Complex magnetic differentiation of cobalts in $ Na_{x} $$ CoO_{2} $ with 22 K Néel temperature
Abstract Single crystals of sodium cobaltates $ Na_{x} $$ CoO_{2} $ with x ≈ 0.8 were grown by the floating zone technique. Using electrochemical Na de-intercalation method we reduced the sodium content in the as-grown crystals down to pure phase with 22 K Néel temperature and x ≈ 0.77. The 59Co NMR...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Mukhamedshin, I. R. [verfasserIn] |
|---|
| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2014 |
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| Schlagwörter: |
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| Anmerkung: |
© Pleiades Publishing, Inc. 2014 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of experimental and theoretical physics / JETP letters - Pleiades Publishing, 1993, 99(2014), 8 vom: Juni, Seite 471-475 |
|---|---|
| Übergeordnetes Werk: |
volume:99 ; year:2014 ; number:8 ; month:06 ; pages:471-475 |
| Links: |
|---|
| DOI / URN: |
10.1134/S0021364014080116 |
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OLC2085803075 |
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| 520 | |a Abstract Single crystals of sodium cobaltates $ Na_{x} $$ CoO_{2} $ with x ≈ 0.8 were grown by the floating zone technique. Using electrochemical Na de-intercalation method we reduced the sodium content in the as-grown crystals down to pure phase with 22 K Néel temperature and x ≈ 0.77. The 59Co NMR study in the paramagnetic state of the TN = 22 K phase permitted us to evidence that at least 6 Co sites are differentiated. They could be separated by their magnetic behavior into three types: a single site with cobalt close to non-magnetic $ Co^{3+} $, two sites with the most magnetic cobalts in the system, and the remaining three sites displaying an intermediate behavior. This unusual magnetic differentiation calls for more detailed NMR experiments on our well characterized samples. | ||
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| 700 | 1 | |a Salosin, M. A. |4 aut | |
| 700 | 1 | |a Alloul, H. |4 aut | |
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10.1134/S0021364014080116 doi (DE-627)OLC2085803075 (DE-He213)S0021364014080116-p DE-627 ger DE-627 rakwb eng 530 VZ 33.00 bkl Mukhamedshin, I. R. verfasserin aut Complex magnetic differentiation of cobalts in $ Na_{x} $$ CoO_{2} $ with 22 K Néel temperature 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Inc. 2014 Abstract Single crystals of sodium cobaltates $ Na_{x} $$ CoO_{2} $ with x ≈ 0.8 were grown by the floating zone technique. Using electrochemical Na de-intercalation method we reduced the sodium content in the as-grown crystals down to pure phase with 22 K Néel temperature and x ≈ 0.77. The 59Co NMR study in the paramagnetic state of the TN = 22 K phase permitted us to evidence that at least 6 Co sites are differentiated. They could be separated by their magnetic behavior into three types: a single site with cobalt close to non-magnetic $ Co^{3+} $, two sites with the most magnetic cobalts in the system, and the remaining three sites displaying an intermediate behavior. This unusual magnetic differentiation calls for more detailed NMR experiments on our well characterized samples. JETP Letter Sodium Content Grown Crystal Charge Disproportionation Crystal Ingot Gilmutdinov, I. F. aut Salosin, M. A. aut Alloul, H. aut Enthalten in Journal of experimental and theoretical physics / JETP letters Pleiades Publishing, 1993 99(2014), 8 vom: Juni, Seite 471-475 (DE-627)182384713 (DE-600)917787-5 (DE-576)053745841 0021-3640 nnns volume:99 year:2014 number:8 month:06 pages:471-475 https://doi.org/10.1134/S0021364014080116 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY 33.00 VZ AR 99 2014 8 06 471-475 |
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10.1134/S0021364014080116 doi (DE-627)OLC2085803075 (DE-He213)S0021364014080116-p DE-627 ger DE-627 rakwb eng 530 VZ 33.00 bkl Mukhamedshin, I. R. verfasserin aut Complex magnetic differentiation of cobalts in $ Na_{x} $$ CoO_{2} $ with 22 K Néel temperature 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Inc. 2014 Abstract Single crystals of sodium cobaltates $ Na_{x} $$ CoO_{2} $ with x ≈ 0.8 were grown by the floating zone technique. Using electrochemical Na de-intercalation method we reduced the sodium content in the as-grown crystals down to pure phase with 22 K Néel temperature and x ≈ 0.77. The 59Co NMR study in the paramagnetic state of the TN = 22 K phase permitted us to evidence that at least 6 Co sites are differentiated. They could be separated by their magnetic behavior into three types: a single