Synthesis, magnetic and spectral studies on polystyrene-anchored coordination complexes of bi-, tri-, tetra- and hexavalent metal ions with unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide
Abstract Polystyrene-anchored Cu(II), Zn(II), Cd(II), Ni(II), Mn(II), $ MoO_{2} $(II), $ UO_{2} $(II), Fe(III) and Zr(IV), complexes of the unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from the condensation of chloromethylated polystyrene, 3-formylsalicylic acid, ethylenediamine...
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| Autor*in: |
Kumar, Dinesh [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2009 |
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| Schlagwörter: |
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| Anmerkung: |
© Indian Academy of Sciences 2009 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of chemical sciences - Springer-Verlag, 2004, 121(2009), 1 vom: Jan., Seite 57-64 |
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| Übergeordnetes Werk: |
volume:121 ; year:2009 ; number:1 ; month:01 ; pages:57-64 |
| Links: |
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| DOI / URN: |
10.1007/s12039-009-0006-y |
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| Katalog-ID: |
OLC210275619X |
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| 100 | 1 | |a Kumar, Dinesh |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Synthesis, magnetic and spectral studies on polystyrene-anchored coordination complexes of bi-, tri-, tetra- and hexavalent metal ions with unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide |
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| 520 | |a Abstract Polystyrene-anchored Cu(II), Zn(II), Cd(II), Ni(II), Mn(II), $ MoO_{2} $(II), $ UO_{2} $(II), Fe(III) and Zr(IV), complexes of the unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from the condensation of chloromethylated polystyrene, 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide (PS-$ LH_{2} $) has been synthesized. The polystyrene anchored complexes have the formulae: PS-LM (where M = Cu, Zn, Cd, Ni, $ MoO_{2} $, $ UO_{2} $), PS-LFeCl·DMF, PS-LMn·2DMF and PS-LZr(OH)2·DMF. The polystyrene-anchored coordination compounds have been characterized by elemental analysis, IR, reflectance, ESR and magnetic susceptibility measurements. The per cent reaction conversion of polystyrene anchored Schiff base to polystyrene supported coordination compounds lies between 28·98 and 85·9. The coordinated dimethylformamide is completely lost on heating the complexes. The shifts of the ν(C=N)(azomethine) and ν(C-O)(phenolic) stretches have been monitored in order to find out the donor sites of the ligands. The Cu(II) complex is paramagnetic with square planar structure; the Ni(II) complex is diamagnetic with square planar structure; the Zn(II) and Cd(II) complexes are diamagnetic and have tetrahedral structure; the Mn(II) and Fe(III) complexes are paramagnetic and have octahedral structure; the $ MoO_{2} $(II) and $ UO_{2} $(II) complexes are diamagnetic and have octahedral structure and the Zr(IV) complexes are diamagnetic and have pentagonal bipyramidal structure. | ||
| 650 | 4 | |a Polystyrene-anchored ligands | |
| 650 | 4 | |a polystyrene-anchored complexes | |
| 650 | 4 | |a tetradentate | |
| 650 | 4 | |a IR | |
| 650 | 4 | |a reflectance | |
| 650 | 4 | |a ESSR and magnetic susceptibility measurements | |
| 700 | 1 | |a Syamal, Arun |4 aut | |
| 700 | 1 | |a Sharma, Lalit Kumar |4 aut | |
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35.00$jChemie: Allgemeines 35.04$jAusbildung$jBeruf$jOrganisationen$XChemie |
