Cyanide-bridged one-dimensional bimetallic complexes based on a tridentate copper(II) building block: synthesis, crystal structures and magnetic properties
Abstract The reactions of [$ M^{III} $(CN)6]3− (M = Cr or Co) with $ Cu^{II} $ complexes of a tridentate schiff base [Cu(aemp)Cl] or [Cu(aemp)Ac]2 (Haemp = 2-[(2-amino-ethylimino)-methyl]-phenol) give rise to 1D cyanide-bridged bimetallic coordination polymers [$ Cu_{4} $(aemp)4($ H_{2} $O)2][Cr(CN)...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Li, Shu-Tao [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2014 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer International Publishing Switzerland 2014 |
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| Übergeordnetes Werk: |
Enthalten in: Transition metal chemistry - Springer International Publishing, 1975, 39(2014), 4 vom: 12. März, Seite 387-392 |
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| Übergeordnetes Werk: |
volume:39 ; year:2014 ; number:4 ; day:12 ; month:03 ; pages:387-392 |
| Links: |
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| DOI / URN: |
10.1007/s11243-014-9812-2 |
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OLC2084050278 |
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| 520 | |a Abstract The reactions of [$ M^{III} $(CN)6]3− (M = Cr or Co) with $ Cu^{II} $ complexes of a tridentate schiff base [Cu(aemp)Cl] or [Cu(aemp)Ac]2 (Haemp = 2-[(2-amino-ethylimino)-methyl]-phenol) give rise to 1D cyanide-bridged bimetallic coordination polymers [$ Cu_{4} $(aemp)4($ H_{2} $O)2][Cr(CN)6]Cl (1) and [$ Cu_{3} $(aemp)3($ H_{2} $O)][Co(CN)6]·$ 2H_{2} $O·MeOH (2). In complex 1, the six cyanide ligands of the [Cr(CN)6]3− moiety are involved in bridging, while in complex 2 only five cyanide ligands act as bridges to give a neutral chain. Magnetic studies reveal that complex 1 exhibits intermetallic ferromagnetic coupling, with J = 8.2 $ cm^{−1} $. | ||
| 650 | 4 | |a Magnetic Coupling | |
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| 650 | 4 | |a Tridentate Ligand | |
| 650 | 4 | |a Ferromagnetic Coupling | |
| 650 | 4 | |a Cyanide Ligand | |
| 700 | 1 | |a Zhao, Chong-Chao |4 aut | |
| 700 | 1 | |a Cui, Ai-Li |4 aut | |
| 700 | 1 | |a Kou, Hui-Zhong |4 aut | |
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10.1007/s11243-014-9812-2 doi (DE-627)OLC2084050278 (DE-He213)s11243-014-9812-2-p DE-627 ger DE-627 rakwb eng 660 VZ Li, Shu-Tao verfasserin aut Cyanide-bridged one-dimensional bimetallic complexes based on a tridentate copper(II) building block: synthesis, crystal structures and magnetic properties 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer International Publishing Switzerland 2014 Abstract The reactions of [$ M^{III} $(CN)6]3− (M = Cr or Co) with $ Cu^{II} $ complexes of a tridentate schiff base [Cu(aemp)Cl] or [Cu(aemp)Ac]2 (Haemp = 2-[(2-amino-ethylimino)-methyl]-phenol) give rise to 1D cyanide-bridged bimetallic coordination polymers [$ Cu_{4} $(aemp)4($ H_{2} $O)2][Cr(CN)6]Cl (1) and [$ Cu_{3} $(aemp)3($ H_{2} $O)][Co(CN)6]·$ 2H_{2} $O·MeOH (2). In complex 1, the six cyanide ligands of the [Cr(CN)6]3− moiety are involved in bridging, while in complex 2 only five cyanide ligands act as bridges to give a neutral chain. Magnetic studies reveal that complex 1 exhibits intermetallic ferromagnetic coupling, with J = 8.2 $ cm^{−1} $. Magnetic Coupling Magnetic Susceptibility Measurement Tridentate Ligand Ferromagnetic Coupling Cyanide Ligand Zhao, Chong-Chao aut Cui, Ai-Li aut Kou, Hui-Zhong aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 39(2014), 4 vom: 12. März, Seite 387-392 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:39 year:2014 number:4 day:12 month:03 pages:387-392 https://doi.org/10.1007/s11243-014-9812-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 39 2014 4 12 03 387-392 |
