Modification of sulfonated polyphenylquinoxaline by alkali and alkaline earth metal cations
Abstract Salts of sulfonated polyphenylquinoxaline (SPPQ) containing alkaline earth metal ions—$ Mg^{2+} $, $ Ca^{2+} $, and $ Ba^{2+} $—were synthesized. The paper considers their solubilities, the properties of solutions, and thermal stability in comparison with analogous characteristics of SPPQ s...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Vasil’ev, V. G. [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2016 |
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| Schlagwörter: |
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| Anmerkung: |
© Pleiades Publishing, Ltd. 2016 |
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| Übergeordnetes Werk: |
Enthalten in: Doklady physical chemistry - Pleiades Publishing, 1963, 466(2016), 2 vom: Feb., Seite 29-31 |
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| Übergeordnetes Werk: |
volume:466 ; year:2016 ; number:2 ; month:02 ; pages:29-31 |
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| DOI / URN: |
10.1134/S0012501616020019 |
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| 520 | |a Abstract Salts of sulfonated polyphenylquinoxaline (SPPQ) containing alkaline earth metal ions—$ Mg^{2+} $, $ Ca^{2+} $, and $ Ba^{2+} $—were synthesized. The paper considers their solubilities, the properties of solutions, and thermal stability in comparison with analogous characteristics of SPPQ salts with alkali metals. The introduction of alkaline earth metal cations into SPPQ affords soluble polymeric salts having high thermal stability. Solutions of SPPQ salts in N-methylpyrrolidone (N-MP) containing $ Mg^{2+} $, $ Ca^{2+} $, and $ Ba^{2+} $ ions do not exhibit polyelectrolyte properties, unlike solutions of SPPQ salts in which the counterions are $ Li^{+} $, $ Na^{+} $, and $ K^{+} $. Solutions of SPPQ and its salts in N-MP can be converted to water-soluble form by dialysis. This opens up new prospects for using the polymeric salts. | ||
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| 700 | 1 | |a Buzin, M. I. |4 aut | |
| 700 | 1 | |a Nikiforova, G. G. |4 aut | |
| 700 | 1 | |a Belomoina, N. M. |4 aut | |
| 700 | 1 | |a Bulycheva, E. G. |4 aut | |
| 700 | 1 | |a Papkov, V. S. |4 aut | |
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10.1134/S0012501616020019 doi (DE-627)OLC2112981412 (DE-He213)S0012501616020019-p DE-627 ger DE-627 rakwb eng 660 VZ Vasil’ev, V. G. verfasserin aut Modification of sulfonated polyphenylquinoxaline by alkali and alkaline earth metal cations 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2016 Abstract Salts of sulfonated polyphenylquinoxaline (SPPQ) containing alkaline earth metal ions—$ Mg^{2+} $, $ Ca^{2+} $, and $ Ba^{2+} $—were synthesized. The paper considers their solubilities, the properties of solutions, and thermal stability in comparison with analogous characteristics of SPPQ salts with alkali metals. The introduction of alkaline earth metal cations into SPPQ affords soluble polymeric salts having high thermal stability. Solutions of SPPQ salts in N-methylpyrrolidone (N-MP) containing $ Mg^{2+} $, $ Ca^{2+} $, and $ Ba^{2+} $ ions do not exhibit polyelectrolyte properties, unlike solutions of SPPQ salts in which the counterions are $ Li^{+} $, $ Na^{+} $, and $ K^{+} $. Solutions of SPPQ and its salts in N-MP can be converted to water-soluble form by dialysis. This opens up new prospects for using the polymeric salts. Aprotic Solvent DOKLADY Physical Chemistry Alkali Metal Salt Polymeric Salt Alkaline Earth Metal Salt Buzin, M. I. aut Nikiforova, G. G. aut Belomoina, N. M. aut Bulycheva, E. G. aut Papkov, V. S. aut Enthalten in Doklady physical chemistry Pleiades Publishing, 1963 466(2016), 2 vom: Feb., Seite 29-31 (DE-627)130357197 (DE-600)595191-4 (DE-576)015894177 0012-5016 nnns volume:466 year:2016 number:2 month:02 pages:29-31 https://doi.org/10.1134/S0012501616020019 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 466 2016 2 02 29-31 |
