Synthesis, structures, and magnetic properties of carboxylate-bridged trinuclear complexes based on low-spin manganese(III)/iron(III) building blocks
Abstract Four linear trinuclear transition metal complexes have been prepared and characterized. The complexes [$ M^{II} $(MeOH)4][$ Fe^{III} $(L)2]2·2MeOH (M = Fe (1) or Ni (2)), [$ Co^{II} $(EtOH)2($ H_{2} $O)2][$ Fe^{III} $(L)2]2·2EtOH (3), and [$ Mn^{II} $(phen)2][$ Mn^{III} $(L)2]2·4MeOH (4) ($...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Chen, Xi [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2013 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer Science+Business Media Dordrecht 2013 |
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| Übergeordnetes Werk: |
Enthalten in: Transition metal chemistry - Springer Netherlands, 1975, 38(2013), 6 vom: 31. Mai, Seite 683-688 |
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| Übergeordnetes Werk: |
volume:38 ; year:2013 ; number:6 ; day:31 ; month:05 ; pages:683-688 |
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|---|
| DOI / URN: |
10.1007/s11243-013-9737-1 |
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| 520 | |a Abstract Four linear trinuclear transition metal complexes have been prepared and characterized. The complexes [$ M^{II} $(MeOH)4][$ Fe^{III} $(L)2]2·2MeOH (M = Fe (1) or Ni (2)), [$ Co^{II} $(EtOH)2($ H_{2} $O)2][$ Fe^{III} $(L)2]2·2EtOH (3), and [$ Mn^{II} $(phen)2][$ Mn^{III} $(L)2]2·4MeOH (4) ($ H_{2} $L = ((2-carboxyphenyl)azo)-benzaldoxime, phen = 1,10-phenanthroline) possesses a similar syn–anti carboxylate-bridged structure. The terminal Fe(III) or Mn(III) ions are low spin, and the central M(II) ions are high spin. Magnetic measurements show that antiferromagnetic interactions were present between the adjacent metal ions via the syn–anti carboxylate bridges. The antiferromagnetic coupling between low-spin Fe(III) and Ni(II) is unusual, which has been tentatively assigned to the structural distortion of Fe(III). | ||
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10.1007/s11243-013-9737-1 doi (DE-627)OLC208404877X (DE-He213)s11243-013-9737-1-p DE-627 ger DE-627 rakwb eng 660 VZ Chen, Xi verfasserin aut Synthesis, structures, and magnetic properties of carboxylate-bridged trinuclear complexes based on low-spin manganese(III)/iron(III) building blocks 2013 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media Dordrecht 2013 Abstract Four linear trinuclear transition metal complexes have been prepared and characterized. The complexes [$ M^{II} $(MeOH)4][$ Fe^{III} $(L)2]2·2MeOH (M = Fe (1) or Ni (2)), [$ Co^{II} $(EtOH)2($ H_{2} $O)2][$ Fe^{III} $(L)2]2·2EtOH (3), and [$ Mn^{II} $(phen)2][$ Mn^{III} $(L)2]2·4MeOH (4) ($ H_{2} $L = ((2-carboxyphenyl)azo)-benzaldoxime, phen = 1,10-phenanthroline) possesses a similar syn–anti carboxylate-bridged structure. The terminal Fe(III) or Mn(III) ions are low spin, and the central M(II) ions are high spin. Magnetic measurements show that antiferromagnetic interactions were present between the adjacent metal ions via the syn–anti carboxylate bridges. The antiferromagnetic coupling between low-spin Fe(III) and Ni(II) is unusual, which has been tentatively assigned to the structural distortion of Fe(III). Antiferromagnetic Interaction Antiferromagnetic Coupling Central Metal Atom Magnetic Orbital Weak Antiferromagnetic Interaction Cui, Ai-Li aut Liu, Cai-Ming aut Kou, Hui-Zhong aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 38(2013), 6 vom: 31. Mai, Seite 683-688 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:38 year:2013 number:6 day:31 month:05 pages:683-688 https://doi.org/10.1007/s11243-013-9737-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 38 2013 6 31 05 683-688 |
