Three coordination compounds of cobalt with organic carboxylic acids and 1,10-phenanthroline as ligands: syntheses, structures and photocatalytic properties
Abstract Three cobalt-based coordination compounds, [$ Co_{2} $(phen)4($ H_{2} $qptb)]($ H_{3} $qptb)2 (1), [$ Co_{2} $(phen)4($ H_{2} $dczpb)2]·$ 5H_{2} $O (2) and [$ Co_{2} $(phen)4($ H_{2} $odpa)2($ H_{2} $O)2]·$ 2H_{2} $O (3), were obtained from mixtures of quaterphenyl-4,2″,5″,4′-tetracarboxyli...
Ausführliche Beschreibung
Autor*in: |
Wang, Chong-Chen [verfasserIn] |
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Format: |
Artikel |
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Sprache: |
Englisch |
Erschienen: |
2015 |
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Anmerkung: |
© Springer International Publishing Switzerland 2015 |
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Übergeordnetes Werk: |
Enthalten in: Transition metal chemistry - Springer International Publishing, 1975, 40(2015), 5 vom: 04. Juni, Seite 573-584 |
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Übergeordnetes Werk: |
volume:40 ; year:2015 ; number:5 ; day:04 ; month:06 ; pages:573-584 |
Links: |
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DOI / URN: |
10.1007/s11243-015-9950-1 |
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Katalog-ID: |
OLC2084052998 |
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520 | |a Abstract Three cobalt-based coordination compounds, [$ Co_{2} $(phen)4($ H_{2} $qptb)]($ H_{3} $qptb)2 (1), [$ Co_{2} $(phen)4($ H_{2} $dczpb)2]·$ 5H_{2} $O (2) and [$ Co_{2} $(phen)4($ H_{2} $odpa)2($ H_{2} $O)2]·$ 2H_{2} $O (3), were obtained from mixtures of quaterphenyl-4,2″,5″,4′-tetracarboxylic acid ($ H_{4} $qptb), 3,4-dicarboxyl-(3′,4′-dicarboxylazophenyl) benzene ($ H_{2} $dczpb), 4,4′-oxydiphthalic acid ($ H_{2} $odpa), along with 1,10-phenanthroline (phen) and cobalt salts by hydrothermal synthesis. Single-crystal X-ray diffraction reveals that complexes 1–3 contain [$ Co_{2} $(phen)4(L)] units, further joined into 3D frameworks via hydrogen-bonding interactions. All three complexes display considerable thermal stability and exhibit selective absorption in the ultraviolet region, as shown by thermogravimetric analysis and UV–Vis diffuse reflectance spectroscopy, respectively. Complex 1 mediates efficient photocatalytic degradation of methylene blue under UV irradiation. | ||
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10.1007/s11243-015-9950-1 doi (DE-627)OLC2084052998 (DE-He213)s11243-015-9950-1-p DE-627 ger DE-627 rakwb eng 660 VZ Wang, Chong-Chen verfasserin aut Three coordination compounds of cobalt with organic carboxylic acids and 1,10-phenanthroline as ligands: syntheses, structures and photocatalytic properties 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer International Publishing Switzerland 2015 Abstract Three cobalt-based coordination compounds, [$ Co_{2} $(phen)4($ H_{2} $qptb)]($ H_{3} $qptb)2 (1), [$ Co_{2} $(phen)4($ H_{2} $dczpb)2]·$ 5H_{2} $O (2) and [$ Co_{2} $(phen)4($ H_{2} $odpa)2($ H_{2} $O)2]·$ 2H_{2} $O (3), were obtained from mixtures of quaterphenyl-4,2″,5″,4′-tetracarboxylic acid ($ H_{4} $qptb), 3,4-dicarboxyl-(3′,4′-dicarboxylazophenyl) benzene ($ H_{2} $dczpb), 4,4′-oxydiphthalic acid ($ H_{2} $odpa), along with 1,10-phenanthroline (phen) and cobalt salts by hydrothermal synthesis. Single-crystal X-ray diffraction reveals that complexes 1–3 contain [$ Co_{2} $(phen)4(L)] units, further joined into 3D frameworks via hydrogen-bonding interactions. All three complexes display considerable thermal stability and exhibit selective absorption in the ultraviolet region, as shown by thermogravimetric analysis and UV–Vis diffuse reflectance spectroscopy, respectively. Complex 1 mediates efficient photocatalytic degradation of methylene blue under UV irradiation. Methylene Blue Photocatalytic Activity Phen Co2O3 Photocatalytic Degradation Jing, Huan-Ping aut Zhang, Yan-Qiu aut Wang, Peng aut Gao, Shi-Jie aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 40(2015), 5 vom: 04. Juni, Seite 573-584 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:40 year:2015 number:5 day:04 month:06 pages:573-584 https://doi.org/10.1007/s11243-015-9950-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 40 2015 5 04 06 573-584 |
