,5-dimethylpyrazol-1-ylmethyl)aminomethylpyridine (L), and two of its binuclear azido-bridged complexes, [$ Ni_{2} $(L)2($ N_{3} $)2]($ ClO_{4} $)2·2EtOH (1) and [$ Cu_{2} $(L)2($ N_{3} $)2]($ ClO_{4} $)2 (2), have been synthesized and characterized by physico-chemical and spectroscopic methods. The crystal structures of both complexes are reported. Each metal atom in the complexes has a $ MN_{6} $ coordination environment with distorted octahedral geometry. Variable-temperature magnetic susceptibility measurements for complex (1) show typical antiferromagnetic behavior with J value −84.5 ± 1.3 $ cm^{−1} $, whereas complex (2) has no magnetic interactions. Pyrazole Azido Binuclear Complex Pyrazole Ring Dimethylpyrazole Kumar, Sujit B. aut Suresh, E. aut Ribas, Joan aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 35(2010), 6 vom: 14. Juli, Seite 757-763 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:35 year:2010 number:6 day:14 month:07 pages:757-763 https://doi.org/10.1007/s11243-010-9390-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 35 2010 6 14 07 757-763 |
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10.1007/s11243-010-9390-x doi (DE-627)OLC2084042054 (DE-He213)s11243-010-9390-x-p DE-627 ger DE-627 rakwb eng 660 VZ Mahendrasinh, Zala verfasserin aut Synthesis, characterization, structure and magnetic properties of azido-bridged nickel(II) and copper(II) complexes with a pyridylpyrazole-based ligand 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media B.V. 2010 Abstract A new pyridylpyrazole-containing tetradentate ligand, namely N,N-bis(3,5-dimethylpyrazol-1-ylmethyl)aminomethylpyridine (L), and two of its binuclear azido-bridged complexes, [$ Ni_{2} $(L)2($ N_{3} $)2]($ ClO_{4} $)2·2EtOH (1) and [$ Cu_{2} $(L)2($ N_{3} $)2]($ ClO_{4} $)2 (2), have been synthesized and characterized by physico-chemical and spectroscopic methods. The crystal structures of both complexes are reported. Each metal atom in the complexes has a $ MN_{6} $ coordination environment with distorted octahedral geometry. Variable-temperature magnetic susceptibility measurements for complex (1) show typical antiferromagnetic behavior with J value −84.5 ± 1.3 $ cm^{−1} $, whereas complex (2) has no magnetic interactions. Pyrazole Azido Binuclear Complex Pyrazole Ring Dimethylpyrazole Kumar, Sujit B. aut Suresh, E. aut Ribas, Joan aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 35(2010), 6 vom: 14. Juli, Seite 757-763 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:35 year:2010 number:6 day:14 month:07 pages:757-763 https://doi.org/10.1007/s11243-010-9390-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 35 2010 6 14 07 757-763 |
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10.1007/s11243-010-9390-x doi (DE-627)OLC2084042054 (DE-He213)s11243-010-9390-x-p DE-627 ger DE-627 rakwb eng 660 VZ Mahendrasinh, Zala verfasserin aut Synthesis, characterization, structure and magnetic properties of azido-bridged nickel(II) and copper(II) complexes with a pyridylpyrazole-based ligand 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media B.V. 2010 Abstract A new pyridylpyrazole-containing tetradentate ligand, namely N,N-bis(3,5-dimethylpyrazol-1-ylmethyl)aminomethylpyridine (L), and two of its binuclear azido-bridged complexes, [$ Ni_{2} $(L)2($ N_{3} $)2]($ ClO_{4} $)2·2EtOH (1) and [$ Cu_{2} $(L)2($ N_{3} $)2]($ ClO_{4} $)2 (2), have been synthesized and characterized by physico-chemical and spectroscopic methods. The crystal structures of both complexes are reported. Each metal atom in the complexes has a $ MN_{6} $ coordination environment with distorted octahedral geometry. Variable-temperature magnetic susceptibility measurements for complex (1) show typical antiferromagnetic behavior with J value −84.5 ± 1.3 $ cm^{−1} $, whereas complex (2) has no magnetic interactions. Pyrazole Azido Binuclear Complex Pyrazole Ring Dimethylpyrazole Kumar, Sujit B. aut Suresh, E. aut Ribas, Joan aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 35(2010), 6 vom: 14. Juli, Seite 757-763 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:35 year:2010 number:6 day:14 month:07 pages:757-763 https://doi.org/10.1007/s11243-010-9390-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 35 2010 6 14 07 757-763 |
