Length-dependent melting behavior of Sn nanowires
Abstract Using in situ transmission electron microscopy, we report the observation of the melting behavior of one-dimensional nanostructures of Sn with different length/width aspect ratios. The melting of small aspect-ratio nanowires (nanorods) results in the expansion of liquid Sn along both axial...
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| Autor*in: |
Yin, Qiyue [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2017 |
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| Systematik: |
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| Anmerkung: |
© The Materials Research Society 2017 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of materials research - Springer International Publishing, 1986, 32(2017), 6 vom: 21. Feb., Seite 1194-1202 |
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| Übergeordnetes Werk: |
volume:32 ; year:2017 ; number:6 ; day:21 ; month:02 ; pages:1194-1202 |
| Links: |
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| DOI / URN: |
10.1557/jmr.2017.45 |
|---|
| Katalog-ID: |
OLC2123769908 |
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| 520 | |a Abstract Using in situ transmission electron microscopy, we report the observation of the melting behavior of one-dimensional nanostructures of Sn with different length/width aspect ratios. The melting of small aspect-ratio nanowires (nanorods) results in the expansion of liquid Sn along both axial and radial directions with the tendency to form an isometric or spherical particle, thereby minimizing the total surface area. For nanowires with the length/width aspect ratio of ∼10.5, perturbation along the liquid stream causes an unstable necking phenomenon and the whole wire tends to shrink into a spherical particle. In contrast, Rayleigh instability sets in for the melting of the nanowires with the length/width aspect ratio as large as ∼21, which gives rise to necking and fragmentation of the wire into particles. The amorphous native surface oxide ($ SnO_{x} $) layer serves as a confinement tube and plays an important role in the melting induced morphological evolution of Sn nanowires. A thin $ SnO_{x} $ layer is flexible with the ability to shrink or expand upon the flow of molten Sn. The increased rigidity for a thick $ SnO_{x} $ surface layer kinetically suppresses bulging and necking formation in molten Sn nanowires. | ||
| 700 | 1 | |a Gao, Fan |4 aut | |
| 700 | 1 | |a Wang, Jirui |4 aut | |
| 700 | 1 | |a Gu, Zhiyong |4 aut | |
| 700 | 1 | |a Stach, Eric A. |4 aut | |
| 700 | 1 | |a Zhou, Guangwen |4 aut | |
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10.1557/jmr.2017.45 doi (DE-627)OLC2123769908 (DE-He213)jmr.2017.45-p DE-627 ger DE-627 rakwb eng 670 VZ VA 5350 VZ rvk Yin, Qiyue verfasserin aut Length-dependent melting behavior of Sn nanowires 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Materials Research Society 2017 Abstract Using in situ transmission electron microscopy, we report the observation of the melting behavior of one-dimensional nanostructures of Sn with different length/width aspect ratios. The melting of small aspect-ratio nanowires (nanorods) results in the expansion of liquid Sn along both axial and radial directions with the tendency to form an isometric or spherical particle, thereby minimizing the total surface area. For nanowires with the length/width aspect ratio of ∼10.5, perturbation along the liquid stream causes an unstable necking phenomenon and the whole wire tends to shrink into a spherical particle. In contrast, Rayleigh instability sets in for the melting of the nanowires with the length/width aspect ratio as large as ∼21, which gives rise to necking and fragmentation of the wire into particles. The amorphous native surface oxide ($ SnO_{x} $) layer serves as a confinement tube and plays an important role in the melting induced morphological evolution of Sn nanowires. A thin $ SnO_{x} $ layer is flexible with the ability to shrink or expand upon the flow of molten Sn. The increased rigidity for a thick $ SnO_{x} $ surface layer kinetically suppresses bulging and necking formation in molten Sn nanowires. Gao, Fan aut Wang, Jirui aut Gu, Zhiyong aut Stach, Eric A. aut Zhou, Guangwen aut Enthalten in Journal of materials research Springer International Publishing, 1986 32(2017), 6 vom: 21. Feb., Seite 1194-1202 (DE-627)129206288 (DE-600)54876-5 (DE-576)01445744X 0884-2914 nnns volume:32 year:2017 number:6 day:21 month:02 pages:1194-1202 https://doi.org/10.1557/jmr.2017.45 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_21 GBV_ILN_24 GBV_ILN_70 GBV_ILN_2005 GBV_ILN_2020 GBV_ILN_4126 GBV_ILN_4319 GBV_ILN_4323 VA 5350 AR 32 2017 6 21 02 1194-1202 |
