Synthesis, structural topology, DFT, and photoluminescence properties of Sm(III) and octacyanomolybdate(V) building-block-based 1-D chain complex
Abstract A new one-dimensional cyanide-based coordination polymer comprising Sm(III) and octacyanomolybdate(V) building blocks was prepared and characterized through single-crystal X-ray diffraction and elemental analyses. The new compound consisted of one-dimensional chains of [Sm(terpy)(DMF)4] [Mo...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Muddassir, Mohd. [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2020 |
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| Anmerkung: |
© Springer Nature Switzerland AG 2020 |
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| Übergeordnetes Werk: |
Enthalten in: Transition metal chemistry - Springer International Publishing, 1975, 46(2020), 2 vom: 07. Nov., Seite 129-137 |
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| Übergeordnetes Werk: |
volume:46 ; year:2020 ; number:2 ; day:07 ; month:11 ; pages:129-137 |
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| DOI / URN: |
10.1007/s11243-020-00429-1 |
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| 520 | |a Abstract A new one-dimensional cyanide-based coordination polymer comprising Sm(III) and octacyanomolybdate(V) building blocks was prepared and characterized through single-crystal X-ray diffraction and elemental analyses. The new compound consisted of one-dimensional chains of [Sm(terpy)(DMF)4] [Mo(CN)8] (complex 1) (terpy: 2,2′:6′,2′′-terpyridine; DMF: N,N-dimethylformamide), where each Mo(CN)8 entity served as a bis-monodentate bridging ligand of two Sm(III) ions alternately through two of its six cyanide groups at cis positions. The corresponding chains were formed by hydrogen bonds, and van der Waals interactions to form a two-dimensional supramolecular structure that stabilized the entire molecule. Considering all the intermolecular interactions during the simplification procedure, we obtained a description of the molecular packing. The calculation results indicated that the underlying net corresponds to a new topology with the following point symbol {337.468.530.6}{38.42}. Density functional theory studies were also performed to elucidate the electronic structure within the entire complex. The good luminescence of the complex makes it a suitable material for construction of photoluminescent materials, to explore the intrinsic optical properties of lanthanides, and in sensing for detection of different hazardous/explosive materials. | ||
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10.1007/s11243-020-00429-1 doi (DE-627)OLC2123750239 (DE-He213)s11243-020-00429-1-p DE-627 ger DE-627 rakwb eng 660 VZ Muddassir, Mohd. verfasserin (orcid)0000-0001-7069-2557 aut Synthesis, structural topology, DFT, and photoluminescence properties of Sm(III) and octacyanomolybdate(V) building-block-based 1-D chain complex 2020 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Nature Switzerland AG 2020 Abstract A new one-dimensional cyanide-based coordination polymer comprising Sm(III) and octacyanomolybdate(V) building blocks was prepared and characterized through single-crystal X-ray diffraction and elemental analyses. The new compound consisted of one-dimensional chains of [Sm(terpy)(DMF)4] [Mo(CN)8] (complex 1) (terpy: 2,2′:6′,2′′-terpyridine; DMF: N,N-dimethylformamide), where each Mo(CN)8 entity served as a bis-monodentate bridging ligand of two Sm(III) ions alternately through two of its six cyanide groups at cis positions. The corresponding chains were formed by hydrogen bonds, and van der Waals interactions to form a two-dimensional supramolecular structure that stabilized the entire molecule. Considering all the intermolecular interactions during the simplification procedure, we obtained a description of the molecular packing. The calculation results indicated that the underlying net corresponds to a new topology with the following point symbol {337.468.530.6}{38.42}. Density functional theory studies were also performed to elucidate the electronic structure within the entire complex. The good luminescence of the complex makes it a suitable material for construction of photoluminescent materials, to explore the intrinsic optical properties of lanthanides, and in sensing for detection of different hazardous/explosive materials. Alarifi, Abdullah aut Afzal, Mohd aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 46(2020), 2 vom: 07. Nov., Seite 129-137 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:46 year:2020 number:2 day:07 month:11 pages:129-137 https://doi.org/10.1007/s11243-020-00429-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_4125 AR 46 2020 2 07 11 129-137 |