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10.1134/S0012501616020019 doi (DE-627)OLC2112981412 (DE-He213)S0012501616020019-p DE-627 ger DE-627 rakwb eng 660 VZ Vasil’ev, V. G. verfasserin aut Modification of sulfonated polyphenylquinoxaline by alkali and alkaline earth metal cations 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2016 Abstract Salts of sulfonated polyphenylquinoxaline (SPPQ) containing alkaline earth metal ions—$ Mg^{2+} $, $ Ca^{2+} $, and $ Ba^{2+} $—were synthesized. The paper considers their solubilities, the properties of solutions, and thermal stability in comparison with analogous characteristics of SPPQ salts with alkali metals. The introduction of alkaline earth metal cations into SPPQ affords soluble polymeric salts having high thermal stability. Solutions of SPPQ salts in N-methylpyrrolidone (N-MP) containing $ Mg^{2+} $, $ Ca^{2+} $, and $ Ba^{2+} $ ions do not exhibit polyelectrolyte properties, unlike solutions of SPPQ salts in which the counterions are $ Li^{+} $, $ Na^{+} $, and $ K^{+} $. Solutions of SPPQ and its salts in N-MP can be converted to water-soluble form by dialysis. This opens up new prospects for using the polymeric salts. Aprotic Solvent DOKLADY Physical Chemistry Alkali Metal Salt Polymeric Salt Alkaline Earth Metal Salt Buzin, M. I. aut Nikiforova, G. G. aut Belomoina, N. M. aut Bulycheva, E. G. aut Papkov, V. S. aut Enthalten in Doklady physical chemistry Pleiades Publishing, 1963 466(2016), 2 vom: Feb., Seite 29-31 (DE-627)130357197 (DE-600)595191-4 (DE-576)015894177 0012-5016 nnns volume:466 year:2016 number:2 month:02 pages:29-31 https://doi.org/10.1134/S0012501616020019 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 466 2016 2 02 29-31 |
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10.1134/S0012501616020019 doi (DE-627)OLC2112981412 (DE-He213)S0012501616020019-p DE-627 ger DE-627 rakwb eng 660 VZ Vasil’ev, V. G. verfasserin aut Modification of sulfonated polyphenylquinoxaline by alkali and alkaline earth metal cations 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2016 Abstract Salts of sulfonated polyphenylquinoxaline (SPPQ) containing alkaline earth metal ions—$ Mg^{2+} $, $ Ca^{2+} $, and $ Ba^{2+} $—were synthesized. The paper considers their solubilities, the properties of solutions, and thermal stability in comparison with analogous characteristics of SPPQ salts with alkali metals. The introduction of alkaline earth metal cations into SPPQ affords soluble polymeric salts having high thermal stability. Solutions of SPPQ salts in N-methylpyrrolidone (N-MP) containing $ Mg^{2+} $, $ Ca^{2+} $, and $ Ba^{2+} $ ions do not exhibit polyelectrolyte properties, unlike solutions of SPPQ salts in which the counterions are $ Li^{+} $, $ Na^{+} $, and $ K^{+} $. Solutions of SPPQ and its salts in N-MP can be converted to water-soluble form by dialysis. This opens up new prospects for using the polymeric salts. Aprotic Solvent DOKLADY Physical Chemistry Alkali Metal Salt Polymeric Salt Alkaline Earth Metal Salt Buzin, M. I. aut Nikiforova, G. G. aut Belomoina, N. M. aut Bulycheva, E. G. aut Papkov, V. S. aut Enthalten in Doklady physical chemistry Pleiades Publishing, 1963 466(2016), 2 vom: Feb., Seite 29-31 (DE-627)130357197 (DE-600)595191-4 (DE-576)015894177 0012-5016 nnns volume:466 year:2016 number:2 month:02 pages:29-31 https://doi.org/10.1134/S0012501616020019 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 466 2016 2 02 29-31 |