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10.1007/s11243-014-9812-2 doi (DE-627)OLC2084050278 (DE-He213)s11243-014-9812-2-p DE-627 ger DE-627 rakwb eng 660 VZ Li, Shu-Tao verfasserin aut Cyanide-bridged one-dimensional bimetallic complexes based on a tridentate copper(II) building block: synthesis, crystal structures and magnetic properties 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer International Publishing Switzerland 2014 Abstract The reactions of [$ M^{III} $(CN)6]3− (M = Cr or Co) with $ Cu^{II} $ complexes of a tridentate schiff base [Cu(aemp)Cl] or [Cu(aemp)Ac]2 (Haemp = 2-[(2-amino-ethylimino)-methyl]-phenol) give rise to 1D cyanide-bridged bimetallic coordination polymers [$ Cu_{4} $(aemp)4($ H_{2} $O)2][Cr(CN)6]Cl (1) and [$ Cu_{3} $(aemp)3($ H_{2} $O)][Co(CN)6]·$ 2H_{2} $O·MeOH (2). In complex 1, the six cyanide ligands of the [Cr(CN)6]3− moiety are involved in bridging, while in complex 2 only five cyanide ligands act as bridges to give a neutral chain. Magnetic studies reveal that complex 1 exhibits intermetallic ferromagnetic coupling, with J = 8.2 $ cm^{−1} $. Magnetic Coupling Magnetic Susceptibility Measurement Tridentate Ligand Ferromagnetic Coupling Cyanide Ligand Zhao, Chong-Chao aut Cui, Ai-Li aut Kou, Hui-Zhong aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 39(2014), 4 vom: 12. März, Seite 387-392 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:39 year:2014 number:4 day:12 month:03 pages:387-392 https://doi.org/10.1007/s11243-014-9812-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 39 2014 4 12 03 387-392 |
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10.1007/s11243-014-9812-2 doi (DE-627)OLC2084050278 (DE-He213)s11243-014-9812-2-p DE-627 ger DE-627 rakwb eng 660 VZ Li, Shu-Tao verfasserin aut Cyanide-bridged one-dimensional bimetallic complexes based on a tridentate copper(II) building block: synthesis, crystal structures and magnetic properties 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer International Publishing Switzerland 2014 Abstract The reactions of [$ M^{III} $(CN)6]3− (M = Cr or Co) with $ Cu^{II} $ complexes of a tridentate schiff base [Cu(aemp)Cl] or [Cu(aemp)Ac]2 (Haemp = 2-[(2-amino-ethylimino)-methyl]-phenol) give rise to 1D cyanide-bridged bimetallic coordination polymers [$ Cu_{4} $(aemp)4($ H_{2} $O)2][Cr(CN)6]Cl (1) and [$ Cu_{3} $(aemp)3($ H_{2} $O)][Co(CN)6]·$ 2H_{2} $O·MeOH (2). In complex 1, the six cyanide ligands of the [Cr(CN)6]3− moiety are involved in bridging, while in complex 2 only five cyanide ligands act as bridges to give a neutral chain. Magnetic studies reveal that complex 1 exhibits intermetallic ferromagnetic coupling, with J = 8.2 $ cm^{−1} $. Magnetic Coupling Magnetic Susceptibility Measurement Tridentate Ligand Ferromagnetic Coupling Cyanide Ligand Zhao, Chong-Chao aut Cui, Ai-Li aut Kou, Hui-Zhong aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 39(2014), 4 vom: 12. März, Seite 387-392 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:39 year:2014 number:4 day:12 month:03 pages:387-392 https://doi.org/10.1007/s11243-014-9812-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 39 2014 4 12 03 387-392 |