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10.1007/s11243-015-9950-1 doi (DE-627)OLC2084052998 (DE-He213)s11243-015-9950-1-p DE-627 ger DE-627 rakwb eng 660 VZ Wang, Chong-Chen verfasserin aut Three coordination compounds of cobalt with organic carboxylic acids and 1,10-phenanthroline as ligands: syntheses, structures and photocatalytic properties 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer International Publishing Switzerland 2015 Abstract Three cobalt-based coordination compounds, [$ Co_{2} $(phen)4($ H_{2} $qptb)]($ H_{3} $qptb)2 (1), [$ Co_{2} $(phen)4($ H_{2} $dczpb)2]·$ 5H_{2} $O (2) and [$ Co_{2} $(phen)4($ H_{2} $odpa)2($ H_{2} $O)2]·$ 2H_{2} $O (3), were obtained from mixtures of quaterphenyl-4,2″,5″,4′-tetracarboxylic acid ($ H_{4} $qptb), 3,4-dicarboxyl-(3′,4′-dicarboxylazophenyl) benzene ($ H_{2} $dczpb), 4,4′-oxydiphthalic acid ($ H_{2} $odpa), along with 1,10-phenanthroline (phen) and cobalt salts by hydrothermal synthesis. Single-crystal X-ray diffraction reveals that complexes 1–3 contain [$ Co_{2} $(phen)4(L)] units, further joined into 3D frameworks via hydrogen-bonding interactions. All three complexes display considerable thermal stability and exhibit selective absorption in the ultraviolet region, as shown by thermogravimetric analysis and UV–Vis diffuse reflectance spectroscopy, respectively. Complex 1 mediates efficient photocatalytic degradation of methylene blue under UV irradiation. Methylene Blue Photocatalytic Activity Phen Co2O3 Photocatalytic Degradation Jing, Huan-Ping aut Zhang, Yan-Qiu aut Wang, Peng aut Gao, Shi-Jie aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 40(2015), 5 vom: 04. Juni, Seite 573-584 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:40 year:2015 number:5 day:04 month:06 pages:573-584 https://doi.org/10.1007/s11243-015-9950-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 40 2015 5 04 06 573-584 |
allfields_unstemmed |
10.1007/s11243-015-9950-1 doi (DE-627)OLC2084052998 (DE-He213)s11243-015-9950-1-p DE-627 ger DE-627 rakwb eng 660 VZ Wang, Chong-Chen verfasserin aut Three coordination compounds of cobalt with organic carboxylic acids and 1,10-phenanthroline as ligands: syntheses, structures and photocatalytic properties 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer International Publishing Switzerland 2015 Abstract Three cobalt-based coordination compounds, [$ Co_{2} $(phen)4($ H_{2} $qptb)]($ H_{3} $qptb)2 (1), [$ Co_{2} $(phen)4($ H_{2} $dczpb)2]·$ 5H_{2} $O (2) and [$ Co_{2} $(phen)4($ H_{2} $odpa)2($ H_{2} $O)2]·$ 2H_{2} $O (3), were obtained from mixtures of quaterphenyl-4,2″,5″,4′-tetracarboxylic acid ($ H_{4} $qptb), 3,4-dicarboxyl-(3′,4′-dicarboxylazophenyl) benzene ($ H_{2} $dczpb), 4,4′-oxydiphthalic acid ($ H_{2} $odpa), along with 1,10-phenanthroline (phen) and cobalt salts by hydrothermal synthesis. Single-crystal X-ray diffraction reveals that complexes 1–3 contain [$ Co_{2} $(phen)4(L)] units, further joined into 3D frameworks via hydrogen-bonding interactions. All three complexes display considerable thermal stability and exhibit selective absorption in the ultraviolet region, as shown by thermogravimetric analysis and UV–Vis diffuse reflectance spectroscopy, respectively. Complex 1 mediates efficient photocatalytic degradation of methylene blue under UV irradiation. Methylene Blue Photocatalytic Activity Phen Co2O3 Photocatalytic Degradation Jing, Huan-Ping aut Zhang, Yan-Qiu aut Wang, Peng aut Gao, Shi-Jie aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 40(2015), 5 vom: 04. Juni, Seite 573-584 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:40 year:2015 number:5 day:04 month:06 pages:573-584 https://doi.org/10.1007/s11243-015-9950-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 40 2015 5 04 06 573-584 |
