A novel stable solid formed by $ C_{60} $ + oxygen at high P($ O_{2} $)

Abstract We report the formation of a novel solid form of carbon + oxygen. Exposure of $ C_{60} $ to high oxygen pressure [P($ O_{2} $) ≍ 100 MPa] for several days at slightly above ambient temperature results in absorption of significant amounts of oxygen (up to ∼48% by weight after 3 days). X-ray...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Morris, D. E. [verfasserIn] Singh, K. K. Sinha, A. P. B.

Format:	Artikel
Sprache:	Englisch

Erschienen:	1993

Systematik:	VA 5350

Anmerkung:	© The Materials Research Society 1993

Übergeordnetes Werk:	Enthalten in: Journal of materials research - Springer International Publishing, 1986, 8(1993), 9 vom: 01. Sept., Seite 2273-2276
Übergeordnetes Werk:	volume:8 ; year:1993 ; number:9 ; day:01 ; month:09 ; pages:2273-2276

Links:	Volltext

DOI / URN:	10.1557/JMR.1993.2273

Katalog-ID:	OLC2121421270

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allfields	10.1557/JMR.1993.2273 doi (DE-627)OLC2121421270 (DE-He213)JMR.1993.2273-p DE-627 ger DE-627 rakwb eng 670 VZ VA 5350 VZ rvk Morris, D. E. verfasserin aut A novel stable solid formed by $ C_{60} $ + oxygen at high P($ O_{2} $) 1993 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Materials Research Society 1993 Abstract We report the formation of a novel solid form of carbon + oxygen. Exposure of $ C_{60} $ to high oxygen pressure [P($ O_{2} $) ≍ 100 MPa] for several days at slightly above ambient temperature results in absorption of significant amounts of oxygen (up to ∼48% by weight after 3 days). X-ray diffraction measurements showed that the $ C_{60} $ pellets had become amorphous. Although part of the added weight is slowly lost in flowing oxygen at ambient pressure and temperature, most remains up to at least 100 °C. Heating in flowing He at 200 °C brought the weight back to near the original value. The reaction appears to be specific to $ C_{60} $ since the amorphous outgassed material had lost the capacity to absorb oxygen at high P($ O_{2} $), and the oxygen absorption effect was absent in powdered graphite and in commercial amorphous carbon. The Raman spectrum differs from those of $ C_{60} $, soot, amorphous carbon, graphite, and diamond. Singh, K. K. aut Sinha, A. P. B. aut Enthalten in Journal of materials research Springer International Publishing, 1986 8(1993), 9 vom: 01. Sept., Seite 2273-2276 (DE-627)129206288 (DE-600)54876-5 (DE-576)01445744X 0884-2914 nnns volume:8 year:1993 number:9 day:01 month:09 pages:2273-2276 https://doi.org/10.1557/JMR.1993.2273 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_21 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_30 GBV_ILN_31 GBV_ILN_40 GBV_ILN_70 GBV_ILN_100 GBV_ILN_130 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2010 GBV_ILN_2020 GBV_ILN_2027 GBV_ILN_4126 GBV_ILN_4155 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4315 GBV_ILN_4319 GBV_ILN_4323 VA 5350 AR 8 1993 9 01 09 2273-2276
spelling	10.1557/JMR.1993.2273 doi (DE-627)OLC2121421270 (DE-He213)JMR.1993.2273-p DE-627 ger DE-627 rakwb eng 670 VZ VA 5350 VZ rvk Morris, D. E. verfasserin aut A novel stable solid formed by $ C_{60} $ + oxygen at high P($ O_{2} $) 1993 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Materials Research Society 1993 Abstract We report the formation of a novel solid form of carbon + oxygen. Exposure of $ C_{60} $ to high oxygen pressure [P($ O_{2} $) ≍ 100 MPa] for several days at slightly above ambient temperature results in absorption of significant amounts of oxygen (up to ∼48% by weight after 3 days). X-ray diffraction measurements showed that the $ C_{60} $ pellets had become amorphous. Although part of the added weight is slowly lost in flowing oxygen at ambient pressure and temperature, most remains up to at least 100 °C. Heating