Synthesis, characterization, and antibacterial activities of copper(I) bromide complexes of thioureas: X-ray structure of [Cu(Metu)4]Br
Abstract Copper(I) complexes of thioureas having the general formulae [$ CuL_{n} $Br] and [$ CuL_{n} $]Br [where, n = 1 − 4 and L = thiourea (Tu), N-methylthiourea (Metu), N-ethylthiourea (Ettu), N,$ N^{′} $-dipropylthiourea (Dprtu), N,$ N^{′} $-dibutylthiourea (Dbtu) or N,$ N^{′} $-diphenylthiourea...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Mufakkar, Muhammad [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2011 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer Science+Business Media B.V. 2011 |
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| Übergeordnetes Werk: |
Enthalten in: Transition metal chemistry - Springer Netherlands, 1975, 36(2011), 5 vom: 11. Mai, Seite 505-512 |
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| Übergeordnetes Werk: |
volume:36 ; year:2011 ; number:5 ; day:11 ; month:05 ; pages:505-512 |
| Links: |
|---|
| DOI / URN: |
10.1007/s11243-011-9496-9 |
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| Katalog-ID: |
OLC2084044154 |
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| 100 | 1 | |a Mufakkar, Muhammad |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Synthesis, characterization, and antibacterial activities of copper(I) bromide complexes of thioureas: X-ray structure of [Cu(Metu)4]Br |
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| 520 | |a Abstract Copper(I) complexes of thioureas having the general formulae [$ CuL_{n} $Br] and [$ CuL_{n} $]Br [where, n = 1 − 4 and L = thiourea (Tu), N-methylthiourea (Metu), N-ethylthiourea (Ettu), N,$ N^{′} $-dipropylthiourea (Dprtu), N,$ N^{′} $-dibutylthiourea (Dbtu) or N,$ N^{′} $-diphenylthiourea (Dphtu)] were prepared and characterized by elemental analysis, IR, and NMR (1H and 13C) spectroscopy. The crystal structure of one of them, [Cu(Metu)4]Br (1), was determined by X-ray crystallography. The X-ray structure of 1 describes a tetrahedral geometry around copper(I) with all Metu ligands binding through sulfur atoms. An upfield shift in the 13C NMR and downfield shift in the 1H NMR spectra are consistent with the thione coordination to copper(I). Antimicrobial activities of the complexes were evaluated by the minimum inhibitory concentration method. The results showed that only [Cu(Ettu)3Br] was effective in inhibiting the growth of all the tested organisms (gram-positive, gram-negative bacteria, and Candida sp.), while the other complexes were not effective against all the organisms. | ||
| 650 | 4 | |a Thiourea | |
| 650 | 4 | |a CuBr | |
| 650 | 4 | |a Cefixime | |
| 650 | 4 | |a Thioamides | |
| 650 | 4 | |a Bromide Complex | |
| 700 | 1 | |a Isab, Anvarhusein A. |4 aut | |
| 700 | 1 | |a Rüffer, Tobias |4 aut | |
| 700 | 1 | |a Lang, Heinrich |4 aut | |
| 700 | 1 | |a Ahmad, Saeed |4 aut | |
| 700 | 1 | |a Arshad, Najma |4 aut | |
| 700 | 1 | |a Waheed, Abdul |4 aut | |
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10.1007/s11243-011-9496-9 doi (DE-627)OLC2084044154 (DE-He213)s11243-011-9496-9-p DE-627 ger DE-627 rakwb eng 660 VZ Mufakkar, Muhammad verfasserin aut Synthesis, characterization, and antibacterial activities of copper(I) bromide complexes of thioureas: X-ray structure of [Cu(Metu)4]Br 2011 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media B.V. 2011 Abstract Copper(I) complexes of thioureas having the general formulae [$ CuL_{n} $Br] and [$ CuL_{n} $]Br [where, n = 1 − 4 and L = thiourea (Tu), N-methylthiourea (Metu), N-ethylthiourea (Ettu), N,$ N^{′} $-dipropylthiourea (Dprtu), N,$ N^{′} $-dibutylthiourea (Dbtu) or N,$ N^{′} $-diphenylthiourea (Dphtu)] were prepared and characterized by elemental analysis, IR, and NMR (1H and 13C) spectroscopy. The