Solvent-induced syntheses of three heterothiometallic W/S/Cu cluster-based coordination polymers with isomeric architectures and effective photocatalytic properties

Abstract Reactions of ($ NH_{4} $)$ WS_{4} $, CuCN and pyridine (Py) in different reaction solvents, namely DMF, DMSO and aniline, generated three isomeric heterothiometallic W/S/Cu cluster-based coordination polymers [$ WS_{4} $$ Cu_{4} $(CN)2(Py)4]n (1 and 2) and {[$ WS_{4} $$ Cu_{4} $(CN)2(Py)4]2...
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Autor*in:	Zhang, Jinfang [verfasserIn] Wang, Chao Chen, Weitao Lin, Huihui Wang, Yinlin Zhang, Chi

Format:	Artikel
Sprache:	Englisch

Erschienen:	2015

Schlagwörter:	Photocatalytic Activity Visible Light Irradiation Photocatalytic Performance Photocatalytic Property Tetrazine

Anmerkung:	© Springer International Publishing Switzerland 2015

Übergeordnetes Werk:	Enthalten in: Transition metal chemistry - Springer International Publishing, 1975, 40(2015), 4 vom: 18. März, Seite 405-412
Übergeordnetes Werk:	volume:40 ; year:2015 ; number:4 ; day:18 ; month:03 ; pages:405-412