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10.1007/s11243-020-00429-1 doi (DE-627)OLC2123750239 (DE-He213)s11243-020-00429-1-p DE-627 ger DE-627 rakwb eng 660 VZ Muddassir, Mohd. verfasserin (orcid)0000-0001-7069-2557 aut Synthesis, structural topology, DFT, and photoluminescence properties of Sm(III) and octacyanomolybdate(V) building-block-based 1-D chain complex 2020 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Nature Switzerland AG 2020 Abstract A new one-dimensional cyanide-based coordination polymer comprising Sm(III) and octacyanomolybdate(V) building blocks was prepared and characterized through single-crystal X-ray diffraction and elemental analyses. The new compound consisted of one-dimensional chains of [Sm(terpy)(DMF)4] [Mo(CN)8] (complex 1) (terpy: 2,2′:6′,2′′-terpyridine; DMF: N,N-dimethylformamide), where each Mo(CN)8 entity served as a bis-monodentate bridging ligand of two Sm(III) ions alternately through two of its six cyanide groups at cis positions. The corresponding chains were formed by hydrogen bonds, and van der Waals interactions to form a two-dimensional supramolecular structure that stabilized the entire molecule. Considering all the intermolecular interactions during the simplification procedure, we obtained a description of the molecular packing. The calculation results indicated that the underlying net corresponds to a new topology with the following point symbol {337.468.530.6}{38.42}. Density functional theory studies were also performed to elucidate the electronic structure within the entire complex. The good luminescence of the complex makes it a suitable material for construction of photoluminescent materials, to explore the intrinsic optical properties of lanthanides, and in sensing for detection of different hazardous/explosive materials. Alarifi, Abdullah aut Afzal, Mohd aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 46(2020), 2 vom: 07. Nov., Seite 129-137 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:46 year:2020 number:2 day:07 month:11 pages:129-137 https://doi.org/10.1007/s11243-020-00429-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_4125 AR 46 2020 2 07 11 129-137 |
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10.1007/s11243-020-00429-1 doi (DE-627)OLC2123750239 (DE-He213)s11243-020-00429-1-p DE-627 ger DE-627 rakwb eng 660 VZ Muddassir, Mohd. verfasserin (orcid)0000-0001-7069-2557 aut Synthesis, structural topology, DFT, and photoluminescence properties of Sm(III) and octacyanomolybdate(V) building-block-based 1-D chain complex 2020 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Nature Switzerland AG 2020 Abstract A new one-dimensional cyanide-based coordination polymer comprising Sm(III) and octacyanomolybdate(V) building blocks was prepared and characterized through single-crystal X-ray diffraction and elemental analyses. The new compound consisted of one-dimensional chains of [Sm(terpy)(DMF)4] [Mo(CN)8] (complex 1) (terpy: 2,2′:6′,2′′-terpyridine; DMF: N,N-dimethylformamide), where each Mo(CN)8 entity served as a bis-monodentate bridging ligand of two Sm(III) ions alternately through two of its six cyanide groups at cis positions. The corresponding chains were formed by hydrogen bonds, and van der Waals interactions to form a two-dimensional supramolecular structure that stabilized the entire molecule. Considering all the intermolecular interactions during the simplification procedure, we obtained a description of the molecular packing. The calculation results indicated that the underlying net corresponds to a new topology with the following point symbol {337.468.530.6}{38.42}. Density functional theory studies were also performed to elucidate the electronic structure within the entire complex. The good luminescence of the complex makes it a suitable material for construction of photoluminescent materials, to explore the intrinsic optical properties of lanthanides, and in sensing for detection of different hazardous/explosive materials. Alarifi, Abdullah aut Afzal, Mohd aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 46(2020), 2 vom: 07. Nov., Seite 129-137 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:46 year:2020 number:2 day:07 month:11 pages:129-137 https://doi.org/10.1007/s11243-020-00429-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_4125 AR 46 2020 2 07 11 129-137 |