crystal structure of one of them, [Cu(Metu)4]Br (1), was determined by X-ray crystallography. The X-ray structure of 1 describes a tetrahedral geometry around copper(I) with all Metu ligands binding through sulfur atoms. An upfield shift in the 13C NMR and downfield shift in the 1H NMR spectra are consistent with the thione coordination to copper(I). Antimicrobial activities of the complexes were evaluated by the minimum inhibitory concentration method. The results showed that only [Cu(Ettu)3Br] was effective in inhibiting the growth of all the tested organisms (gram-positive, gram-negative bacteria, and Candida sp.), while the other complexes were not effective against all the organisms. Thiourea CuBr Cefixime Thioamides Bromide Complex Isab, Anvarhusein A. aut Rüffer, Tobias aut Lang, Heinrich aut Ahmad, Saeed aut Arshad, Najma aut Waheed, Abdul aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 36(2011), 5 vom: 11. Mai, Seite 505-512 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:36 year:2011 number:5 day:11 month:05 pages:505-512 https://doi.org/10.1007/s11243-011-9496-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 36 2011 5 11 05 505-512 |
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10.1007/s11243-011-9496-9 doi (DE-627)OLC2084044154 (DE-He213)s11243-011-9496-9-p DE-627 ger DE-627 rakwb eng 660 VZ Mufakkar, Muhammad verfasserin aut Synthesis, characterization, and antibacterial activities of copper(I) bromide complexes of thioureas: X-ray structure of [Cu(Metu)4]Br 2011 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media B.V. 2011 Abstract Copper(I) complexes of thioureas having the general formulae [$ CuL_{n} $Br] and [$ CuL_{n} $]Br [where, n = 1 − 4 and L = thiourea (Tu), N-methylthiourea (Metu), N-ethylthiourea (Ettu), N,$ N^{′} $-dipropylthiourea (Dprtu), N,$ N^{′} $-dibutylthiourea (Dbtu) or N,$ N^{′} $-diphenylthiourea (Dphtu)] were prepared and characterized by elemental analysis, IR, and NMR (1H and 13C) spectroscopy. The crystal structure of one of them, [Cu(Metu)4]Br (1), was determined by X-ray crystallography. The X-ray structure of 1 describes a tetrahedral geometry around copper(I) with all Metu ligands binding through sulfur atoms. An upfield shift in the 13C NMR and downfield shift in the 1H NMR spectra are consistent with the thione coordination to copper(I). Antimicrobial activities of the complexes were evaluated by the minimum inhibitory concentration method. The results showed that only [Cu(Ettu)3Br] was effective in inhibiting the growth of all the tested organisms (gram-positive, gram-negative bacteria, and Candida sp.), while the other complexes were not effective against all the organisms. Thiourea CuBr Cefixime Thioamides Bromide Complex Isab, Anvarhusein A. aut Rüffer, Tobias aut Lang, Heinrich aut Ahmad, Saeed aut Arshad, Najma aut Waheed, Abdul aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 36(2011), 5 vom: 11. Mai, Seite 505-512 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:36 year:2011 number:5 day:11 month:05 pages:505-512 https://doi.org/10.1007/s11243-011-9496-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 36 2011 5 11 05 505-512 |
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10.1007/s11243-011-9496-9 doi (DE-627)OLC2084044154 (DE-He213)s11243-011-9496-9-p DE-627 ger DE-627 rakwb eng 660 VZ Mufakkar, Muhammad verfasserin aut Synthesis, characterization, and antibacterial activities of copper(I) bromide complexes of thioureas: X-ray structure of [Cu(Metu)4]Br 2011 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media B.V. 2011 Abstract Copper(I) complexes of thioureas having the general formulae [$ CuL_{n} $Br] and [$ CuL_{n} $]Br [where, n = 1 − 4 and L = thiourea (Tu), N-methylthiourea (Metu), N-ethylthiourea (Ettu), N,$ N^{′} $-dipropylthiourea (Dprtu), N,$ N^{′} $-dibutylthiourea (Dbtu) or N,$ N^{′} $-diphenylthiourea (Dphtu)] were prepared and characterized by elemental analysis, IR, and NMR (1H and 13C) spectroscopy. The crystal structure of one of them, [Cu(Metu)4]Br (1), was determined by X-ray crystallography. The X-ray structure of 1 describes a tetrahedral geometry around copper(I) with all Metu ligands binding through sulfur atoms. An upfield shift in the 13C NMR and downfield shift in the 1H NMR spectra are consistent with the thione coordination to copper(I). Antimicrobial activities of the complexes were evaluated by the minimum inhibitory concentration method. The results showed that only [Cu(Ettu)3Br] was effective in inhibiting the growth of all the tested organisms (gram-positive, gram-negative bacteria, and Candida sp.), while the other complexes were not effective against all the organisms. Thiourea CuBr Cefixime Thioamides Bromide Complex Isab, Anvarhusein A. aut Rüffer, Tobias aut Lang, Heinrich aut Ahmad, Saeed aut Arshad, Najma aut Waheed, Abdul aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 36(2011), 5 vom: 11. Mai, Seite 505-512 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:36 year:2011 number:5 day:11 month:05 pages:505-512 https://doi.org/10.1007/s11243-011-9496-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 36 2011 5 11 05 505-512 |
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10.1007/s11243-011-9496-9 doi (DE-627)OLC2084044154 (DE-He213)s11243-011-9496-9-p DE-627 ger DE-627 rakwb eng 660 VZ Mufakkar, Muhammad verfasserin aut Synthesis, characterization, and antibacterial activities of copper(I) bromide complexes of thioureas: X-ray structure of [Cu(Metu)4]Br 2011 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media B.V. 2011 Abstract Copper(I) complexes of thioureas having the general formulae [$ CuL_{n} $Br] and [$ CuL_{n} $]Br [where, n = 1 − 4 and L = thiourea (Tu), N-methylthiourea (Metu), N-ethylthiourea (Ettu), N,$ N^{′} $-dipropylthiourea (Dprtu), N,$ N^{′} $-dibutylthiourea (Dbtu) or N,$ N^{′} $-diphenylthiourea (Dphtu)] were prepared and characterized by elemental analysis, IR, and NMR (1H and 13C) spectroscopy. The crystal structure of one of them, [Cu(Metu)4]Br (1), was determined by X-ray crystallography. The X-ray structure of 1 describes a tetrahedral geometry around copper(I) with all Metu ligands binding through sulfur atoms. An upfield shift in the 13C NMR and downfield shift in the 1H NMR spectra are consistent with the thione coordination to copper(I). Antimicrobial activities of the complexes were evaluated by the minimum inhibitory concentration method. The results showed that only [Cu(Ettu)3Br] was effective in inhibiting the growth of all the tested organisms (gram-positive, gram-negative bacteria, and Candida sp.), while the other complexes were not effective against all the organisms. Thiourea CuBr Cefixime Thioamides Bromide Complex Isab, Anvarhusein A. aut Rüffer, Tobias aut Lang, Heinrich aut Ahmad, Saeed aut Arshad, Najma aut Waheed, Abdul aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 36(2011), 5 vom: 11. Mai, Seite 505-512 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:36 year:2011 number:5 day:11 month:05 pages:505-512 https://doi.org/10.1007/s11243-011-9496-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 36 2011 5 11 05 505-512 |
