Preparation and crystal structure of a triple parallel interpenetrated copper coordination polymer based on a flexible bis(imidazole) ligand
Abstract A Cu(II) coordination polymer, [Cu(L)(bdc)]n (L = 1,4-bis(imidazole)butane, bdc = 1,3-benzenedicarboxylate) has been hydrothermally synthesized and characterized by elemental analysis, IR spectrum, thermogravimetric analysis, and single-crystal X-ray diffraction. The complex is a rare examp...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Qin, Li [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2013 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer Science+Business Media Dordrecht 2013 |
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| Übergeordnetes Werk: |
Enthalten in: Transition metal chemistry - Springer Netherlands, 1975, 38(2013), 4 vom: 02. März, Seite 407-412 |
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| Übergeordnetes Werk: |
volume:38 ; year:2013 ; number:4 ; day:02 ; month:03 ; pages:407-412 |
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| DOI / URN: |
10.1007/s11243-013-9705-9 |
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| 520 | |a Abstract A Cu(II) coordination polymer, [Cu(L)(bdc)]n (L = 1,4-bis(imidazole)butane, bdc = 1,3-benzenedicarboxylate) has been hydrothermally synthesized and characterized by elemental analysis, IR spectrum, thermogravimetric analysis, and single-crystal X-ray diffraction. The complex is a rare example of a threefold parallel interpenetrated coordination bonding network based on undulant [$ Cu_{4} $(μ2-L)2(μ2-bdc)2] parallelograms with $ 4^{4} $-sql layer. The heterogeneous catalytic activity of the complex was tested for the degradation of Congo red azo dye in a Fenton-like process in which the degradation efficiency reached 94 % after 100 min. Kinetic analysis indicates that the degradation rate of the dye can be approximated by pseudo-first-order kinetics. | ||
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| 650 | 4 | |a Copper Coordination Polymer | |
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| 700 | 1 | |a Li, Guang Yue |4 aut | |
| 700 | 1 | |a Xiao, Shu Lin |4 aut | |
| 700 | 1 | |a Cui, Guang Hua |4 aut | |
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10.1007/s11243-013-9705-9 doi (DE-627)OLC2084048133 (DE-He213)s11243-013-9705-9-p DE-627 ger DE-627 rakwb eng 660 VZ Qin, Li verfasserin aut Preparation and crystal structure of a triple parallel interpenetrated copper coordination polymer based on a flexible bis(imidazole) ligand 2013 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media Dordrecht 2013 Abstract A Cu(II) coordination polymer, [Cu(L)(bdc)]n (L = 1,4-bis(imidazole)butane, bdc = 1,3-benzenedicarboxylate) has been hydrothermally synthesized and characterized by elemental analysis, IR spectrum, thermogravimetric analysis, and single-crystal X-ray diffraction. The complex is a rare example of a threefold parallel interpenetrated coordination bonding network based on undulant [$ Cu_{4} $(μ2-L)2(μ2-bdc)2] parallelograms with $ 4^{4} $-sql layer. The heterogeneous catalytic activity of the complex was tested for the degradation of Congo red azo dye in a Fenton-like process in which the degradation efficiency reached 94 % after 100 min. Kinetic analysis indicates that the degradation rate of the dye can be approximated by pseudo-first-order kinetics. Coordination Polymer Degradation Efficiency Catalytic Degradation Monodentate Carboxylate Group Copper Coordination Polymer Gu, Yu aut Li, Guang Yue aut Xiao, Shu Lin aut Cui, Guang Hua aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 38(2013), 4 vom: 02. März, Seite 407-412 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:38 year:2013 number:4 day:02 month:03 pages:407-412 https://doi.org/10.1007/s11243-013-9705-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 38 2013 4 02 03 407-412 |
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10.1007/s11243-013-9705-9 doi (DE-627)OLC2084048133 (DE-He213)s11243-013-9705-9-p DE-627 ger DE-627 rakwb eng 660 VZ Qin, Li verfasserin aut Preparation and crystal structure of a triple parallel interpenetrated copper coordination polymer based on a flexible bis(imidazole) ligand 2013 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media Dordrecht 2013 Abstract A Cu(II) coordination polymer, [Cu(L)(bdc)]n (L = 1,4-bis(imidazole)butane, bdc = 1,3-benzenedicarboxylate) has been hydrothermally synthesized and characterized by elemental analysis, IR spectrum, thermogravimetric analysis, and single-crystal X-ray diffraction. The complex is a