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10.1007/s11243-020-00429-1 doi (DE-627)OLC2123750239 (DE-He213)s11243-020-00429-1-p DE-627 ger DE-627 rakwb eng 660 VZ Muddassir, Mohd. verfasserin (orcid)0000-0001-7069-2557 aut Synthesis, structural topology, DFT, and photoluminescence properties of Sm(III) and octacyanomolybdate(V) building-block-based 1-D chain complex 2020 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Nature Switzerland AG 2020 Abstract A new one-dimensional cyanide-based coordination polymer comprising Sm(III) and octacyanomolybdate(V) building blocks was prepared and characterized through single-crystal X-ray diffraction and elemental analyses. The new compound consisted of one-dimensional chains of [Sm(terpy)(DMF)4] [Mo(CN)8] (complex 1) (terpy: 2,2′:6′,2′′-terpyridine; DMF: N,N-dimethylformamide), where each Mo(CN)8 entity served as a bis-monodentate bridging ligand of two Sm(III) ions alternately through two of its six cyanide groups at cis positions. The corresponding chains were formed by hydrogen bonds, and van der Waals interactions to form a two-dimensional supramolecular structure that stabilized the entire molecule. Considering all the intermolecular interactions during the simplification procedure, we obtained a description of the molecular packing. The calculation results indicated that the underlying net corresponds to a new topology with the following point symbol {337.468.530.6}{38.42}. Density functional theory studies were also performed to elucidate the electronic structure within the entire complex. The good luminescence of the complex makes it a suitable material for construction of photoluminescent materials, to explore the intrinsic optical properties of lanthanides, and in sensing for detection of different hazardous/explosive materials. Alarifi, Abdullah aut Afzal, Mohd aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 46(2020), 2 vom: 07. Nov., Seite 129-137 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:46 year:2020 number:2 day:07 month:11 pages:129-137 https://doi.org/10.1007/s11243-020-00429-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_4125 AR 46 2020 2 07 11 129-137 |
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10.1007/s11243-020-00429-1 doi (DE-627)OLC2123750239 (DE-He213)s11243-020-00429-1-p DE-627 ger DE-627 rakwb eng 660 VZ Muddassir, Mohd. verfasserin (orcid)0000-0001-7069-2557 aut Synthesis, structural topology, DFT, and photoluminescence properties of Sm(III) and octacyanomolybdate(V) building-block-based 1-D chain complex 2020 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Nature Switzerland AG 2020 Abstract A new one-dimensional cyanide-based coordination polymer comprising Sm(III) and octacyanomolybdate(V) building blocks was prepared and characterized through single-crystal X-ray diffraction and elemental analyses. The new compound consisted of one-dimensional chains of [Sm(terpy)(DMF)4] [Mo(CN)8] (complex 1) (terpy: 2,2′:6′,2′′-terpyridine; DMF: N,N-dimethylformamide), where each Mo(CN)8 entity served as a bis-monodentate bridging ligand of two Sm(III) ions alternately through two of its six cyanide groups at cis positions. The corresponding chains were formed by hydrogen bonds, and van der Waals interactions to form a two-dimensional supramolecular structure that stabilized the entire molecule. Considering all the intermolecular interactions during the simplification procedure, we obtained a description of the molecular packing. The calculation results indicated that the underlying net corresponds to a new topology with the following point symbol {337.468.530.6}{38.42}. Density functional theory studies were also performed to elucidate the electronic structure within the entire complex. The good luminescence of the complex makes it a suitable material for construction of photoluminescent materials, to explore the intrinsic optical properties of lanthanides, and in sensing for detection of different hazardous/explosive materials. Alarifi, Abdullah aut Afzal, Mohd aut Enthalten in Transition metal chemistry Springer International Publishing, 1975 46(2020), 2 vom: 07. Nov., Seite 129-137 (DE-627)129605417 (DE-600)242084-3 (DE-576)015099652 0340-4285 nnns volume:46 year:2020 number:2 day:07 month:11 pages:129-137 https://doi.org/10.1007/s11243-020-00429-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_4125 AR 46 2020 2 07 11 129-137 |
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Synthesis, structural topology, DFT, and photoluminescence properties of Sm(III) and octacyanomolybdate(V) building-block-based 1-D chain complex |