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10.1557/jmr.2017.45 doi (DE-627)OLC2123769908 (DE-He213)jmr.2017.45-p DE-627 ger DE-627 rakwb eng 670 VZ VA 5350 VZ rvk Yin, Qiyue verfasserin aut Length-dependent melting behavior of Sn nanowires 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Materials Research Society 2017 Abstract Using in situ transmission electron microscopy, we report the observation of the melting behavior of one-dimensional nanostructures of Sn with different length/width aspect ratios. The melting of small aspect-ratio nanowires (nanorods) results in the expansion of liquid Sn along both axial and radial directions with the tendency to form an isometric or spherical particle, thereby minimizing the total surface area. For nanowires with the length/width aspect ratio of ∼10.5, perturbation along the liquid stream causes an unstable necking phenomenon and the whole wire tends to shrink into a spherical particle. In contrast, Rayleigh instability sets in for the melting of the nanowires with the length/width aspect ratio as large as ∼21, which gives rise to necking and fragmentation of the wire into particles. The amorphous native surface oxide ($ SnO_{x} $) layer serves as a confinement tube and plays an important role in the melting induced morphological evolution of Sn nanowires. A thin $ SnO_{x} $ layer is flexible with the ability to shrink or expand upon the flow of molten Sn. The increased rigidity for a thick $ SnO_{x} $ surface layer kinetically suppresses bulging and necking formation in molten Sn nanowires. Gao, Fan aut Wang, Jirui aut Gu, Zhiyong aut Stach, Eric A. aut Zhou, Guangwen aut Enthalten in Journal of materials research Springer International Publishing, 1986 32(2017), 6 vom: 21. Feb., Seite 1194-1202 (DE-627)129206288 (DE-600)54876-5 (DE-576)01445744X 0884-2914 nnns volume:32 year:2017 number:6 day:21 month:02 pages:1194-1202 https://doi.org/10.1557/jmr.2017.45 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_21 GBV_ILN_24 GBV_ILN_70 GBV_ILN_2005 GBV_ILN_2020 GBV_ILN_4126 GBV_ILN_4319 GBV_ILN_4323 VA 5350 AR 32 2017 6 21 02 1194-1202 |
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10.1557/jmr.2017.45 doi (DE-627)OLC2123769908 (DE-He213)jmr.2017.45-p DE-627 ger DE-627 rakwb eng 670 VZ VA 5350 VZ rvk Yin, Qiyue verfasserin aut Length-dependent melting behavior of Sn nanowires 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Materials Research Society 2017 Abstract Using in situ transmission electron microscopy, we report the observation of the melting behavior of one-dimensional nanostructures of Sn with different length/width aspect ratios. The melting of small aspect-ratio nanowires (nanorods) results in the expansion of liquid Sn along both axial and radial directions with the tendency to form an isometric or spherical particle, thereby minimizing the total surface area. For nanowires with the length/width aspect ratio of ∼10.5, perturbation along the liquid stream causes an unstable necking phenomenon and the whole wire tends to shrink into a spherical particle. In contrast, Rayleigh instability sets in for the melting of the nanowires with the length/width aspect ratio as large as ∼21, which gives rise to necking and fragmentation of the wire into particles. The amorphous native surface oxide ($ SnO_{x} $) layer serves as a confinement tube and plays an important role in the melting induced morphological evolution of Sn nanowires. A thin $ SnO_{x} $ layer is flexible with the ability to shrink or expand upon the flow of molten Sn. The increased rigidity for a thick $ SnO_{x} $ surface layer kinetically suppresses bulging and necking formation in molten Sn nanowires. Gao, Fan aut Wang, Jirui aut Gu, Zhiyong aut Stach, Eric A. aut Zhou, Guangwen aut Enthalten in Journal of materials research Springer International Publishing, 1986 32(2017), 6 vom: 21. Feb., Seite 1194-1202 (DE-627)129206288 (DE-600)54876-5 (DE-576)01445744X 0884-2914 nnns volume:32 year:2017 number:6 day:21 month:02 pages:1194-1202 https://doi.org/10.1557/jmr.2017.45 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_21 GBV_ILN_24 GBV_ILN_70 GBV_ILN_2005 GBV_ILN_2020 GBV_ILN_4126 GBV_ILN_4319 GBV_ILN_4323 VA 5350 AR 32 2017 6 21 02 1194-1202 |
