Dye Removal Characteristics of Magnetic Biochar Derived from Sewage Sludge: Isotherm, Thermodynamics, Kinetics, and Mechanism
Abstract The efficient and relatively simple modification of various biochars to facilitate their environmental applications and enhance the cost/effectiveness ratio is still a challenge. In this work, biochar prepared by pyrolysis of wastewater sewage sludge at 400 °C and 750 °C was tested for meth...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Zeghioud, Hicham [verfasserIn] |
|---|
| Format: |
Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2023 |
|---|
| Schlagwörter: |
|---|
| Systematik: |
|
|---|
| Anmerkung: |
© The Author(s), under exclusive licence to Springer Nature Switzerland AG 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
|---|
| Übergeordnetes Werk: |
Enthalten in: Water, air & soil pollution - Springer International Publishing, 1971, 234(2023), 4 vom: 27. März |
|---|---|
| Übergeordnetes Werk: |
volume:234 ; year:2023 ; number:4 ; day:27 ; month:03 |
| Links: |
|---|
| DOI / URN: |
10.1007/s11270-023-06251-6 |
|---|
| Katalog-ID: |
OLC2134625686 |
|---|
| LEADER | 01000naa a22002652 4500 | ||
|---|---|---|---|
| 001 | OLC2134625686 | ||
| 003 | DE-627 | ||
| 005 | 20230510162759.0 | ||
| 007 | tu | ||
| 008 | 230510s2023 xx ||||| 00| ||eng c | ||
| 024 | 7 | |a 10.1007/s11270-023-06251-6 |2 doi | |
| 035 | |a (DE-627)OLC2134625686 | ||
| 035 | |a (DE-He213)s11270-023-06251-6-p | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 082 | 0 | 4 | |a 570 |a 333.7 |q VZ |
| 084 | |a 12 |a 13 |2 ssgn | ||
| 084 | |a BIODIV |q DE-30 |2 fid | ||
| 084 | |a ZC 7520 |q VZ |2 rvk | ||
| 084 | |a ZC 7520 |q VZ |2 rvk | ||
| 100 | 1 | |a Zeghioud, Hicham |e verfasserin |0 (orcid)0000-0002-3113-041X |4 aut | |
| 245 | 1 | 0 | |a Dye Removal Characteristics of Magnetic Biochar Derived from Sewage Sludge: Isotherm, Thermodynamics, Kinetics, and Mechanism |
| 264 | 1 | |c 2023 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a ohne Hilfsmittel zu benutzen |b n |2 rdamedia | ||
| 338 | |a Band |b nc |2 rdacarrier | ||
| 500 | |a © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. | ||
| 520 | |a Abstract The efficient and relatively simple modification of various biochars to facilitate their environmental applications and enhance the cost/effectiveness ratio is still a challenge. In this work, biochar prepared by pyrolysis of wastewater sewage sludge at 400 °C and 750 °C was tested for methylene blue (MB) adsorption. Biochar which was prepared at 750 °C (SSB) and presented high adsorption capacity was magnetized by applying co-precipitation techniques. The magnetic biochar was obtained (SSMB) and the pristine biochar for methylene blue (MB) was removed in an aqueous solution. The sewage sludge biochar (SSB) and the magnetic sewage sludge biochar (SSMB) were characterized by SEM-EDS, BET, mercury porosimeter, FTIR, and Raman spectroscopy. The results showed a decrease in specific surface area and total pore volume after magnetization from 51.82 to 3.37 $ m^{2} $/g and from 0.899 to 0.588 $ cm^{3} $/g, respectively. An increase in the average pore diameter (from 0.086 to 1.109 μm) and surface functional groups was recorded in SSMB compared to SSB. SSMB presented 55.6 mg/g of adsorption capacity meanwhile SSB presented a value of 54.23 mg/g for the removal of C0 = 40 mg/L of MB under an optimized pH and biochar dose. The kinetic study and isotherm modeling revealed that the adsorption of MB on SSB and SSMB is driven by physical interactions on heterogenous sites dominated by pore filling, hydrogen bonding, π-π, and n-π interaction mechanism. The thermodynamic study showed that the adsorption is endothermic and favorable on both biochars. The regeneration tests exhibit NaOH treatment for MB desorption as a promising technique with a minor loss of adsorption capacities of 7.6 and 5.8% for SSB and SSMB, respectively. | ||