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Abstract A new one-dimensional cyanide-based coordination polymer comprising Sm(III) and octacyanomolybdate(V) building blocks was prepared and characterized through single-crystal X-ray diffraction and elemental analyses. The new compound consisted of one-dimensional chains of [Sm(terpy)(DMF)4] [Mo(CN)8] (complex 1) (terpy: 2,2′:6′,2′′-terpyridine; DMF: N,N-dimethylformamide), where each Mo(CN)8 entity served as a bis-monodentate bridging ligand of two Sm(III) ions alternately through two of its six cyanide groups at cis positions. The corresponding chains were formed by hydrogen bonds, and van der Waals interactions to form a two-dimensional supramolecular structure that stabilized the entire molecule. Considering all the intermolecular interactions during the simplification procedure, we obtained a description of the molecular packing. The calculation results indicated that the underlying net corresponds to a new topology with the following point symbol {337.468.530.6}{38.42}. Density functional theory studies were also performed to elucidate the electronic structure within the entire complex. The good luminescence of the complex makes it a suitable material for construction of photoluminescent materials, to explore the intrinsic optical properties of lanthanides, and in sensing for detection of different hazardous/explosive materials. © Springer Nature Switzerland AG 2020 |
| abstractGer |
Abstract A new one-dimensional cyanide-based coordination polymer comprising Sm(III) and octacyanomolybdate(V) building blocks was prepared and characterized through single-crystal X-ray diffraction and elemental analyses. The new compound consisted of one-dimensional chains of [Sm(terpy)(DMF)4] [Mo(CN)8] (complex 1) (terpy: 2,2′:6′,2′′-terpyridine; DMF: N,N-dimethylformamide), where each Mo(CN)8 entity served as a bis-monodentate bridging ligand of two Sm(III) ions alternately through two of its six cyanide groups at cis positions. The corresponding chains were formed by hydrogen bonds, and van der Waals interactions to form a two-dimensional supramolecular structure that stabilized the entire molecule. Considering all the intermolecular interactions during the simplification procedure, we obtained a description of the molecular packing. The calculation results indicated that the underlying net corresponds to a new topology with the following point symbol {337.468.530.6}{38.42}. Density functional theory studies were also performed to elucidate the electronic structure within the entire complex. The good luminescence of the complex makes it a suitable material for construction of photoluminescent materials, to explore the intrinsic optical properties of lanthanides, and in sensing for detection of different hazardous/explosive materials. © Springer Nature Switzerland AG 2020 |
| abstract_unstemmed |
Abstract A new one-dimensional cyanide-based coordination polymer comprising Sm(III) and octacyanomolybdate(V) building blocks was prepared and characterized through single-crystal X-ray diffraction and elemental analyses. The new compound consisted of one-dimensional chains of [Sm(terpy)(DMF)4] [Mo(CN)8] (complex 1) (terpy: 2,2′:6′,2′′-terpyridine; DMF: N,N-dimethylformamide), where each Mo(CN)8 entity served as a bis-monodentate bridging ligand of two Sm(III) ions alternately through two of its six cyanide groups at cis positions. The corresponding chains were formed by hydrogen bonds, and van der Waals interactions to form a two-dimensional supramolecular structure that stabilized the entire molecule. Considering all the intermolecular interactions during the simplification procedure, we obtained a description of the molecular packing. The calculation results indicated that the underlying net corresponds to a new topology with the following point symbol {337.468.530.6}{38.42}. Density functional theory studies were also performed to elucidate the electronic structure within the entire complex. The good luminescence of the complex makes it a suitable material for construction of photoluminescent materials, to explore the intrinsic optical properties of lanthanides, and in sensing for detection of different hazardous/explosive materials. © Springer Nature Switzerland AG 2020 |
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Synthesis, structural topology, DFT, and photoluminescence properties of Sm(III) and octacyanomolybdate(V) building-block-based 1-D chain complex |
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https://doi.org/10.1007/s11243-020-00429-1 |
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Alarifi, Abdullah Afzal, Mohd |
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10.1007/s11243-020-00429-1 |
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