Investigation of thiophene flanked diketopyrrolopyrrole monomers with straight and branched alkyl chains and their electropolymerization study
Abstract Diketopyrrolopyrrole (DPP) is a critically important building block that has gained importance in the organic electronics community because of its wide applicability in various devices. In this work, the thiophene flanked DPP moiety attached to alkyl chains of various lengths (this includes...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Ponnappa, Supreetha Paleyanda [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2017 |
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| Systematik: |
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| Anmerkung: |
© The Materials Research Society 2017 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of materials research - Springer International Publishing, 1986, 32(2017), 14 vom: 01. Juli, Seite 2707-2718 |
|---|---|
| Übergeordnetes Werk: |
volume:32 ; year:2017 ; number:14 ; day:01 ; month:07 ; pages:2707-2718 |
| Links: |
|---|
| DOI / URN: |
10.1557/jmr.2017.158 |
|---|
| Katalog-ID: |
OLC2122242345 |
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| 520 | |a Abstract Diketopyrrolopyrrole (DPP) is a critically important building block that has gained importance in the organic electronics community because of its wide applicability in various devices. In this work, the thiophene flanked DPP moiety attached to alkyl chains of various lengths (this includes straight octyl and branched ethyl hexyl units) has been used as the monomer for electropolymerization. This paper focuses on the study of optical, thermal, solid state ordering and electrochemical properties of these electron deficient monomers using various characterization techniques such as UV–Vis spectrometry (UV), photo-luminescence spectroscopy (PL), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), X-ray diffraction (XRD), cyclic voltammetry (CV), as well as ab initio modeling. These monomers exhibit broad absorption spectra from the ultraviolet (280–400 nm) to visible (400–600 nm) regions and emission spectra between 560 and 610 nm. The band gaps of these monomers were calculated to be in the range of 2.00–2.20 eV. These monomers were electropolymerized by scanning the potential between −0.5 and 2.0 V versus ferrocene for up to 50 cycles on a glassy carbon electrode. | ||
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| 700 | 1 | |a Sonar, Prashant |4 aut | |
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10.1557/jmr.2017.158 doi (DE-627)OLC2122242345 (DE-He213)jmr.2017.158-p DE-627 ger DE-627 rakwb eng 670 VZ VA 5350 VZ rvk Ponnappa, Supreetha Paleyanda verfasserin aut Investigation of thiophene flanked diketopyrrolopyrrole monomers with straight and branched alkyl chains and their electropolymerization study 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Materials Research Society 2017 Abstract Diketopyrrolopyrrole (DPP) is a critically important building block that has gained importance in the organic electronics community because of its wide applicability in various devices. In this work, the thiophene flanked DPP moiety attached to alkyl chains of various lengths (this includes straight octyl and branched ethyl hexyl units) has been used as the monomer for electropolymerization. This paper focuses on the study of optical, thermal, solid state ordering and electrochemical properties of these electron deficient monomers using various characterization techniques such as UV–Vis spectrometry (UV), photo-luminescence spectroscopy (PL), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), X-ray diffraction (XRD), cyclic voltammetry (CV), as well as ab initio modeling. These monomers exhibit broad absorption spectra from the ultraviolet (280–400 nm) to visible (400–600 nm) regions and emission spectra between 560 and 610 nm. The band gaps of these monomers were calculated to be in the range of 2.00–2.20 eV. These monomers were electropolymerized by scanning the potential between −0.5 and 2.0 V versus ferrocene for up to 50 cycles on a glassy carbon electrode. Arumugam, Sivanesan aut Manzhos, Sergei aut MacLeod, Jennifer aut Spratt, Henry J. aut O’Mullane, Anthony P. aut Sonar, Prashant aut Enthalten in Journal of materials research Springer International Publishing, 1986 32(2017), 14 vom: 01. Juli, Seite 2707-2718 (DE-627)129206288 (DE-600)54876-5 (DE-576)01445744X 0884-2914 nnns volume:32 year:2017 number:14 day:01 month:07 pages:2707-2718 https://doi.org/10.1557/jmr.2017.158 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_21 GBV_ILN_24 GBV_ILN_70 GBV_ILN_2005 GBV_ILN_2020 GBV_ILN_4126 GBV_ILN_4319 GBV_ILN_4323 VA 5350 AR 32 2017 14 01 07 2707-2718 |