site with cobalt close to non-magnetic $ Co^{3+} $, two sites with the most magnetic cobalts in the system, and the remaining three sites displaying an intermediate behavior. This unusual magnetic differentiation calls for more detailed NMR experiments on our well characterized samples. JETP Letter Sodium Content Grown Crystal Charge Disproportionation Crystal Ingot Gilmutdinov, I. F. aut Salosin, M. A. aut Alloul, H. aut Enthalten in Journal of experimental and theoretical physics / JETP letters Pleiades Publishing, 1993 99(2014), 8 vom: Juni, Seite 471-475 (DE-627)182384713 (DE-600)917787-5 (DE-576)053745841 0021-3640 nnns volume:99 year:2014 number:8 month:06 pages:471-475 https://doi.org/10.1134/S0021364014080116 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY 33.00 VZ AR 99 2014 8 06 471-475 |
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10.1134/S0021364014080116 doi (DE-627)OLC2085803075 (DE-He213)S0021364014080116-p DE-627 ger DE-627 rakwb eng 530 VZ 33.00 bkl Mukhamedshin, I. R. verfasserin aut Complex magnetic differentiation of cobalts in $ Na_{x} $$ CoO_{2} $ with 22 K Néel temperature 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Inc. 2014 Abstract Single crystals of sodium cobaltates $ Na_{x} $$ CoO_{2} $ with x ≈ 0.8 were grown by the floating zone technique. Using electrochemical Na de-intercalation method we reduced the sodium content in the as-grown crystals down to pure phase with 22 K Néel temperature and x ≈ 0.77. The 59Co NMR study in the paramagnetic state of the TN = 22 K phase permitted us to evidence that at least 6 Co sites are differentiated. They could be separated by their magnetic behavior into three types: a single site with cobalt close to non-magnetic $ Co^{3+} $, two sites with the most magnetic cobalts in the system, and the remaining three sites displaying an intermediate behavior. This unusual magnetic differentiation calls for more detailed NMR experiments on our well characterized samples. JETP Letter Sodium Content Grown Crystal Charge Disproportionation Crystal Ingot Gilmutdinov, I. F. aut Salosin, M. A. aut Alloul, H. aut Enthalten in Journal of experimental and theoretical physics / JETP letters Pleiades Publishing, 1993 99(2014), 8 vom: Juni, Seite 471-475 (DE-627)182384713 (DE-600)917787-5 (DE-576)053745841 0021-3640 nnns volume:99 year:2014 number:8 month:06 pages:471-475 https://doi.org/10.1134/S0021364014080116 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY 33.00 VZ AR 99 2014 8 06 471-475 |
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10.1134/S0021364014080116 doi (DE-627)OLC2085803075 (DE-He213)S0021364014080116-p DE-627 ger DE-627 rakwb eng 530 VZ 33.00 bkl Mukhamedshin, I. R. verfasserin aut Complex magnetic differentiation of cobalts in $ Na_{x} $$ CoO_{2} $ with 22 K Néel temperature 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Inc. 2014 Abstract Single crystals of sodium cobaltates $ Na_{x} $$ CoO_{2} $ with x ≈ 0.8 were grown by the floating zone technique. Using electrochemical Na de-intercalation method we reduced the sodium content in the as-grown crystals down to pure phase with 22 K Néel temperature and x ≈ 0.77. The 59Co NMR study in the paramagnetic state of the TN = 22 K phase permitted us to evidence that at least 6 Co sites are differentiated. They could be separated by their magnetic behavior into three types: a single site with cobalt close to non-magnetic $ Co^{3+} $, two sites with the most magnetic cobalts in the system, and the remaining three sites displaying an intermediate behavior. This unusual magnetic differentiation calls for more detailed NMR experiments on our well characterized samples. JETP Letter Sodium Content Grown Crystal Charge Disproportionation Crystal Ingot Gilmutdinov, I. F. aut Salosin, M. A. aut Alloul, H. aut Enthalten in Journal of experimental and theoretical physics / JETP letters Pleiades Publishing, 1993 99(2014), 8 vom: Juni, Seite 471-475 (DE-627)182384713 (DE-600)917787-5 (DE-576)053745841 0021-3640 nnns volume:99 year:2014 number:8 month:06 pages:471-475 https://doi.org/10.1134/S0021364014080116 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY 33.00 VZ AR 99 2014 8 06 471-475 |