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10.1007/s12039-009-0006-y doi (DE-627)OLC210275619X (DE-He213)s12039-009-0006-y-p DE-627 ger DE-627 rakwb eng 000 500 060 VZ 35.00$jChemie: Allgemeines bkl 35.04$jAusbildung$jBeruf$jOrganisationen$XChemie bkl Kumar, Dinesh verfasserin aut Synthesis, magnetic and spectral studies on polystyrene-anchored coordination complexes of bi-, tri-, tetra- and hexavalent metal ions with unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Indian Academy of Sciences 2009 Abstract Polystyrene-anchored Cu(II), Zn(II), Cd(II), Ni(II), Mn(II), $ MoO_{2} $(II), $ UO_{2} $(II), Fe(III) and Zr(IV), complexes of the unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from the condensation of chloromethylated polystyrene, 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide (PS-$ LH_{2} $) has been synthesized. The polystyrene anchored complexes have the formulae: PS-LM (where M = Cu, Zn, Cd, Ni, $ MoO_{2} $, $ UO_{2} $), PS-LFeCl·DMF, PS-LMn·2DMF and PS-LZr(OH)2·DMF. The polystyrene-anchored coordination compounds have been characterized by elemental analysis, IR, reflectance, ESR and magnetic susceptibility measurements. The per cent reaction conversion of polystyrene anchored Schiff base to polystyrene supported coordination compounds lies between 28·98 and 85·9. The coordinated dimethylformamide is completely lost on heating the complexes. The shifts of the ν(C=N)(azomethine) and ν(C-O)(phenolic) stretches have been monitored in order to find out the donor sites of the ligands. The Cu(II) complex is paramagnetic with square planar structure; the Ni(II) complex is diamagnetic with square planar structure; the Zn(II) and Cd(II) complexes are diamagnetic and have tetrahedral structure; the Mn(II) and Fe(III) complexes are paramagnetic and have octahedral structure; the $ MoO_{2} $(II) and $ UO_{2} $(II) complexes are diamagnetic and have octahedral structure and the Zr(IV) complexes are diamagnetic and have pentagonal bipyramidal structure. Polystyrene-anchored ligands polystyrene-anchored complexes tetradentate IR reflectance ESSR and magnetic susceptibility measurements Syamal, Arun aut Sharma, Lalit Kumar aut Enthalten in Journal of chemical sciences Springer-Verlag, 2004 121(2009), 1 vom: Jan., Seite 57-64 (DE-627)385831307 (DE-600)2143421-9 (DE-576)111316219 0974-3626 nnns volume:121 year:2009 number:1 month:01 pages:57-64 https://doi.org/10.1007/s12039-009-0006-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT GBV_ILN_40 GBV_ILN_70 GBV_ILN_179 GBV_ILN_2003 GBV_ILN_4012 GBV_ILN_4082 35.00$jChemie: Allgemeines VZ 106422014 (DE-625)106422014 35.04$jAusbildung$jBeruf$jOrganisationen$XChemie VZ 106407821 (DE-625)106407821 AR 121 2009 1 01 57-64 |
| spelling |
10.1007/s12039-009-0006-y doi (DE-627)OLC210275619X (DE-He213)s12039-009-0006-y-p DE-627 ger DE-627 rakwb eng 000 500 060 VZ 35.00$jChemie: Allgemeines bkl 35.04$jAusbildung$jBeruf$jOrganisationen$XChemie bkl Kumar, Dinesh verfasserin aut Synthesis, magnetic and spectral studies on polystyrene-anchored coordination complexes of bi-, tri-, tetra- and hexavalent metal ions with unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Indian Academy of Sciences 2009 Abstract Polystyrene-anchored Cu(II), Zn(II), Cd(II), Ni(II), Mn(II), $ MoO_{2} $(II), $ UO_{2} $(II), Fe(III) and Zr(IV), complexes of the unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from the condensation of chloromethylated polystyrene, 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide (PS-$ LH_{2} $) has been synthesized. The polystyrene anchored complexes have the formulae: PS-LM (where M = Cu, Zn, Cd, Ni, $ MoO_{2} $, $ UO_{2} $), PS-LFeCl·DMF, PS-LMn·2DMF and PS-LZr(OH)2·DMF. The polystyrene-anchored coordination compounds have been characterized by elemental analysis, IR, reflectance, ESR and magnetic susceptibility measurements. The per cent reaction conversion of polystyrene anchored Schiff base to polystyrene supported coordination compounds lies between 28·98 and 85·9. The coordinated dimethylformamide is completely lost on heating the complexes. The shifts of the ν(C=N)(azomethine) and ν(C-O)(phenolic) stretches have been monitored in order to find out the donor sites of the ligands. The Cu(II) complex is paramagnetic with square planar structure; the Ni(II) complex is diamagnetic with square planar structure; the Zn(II) and Cd(II) complexes are diamagnetic and have tetrahedral structure; the Mn(II) and Fe(III) complexes are paramagnetic and have octahedral structure; the $ MoO_{2} $(II) and $ UO_{2} $(II) complexes are diamagnetic and have octahedral structure and the Zr(IV) complexes