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10.1557/jmr.2017.45 doi (DE-627)OLC2123769908 (DE-He213)jmr.2017.45-p DE-627 ger DE-627 rakwb eng 670 VZ VA 5350 VZ rvk Yin, Qiyue verfasserin aut Length-dependent melting behavior of Sn nanowires 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Materials Research Society 2017 Abstract Using in situ transmission electron microscopy, we report the observation of the melting behavior of one-dimensional nanostructures of Sn with different length/width aspect ratios. The melting of small aspect-ratio nanowires (nanorods) results in the expansion of liquid Sn along both axial and radial directions with the tendency to form an isometric or spherical particle, thereby minimizing the total surface area. For nanowires with the length/width aspect ratio of ∼10.5, perturbation along the liquid stream causes an unstable necking phenomenon and the whole wire tends to shrink into a spherical particle. In contrast, Rayleigh instability sets in for the melting of the nanowires with the length/width aspect ratio as large as ∼21, which gives rise to necking and fragmentation of the wire into particles. The amorphous native surface oxide ($ SnO_{x} $) layer serves as a confinement tube and plays an important role in the melting induced morphological evolution of Sn nanowires. A thin $ SnO_{x} $ layer is flexible with the ability to shrink or expand upon the flow of molten Sn. The increased rigidity for a thick $ SnO_{x} $ surface layer kinetically suppresses bulging and necking formation in molten Sn nanowires. Gao, Fan aut Wang, Jirui aut Gu, Zhiyong aut Stach, Eric A. aut Zhou, Guangwen aut Enthalten in Journal of materials research Springer International Publishing, 1986 32(2017), 6 vom: 21. Feb., Seite 1194-1202 (DE-627)129206288 (DE-600)54876-5 (DE-576)01445744X 0884-2914 nnns volume:32 year:2017 number:6 day:21 month:02 pages:1194-1202 https://doi.org/10.1557/jmr.2017.45 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_21 GBV_ILN_24 GBV_ILN_70 GBV_ILN_2005 GBV_ILN_2020 GBV_ILN_4126 GBV_ILN_4319 GBV_ILN_4323 VA 5350 AR 32 2017 6 21 02 1194-1202 |
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10.1557/jmr.2017.45 doi (DE-627)OLC2123769908 (DE-He213)jmr.2017.45-p DE-627 ger DE-627 rakwb eng 670 VZ VA 5350 VZ rvk Yin, Qiyue verfasserin aut Length-dependent melting behavior of Sn nanowires 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Materials Research Society 2017 Abstract Using in situ transmission electron microscopy, we report the observation of the melting behavior of one-dimensional nanostructures of Sn with different length/width aspect ratios. The melting of small aspect-ratio nanowires (nanorods) results in the expansion of liquid Sn along both axial and radial directions with the tendency to form an isometric or spherical particle, thereby minimizing the total surface area. For nanowires with the length/width aspect ratio of ∼10.5, perturbation along the liquid stream causes an unstable necking phenomenon and the whole wire tends to shrink into a spherical particle. In contrast, Rayleigh instability sets in for the melting of the nanowires with the length/width aspect ratio as large as ∼21, which gives rise to necking and fragmentation of the wire into particles. The amorphous native surface oxide ($ SnO_{x} $) layer serves as a confinement tube and plays an important role in the melting induced morphological evolution of Sn nanowires. A thin $ SnO_{x} $ layer is flexible with the ability to shrink or expand upon the flow of molten Sn. The increased rigidity for a thick $ SnO_{x} $ surface layer kinetically suppresses bulging and necking formation in molten Sn nanowires. Gao, Fan aut Wang, Jirui aut Gu, Zhiyong aut Stach, Eric A. aut Zhou, Guangwen aut Enthalten in Journal of materials research Springer International Publishing, 1986 32(2017), 6 vom: 21. Feb., Seite 1194-1202 (DE-627)129206288 (DE-600)54876-5 (DE-576)01445744X 0884-2914 nnns volume:32 year:2017 number:6 day:21 month:02 pages:1194-1202 https://doi.org/10.1557/jmr.2017.45 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_21 GBV_ILN_24 GBV_ILN_70 GBV_ILN_2005 GBV_ILN_2020 GBV_ILN_4126 GBV_ILN_4319 GBV_ILN_4323 VA 5350 AR 32 2017 6 21 02 1194-1202 |
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Length-dependent melting behavior of Sn nanowires |