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10.1007/s11243-013-9737-1 doi (DE-627)OLC208404877X (DE-He213)s11243-013-9737-1-p DE-627 ger DE-627 rakwb eng 660 VZ Chen, Xi verfasserin aut Synthesis, structures, and magnetic properties of carboxylate-bridged trinuclear complexes based on low-spin manganese(III)/iron(III) building blocks 2013 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media Dordrecht 2013 Abstract Four linear trinuclear transition metal complexes have been prepared and characterized. The complexes [$ M^{II} $(MeOH)4][$ Fe^{III} $(L)2]2·2MeOH (M = Fe (1) or Ni (2)), [$ Co^{II} $(EtOH)2($ H_{2} $O)2][$ Fe^{III} $(L)2]2·2EtOH (3), and [$ Mn^{II} $(phen)2][$ Mn^{III} $(L)2]2·4MeOH (4) ($ H_{2} $L = ((2-carboxyphenyl)azo)-benzaldoxime, phen = 1,10-phenanthroline) possesses a similar syn–anti carboxylate-bridged structure. The terminal Fe(III) or Mn(III) ions are low spin, and the central M(II) ions are high spin. Magnetic measurements show that antiferromagnetic interactions were present between the adjacent metal ions via the syn–anti carboxylate bridges. The antiferromagnetic coupling between low-spin Fe(III) and Ni(II) is unusual, which has been tentatively assigned to the structural distortion of Fe(III). Antiferromagnetic Interaction Antiferromagnetic Coupling Central Metal Atom Magnetic Orbital Weak Antiferromagnetic Interaction Cui, Ai-Li aut Liu, Cai-Ming aut Kou, Hui-Zhong aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 38(2013), 6 vom: 31. Mai, Seite 683-688 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:38 year:2013 number:6 day:31 month:05 pages:683-688 https://doi.org/10.1007/s11243-013-9737-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 38 2013 6 31 05 683-688 |
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10.1007/s11243-013-9737-1 doi (DE-627)OLC208404877X (DE-He213)s11243-013-9737-1-p DE-627 ger DE-627 rakwb eng 660 VZ Chen, Xi verfasserin aut Synthesis, structures, and magnetic properties of carboxylate-bridged trinuclear complexes based on low-spin manganese(III)/iron(III) building blocks 2013 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media Dordrecht 2013 Abstract Four linear trinuclear transition metal complexes have been prepared and characterized. The complexes [$ M^{II} $(MeOH)4][$ Fe^{III} $(L)2]2·2MeOH (M = Fe (1) or Ni (2)), [$ Co^{II} $(EtOH)2($ H_{2} $O)2][$ Fe^{III} $(L)2]2·2EtOH (3), and [$ Mn^{II} $(phen)2][$ Mn^{III} $(L)2]2·4MeOH (4) ($ H_{2} $L = ((2-carboxyphenyl)azo)-benzaldoxime, phen = 1,10-phenanthroline) possesses a similar syn–anti carboxylate-bridged structure. The terminal Fe(III) or Mn(III) ions are low spin, and the central M(II) ions are high spin. Magnetic measurements show that antiferromagnetic interactions were present between the adjacent metal ions via the syn–anti carboxylate bridges. The antiferromagnetic coupling between low-spin Fe(III) and Ni(II) is unusual, which has been tentatively assigned to the structural distortion of Fe(III). Antiferromagnetic Interaction Antiferromagnetic Coupling Central Metal Atom Magnetic Orbital Weak Antiferromagnetic Interaction Cui, Ai-Li aut Liu, Cai-Ming aut Kou, Hui-Zhong aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 38(2013), 6 vom: 31. Mai, Seite 683-688 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:38 year:2013 number:6 day:31 month:05 pages:683-688 https://doi.org/10.1007/s11243-013-9737-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 38 2013 6 31 05 683-688 |