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10.1007/s11243-011-9496-9 doi (DE-627)OLC2084044154 (DE-He213)s11243-011-9496-9-p DE-627 ger DE-627 rakwb eng 660 VZ Mufakkar, Muhammad verfasserin aut Synthesis, characterization, and antibacterial activities of copper(I) bromide complexes of thioureas: X-ray structure of [Cu(Metu)4]Br 2011 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media B.V. 2011 Abstract Copper(I) complexes of thioureas having the general formulae [$ CuL_{n} $Br] and [$ CuL_{n} $]Br [where, n = 1 − 4 and L = thiourea (Tu), N-methylthiourea (Metu), N-ethylthiourea (Ettu), N,$ N^{′} $-dipropylthiourea (Dprtu), N,$ N^{′} $-dibutylthiourea (Dbtu) or N,$ N^{′} $-diphenylthiourea (Dphtu)] were prepared and characterized by elemental analysis, IR, and NMR (1H and 13C) spectroscopy. The crystal structure of one of them, [Cu(Metu)4]Br (1), was determined by X-ray crystallography. The X-ray structure of 1 describes a tetrahedral geometry around copper(I) with all Metu ligands binding through sulfur atoms. An upfield shift in the 13C NMR and downfield shift in the 1H NMR spectra are consistent with the thione coordination to copper(I). Antimicrobial activities of the complexes were evaluated by the minimum inhibitory concentration method. The results showed that only [Cu(Ettu)3Br] was effective in inhibiting the growth of all the tested organisms (gram-positive, gram-negative bacteria, and Candida sp.), while the other complexes were not effective against all the organisms. Thiourea CuBr Cefixime Thioamides Bromide Complex Isab, Anvarhusein A. aut Rüffer, Tobias aut Lang, Heinrich aut Ahmad, Saeed aut Arshad, Najma aut Waheed, Abdul aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 36(2011), 5 vom: 11. Mai, Seite 505-512 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:36 year:2011 number:5 day:11 month:05 pages:505-512 https://doi.org/10.1007/s11243-011-9496-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 36 2011 5 11 05 505-512 |
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660 VZ Synthesis, characterization, and antibacterial activities of copper(I) bromide complexes of thioureas: X-ray structure of [Cu(Metu)4]Br Thiourea CuBr Cefixime Thioamides Bromide Complex |
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ddc 660 misc Thiourea misc CuBr misc Cefixime misc Thioamides misc Bromide Complex |
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ddc 660 misc Thiourea misc CuBr misc Cefixime misc Thioamides misc Bromide Complex |
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Synthesis, characterization, and antibacterial activities of copper(I) bromide complexes of thioureas: X-ray structure of [Cu(Metu)4]Br |
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(DE-627)OLC2084044154 (DE-He213)s11243-011-9496-9-p |
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Synthesis, characterization, and antibacterial activities of copper(I) bromide complexes of thioureas: X-ray structure of [Cu(Metu)4]Br |
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Mufakkar, Muhammad |
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Transition metal chemistry |
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Transition metal chemistry |
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eng |
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600 - Technology |
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2011 |
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Mufakkar, Muhammad Isab, Anvarhusein A. Rüffer, Tobias Lang, Heinrich Ahmad, Saeed Arshad, Najma Waheed, Abdul |
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10.1007/s11243-011-9496-9 |
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660 |
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synthesis, characterization, and antibacterial activities of copper(i) bromide complexes of thioureas: x-ray structure of [cu(metu)4]br |
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Synthesis, characterization, and antibacterial activities of copper(I) bromide complexes of thioureas: X-ray structure of [Cu(Metu)4]Br |
| abstract |