Links:	Volltext

DOI / URN:	10.1007/s11243-015-9930-5

Katalog-ID:	OLC2084052610

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520			\|a Abstract Reactions of ($ NH_{4} $)$ WS_{4} $, CuCN and pyridine (Py) in different reaction solvents, namely DMF, DMSO and aniline, generated three isomeric heterothiometallic W/S/Cu cluster-based coordination polymers [$ WS_{4} $$ Cu_{4} $(CN)2(Py)4]n (1 and 2) and {[$ WS_{4} $$ Cu_{4} $(CN)2(Py)4]2·$ 4CH_{3} $CN}n3. All three complexes are constructed from planar ‘open’ [W($ µ_{3} $-S)4$ Cu_{4} $]2+ clusters, $ CN^{−} $ bridges and terminal Py ligands, but exhibit distinct architectures, consisting of a unique 1-D serrated chain for 1, a 2-D (4,4) network for 2 and a 1-D linear chain for 3. The photocatalytic activities of complex 1 were explored by monitoring the photodegradation of methylene blue, revealing that this complex exhibits effective photocatalytic properties under visible light irradiation.
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allfields	10.1007/s11243-015-9930-5 doi (DE-627)OLC2084052610 (DE-He213)s11243-015-9930-5-p DE-627 ger DE-627 rakwb eng 660 VZ Zhang, Jinfang verfasserin aut Solvent-induced syntheses of three heterothiometallic W/S/Cu cluster-based coordination polymers with isomeric architectures and effective photocatalytic properties 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer International Publishing Switzerland 2015 Abstract Reactions of ($ NH_{4} $)$ WS_{4} $, CuCN and pyridine (Py) in different reaction solvents, namely DMF, DMSO and aniline, generated three isomeric heterothiometallic W/S/Cu cluster-based coordination polymers [$ WS_{4} $$ Cu_{4} $(CN)2(Py)4]n (1 and 2) and {[$ WS_{4} $$ Cu_{4} $(CN)2(Py)4]2·$ 4CH_{3} $CN}n3. All three complexes are constructed from planar ‘open’ [W($ µ_{3} $-S)4$ Cu_{4} $]2+ clusters, $ CN^{−} $ bridges and terminal Py ligands, but exhibit distinct architectures, consisting of a unique 1-D serrated chain for 1, a 2-D (4,4) network for 2 and a 1-D linear chain for 3. The photocatalytic activities of complex 1 were explored by monitoring the photodegradation of methylene blue, revealing that this complex exhibits effective photocatalytic properties under visible light irradiation. Photocatalytic Activity Visible Light Irradiation Photocatalytic Performance Photocatalytic Property Tetrazine Wang, Chao aut Chen, Weitao aut Lin, Huihui aut Wang, Yinlin aut Zhang, Chi aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 40(2015), 4 vom: 18. März, Seite 405-412 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:40 year:2015 number:4 day:18 month:03 pages:405-412 https://doi.org/10.1007/s11243-015-9930-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 40 2015 4 18 03 405-412
spelling	10.1007/s11243-015-9930-5 doi (DE-627)OLC2084052610 (DE-He213)s11243-015-9930-5-p DE-627 ger DE-627 rakwb eng 660 VZ Zhang, Jinfang verfasserin aut Solvent-induced syntheses of three heterothiometallic W/S/Cu cluster-based coordination polymers with isomeric architectures and effective photocatalytic properties 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer International Publishing Switzerland 2015 Abstract Reactions of ($ NH_{4} $)$ WS_{4} $, CuCN and pyridine (Py) in different reaction solvents, namely DMF, DMSO and aniline, generated three isomeric heterothiometallic W/S/Cu cluster-based coordination polymers [$ WS_{4} $$ Cu_{4} $(CN)2(Py)4]n (1 and 2) and {[$ WS_{4} $$ Cu_{4} $(CN)2(Py)4]2·$ 4CH_{3} $CN}n3. All three complexes are constructed from planar ‘open’ [W($ µ_{3} $-S)4$ Cu_{4} $]2+ clusters, $ CN^{−} $ bridges and terminal Py ligands, but exhibit distinct architectures, consisting of a unique 1-D serrated chain for 1, a 2-D (4,4) network for 2 and a 1-D linear chain for 3. The photocatalytic activities of complex 1 were explored by monitoring the photodegradation of methylene blue, revealing that this complex exhibits effective photocatalytic properties under visible light irradiation. Photocatalytic Activity Visible Light Irradiation Photocatalytic Performance Photocatalytic Property Tetrazine Wang, Chao aut Chen, Weitao aut Lin, Huihui aut Wang, Yinlin aut Zhang, Chi aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 40(2015), 4 vom: 18. März, Seite 405-412 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:40 year:2015 number:4 day:18 month:03 pages:405-412 https://doi.org/10.1007/s11243-015-9930-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 40 2015 4 18 03 405-412