in flowing He at 200 °C brought the weight back to near the original value. The reaction appears to be specific to $ C_{60} $ since the amorphous outgassed material had lost the capacity to absorb oxygen at high P($ O_{2} $), and the oxygen absorption effect was absent in powdered graphite and in commercial amorphous carbon. The Raman spectrum differs from those of $ C_{60} $, soot, amorphous carbon, graphite, and diamond. Singh, K. K. aut Sinha, A. P. B. aut Enthalten in Journal of materials research Springer International Publishing, 1986 8(1993), 9 vom: 01. Sept., Seite 2273-2276 (DE-627)129206288 (DE-600)54876-5 (DE-576)01445744X 0884-2914 nnns volume:8 year:1993 number:9 day:01 month:09 pages:2273-2276 https://doi.org/10.1557/JMR.1993.2273 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_21 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_30 GBV_ILN_31 GBV_ILN_40 GBV_ILN_70 GBV_ILN_100 GBV_ILN_130 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2010 GBV_ILN_2020 GBV_ILN_2027 GBV_ILN_4126 GBV_ILN_4155 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4315 GBV_ILN_4319 GBV_ILN_4323 VA 5350 AR 8 1993 9 01 09 2273-2276
allfields_unstemmed	10.1557/JMR.1993.2273 doi (DE-627)OLC2121421270 (DE-He213)JMR.1993.2273-p DE-627 ger DE-627 rakwb eng 670 VZ VA 5350 VZ rvk Morris, D. E. verfasserin aut A novel stable solid formed by $ C_{60} $ + oxygen at high P($ O_{2} $) 1993 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Materials Research Society 1993 Abstract We report the formation of a novel solid form of carbon + oxygen. Exposure of $ C_{60} $ to high oxygen pressure [P($ O_{2} $) ≍ 100 MPa] for several days at slightly above ambient temperature results in absorption of significant amounts of oxygen (up to ∼48% by weight after 3 days). X-ray diffraction measurements showed that the $ C_{60} $ pellets had become amorphous. Although part of the added weight is slowly lost in flowing oxygen at ambient pressure and temperature, most remains up to at least 100 °C. Heating in flowing He at 200 °C brought the weight back to near the original value. The reaction appears to be specific to $ C_{60} $ since the amorphous outgassed material had lost the capacity to absorb oxygen at high P($ O_{2} $), and the oxygen absorption effect was absent in powdered graphite and in commercial amorphous carbon. The Raman spectrum differs from those of $ C_{60} $, soot, amorphous carbon, graphite, and diamond. Singh, K. K. aut Sinha, A. P. B. aut Enthalten in Journal of materials research Springer International Publishing, 1986 8(1993), 9 vom: 01. Sept., Seite 2273-2276 (DE-627)129206288 (DE-600)54876-5 (DE-576)01445744X 0884-2914 nnns volume:8 year:1993 number:9 day:01 month:09 pages:2273-2276 https://doi.org/10.1557/JMR.1993.2273 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_21 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_30 GBV_ILN_31 GBV_ILN_40 GBV_ILN_70 GBV_ILN_100 GBV_ILN_130 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2010 GBV_ILN_2020 GBV_ILN_2027 GBV_ILN_4126 GBV_ILN_4155 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4315 GBV_ILN_4319 GBV_ILN_4323 VA 5350 AR 8 1993 9 01 09 2273-2276
allfieldsGer	10.1557/JMR.1993.2273 doi (DE-627)OLC2121421270 (DE-He213)JMR.1993.2273-p DE-627 ger DE-627 rakwb eng 670 VZ VA 5350 VZ rvk Morris, D. E. verfasserin aut A novel stable solid formed by $ C_{60} $ + oxygen at high P($ O_{2} $) 1993 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Materials Research Society 1993 Abstract We report the formation of a novel solid form of carbon + oxygen. Exposure of $ C_{60} $ to high oxygen pressure [P($ O_{2} $) ≍ 100 MPa] for several days at slightly above ambient temperature results in absorption of significant amounts of oxygen (up to ∼48% by weight after 3 days). X-ray diffraction measurements showed that the $ C_{60} $ pellets had become amorphous. Although part of the added weight is slowly lost in flowing oxygen at ambient pressure and temperature, most remains up to at least 100 °C. Heating in flowing He at 200 °C brought the weight back to near the original value. The reaction appears to be specific to $ C_{60} $ since the amorphous outgassed material had lost the capacity to absorb oxygen at high P($ O_{2} $), and the oxygen absorption effect was absent in powdered graphite and in commercial amorphous carbon. The Raman spectrum differs from those of $ C_{60} $, soot, amorphous carbon, graphite, and diamond. Singh, K. K. aut Sinha, A. P. B. aut Enthalten in Journal of materials research Springer International Publishing, 1986 8(1993), 9 vom: 01. Sept., Seite 2273-2276 (DE-627)129206288 (DE-600)54876-5 (DE-576)01445744X 0884-2914 nnns volume:8 year:1993 number:9 day:01 month:09 pages:2273-2276 https://doi.org/10.1557/JMR.1993.2273 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_21 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_30 GBV_ILN_31 GBV_ILN_40 GBV_ILN_70 GBV_ILN_100 GBV_ILN_130 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2010 GBV_ILN_2020 GBV_ILN_2027 GBV_ILN_4126 GBV_ILN_4155 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4315 GBV_ILN_4319 GBV_ILN_4323 VA 5350 AR 8 1993 9 01 09 2273-2276
allfieldsSound	10.1557/JMR.1993.2273 doi (DE-627)OLC2121421270 (DE-He213)JMR.1993.2273-p DE-627 ger DE-627 rakwb eng 670 VZ VA 5350 VZ rvk Morris, D. E. verfasserin aut A novel stable solid formed by $ C_{60} $ + oxygen at high P($ O_{2} $) 1993 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Materials Research Society 1993 Abstract We report the formation of a novel solid form of carbon + oxygen. Exposure of $ C_{60} $ to high oxygen pressure [P($ O_{2} $) ≍ 100 MPa] for several days at slightly above ambient temperature results in absorption of significant amounts of oxygen (up to ∼48% by weight after 3 days). X-ray diffraction measurements showed that the $ C_{60} $ pellets had become amorphous. Although part of the added weight is slowly lost in flowing oxygen at ambient pressure and temperature, most remains up to at least 100 °C. Heating in flowing He at 200 °C brought the weight back to near the original value. The reaction appears to be specific to $ C_{60} $ since the amorphous outgassed material had lost the capacity to absorb oxygen at high P($ O_{2} $), and the oxygen absorption effect was absent in powdered graphite and in commercial amorphous carbon. The Raman spectrum differs from those of $ C_{60} $, soot, amorphous carbon, graphite, and diamond. Singh, K. K. aut Sinha, A. P. B. aut Enthalten in Journal of materials research Springer International Publishing, 1986 8(1993), 9 vom: 01. Sept., Seite 2273-2276 (DE-627)129206288 (DE-600)54876-5 (DE-576)01445744X 0884-2914 nnns volume:8 year:1993 number:9 day:01 month:09 pages:2273-2276 https://doi.org/10.1557/JMR.1993.2273 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_21 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_30 GBV_ILN_31 GBV_ILN_40 GBV_ILN_70 GBV_ILN_100 GBV_ILN_130 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2010 GBV_ILN_2020 GBV_ILN_2027 GBV_ILN_4126 GBV_ILN_4155 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4315 GBV_ILN_4319 GBV_ILN_4323 VA 5350 AR 8 1993 9 01 09 2273-2276
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topic_title	670 VZ VA 5350 VZ rvk A novel stable solid formed by $ C_{60} $ + oxygen at high P($ O_{2} $)
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title	A novel stable solid formed by $ C_{60} $ + oxygen at high P($ O_{2} $)
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title_full	A novel stable solid formed by $ C_{60} $ + oxygen at high P($ O_{2} $)
author_sort	Morris, D. E.
journal	Journal of materials research