rare example of a threefold parallel interpenetrated coordination bonding network based on undulant [$ Cu_{4} $(μ2-L)2(μ2-bdc)2] parallelograms with $ 4^{4} $-sql layer. The heterogeneous catalytic activity of the complex was tested for the degradation of Congo red azo dye in a Fenton-like process in which the degradation efficiency reached 94 % after 100 min. Kinetic analysis indicates that the degradation rate of the dye can be approximated by pseudo-first-order kinetics. Coordination Polymer Degradation Efficiency Catalytic Degradation Monodentate Carboxylate Group Copper Coordination Polymer Gu, Yu aut Li, Guang Yue aut Xiao, Shu Lin aut Cui, Guang Hua aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 38(2013), 4 vom: 02. März, Seite 407-412 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:38 year:2013 number:4 day:02 month:03 pages:407-412 https://doi.org/10.1007/s11243-013-9705-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 38 2013 4 02 03 407-412 |
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10.1007/s11243-013-9705-9 doi (DE-627)OLC2084048133 (DE-He213)s11243-013-9705-9-p DE-627 ger DE-627 rakwb eng 660 VZ Qin, Li verfasserin aut Preparation and crystal structure of a triple parallel interpenetrated copper coordination polymer based on a flexible bis(imidazole) ligand 2013 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media Dordrecht 2013 Abstract A Cu(II) coordination polymer, [Cu(L)(bdc)]n (L = 1,4-bis(imidazole)butane, bdc = 1,3-benzenedicarboxylate) has been hydrothermally synthesized and characterized by elemental analysis, IR spectrum, thermogravimetric analysis, and single-crystal X-ray diffraction. The complex is a rare example of a threefold parallel interpenetrated coordination bonding network based on undulant [$ Cu_{4} $(μ2-L)2(μ2-bdc)2] parallelograms with $ 4^{4} $-sql layer. The heterogeneous catalytic activity of the complex was tested for the degradation of Congo red azo dye in a Fenton-like process in which the degradation efficiency reached 94 % after 100 min. Kinetic analysis indicates that the degradation rate of the dye can be approximated by pseudo-first-order kinetics. Coordination Polymer Degradation Efficiency Catalytic Degradation Monodentate Carboxylate Group Copper Coordination Polymer Gu, Yu aut Li, Guang Yue aut Xiao, Shu Lin aut Cui, Guang Hua aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 38(2013), 4 vom: 02. März, Seite 407-412 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:38 year:2013 number:4 day:02 month:03 pages:407-412 https://doi.org/10.1007/s11243-013-9705-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 38 2013 4 02 03 407-412 |
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10.1007/s11243-013-9705-9 doi (DE-627)OLC2084048133 (DE-He213)s11243-013-9705-9-p DE-627 ger DE-627 rakwb eng 660 VZ Qin, Li verfasserin aut Preparation and crystal structure of a triple parallel interpenetrated copper coordination polymer based on a flexible bis(imidazole) ligand 2013 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media Dordrecht 2013 Abstract A Cu(II) coordination polymer, [Cu(L)(bdc)]n (L = 1,4-bis(imidazole)butane, bdc = 1,3-benzenedicarboxylate) has been hydrothermally synthesized and characterized by elemental analysis, IR spectrum, thermogravimetric analysis, and single-crystal X-ray diffraction. The complex is a rare example of a threefold parallel interpenetrated coordination bonding network based on undulant [$ Cu_{4} $(μ2-L)2(μ2-bdc)2] parallelograms with $ 4^{4} $-sql layer. The heterogeneous catalytic activity of the complex was tested for the degradation of Congo red azo dye in a Fenton-like process in which the degradation efficiency reached 94 % after 100 min. Kinetic analysis indicates that the degradation rate of the dye can be approximated by pseudo-first-order kinetics. Coordination Polymer Degradation Efficiency Catalytic Degradation Monodentate Carboxylate Group Copper Coordination Polymer Gu, Yu aut Li, Guang Yue aut Xiao, Shu Lin aut Cui, Guang Hua aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 38(2013), 4 vom: 02. März, Seite 407-412 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:38 year:2013 number:4 day:02 month:03 pages:407-412 https://doi.org/10.1007/s11243-013-9705-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 38 2013 4 02 03 407-412 |