| abstract |
Abstract Using in situ transmission electron microscopy, we report the observation of the melting behavior of one-dimensional nanostructures of Sn with different length/width aspect ratios. The melting of small aspect-ratio nanowires (nanorods) results in the expansion of liquid Sn along both axial and radial directions with the tendency to form an isometric or spherical particle, thereby minimizing the total surface area. For nanowires with the length/width aspect ratio of ∼10.5, perturbation along the liquid stream causes an unstable necking phenomenon and the whole wire tends to shrink into a spherical particle. In contrast, Rayleigh instability sets in for the melting of the nanowires with the length/width aspect ratio as large as ∼21, which gives rise to necking and fragmentation of the wire into particles. The amorphous native surface oxide ($ SnO_{x} $) layer serves as a confinement tube and plays an important role in the melting induced morphological evolution of Sn nanowires. A thin $ SnO_{x} $ layer is flexible with the ability to shrink or expand upon the flow of molten Sn. The increased rigidity for a thick $ SnO_{x} $ surface layer kinetically suppresses bulging and necking formation in molten Sn nanowires. © The Materials Research Society 2017 |
| abstractGer |
Abstract Using in situ transmission electron microscopy, we report the observation of the melting behavior of one-dimensional nanostructures of Sn with different length/width aspect ratios. The melting of small aspect-ratio nanowires (nanorods) results in the expansion of liquid Sn along both axial and radial directions with the tendency to form an isometric or spherical particle, thereby minimizing the total surface area. For nanowires with the length/width aspect ratio of ∼10.5, perturbation along the liquid stream causes an unstable necking phenomenon and the whole wire tends to shrink into a spherical particle. In contrast, Rayleigh instability sets in for the melting of the nanowires with the length/width aspect ratio as large as ∼21, which gives rise to necking and fragmentation of the wire into particles. The amorphous native surface oxide ($ SnO_{x} $) layer serves as a confinement tube and plays an important role in the melting induced morphological evolution of Sn nanowires. A thin $ SnO_{x} $ layer is flexible with the ability to shrink or expand upon the flow of molten Sn. The increased rigidity for a thick $ SnO_{x} $ surface layer kinetically suppresses bulging and necking formation in molten Sn nanowires. © The Materials Research Society 2017 |
| abstract_unstemmed |
Abstract Using in situ transmission electron microscopy, we report the observation of the melting behavior of one-dimensional nanostructures of Sn with different length/width aspect ratios. The melting of small aspect-ratio nanowires (nanorods) results in the expansion of liquid Sn along both axial and radial directions with the tendency to form an isometric or spherical particle, thereby minimizing the total surface area. For nanowires with the length/width aspect ratio of ∼10.5, perturbation along the liquid stream causes an unstable necking phenomenon and the whole wire tends to shrink into a spherical particle. In contrast, Rayleigh instability sets in for the melting of the nanowires with the length/width aspect ratio as large as ∼21, which gives rise to necking and fragmentation of the wire into particles. The amorphous native surface oxide ($ SnO_{x} $) layer serves as a confinement tube and plays an important role in the melting induced morphological evolution of Sn nanowires. A thin $ SnO_{x} $ layer is flexible with the ability to shrink or expand upon the flow of molten Sn. The increased rigidity for a thick $ SnO_{x} $ surface layer kinetically suppresses bulging and necking formation in molten Sn nanowires. © The Materials Research Society 2017 |
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| title_short |
Length-dependent melting behavior of Sn nanowires |
| url |
https://doi.org/10.1557/jmr.2017.45 |
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false |
| author2 |
Gao, Fan Wang, Jirui Gu, Zhiyong Stach, Eric A. Zhou, Guangwen |
| author2Str |
Gao, Fan Wang, Jirui Gu, Zhiyong Stach, Eric A. Zhou, Guangwen |
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| doi_str |
10.1557/jmr.2017.45 |
| up_date |
2024-07-03T19:59:54.131Z |
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