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10.1007/s11243-015-9950-1 doi (DE-627)OLC2084052998 (DE-He213)s11243-015-9950-1-p DE-627 ger DE-627 rakwb eng 660 VZ Wang, Chong-Chen verfasserin aut Three coordination compounds of cobalt with organic carboxylic acids and 1,10-phenanthroline as ligands: syntheses, structures and photocatalytic properties 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer International Publishing Switzerland 2015 Abstract Three cobalt-based coordination compounds, [$ Co_{2} $(phen)4($ H_{2} $qptb)]($ H_{3} $qptb)2 (1), [$ Co_{2} $(phen)4($ H_{2} $dczpb)2]·$ 5H_{2} $O (2) and [$ Co_{2} $(phen)4($ H_{2} $odpa)2($ H_{2} $O)2]·$ 2H_{2} $O (3), were obtained from mixtures of quaterphenyl-4,2″,5″,4′-tetracarboxylic acid ($ H_{4} $qptb), 3,4-dicarboxyl-(3′,4′-dicarboxylazophenyl) benzene ($ H_{2} $dczpb), 4,4′-oxydiphthalic acid ($ H_{2} $odpa), along with 1,10-phenanthroline (phen) and cobalt salts by hydrothermal synthesis. Single-crystal X-ray diffraction reveals that complexes 1–3 contain [$ Co_{2} $(phen)4(L)] units, further joined into 3D frameworks via hydrogen-bonding interactions. All three complexes display considerable thermal stability and exhibit selective absorption in the ultraviolet region, as shown by thermogravimetric analysis and UV–Vis diffuse reflectance spectroscopy, respectively. Complex 1 mediates efficient photocatalytic degradation of methylene blue under UV irradiation. Methylene Blue Photocatalytic Activity Phen Co2O3 Photocatalytic Degradation Jing, Huan-Ping aut Zhang, Yan-Qiu aut Wang, Peng aut Gao, Shi-Jie aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 40(2015), 5 vom: 04. Juni, Seite 573-584 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:40 year:2015 number:5 day:04 month:06 pages:573-584 https://doi.org/10.1007/s11243-015-9950-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 40 2015 5 04 06 573-584 |
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10.1007/s11243-015-9950-1 doi (DE-627)OLC2084052998 (DE-He213)s11243-015-9950-1-p DE-627 ger DE-627 rakwb eng 660 VZ Wang, Chong-Chen verfasserin aut Three coordination compounds of cobalt with organic carboxylic acids and 1,10-phenanthroline as ligands: syntheses, structures and photocatalytic properties 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer International Publishing Switzerland 2015 Abstract Three cobalt-based coordination compounds, [$ Co_{2} $(phen)4($ H_{2} $qptb)]($ H_{3} $qptb)2 (1), [$ Co_{2} $(phen)4($ H_{2} $dczpb)2]·$ 5H_{2} $O (2) and [$ Co_{2} $(phen)4($ H_{2} $odpa)2($ H_{2} $O)2]·$ 2H_{2} $O (3), were obtained from mixtures of quaterphenyl-4,2″,5″,4′-tetracarboxylic acid ($ H_{4} $qptb), 3,4-dicarboxyl-(3′,4′-dicarboxylazophenyl) benzene ($ H_{2} $dczpb), 4,4′-oxydiphthalic acid ($ H_{2} $odpa), along with 1,10-phenanthroline (phen) and cobalt salts by hydrothermal synthesis. Single-crystal X-ray diffraction reveals that complexes 1–3 contain [$ Co_{2} $(phen)4(L)] units, further joined into 3D frameworks via hydrogen-bonding interactions. All three complexes display considerable thermal stability and exhibit selective absorption in the ultraviolet region, as shown by thermogravimetric analysis and UV–Vis diffuse reflectance spectroscopy, respectively. Complex 1 mediates efficient photocatalytic degradation of methylene blue under UV irradiation. Methylene Blue Photocatalytic Activity Phen Co2O3 Photocatalytic Degradation Jing, Huan-Ping aut Zhang, Yan-Qiu aut Wang, Peng aut Gao, Shi-Jie aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 40(2015), 5 vom: 04. Juni, Seite 573-584 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:40 year:2015 number:5 day:04 month:06 pages:573-584 https://doi.org/10.1007/s11243-015-9950-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 40 2015 5 04 06 573-584 |
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Three coordination compounds of cobalt with organic carboxylic acids and 1,10-phenanthroline as ligands: syntheses, structures and photocatalytic properties |
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Three coordination compounds of cobalt with organic carboxylic acids and 1,10-phenanthroline as ligands: syntheses, structures and photocatalytic properties |
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Wang, Chong-Chen |
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Transition metal chemistry |