Abstract Copper(I) complexes of thioureas having the general formulae [$ CuL_{n} $Br] and [$ CuL_{n} $]Br [where, n = 1 − 4 and L = thiourea (Tu), N-methylthiourea (Metu), N-ethylthiourea (Ettu), N,$ N^{′} $-dipropylthiourea (Dprtu), N,$ N^{′} $-dibutylthiourea (Dbtu) or N,$ N^{′} $-diphenylthiourea (Dphtu)] were prepared and characterized by elemental analysis, IR, and NMR (1H and 13C) spectroscopy. The crystal structure of one of them, [Cu(Metu)4]Br (1), was determined by X-ray crystallography. The X-ray structure of 1 describes a tetrahedral geometry around copper(I) with all Metu ligands binding through sulfur atoms. An upfield shift in the 13C NMR and downfield shift in the 1H NMR spectra are consistent with the thione coordination to copper(I). Antimicrobial activities of the complexes were evaluated by the minimum inhibitory concentration method. The results showed that only [Cu(Ettu)3Br] was effective in inhibiting the growth of all the tested organisms (gram-positive, gram-negative bacteria, and Candida sp.), while the other complexes were not effective against all the organisms. © Springer Science+Business Media B.V. 2011 |
| abstractGer |
Abstract Copper(I) complexes of thioureas having the general formulae [$ CuL_{n} $Br] and [$ CuL_{n} $]Br [where, n = 1 − 4 and L = thiourea (Tu), N-methylthiourea (Metu), N-ethylthiourea (Ettu), N,$ N^{′} $-dipropylthiourea (Dprtu), N,$ N^{′} $-dibutylthiourea (Dbtu) or N,$ N^{′} $-diphenylthiourea (Dphtu)] were prepared and characterized by elemental analysis, IR, and NMR (1H and 13C) spectroscopy. The crystal structure of one of them, [Cu(Metu)4]Br (1), was determined by X-ray crystallography. The X-ray structure of 1 describes a tetrahedral geometry around copper(I) with all Metu ligands binding through sulfur atoms. An upfield shift in the 13C NMR and downfield shift in the 1H NMR spectra are consistent with the thione coordination to copper(I). Antimicrobial activities of the complexes were evaluated by the minimum inhibitory concentration method. The results showed that only [Cu(Ettu)3Br] was effective in inhibiting the growth of all the tested organisms (gram-positive, gram-negative bacteria, and Candida sp.), while the other complexes were not effective against all the organisms. © Springer Science+Business Media B.V. 2011 |
| abstract_unstemmed |
Abstract Copper(I) complexes of thioureas having the general formulae [$ CuL_{n} $Br] and [$ CuL_{n} $]Br [where, n = 1 − 4 and L = thiourea (Tu), N-methylthiourea (Metu), N-ethylthiourea (Ettu), N,$ N^{′} $-dipropylthiourea (Dprtu), N,$ N^{′} $-dibutylthiourea (Dbtu) or N,$ N^{′} $-diphenylthiourea (Dphtu)] were prepared and characterized by elemental analysis, IR, and NMR (1H and 13C) spectroscopy. The crystal structure of one of them, [Cu(Metu)4]Br (1), was determined by X-ray crystallography. The X-ray structure of 1 describes a tetrahedral geometry around copper(I) with all Metu ligands binding through sulfur atoms. An upfield shift in the 13C NMR and downfield shift in the 1H NMR spectra are consistent with the thione coordination to copper(I). Antimicrobial activities of the complexes were evaluated by the minimum inhibitory concentration method. The results showed that only [Cu(Ettu)3Br] was effective in inhibiting the growth of all the tested organisms (gram-positive, gram-negative bacteria, and Candida sp.), while the other complexes were not effective against all the organisms. © Springer Science+Business Media B.V. 2011 |
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Synthesis, characterization, and antibacterial activities of copper(I) bromide complexes of thioureas: X-ray structure of [Cu(Metu)4]Br |
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Isab, Anvarhusein A. Rüffer, Tobias Lang, Heinrich Ahmad, Saeed Arshad, Najma Waheed, Abdul |
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