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10.1557/jmr.2017.158 doi (DE-627)OLC2122242345 (DE-He213)jmr.2017.158-p DE-627 ger DE-627 rakwb eng 670 VZ VA 5350 VZ rvk Ponnappa, Supreetha Paleyanda verfasserin aut Investigation of thiophene flanked diketopyrrolopyrrole monomers with straight and branched alkyl chains and their electropolymerization study 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Materials Research Society 2017 Abstract Diketopyrrolopyrrole (DPP) is a critically important building block that has gained importance in the organic electronics community because of its wide applicability in various devices. In this work, the thiophene flanked DPP moiety attached to alkyl chains of various lengths (this includes straight octyl and branched ethyl hexyl units) has been used as the monomer for electropolymerization. This paper focuses on the study of optical, thermal, solid state ordering and electrochemical properties of these electron deficient monomers using various characterization techniques such as UV–Vis spectrometry (UV), photo-luminescence spectroscopy (PL), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), X-ray diffraction (XRD), cyclic voltammetry (CV), as well as ab initio modeling. These monomers exhibit broad absorption spectra from the ultraviolet (280–400 nm) to visible (400–600 nm) regions and emission spectra between 560 and 610 nm. The band gaps of these monomers were calculated to be in the range of 2.00–2.20 eV. These monomers were electropolymerized by scanning the potential between −0.5 and 2.0 V versus ferrocene for up to 50 cycles on a glassy carbon electrode. Arumugam, Sivanesan aut Manzhos, Sergei aut MacLeod, Jennifer aut Spratt, Henry J. aut O’Mullane, Anthony P. aut Sonar, Prashant aut Enthalten in Journal of materials research Springer International Publishing, 1986 32(2017), 14 vom: 01. Juli, Seite 2707-2718 (DE-627)129206288 (DE-600)54876-5 (DE-576)01445744X 0884-2914 nnns volume:32 year:2017 number:14 day:01 month:07 pages:2707-2718 https://doi.org/10.1557/jmr.2017.158 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_21 GBV_ILN_24 GBV_ILN_70 GBV_ILN_2005 GBV_ILN_2020 GBV_ILN_4126 GBV_ILN_4319 GBV_ILN_4323 VA 5350 AR 32 2017 14 01 07 2707-2718 |
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10.1557/jmr.2017.158 doi (DE-627)OLC2122242345 (DE-He213)jmr.2017.158-p DE-627 ger DE-627 rakwb eng 670 VZ VA 5350 VZ rvk Ponnappa, Supreetha Paleyanda verfasserin aut Investigation of thiophene flanked diketopyrrolopyrrole monomers with straight and branched alkyl chains and their electropolymerization study 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Materials Research Society 2017 Abstract Diketopyrrolopyrrole (DPP) is a critically important building block that has gained importance in the organic electronics community because of its wide applicability in various devices. In this work, the thiophene flanked DPP moiety attached to alkyl chains of various lengths (this includes straight octyl and branched ethyl hexyl units) has been used as the monomer for electropolymerization. This paper focuses on the study of optical, thermal, solid state ordering and electrochemical properties of these electron deficient monomers using various characterization techniques such as UV–Vis spectrometry (UV), photo-luminescence spectroscopy (PL), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), X-ray diffraction (XRD), cyclic voltammetry (CV), as well as ab initio modeling. These monomers exhibit broad absorption spectra from the ultraviolet (280–400 nm) to visible (400–600 nm) regions and emission spectra between 560 and 610 nm. The band gaps of these monomers were calculated to be in the range of 2.00–2.20 eV. These monomers were electropolymerized by scanning the potential between −0.5 and 2.0 V versus ferrocene for up to 50 cycles on a glassy carbon electrode. Arumugam, Sivanesan aut Manzhos, Sergei aut MacLeod, Jennifer aut Spratt, Henry J. aut O’Mullane, Anthony P. aut Sonar, Prashant aut Enthalten in Journal of materials research Springer International Publishing, 1986 32(2017), 14 vom: 01. Juli, Seite 2707-2718 (DE-627)129206288 (DE-600)54876-5 (DE-576)01445744X 0884-2914 nnns volume:32 year:2017 number:14 day:01 month:07 pages:2707-2718 https://doi.org/10.1557/jmr.2017.158 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_21 GBV_ILN_24 GBV_ILN_70 GBV_ILN_2005 GBV_ILN_2020 GBV_ILN_4126 GBV_ILN_4319 GBV_ILN_4323 VA 5350 AR 32 2017 14 01 07 2707-2718 |