are diamagnetic and have pentagonal bipyramidal structure. Polystyrene-anchored ligands polystyrene-anchored complexes tetradentate IR reflectance ESSR and magnetic susceptibility measurements Syamal, Arun aut Sharma, Lalit Kumar aut Enthalten in Journal of chemical sciences Springer-Verlag, 2004 121(2009), 1 vom: Jan., Seite 57-64 (DE-627)385831307 (DE-600)2143421-9 (DE-576)111316219 0974-3626 nnns volume:121 year:2009 number:1 month:01 pages:57-64 https://doi.org/10.1007/s12039-009-0006-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT GBV_ILN_40 GBV_ILN_70 GBV_ILN_179 GBV_ILN_2003 GBV_ILN_4012 GBV_ILN_4082 35.00$jChemie: Allgemeines VZ 106422014 (DE-625)106422014 35.04$jAusbildung$jBeruf$jOrganisationen$XChemie VZ 106407821 (DE-625)106407821 AR 121 2009 1 01 57-64 |
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10.1007/s12039-009-0006-y doi (DE-627)OLC210275619X (DE-He213)s12039-009-0006-y-p DE-627 ger DE-627 rakwb eng 000 500 060 VZ 35.00$jChemie: Allgemeines bkl 35.04$jAusbildung$jBeruf$jOrganisationen$XChemie bkl Kumar, Dinesh verfasserin aut Synthesis, magnetic and spectral studies on polystyrene-anchored coordination complexes of bi-, tri-, tetra- and hexavalent metal ions with unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Indian Academy of Sciences 2009 Abstract Polystyrene-anchored Cu(II), Zn(II), Cd(II), Ni(II), Mn(II), $ MoO_{2} $(II), $ UO_{2} $(II), Fe(III) and Zr(IV), complexes of the unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from the condensation of chloromethylated polystyrene, 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide (PS-$ LH_{2} $) has been synthesized. The polystyrene anchored complexes have the formulae: PS-LM (where M = Cu, Zn, Cd, Ni, $ MoO_{2} $, $ UO_{2} $), PS-LFeCl·DMF, PS-LMn·2DMF and PS-LZr(OH)2·DMF. The polystyrene-anchored coordination compounds have been characterized by elemental analysis, IR, reflectance, ESR and magnetic susceptibility measurements. The per cent reaction conversion of polystyrene anchored Schiff base to polystyrene supported coordination compounds lies between 28·98 and 85·9. The coordinated dimethylformamide is completely lost on heating the complexes. The shifts of the ν(C=N)(azomethine) and ν(C-O)(phenolic) stretches have been monitored in order to find out the donor sites of the ligands. The Cu(II) complex is paramagnetic with square planar structure; the Ni(II) complex is diamagnetic with square planar structure; the Zn(II) and Cd(II) complexes are diamagnetic and have tetrahedral structure; the Mn(II) and Fe(III) complexes are paramagnetic and have octahedral structure; the $ MoO_{2} $(II) and $ UO_{2} $(II) complexes are diamagnetic and have octahedral structure and the Zr(IV) complexes are diamagnetic and have pentagonal bipyramidal structure. Polystyrene-anchored ligands polystyrene-anchored complexes tetradentate IR reflectance ESSR and magnetic susceptibility measurements Syamal, Arun aut Sharma, Lalit Kumar aut Enthalten in Journal of chemical sciences Springer-Verlag, 2004 121(2009), 1 vom: Jan., Seite 57-64 (DE-627)385831307 (DE-600)2143421-9 (DE-576)111316219 0974-3626 nnns volume:121 year:2009 number:1 month:01 pages:57-64 https://doi.org/10.1007/s12039-009-0006-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT GBV_ILN_40 GBV_ILN_70 GBV_ILN_179 GBV_ILN_2003 GBV_ILN_4012 GBV_ILN_4082 35.00$jChemie: Allgemeines VZ 106422014 (DE-625)106422014 35.04$jAusbildung$jBeruf$jOrganisationen$XChemie VZ 106407821 (DE-625)106407821 AR 121 2009 1 01 57-64 |
| allfieldsGer |
