Two double end-on cyanato-bridged dinuclear manganese(II) complexes exhibiting abnormal magnetic coupling for the Mn(II)–N–Mn(II) linkage
Abstract Two cyanato-bridged dinuclear Mn(II) complexes [$ Mn_{2} $(phen)4(μ1,1-NCO)2][$ M^{III} $(bpb)(CN)2]·$ H_{2} $O [M = Fe (1) or Co (2)], [phen = 1,10-phenanthroline, $ bpb^{2−} $ = 1,2-bis(pyridine-2-carboxamido)benzenate] have been synthesized using the synthetic strategy of big anion induc...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Yang, Daisheng [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2015 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer International Publishing Switzerland 2015 |
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| Übergeordnetes Werk: |
Enthalten in: Transition metal chemistry - Springer International Publishing, 1975, 40(2015), 7 vom: 21. Aug., Seite 749-754 |
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| Übergeordnetes Werk: |
volume:40 ; year:2015 ; number:7 ; day:21 ; month:08 ; pages:749-754 |
| Links: |
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| DOI / URN: |
10.1007/s11243-015-9970-x |
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| Katalog-ID: |
OLC2084053390 |
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| 520 | |a Abstract Two cyanato-bridged dinuclear Mn(II) complexes [$ Mn_{2} $(phen)4(μ1,1-NCO)2][$ M^{III} $(bpb)(CN)2]·$ H_{2} $O [M = Fe (1) or Co (2)], [phen = 1,10-phenanthroline, $ bpb^{2−} $ = 1,2-bis(pyridine-2-carboxamido)benzenate] have been synthesized using the synthetic strategy of big anion inducement. Single-crystal X-ray diffraction analysis reveals that both complexes consist of a double end-on (EO) cyanato-bridged dinuclear Mn(II) unit and two free [M(bpb)(CN)2]− building blocks acting as counter-ions. Magnetic studies show the presence of abnormal antiferromagnetic interactions between the two Mn(II) centers through the EO cyanate bridge with J = −1.58(3) $ cm^{−1} $ for complex 1 and −1.82(2) $ cm^{−1} $ for complex 2. The unusual antiferromagnetic interactions of these complexes can be attributed to their small Mn(II)–N–Mn(II) angles. | ||
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| 700 | 1 | |a Zhang, Lifang |4 aut | |
| 700 | 1 | |a Ni, Zhonghai |4 aut | |
| 700 | 1 | |a Wang, Wenfeng |4 aut | |
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10.1007/s11243-015-9970-x doi (DE-627)OLC2084053390 (DE-He213)s11243-015-9970-x-p DE-627 ger DE-627 rakwb eng 660 VZ Yang, Daisheng verfasserin aut Two double end-on cyanato-bridged dinuclear manganese(II) complexes exhibiting abnormal magnetic coupling for the Mn(II)–N–Mn(II) linkage 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer International Publishing Switzerland 2015 Abstract Two cyanato-bridged dinuclear Mn(II) complexes [$ Mn_{2} $(phen)4(μ1,1-NCO)2][$ M^{III} $(bpb)(CN)2]·$ H_{2} $O [M = Fe (1) or Co (2)], [phen = 1,10-phenanthroline, $ bpb^{2−} $ = 1,2-bis(pyridine-2-carboxamido)benzenate] have been synthesized using the synthetic strategy of big anion inducement. Single-crystal X-ray diffraction analysis reveals that both complexes consist of a double end-on (EO) cyanato-bridged dinuclear Mn(II) unit and two free [M(bpb)(CN)2]− building blocks acting as counter-ions. Magnetic studies show the presence of abnormal antiferromagnetic interactions between the two Mn(II) centers through the EO cyanate bridge with J = −1.58(3) $ cm^{−1} $ for complex 1 and −1.82(2) $ cm^{−1} $ for complex 2. The unusual antiferromagnetic interactions of these complexes can be attributed to their small Mn(II)–N–Mn(II) angles. Phen Magnetic Coupling Antiferromagnetic Interaction Antiferromagnetic Coupling Molar Magnetic Susceptibility Zhang, Zhaoming aut Zhang, Lifang aut Ni, Zhonghai aut Wang, Wenfeng aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 40(2015), 7 vom: 21. Aug., Seite 749-754 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:40 year:2015 number:7 day:21 month:08 pages:749-754 https://doi.org/10.1007/s11243-015-9970-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 40 2015 7 21 08 749-754 |