| 650 | 4 | |a Magnetic biochar | |
| 650 | 4 | |a Adsorption | |
| 650 | 4 | |a Methylene blue | |
| 650 | 4 | |a Mechanism | |
| 650 | 4 | |a Modeling | |
| 700 | 1 | |a Mouhamadou, Sali |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Water, air & soil pollution |d Springer International Publishing, 1971 |g 234(2023), 4 vom: 27. März |w (DE-627)12929134X |w (DE-600)120499-3 |w (DE-576)014472643 |x 0049-6979 |7 nnns |
| 773 | 1 | 8 | |g volume:234 |g year:2023 |g number:4 |g day:27 |g month:03 |
| 856 | 4 | 1 | |u https://doi.org/10.1007/s11270-023-06251-6 |z lizenzpflichtig |3 Volltext |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a SYSFLAG_A | ||
| 912 | |a GBV_OLC | ||
| 912 | |a FID-BIODIV | ||
| 912 | |a SSG-OLC-UMW | ||
| 912 | |a SSG-OLC-TEC | ||
| 912 | |a SSG-OLC-FOR | ||
| 912 | |a SSG-OLC-IBL | ||
| 912 | |a SSG-OPC-GGO | ||
| 936 | r | v | |a ZC 7520 |
| 936 | r | v | |a ZC 7520 |
| 951 | |a AR | ||
| 952 | |d 234 |j 2023 |e 4 |b 27 |c 03 | ||
| author_variant |
h z hz s m sm |
|---|---|
| matchkey_str |
article:00496979:2023----::yrmvlhrceitcomgeibohreiefoswgsugiohrtem |
| hierarchy_sort_str |
2023 |
| publishDate |
2023 |
| allfields |
10.1007/s11270-023-06251-6 doi (DE-627)OLC2134625686 (DE-He213)s11270-023-06251-6-p DE-627 ger DE-627 rakwb eng 570 333.7 VZ 12 13 ssgn BIODIV DE-30 fid ZC 7520 VZ rvk ZC 7520 VZ rvk Zeghioud, Hicham verfasserin (orcid)0000-0002-3113-041X aut Dye Removal Characteristics of Magnetic Biochar Derived from Sewage Sludge: Isotherm, Thermodynamics, Kinetics, and Mechanism 2023 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The efficient and relatively simple modification of various biochars to facilitate their environmental applications and enhance the cost/effectiveness ratio is still a challenge. In this work, biochar prepared by pyrolysis of wastewater sewage sludge at 400 °C and 750 °C was tested for methylene blue (MB) adsorption. Biochar which was prepared at 750 °C (SSB) and presented high adsorption capacity was magnetized by applying co-precipitation techniques. The magnetic biochar was obtained (SSMB) and the pristine biochar for methylene blue (MB) was removed in an aqueous solution. The sewage sludge biochar (SSB) and the magnetic sewage sludge biochar (SSMB) were characterized by SEM-EDS, BET, mercury porosimeter, FTIR, and Raman spectroscopy. The results showed a decrease in specific surface area and total pore volume after magnetization from 51.82 to 3.37 $ m^{2} $/g and from 0.899 to 0.588 $ cm^{3} $/g, respectively. An increase in the average pore diameter (from 0.086 to 1.109 μm) and surface functional groups was recorded in SSMB compared to SSB. SSMB presented 55.6 mg/g of adsorption capacity meanwhile SSB presented a value of 54.23 mg/g for the removal of C0 = 40 mg/L of MB under an optimized pH and biochar dose. The kinetic study and isotherm modeling revealed that the adsorption of MB on SSB and SSMB is driven by physical interactions on heterogenous sites dominated by pore filling, hydrogen bonding, π-π, and n-π interaction mechanism. The thermodynamic study showed that the adsorption is endothermic and favorable on both biochars. The regeneration tests exhibit NaOH treatment for MB desorption as a promising technique with a minor loss of adsorption capacities of 7.6 and 5.8% for SSB and SSMB, respectively. Magnetic biochar Adsorption Methylene blue Mechanism Modeling Mouhamadou, Sali aut Enthalten in Water, air & soil pollution Springer International Publishing, 1971 234(2023), 4 vom: 27. März (DE-627)12929134X (DE-600)120499-3 (DE-576)014472643 0049-6979 nnns volume:234 year:2023 number:4 day:27 month:03 https://doi.org/10.1007/s11270-023-06251-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-UMW SSG-OLC-TEC SSG-OLC-FOR SSG-OLC-IBL SSG-OPC-GGO ZC 7520 ZC 7520 AR 234 2023 4 27 03 |