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10.1007/s11243-014-9812-2 doi (DE-627)OLC2084050278 (DE-He213)s11243-014-9812-2-p DE-627 ger DE-627 rakwb eng 660 VZ Li, Shu-Tao verfasserin aut Cyanide-bridged one-dimensional bimetallic complexes based on a tridentate copper(II) building block: synthesis, crystal structures and magnetic properties 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer International Publishing Switzerland 2014 Abstract The reactions of [$ M^{III} $(CN)6]3− (M = Cr or Co) with $ Cu^{II} $ complexes of a tridentate schiff base [Cu(aemp)Cl] or [Cu(aemp)Ac]2 (Haemp = 2-[(2-amino-ethylimino)-methyl]-phenol) give rise to 1D cyanide-bridged bimetallic coordination polymers [$ Cu_{4} $(aemp)4($ H_{2} $O)2][Cr(CN)6]Cl (1) and [$ Cu_{3} $(aemp)3($ H_{2} $O)][Co(CN)6]·$ 2H_{2} $O·MeOH (2). In complex 1, the six cyanide ligands of the [Cr(CN)6]3− moiety are involved in bridging, while in complex 2 only five cyanide ligands act as bridges to give a neutral chain. Magnetic studies reveal that complex 1 exhibits intermetallic ferromagnetic coupling, with J = 8.2 $ cm^{−1} $. Magnetic Coupling Magnetic Susceptibility Measurement Tridentate Ligand Ferromagnetic Coupling Cyanide Ligand Zhao, Chong-Chao aut Cui, Ai-Li aut Kou, Hui-Zhong aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 39(2014), 4 vom: 12. März, Seite 387-392 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:39 year:2014 number:4 day:12 month:03 pages:387-392 https://doi.org/10.1007/s11243-014-9812-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 39 2014 4 12 03 387-392 |
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10.1007/s11243-014-9812-2 doi (DE-627)OLC2084050278 (DE-He213)s11243-014-9812-2-p DE-627 ger DE-627 rakwb eng 660 VZ Li, Shu-Tao verfasserin aut Cyanide-bridged one-dimensional bimetallic complexes based on a tridentate copper(II) building block: synthesis, crystal structures and magnetic properties 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer International Publishing Switzerland 2014 Abstract The reactions of [$ M^{III} $(CN)6]3− (M = Cr or Co) with $ Cu^{II} $ complexes of a tridentate schiff base [Cu(aemp)Cl] or [Cu(aemp)Ac]2 (Haemp = 2-[(2-amino-ethylimino)-methyl]-phenol) give rise to 1D cyanide-bridged bimetallic coordination polymers [$ Cu_{4} $(aemp)4($ H_{2} $O)2][Cr(CN)6]Cl (1) and [$ Cu_{3} $(aemp)3($ H_{2} $O)][Co(CN)6]·$ 2H_{2} $O·MeOH (2). In complex 1, the six cyanide ligands of the [Cr(CN)6]3− moiety are involved in bridging, while in complex 2 only five cyanide ligands act as bridges to give a neutral chain. Magnetic studies reveal that complex 1 exhibits intermetallic ferromagnetic coupling, with J = 8.2 $ cm^{−1} $. Magnetic Coupling Magnetic Susceptibility Measurement Tridentate Ligand Ferromagnetic Coupling Cyanide Ligand Zhao, Chong-Chao aut Cui, Ai-Li aut Kou, Hui-Zhong aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 39(2014), 4 vom: 12. März, Seite 387-392 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:39 year:2014 number:4 day:12 month:03 pages:387-392 https://doi.org/10.1007/s11243-014-9812-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 39 2014 4 12 03 387-392 |