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Wang, Chong-Chen Jing, Huan-Ping Zhang, Yan-Qiu Wang, Peng Gao, Shi-Jie |
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10.1007/s11243-015-9950-1 |
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three coordination compounds of cobalt with organic carboxylic acids and 1,10-phenanthroline as ligands: syntheses, structures and photocatalytic properties |
title_auth |
Three coordination compounds of cobalt with organic carboxylic acids and 1,10-phenanthroline as ligands: syntheses, structures and photocatalytic properties |
abstract |
Abstract Three cobalt-based coordination compounds, [$ Co_{2} $(phen)4($ H_{2} $qptb)]($ H_{3} $qptb)2 (1), [$ Co_{2} $(phen)4($ H_{2} $dczpb)2]·$ 5H_{2} $O (2) and [$ Co_{2} $(phen)4($ H_{2} $odpa)2($ H_{2} $O)2]·$ 2H_{2} $O (3), were obtained from mixtures of quaterphenyl-4,2″,5″,4′-tetracarboxylic acid ($ H_{4} $qptb), 3,4-dicarboxyl-(3′,4′-dicarboxylazophenyl) benzene ($ H_{2} $dczpb), 4,4′-oxydiphthalic acid ($ H_{2} $odpa), along with 1,10-phenanthroline (phen) and cobalt salts by hydrothermal synthesis. Single-crystal X-ray diffraction reveals that complexes 1–3 contain [$ Co_{2} $(phen)4(L)] units, further joined into 3D frameworks via hydrogen-bonding interactions. All three complexes display considerable thermal stability and exhibit selective absorption in the ultraviolet region, as shown by thermogravimetric analysis and UV–Vis diffuse reflectance spectroscopy, respectively. Complex 1 mediates efficient photocatalytic degradation of methylene blue under UV irradiation. © Springer International Publishing Switzerland 2015 |
abstractGer |
Abstract Three cobalt-based coordination compounds, [$ Co_{2} $(phen)4($ H_{2} $qptb)]($ H_{3} $qptb)2 (1), [$ Co_{2} $(phen)4($ H_{2} $dczpb)2]·$ 5H_{2} $O (2) and [$ Co_{2} $(phen)4($ H_{2} $odpa)2($ H_{2} $O)2]·$ 2H_{2} $O (3), were obtained from mixtures of quaterphenyl-4,2″,5″,4′-tetracarboxylic acid ($ H_{4} $qptb), 3,4-dicarboxyl-(3′,4′-dicarboxylazophenyl) benzene ($ H_{2} $dczpb), 4,4′-oxydiphthalic acid ($ H_{2} $odpa), along with 1,10-phenanthroline (phen) and cobalt salts by hydrothermal synthesis. Single-crystal X-ray diffraction reveals that complexes 1–3 contain [$ Co_{2} $(phen)4(L)] units, further joined into 3D frameworks via hydrogen-bonding interactions. All three complexes display considerable thermal stability and exhibit selective absorption in the ultraviolet region, as shown by thermogravimetric analysis and UV–Vis diffuse reflectance spectroscopy, respectively. Complex 1 mediates efficient photocatalytic degradation of methylene blue under UV irradiation. © Springer International Publishing Switzerland 2015 |
abstract_unstemmed |
Abstract Three cobalt-based coordination compounds, [$ Co_{2} $(phen)4($ H_{2} $qptb)]($ H_{3} $qptb)2 (1), [$ Co_{2} $(phen)4($ H_{2} $dczpb)2]·$ 5H_{2} $O (2) and [$ Co_{2} $(phen)4($ H_{2} $odpa)2($ H_{2} $O)2]·$ 2H_{2} $O (3), were obtained from mixtures of quaterphenyl-4,2″,5″,4′-tetracarboxylic acid ($ H_{4} $qptb), 3,4-dicarboxyl-(3′,4′-dicarboxylazophenyl) benzene ($ H_{2} $dczpb), 4,4′-oxydiphthalic acid ($ H_{2} $odpa), along with 1,10-phenanthroline (phen) and cobalt salts by hydrothermal synthesis. Single-crystal X-ray diffraction reveals that complexes 1–3 contain [$ Co_{2} $(phen)4(L)] units, further joined into 3D frameworks via hydrogen-bonding interactions. All three complexes display considerable thermal stability and exhibit selective absorption in the ultraviolet region, as shown by thermogravimetric analysis and UV–Vis diffuse reflectance spectroscopy, respectively. Complex 1 mediates efficient photocatalytic degradation of methylene blue under UV irradiation. © Springer International Publishing Switzerland 2015 |
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title_short |
Three coordination compounds of cobalt with organic carboxylic acids and 1,10-phenanthroline as ligands: syntheses, structures and photocatalytic properties |
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https://doi.org/10.1007/s11243-015-9950-1 |
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