| spelling |
10.1007/s11270-023-06251-6 doi (DE-627)OLC2134625686 (DE-He213)s11270-023-06251-6-p DE-627 ger DE-627 rakwb eng 570 333.7 VZ 12 13 ssgn BIODIV DE-30 fid ZC 7520 VZ rvk ZC 7520 VZ rvk Zeghioud, Hicham verfasserin (orcid)0000-0002-3113-041X aut Dye Removal Characteristics of Magnetic Biochar Derived from Sewage Sludge: Isotherm, Thermodynamics, Kinetics, and Mechanism 2023 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The efficient and relatively simple modification of various biochars to facilitate their environmental applications and enhance the cost/effectiveness ratio is still a challenge. In this work, biochar prepared by pyrolysis of wastewater sewage sludge at 400 °C and 750 °C was tested for methylene blue (MB) adsorption. Biochar which was prepared at 750 °C (SSB) and presented high adsorption capacity was magnetized by applying co-precipitation techniques. The magnetic biochar was obtained (SSMB) and the pristine biochar for methylene blue (MB) was removed in an aqueous solution. The sewage sludge biochar (SSB) and the magnetic sewage sludge biochar (SSMB) were characterized by SEM-EDS, BET, mercury porosimeter, FTIR, and Raman spectroscopy. The results showed a decrease in specific surface area and total pore volume after magnetization from 51.82 to 3.37 $ m^{2} $/g and from 0.899 to 0.588 $ cm^{3} $/g, respectively. An increase in the average pore diameter (from 0.086 to 1.109 μm) and surface functional groups was recorded in SSMB compared to SSB. SSMB presented 55.6 mg/g of adsorption capacity meanwhile SSB presented a value of 54.23 mg/g for the removal of C0 = 40 mg/L of MB under an optimized pH and biochar dose. The kinetic study and isotherm modeling revealed that the adsorption of MB on SSB and SSMB is driven by physical interactions on heterogenous sites dominated by pore filling, hydrogen bonding, π-π, and n-π interaction mechanism. The thermodynamic study showed that the adsorption is endothermic and favorable on both biochars. The regeneration tests exhibit NaOH treatment for MB desorption as a promising technique with a minor loss of adsorption capacities of 7.6 and 5.8% for SSB and SSMB, respectively. Magnetic biochar Adsorption Methylene blue Mechanism Modeling Mouhamadou, Sali aut Enthalten in Water, air & soil pollution Springer International Publishing, 1971 234(2023), 4 vom: 27. März (DE-627)12929134X (DE-600)120499-3 (DE-576)014472643 0049-6979 nnns volume:234 year:2023 number:4 day:27 month:03 https://doi.org/10.1007/s11270-023-06251-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-UMW SSG-OLC-TEC SSG-OLC-FOR SSG-OLC-IBL SSG-OPC-GGO ZC 7520 ZC 7520 AR 234 2023 4 27 03 |
| allfields_unstemmed |
10.1007/s11270-023-06251-6 doi (DE-627)OLC2134625686 (DE-He213)s11270-023-06251-6-p DE-627 ger DE-627 rakwb eng 570 333.7 VZ 12 13 ssgn BIODIV DE-30 fid ZC 7520 VZ rvk ZC 7520 VZ rvk Zeghioud, Hicham verfasserin (orcid)0000-0002-3113-041X aut Dye Removal Characteristics of Magnetic Biochar Derived from Sewage Sludge: Isotherm, Thermodynamics, Kinetics, and Mechanism 2023 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The efficient and relatively simple modification of various biochars to facilitate their environmental applications and enhance the cost/effectiveness ratio is still a challenge. In this work, biochar prepared by pyrolysis of wastewater sewage sludge at 400 °C and 750 °C was tested for methylene blue (MB) adsorption. Biochar which was prepared at 750 °C (SSB) and presented high adsorption capacity was magnetized by applying co-precipitation techniques. The magnetic biochar was obtained (SSMB) and the pristine biochar for methylene blue (MB) was removed in an aqueous solution. The sewage sludge biochar (SSB) and the magnetic sewage sludge