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cyanide-bridged one-dimensional bimetallic complexes based on a tridentate copper(ii) building block: synthesis, crystal structures and magnetic properties |
| title_auth |
Cyanide-bridged one-dimensional bimetallic complexes based on a tridentate copper(II) building block: synthesis, crystal structures and magnetic properties |
| abstract |
Abstract The reactions of [$ M^{III} $(CN)6]3− (M = Cr or Co) with $ Cu^{II} $ complexes of a tridentate schiff base [Cu(aemp)Cl] or [Cu(aemp)Ac]2 (Haemp = 2-[(2-amino-ethylimino)-methyl]-phenol) give rise to 1D cyanide-bridged bimetallic coordination polymers [$ Cu_{4} $(aemp)4($ H_{2} $O)2][Cr(CN)6]Cl (1) and [$ Cu_{3} $(aemp)3($ H_{2} $O)][Co(CN)6]·$ 2H_{2} $O·MeOH (2). In complex 1, the six cyanide ligands of the [Cr(CN)6]3− moiety are involved in bridging, while in complex 2 only five cyanide ligands act as bridges to give a neutral chain. Magnetic studies reveal that complex 1 exhibits intermetallic ferromagnetic coupling, with J = 8.2 $ cm^{−1} $. © Springer International Publishing Switzerland 2014 |
| abstractGer |
Abstract The reactions of [$ M^{III} $(CN)6]3− (M = Cr or Co) with $ Cu^{II} $ complexes of a tridentate schiff base [Cu(aemp)Cl] or [Cu(aemp)Ac]2 (Haemp = 2-[(2-amino-ethylimino)-methyl]-phenol) give rise to 1D cyanide-bridged bimetallic coordination polymers [$ Cu_{4} $(aemp)4($ H_{2} $O)2][Cr(CN)6]Cl (1) and [$ Cu_{3} $(aemp)3($ H_{2} $O)][Co(CN)6]·$ 2H_{2} $O·MeOH (2). In complex 1, the six cyanide ligands of the [Cr(CN)6]3− moiety are involved in bridging, while in complex 2 only five cyanide ligands act as bridges to give a neutral chain. Magnetic studies reveal that complex 1 exhibits intermetallic ferromagnetic coupling, with J = 8.2 $ cm^{−1} $. © Springer International Publishing Switzerland 2014 |
| abstract_unstemmed |
Abstract The reactions of [$ M^{III} $(CN)6]3− (M = Cr or Co) with $ Cu^{II} $ complexes of a tridentate schiff base [Cu(aemp)Cl] or [Cu(aemp)Ac]2 (Haemp = 2-[(2-amino-ethylimino)-methyl]-phenol) give rise to 1D cyanide-bridged bimetallic coordination polymers [$ Cu_{4} $(aemp)4($ H_{2} $O)2][Cr(CN)6]Cl (1) and [$ Cu_{3} $(aemp)3($ H_{2} $O)][Co(CN)6]·$ 2H_{2} $O·MeOH (2). In complex 1, the six cyanide ligands of the [Cr(CN)6]3− moiety are involved in bridging, while in complex 2 only five cyanide ligands act as bridges to give a neutral chain. Magnetic studies reveal that complex 1 exhibits intermetallic ferromagnetic coupling, with J = 8.2 $ cm^{−1} $. © Springer International Publishing Switzerland 2014 |
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4 |
| title_short |
Cyanide-bridged one-dimensional bimetallic complexes based on a tridentate copper(II) building block: synthesis, crystal structures and magnetic properties |
| url |
https://doi.org/10.1007/s11243-014-9812-2 |
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| author2 |
Zhao, Chong-Chao Cui, Ai-Li Kou, Hui-Zhong |
| author2Str |
Zhao, Chong-Chao Cui, Ai-Li Kou, Hui-Zhong |
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| doi_str |
10.1007/s11243-014-9812-2 |
| up_date |
2024-07-04T01:20:25.202Z |
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