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10.1134/S0012501616020019 doi (DE-627)OLC2112981412 (DE-He213)S0012501616020019-p DE-627 ger DE-627 rakwb eng 660 VZ Vasil’ev, V. G. verfasserin aut Modification of sulfonated polyphenylquinoxaline by alkali and alkaline earth metal cations 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2016 Abstract Salts of sulfonated polyphenylquinoxaline (SPPQ) containing alkaline earth metal ions—$ Mg^{2+} $, $ Ca^{2+} $, and $ Ba^{2+} $—were synthesized. The paper considers their solubilities, the properties of solutions, and thermal stability in comparison with analogous characteristics of SPPQ salts with alkali metals. The introduction of alkaline earth metal cations into SPPQ affords soluble polymeric salts having high thermal stability. Solutions of SPPQ salts in N-methylpyrrolidone (N-MP) containing $ Mg^{2+} $, $ Ca^{2+} $, and $ Ba^{2+} $ ions do not exhibit polyelectrolyte properties, unlike solutions of SPPQ salts in which the counterions are $ Li^{+} $, $ Na^{+} $, and $ K^{+} $. Solutions of SPPQ and its salts in N-MP can be converted to water-soluble form by dialysis. This opens up new prospects for using the polymeric salts. Aprotic Solvent DOKLADY Physical Chemistry Alkali Metal Salt Polymeric Salt Alkaline Earth Metal Salt Buzin, M. I. aut Nikiforova, G. G. aut Belomoina, N. M. aut Bulycheva, E. G. aut Papkov, V. S. aut Enthalten in Doklady physical chemistry Pleiades Publishing, 1963 466(2016), 2 vom: Feb., Seite 29-31 (DE-627)130357197 (DE-600)595191-4 (DE-576)015894177 0012-5016 nnns volume:466 year:2016 number:2 month:02 pages:29-31 https://doi.org/10.1134/S0012501616020019 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 466 2016 2 02 29-31 |
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10.1134/S0012501616020019 doi (DE-627)OLC2112981412 (DE-He213)S0012501616020019-p DE-627 ger DE-627 rakwb eng 660 VZ Vasil’ev, V. G. verfasserin aut Modification of sulfonated polyphenylquinoxaline by alkali and alkaline earth metal cations 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2016 Abstract Salts of sulfonated polyphenylquinoxaline (SPPQ) containing alkaline earth metal ions—$ Mg^{2+} $, $ Ca^{2+} $, and $ Ba^{2+} $—were synthesized. The paper considers their solubilities, the properties of solutions, and thermal stability in comparison with analogous characteristics of SPPQ salts with alkali metals. The introduction of alkaline earth metal cations into SPPQ affords soluble polymeric salts having high thermal stability. Solutions of SPPQ salts in N-methylpyrrolidone (N-MP) containing $ Mg^{2+} $, $ Ca^{2+} $, and $ Ba^{2+} $ ions do not exhibit polyelectrolyte properties, unlike solutions of SPPQ salts in which the counterions are $ Li^{+} $, $ Na^{+} $, and $ K^{+} $. Solutions of SPPQ and its salts in N-MP can be converted to water-soluble form by dialysis. This opens up new prospects for using the polymeric salts. Aprotic Solvent DOKLADY Physical Chemistry Alkali Metal Salt Polymeric Salt Alkaline Earth Metal Salt Buzin, M. I. aut Nikiforova, G. G. aut Belomoina, N. M. aut Bulycheva, E. G. aut Papkov, V. S. aut Enthalten in Doklady physical chemistry Pleiades Publishing, 1963 466(2016), 2 vom: Feb., Seite 29-31 (DE-627)130357197 (DE-600)595191-4 (DE-576)015894177 0012-5016 nnns volume:466 year:2016 number:2 month:02 pages:29-31 https://doi.org/10.1134/S0012501616020019 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 466 2016 2 02 29-31 |