biochar (SSMB) were characterized by SEM-EDS, BET, mercury porosimeter, FTIR, and Raman spectroscopy. The results showed a decrease in specific surface area and total pore volume after magnetization from 51.82 to 3.37 $ m^{2} $/g and from 0.899 to 0.588 $ cm^{3} $/g, respectively. An increase in the average pore diameter (from 0.086 to 1.109 μm) and surface functional groups was recorded in SSMB compared to SSB. SSMB presented 55.6 mg/g of adsorption capacity meanwhile SSB presented a value of 54.23 mg/g for the removal of C0 = 40 mg/L of MB under an optimized pH and biochar dose. The kinetic study and isotherm modeling revealed that the adsorption of MB on SSB and SSMB is driven by physical interactions on heterogenous sites dominated by pore filling, hydrogen bonding, π-π, and n-π interaction mechanism. The thermodynamic study showed that the adsorption is endothermic and favorable on both biochars. The regeneration tests exhibit NaOH treatment for MB desorption as a promising technique with a minor loss of adsorption capacities of 7.6 and 5.8% for SSB and SSMB, respectively. Magnetic biochar Adsorption Methylene blue Mechanism Modeling Mouhamadou, Sali aut Enthalten in Water, air & soil pollution Springer International Publishing, 1971 234(2023), 4 vom: 27. März (DE-627)12929134X (DE-600)120499-3 (DE-576)014472643 0049-6979 nnns volume:234 year:2023 number:4 day:27 month:03 https://doi.org/10.1007/s11270-023-06251-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-UMW SSG-OLC-TEC SSG-OLC-FOR SSG-OLC-IBL SSG-OPC-GGO ZC 7520 ZC 7520 AR 234 2023 4 27 03 |
| allfieldsGer |
10.1007/s11270-023-06251-6 doi (DE-627)OLC2134625686 (DE-He213)s11270-023-06251-6-p DE-627 ger DE-627 rakwb eng 570 333.7 VZ 12 13 ssgn BIODIV DE-30 fid ZC 7520 VZ rvk ZC 7520 VZ rvk Zeghioud, Hicham verfasserin (orcid)0000-0002-3113-041X aut Dye Removal Characteristics of Magnetic Biochar Derived from Sewage Sludge: Isotherm, Thermodynamics, Kinetics, and Mechanism 2023 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The efficient and relatively simple modification of various biochars to facilitate their environmental applications and enhance the cost/effectiveness ratio is still a challenge. In this work, biochar prepared by pyrolysis of wastewater sewage sludge at 400 °C and 750 °C was tested for methylene blue (MB) adsorption. Biochar which was prepared at 750 °C (SSB) and presented high adsorption capacity was magnetized by applying co-precipitation techniques. The magnetic biochar was obtained (SSMB) and the pristine biochar for methylene blue (MB) was removed in an aqueous solution. The sewage sludge biochar (SSB) and the magnetic sewage sludge biochar (SSMB) were characterized by SEM-EDS, BET, mercury porosimeter, FTIR, and Raman spectroscopy. The results showed a decrease in specific surface area and total pore volume after magnetization from 51.82 to 3.37 $ m^{2} $/g and from 0.899 to 0.588 $ cm^{3} $/g, respectively. An increase in the average pore diameter (from 0.086 to 1.109 μm) and surface functional groups was recorded in SSMB compared to SSB. SSMB presented 55.6 mg/g of adsorption capacity meanwhile SSB presented a value of 54.23 mg/g for the removal of C0 = 40 mg/L of MB under an optimized pH and biochar dose. The kinetic study and isotherm modeling revealed that the adsorption of MB on SSB and SSMB is driven by physical interactions on heterogenous sites dominated by pore filling, hydrogen bonding, π-π, and n-π interaction mechanism. The thermodynamic study showed that the adsorption is endothermic and favorable on both biochars. The regeneration tests exhibit NaOH treatment for MB desorption as a promising technique with a minor loss of adsorption capacities of 7.6 and 5.8% for SSB and SSMB, respectively. Magnetic biochar Adsorption Methylene blue Mechanism Modeling Mouhamadou, Sali aut Enthalten in Water, air & soil pollution Springer International Publishing, 1971 234(2023), 4 vom: 27. März (DE-627)12929134X (DE-600)120499-3 (DE-576)014472643 0049-6979 nnns volume:234 year:2023 number:4 day:27 month:03 https://doi.org/10.1007/s11270-023-06251-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-UMW SSG-OLC-TEC SSG-OLC-FOR SSG-OLC-IBL SSG-OPC-GGO ZC 7520 ZC 7520 AR 234 2023 4 27 03 |