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10.1557/jmr.2017.158 doi (DE-627)OLC2122242345 (DE-He213)jmr.2017.158-p DE-627 ger DE-627 rakwb eng 670 VZ VA 5350 VZ rvk Ponnappa, Supreetha Paleyanda verfasserin aut Investigation of thiophene flanked diketopyrrolopyrrole monomers with straight and branched alkyl chains and their electropolymerization study 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Materials Research Society 2017 Abstract Diketopyrrolopyrrole (DPP) is a critically important building block that has gained importance in the organic electronics community because of its wide applicability in various devices. In this work, the thiophene flanked DPP moiety attached to alkyl chains of various lengths (this includes straight octyl and branched ethyl hexyl units) has been used as the monomer for electropolymerization. This paper focuses on the study of optical, thermal, solid state ordering and electrochemical properties of these electron deficient monomers using various characterization techniques such as UV–Vis spectrometry (UV), photo-luminescence spectroscopy (PL), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), X-ray diffraction (XRD), cyclic voltammetry (CV), as well as ab initio modeling. These monomers exhibit broad absorption spectra from the ultraviolet (280–400 nm) to visible (400–600 nm) regions and emission spectra between 560 and 610 nm. The band gaps of these monomers were calculated to be in the range of 2.00–2.20 eV. These monomers were electropolymerized by scanning the potential between −0.5 and 2.0 V versus ferrocene for up to 50 cycles on a glassy carbon electrode. Arumugam, Sivanesan aut Manzhos, Sergei aut MacLeod, Jennifer aut Spratt, Henry J. aut O’Mullane, Anthony P. aut Sonar, Prashant aut Enthalten in Journal of materials research Springer International Publishing, 1986 32(2017), 14 vom: 01. Juli, Seite 2707-2718 (DE-627)129206288 (DE-600)54876-5 (DE-576)01445744X 0884-2914 nnns volume:32 year:2017 number:14 day:01 month:07 pages:2707-2718 https://doi.org/10.1557/jmr.2017.158 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_21 GBV_ILN_24 GBV_ILN_70 GBV_ILN_2005 GBV_ILN_2020 GBV_ILN_4126 GBV_ILN_4319 GBV_ILN_4323 VA 5350 AR 32 2017 14 01 07 2707-2718 |
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10.1557/jmr.2017.158 doi (DE-627)OLC2122242345 (DE-He213)jmr.2017.158-p DE-627 ger DE-627 rakwb eng 670 VZ VA 5350 VZ rvk Ponnappa, Supreetha Paleyanda verfasserin aut Investigation of thiophene flanked diketopyrrolopyrrole monomers with straight and branched alkyl chains and their electropolymerization study 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Materials Research Society 2017 Abstract Diketopyrrolopyrrole (DPP) is a critically important building block that has gained importance in the organic electronics community because of its wide applicability in various devices. In this work, the thiophene flanked DPP moiety attached to alkyl chains of various lengths (this includes straight octyl and branched ethyl hexyl units) has been used as the monomer for electropolymerization. This paper focuses on the study of optical, thermal, solid state ordering and electrochemical properties of these electron deficient monomers using various characterization techniques such as UV–Vis spectrometry (UV), photo-luminescence spectroscopy (PL), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), X-ray diffraction (XRD), cyclic voltammetry (CV), as well as ab initio modeling. These monomers exhibit broad absorption spectra from the ultraviolet (280–400 nm) to visible (400–600 nm) regions and emission spectra between 560 and 610 nm. The band gaps of these monomers were calculated to be in the range of 2.00–2.20 eV. These monomers were electropolymerized by scanning the potential between −0.5 and 2.0 V versus ferrocene for up to 50 cycles on a glassy carbon electrode. Arumugam, Sivanesan aut Manzhos, Sergei aut MacLeod, Jennifer aut Spratt, Henry J. aut O’Mullane, Anthony P. aut Sonar, Prashant aut Enthalten in Journal of materials research Springer International Publishing, 1986 32(2017), 14 vom: 01. Juli, Seite 2707-2718 (DE-627)129206288 (DE-600)54876-5 (DE-576)01445744X 0884-2914 nnns volume:32 year:2017 number:14 day:01 month:07 pages:2707-2718 https://doi.org/10.1557/jmr.2017.158 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_21 GBV_ILN_24 GBV_ILN_70 GBV_ILN_2005 GBV_ILN_2020 GBV_ILN_4126 GBV_ILN_4319 GBV_ILN_4323 VA 5350 AR 32 2017 14 01 07 2707-2718 |
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Investigation of thiophene flanked diketopyrrolopyrrole monomers with straight and branched alkyl chains and their electropolymerization study |
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(DE-627)OLC2122242345 (DE-He213)jmr.2017.158-p |
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Investigation of thiophene flanked diketopyrrolopyrrole monomers with straight and branched alkyl chains and their electropolymerization study |
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Ponnappa, Supreetha Paleyanda |