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10.1134/S0021364014080116 doi (DE-627)OLC2085803075 (DE-He213)S0021364014080116-p DE-627 ger DE-627 rakwb eng 530 VZ 33.00 bkl Mukhamedshin, I. R. verfasserin aut Complex magnetic differentiation of cobalts in $ Na_{x} $$ CoO_{2} $ with 22 K Néel temperature 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Inc. 2014 Abstract Single crystals of sodium cobaltates $ Na_{x} $$ CoO_{2} $ with x ≈ 0.8 were grown by the floating zone technique. Using electrochemical Na de-intercalation method we reduced the sodium content in the as-grown crystals down to pure phase with 22 K Néel temperature and x ≈ 0.77. The 59Co NMR study in the paramagnetic state of the TN = 22 K phase permitted us to evidence that at least 6 Co sites are differentiated. They could be separated by their magnetic behavior into three types: a single site with cobalt close to non-magnetic $ Co^{3+} $, two sites with the most magnetic cobalts in the system, and the remaining three sites displaying an intermediate behavior. This unusual magnetic differentiation calls for more detailed NMR experiments on our well characterized samples. JETP Letter Sodium Content Grown Crystal Charge Disproportionation Crystal Ingot Gilmutdinov, I. F. aut Salosin, M. A. aut Alloul, H. aut Enthalten in Journal of experimental and theoretical physics / JETP letters Pleiades Publishing, 1993 99(2014), 8 vom: Juni, Seite 471-475 (DE-627)182384713 (DE-600)917787-5 (DE-576)053745841 0021-3640 nnns volume:99 year:2014 number:8 month:06 pages:471-475 https://doi.org/10.1134/S0021364014080116 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY 33.00 VZ AR 99 2014 8 06 471-475 |
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Complex magnetic differentiation of cobalts in $ Na_{x} $$ CoO_{2} $ with 22 K Néel temperature |
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Abstract Single crystals of sodium cobaltates $ Na_{x} $$ CoO_{2} $ with x ≈ 0.8 were grown by the floating zone technique. Using electrochemical Na de-intercalation method we reduced the sodium content in the as-grown crystals down to pure phase with 22 K Néel temperature and x ≈ 0.77. The 59Co NMR study in the paramagnetic state of the TN = 22 K phase permitted us to evidence that at least 6 Co sites are differentiated. They could be separated by their magnetic behavior into three types: a single site with cobalt close to non-magnetic $ Co^{3+} $, two sites with the most magnetic cobalts in the system, and the remaining three sites displaying an intermediate behavior. This unusual magnetic differentiation calls for more detailed NMR experiments on our well characterized samples. © Pleiades Publishing, Inc. 2014 |
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Abstract Single crystals of sodium cobaltates $ Na_{x} $$ CoO_{2} $ with x ≈ 0.8 were grown by the floating zone technique. Using electrochemical Na de-intercalation method we reduced the sodium content in the as-grown crystals down to pure phase with 22 K Néel temperature and x ≈ 0.77. The 59Co NMR study in the paramagnetic state of the TN = 22 K phase permitted us to evidence that at least 6 Co sites are differentiated. They could be separated by their magnetic behavior into three types: a single site with cobalt close to non-magnetic $ Co^{3+} $, two sites with the most magnetic cobalts in the system, and the remaining three sites displaying an intermediate behavior. This unusual magnetic differentiation calls for more detailed NMR experiments on our well characterized samples. © Pleiades Publishing, Inc. 2014 |
| abstract_unstemmed |
Abstract Single crystals of sodium cobaltates $ Na_{x} $$ CoO_{2} $ with x ≈ 0.8 were grown by the floating zone technique. Using electrochemical Na de-intercalation method we reduced the sodium content in the as-grown crystals down to pure phase with 22 K Néel temperature and x ≈ 0.77. The 59Co NMR study in the paramagnetic state of the TN = 22 K phase permitted us to evidence that at least 6 Co sites are differentiated. They could be separated by their magnetic behavior into three types: a single site with cobalt close to non-magnetic $ Co^{3+} $, two sites with the most magnetic cobalts in the system, and the remaining three sites displaying an intermediate behavior. This unusual magnetic differentiation calls for more detailed NMR experiments on our well characterized samples. © Pleiades Publishing, Inc. 2014 |
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Complex magnetic differentiation of cobalts in $ Na_{x} $$ CoO_{2} $ with 22 K Néel temperature |
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https://doi.org/10.1134/S0021364014080116 |
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Gilmutdinov, I. F. Salosin, M. A. Alloul, H. |
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Gilmutdinov, I. F. Salosin, M. A. Alloul, H. |
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182384713 |
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10.1134/S0021364014080116 |
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2024-07-04T07:57:13.761Z |
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