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author_browse	Morris, D. E. Singh, K. K. Sinha, A. P. B.
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author-letter	Morris, D. E.
doi_str_mv	10.1557/JMR.1993.2273
dewey-full	670
title_sort	a novel stable solid formed by $ c_{60} $ + oxygen at high p($ o_{2} $)
title_auth	A novel stable solid formed by $ C_{60} $ + oxygen at high P($ O_{2} $)
abstract	Abstract We report the formation of a novel solid form of carbon + oxygen. Exposure of $ C_{60} $ to high oxygen pressure [P($ O_{2} $) ≍ 100 MPa] for several days at slightly above ambient temperature results in absorption of significant amounts of oxygen (up to ∼48% by weight after 3 days). X-ray diffraction measurements showed that the $ C_{60} $ pellets had become amorphous. Although part of the added weight is slowly lost in flowing oxygen at ambient pressure and temperature, most remains up to at least 100 °C. Heating in flowing He at 200 °C brought the weight back to near the original value. The reaction appears to be specific to $ C_{60} $ since the amorphous outgassed material had lost the capacity to absorb oxygen at high P($ O_{2} $), and the oxygen absorption effect was absent in powdered graphite and in commercial amorphous carbon. The Raman spectrum differs from those of $ C_{60} $, soot, amorphous carbon, graphite, and diamond. © The Materials Research Society 1993
abstractGer	Abstract We report the formation of a novel solid form of carbon + oxygen. Exposure of $ C_{60} $ to high oxygen pressure [P($ O_{2} $) ≍ 100 MPa] for several days at slightly above ambient temperature results in absorption of significant amounts of oxygen (up to ∼48% by weight after 3 days). X-ray diffraction measurements showed that the $ C_{60} $ pellets had become amorphous. Although part of the added weight is slowly lost in flowing oxygen at ambient pressure and temperature, most remains up to at least 100 °C. Heating in flowing He at 200 °C brought the weight back to near the original value. The reaction appears to be specific to $ C_{60} $ since the amorphous outgassed material had lost the capacity to absorb oxygen at high P($ O_{2} $), and the oxygen absorption effect was absent in powdered graphite and in commercial amorphous carbon. The Raman spectrum differs from those of $ C_{60} $, soot, amorphous carbon, graphite, and diamond. © The Materials Research Society 1993
abstract_unstemmed	Abstract We report the formation of a novel solid form of carbon + oxygen. Exposure of $ C_{60} $ to high oxygen pressure [P($ O_{2} $) ≍ 100 MPa] for several days at slightly above ambient temperature results in absorption of significant amounts of oxygen (up to ∼48% by weight after 3 days). X-ray diffraction measurements showed that the $ C_{60} $ pellets had become amorphous. Although part of the added weight is slowly lost in flowing oxygen at ambient pressure and temperature, most remains up to at least 100 °C. Heating in flowing He at 200 °C brought the weight back to near the original value. The reaction appears to be specific to $ C_{60} $ since the amorphous outgassed material had lost the capacity to absorb oxygen at high P($ O_{2} $), and the oxygen absorption effect was absent in powdered graphite and in commercial amorphous carbon. The Raman spectrum differs from those of $ C_{60} $, soot, amorphous carbon, graphite, and diamond. © The Materials Research Society 1993
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container_issue	9
title_short	A novel stable solid formed by $ C_{60} $ + oxygen at high P($ O_{2} $)
url	https://doi.org/10.1557/JMR.1993.2273
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author2	Singh, K. K. Sinha, A. P. B.
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up_date	2024-07-04T06:52:53.098Z
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