10.1007/s12039-009-0006-y doi (DE-627)OLC210275619X (DE-He213)s12039-009-0006-y-p DE-627 ger DE-627 rakwb eng 000 500 060 VZ 35.00$jChemie: Allgemeines bkl 35.04$jAusbildung$jBeruf$jOrganisationen$XChemie bkl Kumar, Dinesh verfasserin aut Synthesis, magnetic and spectral studies on polystyrene-anchored coordination complexes of bi-, tri-, tetra- and hexavalent metal ions with unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Indian Academy of Sciences 2009 Abstract Polystyrene-anchored Cu(II), Zn(II), Cd(II), Ni(II), Mn(II), $ MoO_{2} $(II), $ UO_{2} $(II), Fe(III) and Zr(IV), complexes of the unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from the condensation of chloromethylated polystyrene, 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide (PS-$ LH_{2} $) has been synthesized. The polystyrene anchored complexes have the formulae: PS-LM (where M = Cu, Zn, Cd, Ni, $ MoO_{2} $, $ UO_{2} $), PS-LFeCl·DMF, PS-LMn·2DMF and PS-LZr(OH)2·DMF. The polystyrene-anchored coordination compounds have been characterized by elemental analysis, IR, reflectance, ESR and magnetic susceptibility measurements. The per cent reaction conversion of polystyrene anchored Schiff base to polystyrene supported coordination compounds lies between 28·98 and 85·9. The coordinated dimethylformamide is completely lost on heating the complexes. The shifts of the ν(C=N)(azomethine) and ν(C-O)(phenolic) stretches have been monitored in order to find out the donor sites of the ligands. The Cu(II) complex is paramagnetic with square planar structure; the Ni(II) complex is diamagnetic with square planar structure; the Zn(II) and Cd(II) complexes are diamagnetic and have tetrahedral structure; the Mn(II) and Fe(III) complexes are paramagnetic and have octahedral structure; the $ MoO_{2} $(II) and $ UO_{2} $(II) complexes are diamagnetic and have octahedral structure and the Zr(IV) complexes are diamagnetic and have pentagonal bipyramidal structure. Polystyrene-anchored ligands polystyrene-anchored complexes tetradentate IR reflectance ESSR and magnetic susceptibility measurements Syamal, Arun aut Sharma, Lalit Kumar aut Enthalten in Journal of chemical sciences Springer-Verlag, 2004 121(2009), 1 vom: Jan., Seite 57-64 (DE-627)385831307 (DE-600)2143421-9 (DE-576)111316219 0974-3626 nnns volume:121 year:2009 number:1 month:01 pages:57-64 https://doi.org/10.1007/s12039-009-0006-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT GBV_ILN_40 GBV_ILN_70 GBV_ILN_179 GBV_ILN_2003 GBV_ILN_4012 GBV_ILN_4082 35.00$jChemie: Allgemeines VZ 106422014 (DE-625)106422014 35.04$jAusbildung$jBeruf$jOrganisationen$XChemie VZ 106407821 (DE-625)106407821 AR 121 2009 1 01 57-64 |
| allfieldsSound |
10.1007/s12039-009-0006-y doi (DE-627)OLC210275619X (DE-He213)s12039-009-0006-y-p DE-627 ger DE-627 rakwb eng 000 500 060 VZ 35.00$jChemie: Allgemeines bkl 35.04$jAusbildung$jBeruf$jOrganisationen$XChemie bkl Kumar, Dinesh verfasserin aut Synthesis, magnetic and spectral studies on polystyrene-anchored coordination complexes of bi-, tri-, tetra- and hexavalent metal ions with unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Indian Academy of Sciences 2009 Abstract Polystyrene-anchored Cu(II), Zn(II), Cd(II), Ni(II), Mn(II), $ MoO_{2} $(II), $ UO_{2} $(II), Fe(III) and Zr(IV), complexes of the unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from the condensation of chloromethylated polystyrene, 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide (PS-$ LH_{2} $) has been synthesized. The polystyrene anchored complexes have the formulae: PS-LM (where M = Cu, Zn, Cd, Ni, $ MoO_{2} $, $ UO_{2} $), PS-LFeCl·DMF, PS-LMn·2DMF and PS-LZr(OH)2·DMF. The polystyrene-anchored coordination compounds have been characterized by elemental analysis, IR, reflectance, ESR and magnetic susceptibility measurements. The per cent reaction conversion of polystyrene anchored Schiff base to polystyrene supported coordination compounds lies between 28·98 and 85·9. The coordinated dimethylformamide is completely lost on heating the complexes. The shifts of the ν(C=N)(azomethine) and ν(C-O)(phenolic) stretches have been monitored in order to find out the donor sites of the ligands. The Cu(II) complex is paramagnetic with square planar structure; the Ni(II) complex is diamagnetic with square planar structure; the Zn(II) and Cd(II) complexes are diamagnetic and have tetrahedral structure; the Mn(II) and Fe(III) complexes are paramagnetic and have octahedral structure; the $ MoO_{2} $(II) and $ UO_{2} $(II) complexes are diamagnetic and have octahedral structure and the Zr(IV) complexes are diamagnetic and have pentagonal bipyramidal structure. Polystyrene-anchored ligands polystyrene-anchored complexes tetradentate IR reflectance