allfields_unstemmed	10.1007/s11243-015-9930-5 doi (DE-627)OLC2084052610 (DE-He213)s11243-015-9930-5-p DE-627 ger DE-627 rakwb eng 660 VZ Zhang, Jinfang verfasserin aut Solvent-induced syntheses of three heterothiometallic W/S/Cu cluster-based coordination polymers with isomeric architectures and effective photocatalytic properties 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer International Publishing Switzerland 2015 Abstract Reactions of ($ NH_{4} $)$ WS_{4} $, CuCN and pyridine (Py) in different reaction solvents, namely DMF, DMSO and aniline, generated three isomeric heterothiometallic W/S/Cu cluster-based coordination polymers [$ WS_{4} $$ Cu_{4} $(CN)2(Py)4]n (1 and 2) and {[$ WS_{4} $$ Cu_{4} $(CN)2(Py)4]2·$ 4CH_{3} $CN}n3. All three complexes are constructed from planar ‘open’ [W($ µ_{3} $-S)4$ Cu_{4} $]2+ clusters, $ CN^{−} $ bridges and terminal Py ligands, but exhibit distinct architectures, consisting of a unique 1-D serrated chain for 1, a 2-D (4,4) network for 2 and a 1-D linear chain for 3. The photocatalytic activities of complex 1 were explored by monitoring the photodegradation of methylene blue, revealing that this complex exhibits effective photocatalytic properties under visible light irradiation. Photocatalytic Activity Visible Light Irradiation Photocatalytic Performance Photocatalytic Property Tetrazine Wang, Chao aut Chen, Weitao aut Lin, Huihui aut Wang, Yinlin aut Zhang, Chi aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 40(2015), 4 vom: 18. März, Seite 405-412 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:40 year:2015 number:4 day:18 month:03 pages:405-412 https://doi.org/10.1007/s11243-015-9930-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 40 2015 4 18 03 405-412
allfieldsGer	10.1007/s11243-015-9930-5 doi (DE-627)OLC2084052610 (DE-He213)s11243-015-9930-5-p DE-627 ger DE-627 rakwb eng 660 VZ Zhang, Jinfang verfasserin aut Solvent-induced syntheses of three heterothiometallic W/S/Cu cluster-based coordination polymers with isomeric architectures and effective photocatalytic properties 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer International Publishing Switzerland 2015 Abstract Reactions of ($ NH_{4} $)$ WS_{4} $, CuCN and pyridine (Py) in different reaction solvents, namely DMF, DMSO and aniline, generated three isomeric heterothiometallic W/S/Cu cluster-based coordination polymers [$ WS_{4} $$ Cu_{4} $(CN)2(Py)4]n (1 and 2) and {[$ WS_{4} $$ Cu_{4} $(CN)2(Py)4]2·$ 4CH_{3} $CN}n3. All three complexes are constructed from planar ‘open’ [W($ µ_{3} $-S)4$ Cu_{4} $]2+ clusters, $ CN^{−} $ bridges and terminal Py ligands, but exhibit distinct architectures, consisting of a unique 1-D serrated chain for 1, a 2-D (4,4) network for 2 and a 1-D linear chain for 3. The photocatalytic activities of complex 1 were explored by monitoring the photodegradation of methylene blue, revealing that this complex exhibits effective photocatalytic properties under visible light irradiation. Photocatalytic Activity Visible Light Irradiation Photocatalytic Performance Photocatalytic Property Tetrazine Wang, Chao aut Chen, Weitao aut Lin, Huihui aut Wang, Yinlin aut Zhang, Chi aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 40(2015), 4 vom: 18. März, Seite 405-412 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:40 year:2015 number:4 day:18 month:03 pages:405-412 https://doi.org/10.1007/s11243-015-9930-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 40 2015 4 18 03 405-412
allfieldsSound	10.1007/s11243-015-9930-5 doi (DE-627)OLC2084052610 (DE-He213)s11243-015-9930-5-p DE-627 ger DE-627 rakwb eng 660 VZ Zhang, Jinfang verfasserin aut Solvent-induced syntheses of three heterothiometallic W/S/Cu cluster-based coordination polymers with isomeric architectures and effective photocatalytic properties 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer International Publishing Switzerland 2015 Abstract Reactions of ($ NH_{4} $)$ WS_{4} $, CuCN and pyridine (Py) in different reaction solvents, namely DMF, DMSO and aniline, generated three isomeric heterothiometallic W/S/Cu cluster-based coordination polymers [$ WS_{4} $$ Cu_{4} $(CN)2(Py)4]n (1 and 2) and {[$ WS_{4} $$ Cu_{4} $(CN)2(Py)4]2·$ 4CH_{3} $CN}n3. All three complexes are constructed from planar ‘open’ [W($ µ_{3} $-S)4$ Cu_{4} $]2+ clusters, $ CN^{−} $ bridges and terminal Py ligands, but exhibit distinct architectures, consisting of a unique 1-D serrated chain for 1, a 2-D (4,4) network for 2 and a 1-D linear chain for 3. The photocatalytic activities of complex 1 were explored by monitoring the photodegradation of methylene blue, revealing that this complex exhibits effective photocatalytic properties under visible light irradiation. Photocatalytic Activity Visible Light Irradiation Photocatalytic Performance Photocatalytic Property Tetrazine Wang, Chao aut Chen, Weitao aut Lin, Huihui aut Wang, Yinlin aut Zhang, Chi aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 40(2015), 4 vom: 18. März, Seite 405-412 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:40 year:2015 number:4 day:18 month:03 pages:405-412 https://doi.org/10.1007/s11243-015-9930-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 40 2015 4 18 03 405-412