| allfieldsSound |
10.1007/s11270-023-06251-6 doi (DE-627)OLC2134625686 (DE-He213)s11270-023-06251-6-p DE-627 ger DE-627 rakwb eng 570 333.7 VZ 12 13 ssgn BIODIV DE-30 fid ZC 7520 VZ rvk ZC 7520 VZ rvk Zeghioud, Hicham verfasserin (orcid)0000-0002-3113-041X aut Dye Removal Characteristics of Magnetic Biochar Derived from Sewage Sludge: Isotherm, Thermodynamics, Kinetics, and Mechanism 2023 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The efficient and relatively simple modification of various biochars to facilitate their environmental applications and enhance the cost/effectiveness ratio is still a challenge. In this work, biochar prepared by pyrolysis of wastewater sewage sludge at 400 °C and 750 °C was tested for methylene blue (MB) adsorption. Biochar which was prepared at 750 °C (SSB) and presented high adsorption capacity was magnetized by applying co-precipitation techniques. The magnetic biochar was obtained (SSMB) and the pristine biochar for methylene blue (MB) was removed in an aqueous solution. The sewage sludge biochar (SSB) and the magnetic sewage sludge biochar (SSMB) were characterized by SEM-EDS, BET, mercury porosimeter, FTIR, and Raman spectroscopy. The results showed a decrease in specific surface area and total pore volume after magnetization from 51.82 to 3.37 $ m^{2} $/g and from 0.899 to 0.588 $ cm^{3} $/g, respectively. An increase in the average pore diameter (from 0.086 to 1.109 μm) and surface functional groups was recorded in SSMB compared to SSB. SSMB presented 55.6 mg/g of adsorption capacity meanwhile SSB presented a value of 54.23 mg/g for the removal of C0 = 40 mg/L of MB under an optimized pH and biochar dose. The kinetic study and isotherm modeling revealed that the adsorption of MB on SSB and SSMB is driven by physical interactions on heterogenous sites dominated by pore filling, hydrogen bonding, π-π, and n-π interaction mechanism. The thermodynamic study showed that the adsorption is endothermic and favorable on both biochars. The regeneration tests exhibit NaOH treatment for MB desorption as a promising technique with a minor loss of adsorption capacities of 7.6 and 5.8% for SSB and SSMB, respectively. Magnetic biochar Adsorption Methylene blue Mechanism Modeling Mouhamadou, Sali aut Enthalten in Water, air & soil pollution Springer International Publishing, 1971 234(2023), 4 vom: 27. März (DE-627)12929134X (DE-600)120499-3 (DE-576)014472643 0049-6979 nnns volume:234 year:2023 number:4 day:27 month:03 https://doi.org/10.1007/s11270-023-06251-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-UMW SSG-OLC-TEC SSG-OLC-FOR SSG-OLC-IBL SSG-OPC-GGO ZC 7520 ZC 7520 AR 234 2023 4 27 03 |
| language |
English |
| source |
Enthalten in Water, air & soil pollution 234(2023), 4 vom: 27. März volume:234 year:2023 number:4 day:27 month:03 |
| sourceStr |
Enthalten in Water, air & soil pollution 234(2023), 4 vom: 27. März volume:234 year:2023 number:4 day:27 month:03 |
| format_phy_str_mv |
Article |
| institution |
findex.gbv.de |
| topic_facet |
Magnetic biochar Adsorption Methylene blue Mechanism Modeling |
| dewey-raw |
570 |
| isfreeaccess_bool |
false |
| container_title |
Water, air & soil pollution |
| authorswithroles_txt_mv |
Zeghioud, Hicham @@aut@@ Mouhamadou, Sali @@aut@@ |
| publishDateDaySort_date |
2023-03-27T00:00:00Z |
| hierarchy_top_id |
12929134X |
| dewey-sort |
3570 |
| id |
OLC2134625686 |
| language_de |
englisch |