ESSR and magnetic susceptibility measurements Syamal, Arun aut Sharma, Lalit Kumar aut Enthalten in Journal of chemical sciences Springer-Verlag, 2004 121(2009), 1 vom: Jan., Seite 57-64 (DE-627)385831307 (DE-600)2143421-9 (DE-576)111316219 0974-3626 nnns volume:121 year:2009 number:1 month:01 pages:57-64 https://doi.org/10.1007/s12039-009-0006-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-MAT GBV_ILN_40 GBV_ILN_70 GBV_ILN_179 GBV_ILN_2003 GBV_ILN_4012 GBV_ILN_4082 35.00$jChemie: Allgemeines VZ 106422014 (DE-625)106422014 35.04$jAusbildung$jBeruf$jOrganisationen$XChemie VZ 106407821 (DE-625)106407821 AR 121 2009 1 01 57-64 |
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The polystyrene anchored complexes have the formulae: PS-LM (where M = Cu, Zn, Cd, Ni, $ MoO_{2} $, $ UO_{2} $), PS-LFeCl·DMF, PS-LMn·2DMF and PS-LZr(OH)2·DMF. The polystyrene-anchored coordination compounds have been characterized by elemental analysis, IR, reflectance, ESR and magnetic susceptibility measurements. The per cent reaction conversion of polystyrene anchored Schiff base to polystyrene supported coordination compounds lies between 28·98 and 85·9. The coordinated dimethylformamide is completely lost on heating the complexes. The shifts of the ν(C=N)(azomethine) and ν(C-O)(phenolic) stretches have been monitored in order to find out the donor sites of the ligands. The Cu(II) complex is paramagnetic with square planar structure; the Ni(II) complex is diamagnetic with square planar structure; the Zn(II) and Cd(II) complexes are diamagnetic and have tetrahedral structure; the Mn(II) and Fe(III) complexes are paramagnetic and have octahedral structure; the $ MoO_{2} $(II) and $ UO_{2} $(II) complexes are diamagnetic and have octahedral structure and the Zr(IV) complexes are diamagnetic and have pentagonal bipyramidal structure.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Polystyrene-anchored ligands</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">polystyrene-anchored complexes</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">tetradentate</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">IR</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">reflectance</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">ESSR and magnetic susceptibility measurements</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Syamal, Arun</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Sharma, Lalit Kumar</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of chemical sciences</subfield><subfield code="d">Springer-Verlag, 2004</subfield><subfield code="g">121(2009), 1 vom: Jan., Seite 57-64</subfield><subfield code="w">(DE-627)385831307</subfield><subfield code="w">(DE-600)2143421-9</subfield><subfield code="w">(DE-576)111316219</subfield><subfield code="x">0974-3626</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:121</subfield><subfield code="g">year:2009</subfield><subfield code="g">number:1</subfield><subfield code="g">month:01</subfield><subfield code="g">pages:57-64</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/s12039-009-0006-y</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-MAT</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_179</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4012</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4082</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">35.00$jChemie: Allgemeines</subfield><subfield code="q">VZ</subfield><subfield code="0">106422014</subfield><subfield code="0">(DE-625)106422014</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">35.04$jAusbildung$jBeruf$jOrganisationen$XChemie</subfield><subfield code="q">VZ</subfield><subfield code="0">106407821</subfield><subfield code="0">(DE-625)106407821</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">121</subfield><subfield code="j">2009</subfield><subfield code="e">1</subfield><subfield code="c">01</subfield><subfield code="h">57-64</subfield></datafield></record></collection>
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Kumar, Dinesh |