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10.1007/s11243-013-9737-1 doi (DE-627)OLC208404877X (DE-He213)s11243-013-9737-1-p DE-627 ger DE-627 rakwb eng 660 VZ Chen, Xi verfasserin aut Synthesis, structures, and magnetic properties of carboxylate-bridged trinuclear complexes based on low-spin manganese(III)/iron(III) building blocks 2013 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media Dordrecht 2013 Abstract Four linear trinuclear transition metal complexes have been prepared and characterized. The complexes [$ M^{II} $(MeOH)4][$ Fe^{III} $(L)2]2·2MeOH (M = Fe (1) or Ni (2)), [$ Co^{II} $(EtOH)2($ H_{2} $O)2][$ Fe^{III} $(L)2]2·2EtOH (3), and [$ Mn^{II} $(phen)2][$ Mn^{III} $(L)2]2·4MeOH (4) ($ H_{2} $L = ((2-carboxyphenyl)azo)-benzaldoxime, phen = 1,10-phenanthroline) possesses a similar syn–anti carboxylate-bridged structure. The terminal Fe(III) or Mn(III) ions are low spin, and the central M(II) ions are high spin. Magnetic measurements show that antiferromagnetic interactions were present between the adjacent metal ions via the syn–anti carboxylate bridges. The antiferromagnetic coupling between low-spin Fe(III) and Ni(II) is unusual, which has been tentatively assigned to the structural distortion of Fe(III). Antiferromagnetic Interaction Antiferromagnetic Coupling Central Metal Atom Magnetic Orbital Weak Antiferromagnetic Interaction Cui, Ai-Li aut Liu, Cai-Ming aut Kou, Hui-Zhong aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 38(2013), 6 vom: 31. Mai, Seite 683-688 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:38 year:2013 number:6 day:31 month:05 pages:683-688 https://doi.org/10.1007/s11243-013-9737-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 38 2013 6 31 05 683-688 |
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10.1007/s11243-013-9737-1 doi (DE-627)OLC208404877X (DE-He213)s11243-013-9737-1-p DE-627 ger DE-627 rakwb eng 660 VZ Chen, Xi verfasserin aut Synthesis, structures, and magnetic properties of carboxylate-bridged trinuclear complexes based on low-spin manganese(III)/iron(III) building blocks 2013 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media Dordrecht 2013 Abstract Four linear trinuclear transition metal complexes have been prepared and characterized. The complexes [$ M^{II} $(MeOH)4][$ Fe^{III} $(L)2]2·2MeOH (M = Fe (1) or Ni (2)), [$ Co^{II} $(EtOH)2($ H_{2} $O)2][$ Fe^{III} $(L)2]2·2EtOH (3), and [$ Mn^{II} $(phen)2][$ Mn^{III} $(L)2]2·4MeOH (4) ($ H_{2} $L = ((2-carboxyphenyl)azo)-benzaldoxime, phen = 1,10-phenanthroline) possesses a similar syn–anti carboxylate-bridged structure. The terminal Fe(III) or Mn(III) ions are low spin, and the central M(II) ions are high spin. Magnetic measurements show that antiferromagnetic interactions were present between the adjacent metal ions via the syn–anti carboxylate bridges. The antiferromagnetic coupling between low-spin Fe(III) and Ni(II) is unusual, which has been tentatively assigned to the structural distortion of Fe(III). Antiferromagnetic Interaction Antiferromagnetic Coupling Central Metal Atom Magnetic Orbital Weak Antiferromagnetic Interaction Cui, Ai-Li aut Liu, Cai-Ming aut Kou, Hui-Zhong aut Enthalten in Transition metal chemistry Springer Netherlands, 1975 38(2013), 6 vom: 31. Mai, Seite 683-688 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:38 year:2013 number:6 day:31 month:05 pages:683-688 https://doi.org/10.1007/s11243-013-9737-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 38 2013 6 31 05 683-688 |