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10.1007/s11243-015-9970-x doi (DE-627)OLC2084053390 (DE-He213)s11243-015-9970-x-p DE-627 ger DE-627 rakwb eng 660 VZ Yang, Daisheng verfasserin aut Two double end-on cyanato-bridged dinuclear manganese(II) complexes exhibiting abnormal magnetic coupling for the Mn(II)–N–Mn(II) linkage 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer International Publishing Switzerland 2015 Abstract Two cyanato-bridged dinuclear Mn(II) complexes [$ Mn_{2} $(phen)4(μ1,1-NCO)2][$ M^{III} $(bpb)(CN)2]·$ H_{2} $O [M = Fe (1) or Co (2)], [phen = 1,10-phenanthroline, $ bpb^{2−} $ = 1,2-bis(pyridine-2-carboxamido)benzenate] have been synthesized using the synthetic strategy of big anion inducement. Single-crystal X-ray diffraction analysis reveals that both complexes consist of a double end-on (EO) cyanato-bridged dinuclear Mn(II) unit and two free [M(bpb)(CN)2]− building blocks acting as counter-ions. Magnetic studies show the presence of abnormal antiferromagnetic interactions between the two Mn(II) centers through the EO cyanate bridge with J = −1.58(3) $ cm^{−1} $ for complex 1 and −1.82(2) $ cm^{−1} $ for complex 2. The unusual antiferromagnetic interactions of these complexes can be attributed to their small Mn(II)–N–Mn(II) angles. Phen Magnetic Coupling Antiferromagnetic Interaction Antiferromagnetic Coupling Molar Magnetic Susceptibility Zhang, Zhaoming aut Zhang, Lifang aut Ni, Zhonghai aut Wang, Wenfeng aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 40(2015), 7 vom: 21. Aug., Seite 749-754 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:40 year:2015 number:7 day:21 month:08 pages:749-754 https://doi.org/10.1007/s11243-015-9970-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 40 2015 7 21 08 749-754 |
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10.1007/s11243-015-9970-x doi (DE-627)OLC2084053390 (DE-He213)s11243-015-9970-x-p DE-627 ger DE-627 rakwb eng 660 VZ Yang, Daisheng verfasserin aut Two double end-on cyanato-bridged dinuclear manganese(II) complexes exhibiting abnormal magnetic coupling for the Mn(II)–N–Mn(II) linkage 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer International Publishing Switzerland 2015 Abstract Two cyanato-bridged dinuclear Mn(II) complexes [$ Mn_{2} $(phen)4(μ1,1-NCO)2][$ M^{III} $(bpb)(CN)2]·$ H_{2} $O [M = Fe (1) or Co (2)], [phen = 1,10-phenanthroline, $ bpb^{2−} $ = 1,2-bis(pyridine-2-carboxamido)benzenate] have been synthesized using the synthetic strategy of big anion inducement. Single-crystal X-ray diffraction analysis reveals that both complexes consist of a double end-on (EO) cyanato-bridged dinuclear Mn(II) unit and two free [M(bpb)(CN)2]− building blocks acting as counter-ions. Magnetic studies show the presence of abnormal antiferromagnetic interactions between the two Mn(II) centers through the EO cyanate bridge with J = −1.58(3) $ cm^{−1} $ for complex 1 and −1.82(2) $ cm^{−1} $ for complex 2. The unusual antiferromagnetic interactions of these complexes can be attributed to their small Mn(II)–N–Mn(II) angles. Phen Magnetic Coupling Antiferromagnetic Interaction Antiferromagnetic Coupling Molar Magnetic Susceptibility Zhang, Zhaoming aut Zhang, Lifang aut Ni, Zhonghai aut Wang, Wenfeng aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 40(2015), 7 vom: 21. Aug., Seite 749-754 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:40 year:2015 number:7 day:21 month:08 pages:749-754 https://doi.org/10.1007/s11243-015-9970-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 40 2015 7 21 08 749-754 |