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author	Zhang, Jinfang
spellingShingle	Zhang, Jinfang ddc 660 misc Photocatalytic Activity misc Visible Light Irradiation misc Photocatalytic Performance misc Photocatalytic Property misc Tetrazine Solvent-induced syntheses of three heterothiometallic W/S/Cu cluster-based coordination polymers with isomeric architectures and effective photocatalytic properties
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title_sort	solvent-induced syntheses of three heterothiometallic w/s/cu cluster-based coordination polymers with isomeric architectures and effective photocatalytic properties
title_auth	Solvent-induced syntheses of three heterothiometallic W/S/Cu cluster-based coordination polymers with isomeric architectures and effective photocatalytic properties
abstract	Abstract Reactions of ($ NH_{4} $)$ WS_{4} $, CuCN and pyridine (Py) in different reaction solvents, namely DMF, DMSO and aniline, generated three isomeric heterothiometallic W/S/Cu cluster-based coordination polymers [$ WS_{4} $$ Cu_{4} $(CN)2(Py)4]n (1 and 2) and {[$ WS_{4} $$ Cu_{4} $(CN)2(Py)4]2·$ 4CH_{3} $CN}n3. All three complexes are constructed from planar ‘open’ [W($ µ_{3} $-S)4$ Cu_{4} $]2+ clusters, $ CN^{−} $ bridges and terminal Py ligands, but exhibit distinct architectures, consisting of a unique 1-D serrated chain for 1, a 2-D (4,4) network for 2 and a 1-D linear chain for 3. The photocatalytic activities of complex 1 were explored by monitoring the photodegradation of methylene blue, revealing that this complex exhibits effective photocatalytic properties under visible light irradiation. © Springer International Publishing Switzerland 2015
abstractGer	Abstract Reactions of ($ NH_{4} $)$ WS_{4} $, CuCN and pyridine (Py) in different reaction solvents, namely DMF, DMSO and aniline, generated three isomeric heterothiometallic W/S/Cu cluster-based coordination polymers [$ WS_{4} $$ Cu_{4} $(CN)2(Py)4]n (1 and 2) and {[$ WS_{4} $$ Cu_{4} $(CN)2(Py)4]2·$ 4CH_{3} $CN}n3. All three complexes are constructed from planar ‘open’ [W($ µ_{3} $-S)4$ Cu_{4} $]2+ clusters, $ CN^{−} $ bridges and terminal Py ligands, but exhibit distinct architectures, consisting of a unique 1-D serrated chain for 1, a 2-D (4,4) network for 2 and a 1-D linear chain for 3. The photocatalytic activities of complex 1 were explored by monitoring the photodegradation of methylene blue, revealing that this complex exhibits effective photocatalytic properties under visible light irradiation. © Springer International Publishing Switzerland 2015
abstract_unstemmed	Abstract Reactions of ($ NH_{4} $)$ WS_{4} $, CuCN and pyridine (Py) in different reaction solvents, namely DMF, DMSO and aniline, generated three isomeric heterothiometallic W/S/Cu cluster-based coordination polymers [$ WS_{4} $$ Cu_{4} $(CN)2(Py)4]n (1 and 2) and {[$ WS_{4} $$ Cu_{4} $(CN)2(Py)4]2·$ 4CH_{3} $CN}n3. All three complexes are constructed from planar ‘open’ [W($ µ_{3} $-S)4$ Cu_{4} $]2+ clusters, $ CN^{−} $ bridges and terminal Py ligands, but exhibit distinct architectures, consisting of a unique 1-D serrated chain for 1, a 2-D (4,4) network for 2 and a 1-D linear chain for 3. The photocatalytic activities of complex 1 were explored by monitoring the photodegradation of methylene blue, revealing that this complex exhibits effective photocatalytic properties under visible light irradiation. © Springer International Publishing Switzerland 2015
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container_issue	4
title_short	Solvent-induced syntheses of three heterothiometallic W/S/Cu cluster-based coordination polymers with isomeric architectures and effective photocatalytic properties
url	https://doi.org/10.1007/s11243-015-9930-5
remote_bool	false
author2	Wang, Chao Chen, Weitao Lin, Huihui Wang, Yinlin Zhang, Chi
author2Str	Wang, Chao Chen, Weitao Lin, Huihui Wang, Yinlin Zhang, Chi
ppnlink	129605417
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isOA_txt	false
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doi_str	10.1007/s11243-015-9930-5
up_date	2024-07-04T01:20:57.720Z
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