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10.1007/s11243-010-9390-x doi (DE-627)OLC2084042054 (DE-He213)s11243-010-9390-x-p DE-627 ger DE-627 rakwb eng 660 VZ Mahendrasinh, Zala verfasserin aut Synthesis, characterization, structure and magnetic properties of azido-bridged nickel(II) and copper(II) complexes with a pyridylpyrazole-based ligand 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media B.V. 2010 Abstract A new pyridylpyrazole-containing tetradentate ligand, namely N,N-bis(3,5-dimethylpyrazol-1-ylmethyl)aminomethylpyridine (L), and two of its binuclear azido-bridged complexes, [$ Ni_{2} $(L)2($ N_{3} $)2]($ ClO_{4} $)2·2EtOH (1) and [$ Cu_{2} $(L)2($ N_{3} $)2]($ ClO_{4} $)2 (2), have been synthesized and characterized by physico-chemical and spectroscopic methods. The crystal structures of both complexes are reported. Each metal atom in the complexes has a $ MN_{6} $ coordination environment with distorted octahedral geometry. Variable-temperature magnetic susceptibility measurements for complex (1) show typical antiferromagnetic behavior with J value −84.5 ± 1.3 $ cm^{−1} $, whereas complex (2) has no magnetic interactions. Pyrazole Azido Binuclear Complex Pyrazole Ring Dimethylpyrazole Kumar, Sujit B. aut Suresh, E. aut Ribas, Joan aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 35(2010), 6 vom: 14. Juli, Seite 757-763 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:35 year:2010 number:6 day:14 month:07 pages:757-763 https://doi.org/10.1007/s11243-010-9390-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 35 2010 6 14 07 757-763 |
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Synthesis, characterization, structure and magnetic properties of azido-bridged nickel(II) and copper(II) complexes with a pyridylpyrazole-based ligand |
| abstract |
Abstract A new pyridylpyrazole-containing tetradentate ligand, namely N,N-bis(3,5-dimethylpyrazol-1-ylmethyl)aminomethylpyridine (L), and two of its binuclear azido-bridged complexes, [$ Ni_{2} $(L)2($ N_{3} $)2]($ ClO_{4} $)2·2EtOH (1) and [$ Cu_{2} $(L)2($ N_{3} $)2]($ ClO_{4} $)2 (2), have been synthesized and characterized by physico-chemical and spectroscopic methods. The crystal structures of both complexes are reported. Each metal atom in the complexes has a $ MN_{6} $ coordination environment with distorted octahedral geometry. Variable-temperature magnetic susceptibility measurements for complex (1) show typical antiferromagnetic behavior with J value −84.5 ± 1.3 $ cm^{−1} $, whereas complex (2) has no magnetic interactions. © Springer Science+Business Media B.V. 2010 |
| abstractGer |
Abstract A new pyridylpyrazole-containing tetradentate ligand, namely N,N-bis(3,5-dimethylpyrazol-1-ylmethyl)aminomethylpyridine (L), and two of its binuclear azido-bridged complexes, [$ Ni_{2} $(L)2($ N_{3} $)2]($ ClO_{4} $)2·2EtOH (1) and [$ Cu_{2} $(L)2($ N_{3} $)2]($ ClO_{4} $)2 (2), have been synthesized and characterized by physico-chemical and spectroscopic methods. The crystal structures of both complexes are reported. Each metal atom in the complexes has a $ MN_{6} $ coordination environment with distorted octahedral geometry. Variable-temperature magnetic susceptibility measurements for complex (1) show typical antiferromagnetic behavior with J value −84.5 ± 1.3 $ cm^{−1} $, whereas complex (2) has no magnetic interactions. © Springer Science+Business Media B.V. 2010 |
| abstract_unstemmed |
Abstract A new pyridylpyrazole-containing tetradentate ligand, namely N,N-bis(3,5-dimethylpyrazol-1-ylmethyl)aminomethylpyridine (L), and two of its binuclear azido-bridged complexes, [$ Ni_{2} $(L)2($ N_{3} $)2]($ ClO_{4} $)2·2EtOH (1) and [$ Cu_{2} $(L)2($ N_{3} $)2]($ ClO_{4} $)2 (2), have been synthesized and characterized by physico-chemical and spectroscopic methods. The crystal structures of both complexes are reported. Each metal atom in the complexes has a $ MN_{6} $ coordination environment with distorted octahedral geometry. Variable-temperature magnetic susceptibility measurements for complex (1) show typical antiferromagnetic behavior with J value −84.5 ± 1.3 $ cm^{−1} $, whereas complex (2) has no magnetic interactions. © Springer Science+Business Media B.V. 2010 |
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6 |
| title_short |
Synthesis, characterization, structure and magnetic properties of azido-bridged nickel(II) and copper(II) complexes with a pyridylpyrazole-based ligand |
| url |
https://doi.org/10.1007/s11243-010-9390-x |
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| author2 |
Kumar, Sujit B. Suresh, E. Ribas, Joan |
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Kumar, Sujit B. Suresh, E. Ribas, Joan |
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| doi_str |
10.1007/s11243-010-9390-x |
| up_date |
2024-07-04T01:18:25.911Z |
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