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10.1007/s11243-015-9970-x doi (DE-627)OLC2084053390 (DE-He213)s11243-015-9970-x-p DE-627 ger DE-627 rakwb eng 660 VZ Yang, Daisheng verfasserin aut Two double end-on cyanato-bridged dinuclear manganese(II) complexes exhibiting abnormal magnetic coupling for the Mn(II)–N–Mn(II) linkage 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer International Publishing Switzerland 2015 Abstract Two cyanato-bridged dinuclear Mn(II) complexes [$ Mn_{2} $(phen)4(μ1,1-NCO)2][$ M^{III} $(bpb)(CN)2]·$ H_{2} $O [M = Fe (1) or Co (2)], [phen = 1,10-phenanthroline, $ bpb^{2−} $ = 1,2-bis(pyridine-2-carboxamido)benzenate] have been synthesized using the synthetic strategy of big anion inducement. Single-crystal X-ray diffraction analysis reveals that both complexes consist of a double end-on (EO) cyanato-bridged dinuclear Mn(II) unit and two free [M(bpb)(CN)2]− building blocks acting as counter-ions. Magnetic studies show the presence of abnormal antiferromagnetic interactions between the two Mn(II) centers through the EO cyanate bridge with J = −1.58(3) $ cm^{−1} $ for complex 1 and −1.82(2) $ cm^{−1} $ for complex 2. The unusual antiferromagnetic interactions of these complexes can be attributed to their small Mn(II)–N–Mn(II) angles. Phen Magnetic Coupling Antiferromagnetic Interaction Antiferromagnetic Coupling Molar Magnetic Susceptibility Zhang, Zhaoming aut Zhang, Lifang aut Ni, Zhonghai aut Wang, Wenfeng aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 40(2015), 7 vom: 21. Aug., Seite 749-754 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:40 year:2015 number:7 day:21 month:08 pages:749-754 https://doi.org/10.1007/s11243-015-9970-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 40 2015 7 21 08 749-754 |
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10.1007/s11243-015-9970-x doi (DE-627)OLC2084053390 (DE-He213)s11243-015-9970-x-p DE-627 ger DE-627 rakwb eng 660 VZ Yang, Daisheng verfasserin aut Two double end-on cyanato-bridged dinuclear manganese(II) complexes exhibiting abnormal magnetic coupling for the Mn(II)–N–Mn(II) linkage 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer International Publishing Switzerland 2015 Abstract Two cyanato-bridged dinuclear Mn(II) complexes [$ Mn_{2} $(phen)4(μ1,1-NCO)2][$ M^{III} $(bpb)(CN)2]·$ H_{2} $O [M = Fe (1) or Co (2)], [phen = 1,10-phenanthroline, $ bpb^{2−} $ = 1,2-bis(pyridine-2-carboxamido)benzenate] have been synthesized using the synthetic strategy of big anion inducement. Single-crystal X-ray diffraction analysis reveals that both complexes consist of a double end-on (EO) cyanato-bridged dinuclear Mn(II) unit and two free [M(bpb)(CN)2]− building blocks acting as counter-ions. Magnetic studies show the presence of abnormal antiferromagnetic interactions between the two Mn(II) centers through the EO cyanate bridge with J = −1.58(3) $ cm^{−1} $ for complex 1 and −1.82(2) $ cm^{−1} $ for complex 2. The unusual antiferromagnetic interactions of these complexes can be attributed to their small Mn(II)–N–Mn(II) angles. Phen Magnetic Coupling Antiferromagnetic Interaction Antiferromagnetic Coupling Molar Magnetic Susceptibility Zhang, Zhaoming aut Zhang, Lifang aut Ni, Zhonghai aut Wang, Wenfeng aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 40(2015), 7 vom: 21. Aug., Seite 749-754 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:40 year:2015 number:7 day:21 month:08 pages:749-754 https://doi.org/10.1007/s11243-015-9970-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_4012 GBV_ILN_4125 AR 40 2015 7 21 08 749-754 |