| fullrecord |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">OLC2134625686</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230510162759.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">230510s2023 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s11270-023-06251-6</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2134625686</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)s11270-023-06251-6-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">570</subfield><subfield code="a">333.7</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">12</subfield><subfield code="a">13</subfield><subfield code="2">ssgn</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">BIODIV</subfield><subfield code="q">DE-30</subfield><subfield code="2">fid</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">ZC 7520</subfield><subfield code="q">VZ</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">ZC 7520</subfield><subfield code="q">VZ</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Zeghioud, Hicham</subfield><subfield code="e">verfasserin</subfield><subfield code="0">(orcid)0000-0002-3113-041X</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Dye Removal Characteristics of Magnetic Biochar Derived from Sewage Sludge: Isotherm, Thermodynamics, Kinetics, and Mechanism</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2023</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© The Author(s), under exclusive licence to Springer Nature Switzerland AG 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The efficient and relatively simple modification of various biochars to facilitate their environmental applications and enhance the cost/effectiveness ratio is still a challenge. In this work, biochar prepared by pyrolysis of wastewater sewage sludge at 400 °C and 750 °C was tested for methylene blue (MB) adsorption. Biochar which was prepared at 750 °C (SSB) and presented high adsorption capacity was magnetized by applying co-precipitation techniques. The magnetic biochar was obtained (SSMB) and the pristine biochar for methylene blue (MB) was removed in an aqueous solution. The sewage sludge biochar (SSB) and the magnetic sewage sludge biochar (SSMB) were characterized by SEM-EDS, BET, mercury porosimeter, FTIR, and Raman spectroscopy. The results showed a decrease in specific surface area and total pore volume after magnetization from 51.82 to 3.37 $ m^{2} $/g and from 0.899 to 0.588 $ cm^{3} $/g, respectively. An increase in the average pore diameter (from 0.086 to 1.109 μm) and surface functional groups was recorded in SSMB compared to SSB. SSMB presented 55.6 mg/g of adsorption capacity meanwhile SSB presented a value of 54.23 mg/g for the removal of C0 = 40 mg/L of MB under an optimized pH and biochar dose. The kinetic study and isotherm modeling revealed that the adsorption of MB on SSB and SSMB is driven by physical interactions on heterogenous sites dominated by pore filling, hydrogen bonding, π-π, and n-π interaction mechanism. The thermodynamic study showed that the adsorption is endothermic and favorable on both biochars. The regeneration tests exhibit NaOH treatment for MB desorption as a promising technique with a minor loss of adsorption capacities of 7.6 and 5.8% for SSB and SSMB, respectively.