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Kumar, Dinesh ddc 000 bkl 35.00$jChemie: Allgemeines bkl 35.04$jAusbildung$jBeruf$jOrganisationen$XChemie misc Polystyrene-anchored ligands misc polystyrene-anchored complexes misc tetradentate misc IR misc reflectance misc ESSR and magnetic susceptibility measurements Synthesis, magnetic and spectral studies on polystyrene-anchored coordination complexes of bi-, tri-, tetra- and hexavalent metal ions with unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide |
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000 500 060 VZ 35.00$jChemie: Allgemeines bkl 35.04$jAusbildung$jBeruf$jOrganisationen$XChemie bkl Synthesis, magnetic and spectral studies on polystyrene-anchored coordination complexes of bi-, tri-, tetra- and hexavalent metal ions with unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide Polystyrene-anchored ligands polystyrene-anchored complexes tetradentate IR reflectance ESSR and magnetic susceptibility measurements |
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ddc 000 bkl 35.00$jChemie: Allgemeines bkl 35.04$jAusbildung$jBeruf$jOrganisationen$XChemie misc Polystyrene-anchored ligands misc polystyrene-anchored complexes misc tetradentate misc IR misc reflectance misc ESSR and magnetic susceptibility measurements |
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ddc 000 bkl 35.00$jChemie: Allgemeines bkl 35.04$jAusbildung$jBeruf$jOrganisationen$XChemie misc Polystyrene-anchored ligands misc polystyrene-anchored complexes misc tetradentate misc IR misc reflectance misc ESSR and magnetic susceptibility measurements |
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Synthesis, magnetic and spectral studies on polystyrene-anchored coordination complexes of bi-, tri-, tetra- and hexavalent metal ions with unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide |
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Synthesis, magnetic and spectral studies on polystyrene-anchored coordination complexes of bi-, tri-, tetra- and hexavalent metal ions with unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide |
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Kumar, Dinesh Syamal, Arun Sharma, Lalit Kumar |
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synthesis, magnetic and spectral studies on polystyrene-anchored coordination complexes of bi-, tri-, tetra- and hexavalent metal ions with unsymmetrical dibasic tetradentate onno donor schiff base derived from 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide |
| title_auth |
Synthesis, magnetic and spectral studies on polystyrene-anchored coordination complexes of bi-, tri-, tetra- and hexavalent metal ions with unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide |
| abstract |
Abstract Polystyrene-anchored Cu(II), Zn(II), Cd(II), Ni(II), Mn(II), $ MoO_{2} $(II), $ UO_{2} $(II), Fe(III) and Zr(IV), complexes of the unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from the condensation of chloromethylated polystyrene, 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide (PS-$ LH_{2} $) has been synthesized. The polystyrene anchored complexes have the formulae: PS-LM (where M = Cu, Zn, Cd, Ni, $ MoO_{2} $, $ UO_{2} $), PS-LFeCl·DMF, PS-LMn·2DMF and PS-LZr(OH)2·DMF. The polystyrene-anchored coordination compounds have been characterized by elemental analysis, IR, reflectance, ESR and magnetic susceptibility measurements. The per cent reaction conversion of polystyrene anchored Schiff base to polystyrene supported coordination compounds lies between 28·98 and 85·9. The coordinated dimethylformamide is completely lost on heating the complexes. The shifts of the ν(C=N)(azomethine) and ν(C-O)(phenolic) stretches have been monitored in order to find out the donor sites of the ligands. The Cu(II) complex is paramagnetic with square planar structure; the Ni(II) complex is diamagnetic with square planar structure; the Zn(II) and Cd(II) complexes are diamagnetic and have tetrahedral structure; the Mn(II) and Fe(III) complexes are paramagnetic and have octahedral structure; the $ MoO_{2} $(II) and $ UO_{2} $(II) complexes are diamagnetic and have octahedral structure and the Zr(IV) complexes are diamagnetic and have pentagonal bipyramidal structure. © Indian Academy of Sciences 2009 |