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Yang, Daisheng Zhang, Zhaoming Zhang, Lifang Ni, Zhonghai Wang, Wenfeng |
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Yang, Daisheng |
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two double end-on cyanato-bridged dinuclear manganese(ii) complexes exhibiting abnormal magnetic coupling for the mn(ii)–n–mn(ii) linkage |
| title_auth |
Two double end-on cyanato-bridged dinuclear manganese(II) complexes exhibiting abnormal magnetic coupling for the Mn(II)–N–Mn(II) linkage |
| abstract |
Abstract Two cyanato-bridged dinuclear Mn(II) complexes [$ Mn_{2} $(phen)4(μ1,1-NCO)2][$ M^{III} $(bpb)(CN)2]·$ H_{2} $O [M = Fe (1) or Co (2)], [phen = 1,10-phenanthroline, $ bpb^{2−} $ = 1,2-bis(pyridine-2-carboxamido)benzenate] have been synthesized using the synthetic strategy of big anion inducement. Single-crystal X-ray diffraction analysis reveals that both complexes consist of a double end-on (EO) cyanato-bridged dinuclear Mn(II) unit and two free [M(bpb)(CN)2]− building blocks acting as counter-ions. Magnetic studies show the presence of abnormal antiferromagnetic interactions between the two Mn(II) centers through the EO cyanate bridge with J = −1.58(3) $ cm^{−1} $ for complex 1 and −1.82(2) $ cm^{−1} $ for complex 2. The unusual antiferromagnetic interactions of these complexes can be attributed to their small Mn(II)–N–Mn(II) angles. © Springer International Publishing Switzerland 2015 |
| abstractGer |
Abstract Two cyanato-bridged dinuclear Mn(II) complexes [$ Mn_{2} $(phen)4(μ1,1-NCO)2][$ M^{III} $(bpb)(CN)2]·$ H_{2} $O [M = Fe (1) or Co (2)], [phen = 1,10-phenanthroline, $ bpb^{2−} $ = 1,2-bis(pyridine-2-carboxamido)benzenate] have been synthesized using the synthetic strategy of big anion inducement. Single-crystal X-ray diffraction analysis reveals that both complexes consist of a double end-on (EO) cyanato-bridged dinuclear Mn(II) unit and two free [M(bpb)(CN)2]− building blocks acting as counter-ions. Magnetic studies show the presence of abnormal antiferromagnetic interactions between the two Mn(II) centers through the EO cyanate bridge with J = −1.58(3) $ cm^{−1} $ for complex 1 and −1.82(2) $ cm^{−1} $ for complex 2. The unusual antiferromagnetic interactions of these complexes can be attributed to their small Mn(II)–N–Mn(II) angles. © Springer International Publishing Switzerland 2015 |
| abstract_unstemmed |
Abstract Two cyanato-bridged dinuclear Mn(II) complexes [$ Mn_{2} $(phen)4(μ1,1-NCO)2][$ M^{III} $(bpb)(CN)2]·$ H_{2} $O [M = Fe (1) or Co (2)], [phen = 1,10-phenanthroline, $ bpb^{2−} $ = 1,2-bis(pyridine-2-carboxamido)benzenate] have been synthesized using the synthetic strategy of big anion inducement. Single-crystal X-ray diffraction analysis reveals that both complexes consist of a double end-on (EO) cyanato-bridged dinuclear Mn(II) unit and two free [M(bpb)(CN)2]− building blocks acting as counter-ions. Magnetic studies show the presence of abnormal antiferromagnetic interactions between the two Mn(II) centers through the EO cyanate bridge with J = −1.58(3) $ cm^{−1} $ for complex 1 and −1.82(2) $ cm^{−1} $ for complex 2. The unusual antiferromagnetic interactions of these complexes can be attributed to their small Mn(II)–N–Mn(II) angles. © Springer International Publishing Switzerland 2015 |
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7 |
| title_short |
Two double end-on cyanato-bridged dinuclear manganese(II) complexes exhibiting abnormal magnetic coupling for the Mn(II)–N–Mn(II) linkage |
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Zhang, Zhaoming Zhang, Lifang Ni, Zhonghai Wang, Wenfeng |
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