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modification of sulfonated polyphenylquinoxaline by alkali and alkaline earth metal cations |
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Modification of sulfonated polyphenylquinoxaline by alkali and alkaline earth metal cations |
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Abstract Salts of sulfonated polyphenylquinoxaline (SPPQ) containing alkaline earth metal ions—$ Mg^{2+} $, $ Ca^{2+} $, and $ Ba^{2+} $—were synthesized. The paper considers their solubilities, the properties of solutions, and thermal stability in comparison with analogous characteristics of SPPQ salts with alkali metals. The introduction of alkaline earth metal cations into SPPQ affords soluble polymeric salts having high thermal stability. Solutions of SPPQ salts in N-methylpyrrolidone (N-MP) containing $ Mg^{2+} $, $ Ca^{2+} $, and $ Ba^{2+} $ ions do not exhibit polyelectrolyte properties, unlike solutions of SPPQ salts in which the counterions are $ Li^{+} $, $ Na^{+} $, and $ K^{+} $. Solutions of SPPQ and its salts in N-MP can be converted to water-soluble form by dialysis. This opens up new prospects for using the polymeric salts. © Pleiades Publishing, Ltd. 2016 |
| abstractGer |
Abstract Salts of sulfonated polyphenylquinoxaline (SPPQ) containing alkaline earth metal ions—$ Mg^{2+} $, $ Ca^{2+} $, and $ Ba^{2+} $—were synthesized. The paper considers their solubilities, the properties of solutions, and thermal stability in comparison with analogous characteristics of SPPQ salts with alkali metals. The introduction of alkaline earth metal cations into SPPQ affords soluble polymeric salts having high thermal stability. Solutions of SPPQ salts in N-methylpyrrolidone (N-MP) containing $ Mg^{2+} $, $ Ca^{2+} $, and $ Ba^{2+} $ ions do not exhibit polyelectrolyte properties, unlike solutions of SPPQ salts in which the counterions are $ Li^{+} $, $ Na^{+} $, and $ K^{+} $. Solutions of SPPQ and its salts in N-MP can be converted to water-soluble form by dialysis. This opens up new prospects for using the polymeric salts. © Pleiades Publishing, Ltd. 2016 |
| abstract_unstemmed |
Abstract Salts of sulfonated polyphenylquinoxaline (SPPQ) containing alkaline earth metal ions—$ Mg^{2+} $, $ Ca^{2+} $, and $ Ba^{2+} $—were synthesized. The paper considers their solubilities, the properties of solutions, and thermal stability in comparison with analogous characteristics of SPPQ salts with alkali metals. The introduction of alkaline earth metal cations into SPPQ affords soluble polymeric salts having high thermal stability. Solutions of SPPQ salts in N-methylpyrrolidone (N-MP) containing $ Mg^{2+} $, $ Ca^{2+} $, and $ Ba^{2+} $ ions do not exhibit polyelectrolyte properties, unlike solutions of SPPQ salts in which the counterions are $ Li^{+} $, $ Na^{+} $, and $ K^{+} $. Solutions of SPPQ and its salts in N-MP can be converted to water-soluble form by dialysis. This opens up new prospects for using the polymeric salts. © Pleiades Publishing, Ltd. 2016 |
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Modification of sulfonated polyphenylquinoxaline by alkali and alkaline earth metal cations |
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Buzin, M. I. Nikiforova, G. G. Belomoina, N. M. Bulycheva, E. G. Papkov, V. S. |
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Buzin, M. I. Nikiforova, G. G. Belomoina, N. M. Bulycheva, E. G. Papkov, V. S. |
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10.1134/S0012501616020019 |
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2024-07-03T16:21:53.945Z |
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