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Journal of materials research |
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Ponnappa, Supreetha Paleyanda Arumugam, Sivanesan Manzhos, Sergei MacLeod, Jennifer Spratt, Henry J. O’Mullane, Anthony P. Sonar, Prashant |
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10.1557/jmr.2017.158 |
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investigation of thiophene flanked diketopyrrolopyrrole monomers with straight and branched alkyl chains and their electropolymerization study |
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Investigation of thiophene flanked diketopyrrolopyrrole monomers with straight and branched alkyl chains and their electropolymerization study |
| abstract |
Abstract Diketopyrrolopyrrole (DPP) is a critically important building block that has gained importance in the organic electronics community because of its wide applicability in various devices. In this work, the thiophene flanked DPP moiety attached to alkyl chains of various lengths (this includes straight octyl and branched ethyl hexyl units) has been used as the monomer for electropolymerization. This paper focuses on the study of optical, thermal, solid state ordering and electrochemical properties of these electron deficient monomers using various characterization techniques such as UV–Vis spectrometry (UV), photo-luminescence spectroscopy (PL), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), X-ray diffraction (XRD), cyclic voltammetry (CV), as well as ab initio modeling. These monomers exhibit broad absorption spectra from the ultraviolet (280–400 nm) to visible (400–600 nm) regions and emission spectra between 560 and 610 nm. The band gaps of these monomers were calculated to be in the range of 2.00–2.20 eV. These monomers were electropolymerized by scanning the potential between −0.5 and 2.0 V versus ferrocene for up to 50 cycles on a glassy carbon electrode. © The Materials Research Society 2017 |
| abstractGer |
Abstract Diketopyrrolopyrrole (DPP) is a critically important building block that has gained importance in the organic electronics community because of its wide applicability in various devices. In this work, the thiophene flanked DPP moiety attached to alkyl chains of various lengths (this includes straight octyl and branched ethyl hexyl units) has been used as the monomer for electropolymerization. This paper focuses on the study of optical, thermal, solid state ordering and electrochemical properties of these electron deficient monomers using various characterization techniques such as UV–Vis spectrometry (UV), photo-luminescence spectroscopy (PL), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), X-ray diffraction (XRD), cyclic voltammetry (CV), as well as ab initio modeling. These monomers exhibit broad absorption spectra from the ultraviolet (280–400 nm) to visible (400–600 nm) regions and emission spectra between 560 and 610 nm. The band gaps of these monomers were calculated to be in the range of 2.00–2.20 eV. These monomers were electropolymerized by scanning the potential between −0.5 and 2.0 V versus ferrocene for up to 50 cycles on a glassy carbon electrode. © The Materials Research Society 2017 |
| abstract_unstemmed |
Abstract Diketopyrrolopyrrole (DPP) is a critically important building block that has gained importance in the organic electronics community because of its wide applicability in various devices. In this work, the thiophene flanked DPP moiety attached to alkyl chains of various lengths (this includes straight octyl and branched ethyl hexyl units) has been used as the monomer for electropolymerization. This paper focuses on the study of optical, thermal, solid state ordering and electrochemical properties of these electron deficient monomers using various characterization techniques such as UV–Vis spectrometry (UV), photo-luminescence spectroscopy (PL), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), X-ray diffraction (XRD), cyclic voltammetry (CV), as well as ab initio modeling. These monomers exhibit broad absorption spectra from the ultraviolet (280–400 nm) to visible (400–600 nm) regions and emission spectra between 560 and 610 nm. The band gaps of these monomers were calculated to be in the range of 2.00–2.20 eV. These monomers were electropolymerized by scanning the potential between −0.5 and 2.0 V versus ferrocene for up to 50 cycles on a glassy carbon electrode. © The Materials Research Society 2017 |
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Investigation of thiophene flanked diketopyrrolopyrrole monomers with straight and branched alkyl chains and their electropolymerization study |
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