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10.1007/s11243-013-9705-9 doi (DE-627)OLC2084048133 (DE-He213)s11243-013-9705-9-p DE-627 ger DE-627 rakwb eng 660 VZ Qin, Li verfasserin aut Preparation and crystal structure of a triple parallel interpenetrated copper coordination polymer based on a flexible bis(imidazole) ligand 2013 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media Dordrecht 2013 Abstract A Cu(II) coordination polymer, [Cu(L)(bdc)]n (L = 1,4-bis(imidazole)butane, bdc = 1,3-benzenedicarboxylate) has been hydrothermally synthesized and characterized by elemental analysis, IR spectrum, thermogravimetric analysis, and single-crystal X-ray diffraction. The complex is a rare example of a threefold parallel interpenetrated coordination bonding network based on undulant [$ Cu_{4} $(μ2-L)2(μ2-bdc)2] parallelograms with $ 4^{4} $-sql layer. The heterogeneous catalytic activity of the complex was tested for the degradation of Congo red azo dye in a Fenton-like process in which the degradation efficiency reached 94 % after 100 min. Kinetic analysis indicates that the degradation rate of the dye can be approximated by pseudo-first-order kinetics. Coordination Polymer Degradation Efficiency Catalytic Degradation Monodentate Carboxylate Group Copper Coordination Polymer Gu, Yu aut Li, Guang Yue aut Xiao, Shu Lin aut Cui, Guang Hua aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 38(2013), 4 vom: 02. März, Seite 407-412 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:38 year:2013 number:4 day:02 month:03 pages:407-412 https://doi.org/10.1007/s11243-013-9705-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 38 2013 4 02 03 407-412 |
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Preparation and crystal structure of a triple parallel interpenetrated copper coordination polymer based on a flexible bis(imidazole) ligand |
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Abstract A Cu(II) coordination polymer, [Cu(L)(bdc)]n (L = 1,4-bis(imidazole)butane, bdc = 1,3-benzenedicarboxylate) has been hydrothermally synthesized and characterized by elemental analysis, IR spectrum, thermogravimetric analysis, and single-crystal X-ray diffraction. The complex is a rare example of a threefold parallel interpenetrated coordination bonding network based on undulant [$ Cu_{4} $(μ2-L)2(μ2-bdc)2] parallelograms with $ 4^{4} $-sql layer. The heterogeneous catalytic activity of the complex was tested for the degradation of Congo red azo dye in a Fenton-like process in which the degradation efficiency reached 94 % after 100 min. Kinetic analysis indicates that the degradation rate of the dye can be approximated by pseudo-first-order kinetics. © Springer Science+Business Media Dordrecht 2013 |
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Abstract A Cu(II) coordination polymer, [Cu(L)(bdc)]n (L = 1,4-bis(imidazole)butane, bdc = 1,3-benzenedicarboxylate) has been hydrothermally synthesized and characterized by elemental analysis, IR spectrum, thermogravimetric analysis, and single-crystal X-ray diffraction. The complex is a rare example of a threefold parallel interpenetrated coordination bonding network based on undulant [$ Cu_{4} $(μ2-L)2(μ2-bdc)2] parallelograms with $ 4^{4} $-sql layer. The heterogeneous catalytic activity of the complex was tested for the degradation of Congo red azo dye in a Fenton-like process in which the degradation efficiency reached 94 % after 100 min. Kinetic analysis indicates that the degradation rate of the dye can be approximated by pseudo-first-order kinetics. © Springer Science+Business Media Dordrecht 2013 |
| abstract_unstemmed |
Abstract A Cu(II) coordination polymer, [Cu(L)(bdc)]n (L = 1,4-bis(imidazole)butane, bdc = 1,3-benzenedicarboxylate) has been hydrothermally synthesized and characterized by elemental analysis, IR spectrum, thermogravimetric analysis, and single-crystal X-ray diffraction. The complex is a rare example of a threefold parallel interpenetrated coordination bonding network based on undulant [$ Cu_{4} $(μ2-L)2(μ2-bdc)2] parallelograms with $ 4^{4} $-sql layer. The heterogeneous catalytic activity of the complex was tested for the degradation of Congo red azo dye in a Fenton-like process in which the degradation efficiency reached 94 % after 100 min. Kinetic analysis indicates that the degradation rate of the dye can be approximated by pseudo-first-order kinetics. © Springer Science+Business Media Dordrecht 2013 |
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| title_short |
Preparation and crystal structure of a triple parallel interpenetrated copper coordination polymer based on a flexible bis(imidazole) ligand |
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Gu, Yu Li, Guang Yue Xiao, Shu Lin Cui, Guang Hua |
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