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Chen, Xi |
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660 |
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synthesis, structures, and magnetic properties of carboxylate-bridged trinuclear complexes based on low-spin manganese(iii)/iron(iii) building blocks |
| title_auth |
Synthesis, structures, and magnetic properties of carboxylate-bridged trinuclear complexes based on low-spin manganese(III)/iron(III) building blocks |
| abstract |
Abstract Four linear trinuclear transition metal complexes have been prepared and characterized. The complexes [$ M^{II} $(MeOH)4][$ Fe^{III} $(L)2]2·2MeOH (M = Fe (1) or Ni (2)), [$ Co^{II} $(EtOH)2($ H_{2} $O)2][$ Fe^{III} $(L)2]2·2EtOH (3), and [$ Mn^{II} $(phen)2][$ Mn^{III} $(L)2]2·4MeOH (4) ($ H_{2} $L = ((2-carboxyphenyl)azo)-benzaldoxime, phen = 1,10-phenanthroline) possesses a similar syn–anti carboxylate-bridged structure. The terminal Fe(III) or Mn(III) ions are low spin, and the central M(II) ions are high spin. Magnetic measurements show that antiferromagnetic interactions were present between the adjacent metal ions via the syn–anti carboxylate bridges. The antiferromagnetic coupling between low-spin Fe(III) and Ni(II) is unusual, which has been tentatively assigned to the structural distortion of Fe(III). © Springer Science+Business Media Dordrecht 2013 |
| abstractGer |
Abstract Four linear trinuclear transition metal complexes have been prepared and characterized. The complexes [$ M^{II} $(MeOH)4][$ Fe^{III} $(L)2]2·2MeOH (M = Fe (1) or Ni (2)), [$ Co^{II} $(EtOH)2($ H_{2} $O)2][$ Fe^{III} $(L)2]2·2EtOH (3), and [$ Mn^{II} $(phen)2][$ Mn^{III} $(L)2]2·4MeOH (4) ($ H_{2} $L = ((2-carboxyphenyl)azo)-benzaldoxime, phen = 1,10-phenanthroline) possesses a similar syn–anti carboxylate-bridged structure. The terminal Fe(III) or Mn(III) ions are low spin, and the central M(II) ions are high spin. Magnetic measurements show that antiferromagnetic interactions were present between the adjacent metal ions via the syn–anti carboxylate bridges. The antiferromagnetic coupling between low-spin Fe(III) and Ni(II) is unusual, which has been tentatively assigned to the structural distortion of Fe(III). © Springer Science+Business Media Dordrecht 2013 |
| abstract_unstemmed |
Abstract Four linear trinuclear transition metal complexes have been prepared and characterized. The complexes [$ M^{II} $(MeOH)4][$ Fe^{III} $(L)2]2·2MeOH (M = Fe (1) or Ni (2)), [$ Co^{II} $(EtOH)2($ H_{2} $O)2][$ Fe^{III} $(L)2]2·2EtOH (3), and [$ Mn^{II} $(phen)2][$ Mn^{III} $(L)2]2·4MeOH (4) ($ H_{2} $L = ((2-carboxyphenyl)azo)-benzaldoxime, phen = 1,10-phenanthroline) possesses a similar syn–anti carboxylate-bridged structure. The terminal Fe(III) or Mn(III) ions are low spin, and the central M(II) ions are high spin. Magnetic measurements show that antiferromagnetic interactions were present between the adjacent metal ions via the syn–anti carboxylate bridges. The antiferromagnetic coupling between low-spin Fe(III) and Ni(II) is unusual, which has been tentatively assigned to the structural distortion of Fe(III). © Springer Science+Business Media Dordrecht 2013 |
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Synthesis, structures, and magnetic properties of carboxylate-bridged trinuclear complexes based on low-spin manganese(III)/iron(III) building blocks |
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