| abstractGer |
Abstract Polystyrene-anchored Cu(II), Zn(II), Cd(II), Ni(II), Mn(II), $ MoO_{2} $(II), $ UO_{2} $(II), Fe(III) and Zr(IV), complexes of the unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from the condensation of chloromethylated polystyrene, 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide (PS-$ LH_{2} $) has been synthesized. The polystyrene anchored complexes have the formulae: PS-LM (where M = Cu, Zn, Cd, Ni, $ MoO_{2} $, $ UO_{2} $), PS-LFeCl·DMF, PS-LMn·2DMF and PS-LZr(OH)2·DMF. The polystyrene-anchored coordination compounds have been characterized by elemental analysis, IR, reflectance, ESR and magnetic susceptibility measurements. The per cent reaction conversion of polystyrene anchored Schiff base to polystyrene supported coordination compounds lies between 28·98 and 85·9. The coordinated dimethylformamide is completely lost on heating the complexes. The shifts of the ν(C=N)(azomethine) and ν(C-O)(phenolic) stretches have been monitored in order to find out the donor sites of the ligands. The Cu(II) complex is paramagnetic with square planar structure; the Ni(II) complex is diamagnetic with square planar structure; the Zn(II) and Cd(II) complexes are diamagnetic and have tetrahedral structure; the Mn(II) and Fe(III) complexes are paramagnetic and have octahedral structure; the $ MoO_{2} $(II) and $ UO_{2} $(II) complexes are diamagnetic and have octahedral structure and the Zr(IV) complexes are diamagnetic and have pentagonal bipyramidal structure. © Indian Academy of Sciences 2009 |
| abstract_unstemmed |
Abstract Polystyrene-anchored Cu(II), Zn(II), Cd(II), Ni(II), Mn(II), $ MoO_{2} $(II), $ UO_{2} $(II), Fe(III) and Zr(IV), complexes of the unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from the condensation of chloromethylated polystyrene, 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide (PS-$ LH_{2} $) has been synthesized. The polystyrene anchored complexes have the formulae: PS-LM (where M = Cu, Zn, Cd, Ni, $ MoO_{2} $, $ UO_{2} $), PS-LFeCl·DMF, PS-LMn·2DMF and PS-LZr(OH)2·DMF. The polystyrene-anchored coordination compounds have been characterized by elemental analysis, IR, reflectance, ESR and magnetic susceptibility measurements. The per cent reaction conversion of polystyrene anchored Schiff base to polystyrene supported coordination compounds lies between 28·98 and 85·9. The coordinated dimethylformamide is completely lost on heating the complexes. The shifts of the ν(C=N)(azomethine) and ν(C-O)(phenolic) stretches have been monitored in order to find out the donor sites of the ligands. The Cu(II) complex is paramagnetic with square planar structure; the Ni(II) complex is diamagnetic with square planar structure; the Zn(II) and Cd(II) complexes are diamagnetic and have tetrahedral structure; the Mn(II) and Fe(III) complexes are paramagnetic and have octahedral structure; the $ MoO_{2} $(II) and $ UO_{2} $(II) complexes are diamagnetic and have octahedral structure and the Zr(IV) complexes are diamagnetic and have pentagonal bipyramidal structure. © Indian Academy of Sciences 2009 |
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Synthesis, magnetic and spectral studies on polystyrene-anchored coordination complexes of bi-, tri-, tetra- and hexavalent metal ions with unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">OLC210275619X</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230402063437.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">230402s2009 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s12039-009-0006-y</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC210275619X</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)s12039-009-0006-y-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">000</subfield><subfield code="a">500</subfield><subfield code="a">060</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.00$jChemie: Allgemeines</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.04$jAusbildung$jBeruf$jOrganisationen$XChemie</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Kumar, Dinesh</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Synthesis, magnetic and spectral studies on polystyrene-anchored coordination complexes of bi-, tri-, tetra- and hexavalent metal ions with unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2009</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Indian Academy of Sciences 2009</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Polystyrene-anchored Cu(II), Zn(II), Cd(II), Ni(II), Mn(II), $ MoO_{2} $(II), $ UO_{2} $(II), Fe(III) and Zr(IV), complexes of the unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from the condensation of chloromethylated polystyrene, 3-formylsalicylic acid, ethylenediamine and 2-benzoylacetanilide (PS-$ LH_{2} $) has been synthesized. The polystyrene anchored complexes have the formulae: PS-LM (where M = Cu, Zn, Cd, Ni, $ MoO_{2} $, $ UO_{2} $), PS-LFeCl·DMF, PS-LMn·2DMF and PS-LZr(OH)2·DMF. The polystyrene-anchored coordination compounds have been characterized by elemental analysis, IR, reflectance, ESR and magnetic susceptibility measurements. The per cent reaction conversion of polystyrene anchored Schiff base to polystyrene supported coordination compounds lies between 28·98 and 85·9. The coordinated dimethylformamide is completely lost on heating the complexes. The shifts of the ν(C=N)(azomethine) and ν(C-O)(phenolic) stretches have been monitored in order to find out the donor sites of the ligands. The Cu(II) complex is paramagnetic with square planar structure; the Ni(II) complex is diamagnetic with square planar structure; the Zn(II) and Cd(II) complexes are diamagnetic and have tetrahedral structure; the Mn(II) and Fe(III) complexes are paramagnetic and have octahedral structure; the $ MoO_{2} $(II) and $ UO_{2} $(II) complexes are diamagnetic and have octahedral structure and the Zr(IV) complexes are diamagnetic and have pentagonal bipyramidal structure.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Polystyrene-anchored ligands</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">polystyrene-anchored complexes</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">tetradentate</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">IR</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">reflectance</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">ESSR and magnetic susceptibility measurements</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Syamal, Arun</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Sharma, Lalit Kumar</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of chemical sciences</subfield><subfield code="d">Springer-Verlag, 2004</subfield><subfield code="g">121(2009), 1 vom: Jan., Seite 57-64</subfield><subfield code="w">(DE-627)385831307</subfield><subfield code="w">(DE-600)2143421-9</subfield><subfield code="w">(DE-576)111316219</subfield><subfield code="x">0974-3626</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:121</subfield><subfield code="g">year:2009</subfield><subfield code="g">number:1</subfield><subfield code="g">month:01</subfield><subfield code="g">pages:57-64</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/s12039-009-0006-y</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-MAT</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_179</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4012</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4082</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">35.00$jChemie: Allgemeines</subfield><subfield code="q">VZ</subfield><subfield code="0">106422014</subfield><subfield code="0">(DE-625)106422014</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">35.04$jAusbildung$jBeruf$jOrganisationen$XChemie</subfield><subfield code="q">VZ</subfield><subfield code="0">106407821</subfield><subfield code="0">(DE-625)106407821</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">121</subfield><subfield code="j">2009</subfield><subfield code="e">1</subfield><subfield code="c">01</subfield><subfield code="h">57-64</subfield></datafield></record></collection>
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