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Magnetic biochar</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Adsorption</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Methylene blue</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Mechanism</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Modeling</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Mouhamadou, Sali</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Water, air & soil pollution</subfield><subfield code="d">Springer International Publishing, 1971</subfield><subfield code="g">234(2023), 4 vom: 27. März</subfield><subfield code="w">(DE-627)12929134X</subfield><subfield code="w">(DE-600)120499-3</subfield><subfield code="w">(DE-576)014472643</subfield><subfield code="x">0049-6979</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:234</subfield><subfield code="g">year:2023</subfield><subfield code="g">number:4</subfield><subfield code="g">day:27</subfield><subfield code="g">month:03</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/s11270-023-06251-6</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">FID-BIODIV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-UMW</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-FOR</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-IBL</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OPC-GGO</subfield></datafield><datafield tag="936" ind1="r" ind2="v"><subfield code="a">ZC 7520</subfield></datafield><datafield tag="936" ind1="r" ind2="v"><subfield code="a">ZC 7520</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">234</subfield><subfield code="j">2023</subfield><subfield code="e">4</subfield><subfield code="b">27</subfield><subfield code="c">03</subfield></datafield></record></collection>
|
| author |
Zeghioud, Hicham |
| spellingShingle |
Zeghioud, Hicham ddc 570 ssgn 12 fid BIODIV rvk ZC 7520 misc Magnetic biochar misc Adsorption misc Methylene blue misc Mechanism misc Modeling Dye Removal Characteristics of Magnetic Biochar Derived from Sewage Sludge: Isotherm, Thermodynamics, Kinetics, and Mechanism |
| authorStr |
Zeghioud, Hicham |
| ppnlink_with_tag_str_mv |
@@773@@(DE-627)12929134X |
| format |
Article |
| dewey-ones |
570 - Life sciences; biology 333 - Economics of land & energy |
| delete_txt_mv |
keep |
| author_role |
aut aut |
| collection |
OLC |
| remote_str |
false |
| illustrated |
Not Illustrated |
| issn |
0049-6979 |
| topic_title |
570 333.7 VZ 12 13 ssgn BIODIV DE-30 fid ZC 7520 VZ rvk Dye Removal Characteristics of Magnetic Biochar Derived from Sewage Sludge: Isotherm, Thermodynamics, Kinetics, and Mechanism Magnetic biochar Adsorption Methylene blue Mechanism Modeling |
| topic |
ddc 570 ssgn 12 fid BIODIV rvk ZC 7520 misc Magnetic biochar misc Adsorption misc Methylene blue misc Mechanism misc Modeling |
| topic_unstemmed |
ddc 570 ssgn 12 fid BIODIV rvk ZC 7520 misc Magnetic biochar misc Adsorption misc Methylene blue misc Mechanism misc Modeling |
| topic_browse |
ddc 570 ssgn 12 fid BIODIV rvk ZC 7520 misc Magnetic biochar misc Adsorption misc Methylene blue misc Mechanism misc Modeling |
| format_facet |
Aufsätze Gedruckte Aufsätze |
| format_main_str_mv |
Text Zeitschrift/Artikel |
| carriertype_str_mv |
nc |
| hierarchy_parent_title |
Water, air & soil pollution |
| hierarchy_parent_id |
12929134X |
| dewey-tens |
570 - Life sciences; biology 330 - Economics |
| hierarchy_top_title |
Water, air & soil pollution |
| isfreeaccess_txt |
false |
| familylinks_str_mv |
(DE-627)12929134X (DE-600)120499-3 (DE-576)014472643 |
| title |
Dye Removal Characteristics of Magnetic Biochar Derived from Sewage Sludge: Isotherm, Thermodynamics, Kinetics, and Mechanism |
| ctrlnum |
(DE-627)OLC2134625686 (DE-He213)s11270-023-06251-6-p |
| title_full |
Dye Removal Characteristics of Magnetic Biochar Derived from Sewage Sludge: Isotherm, Thermodynamics, Kinetics, and Mechanism |
| author_sort |
Zeghioud, Hicham |
| journal |
Water, air & soil pollution |
| journalStr |
Water, air & soil pollution |
| lang_code |
eng |
| isOA_bool |
false |
| dewey-hundreds |
500 - Science 300 - Social sciences |
| recordtype |
marc |
| publishDateSort |
2023 |
| contenttype_str_mv |
txt |
| author_browse |
Zeghioud, Hicham Mouhamadou, Sali |
| container_volume |
234 |
| class |
570 333.7 VZ 12 13 ssgn BIODIV DE-30 fid ZC 7520 VZ rvk |
| format_se |
Aufsätze |
| author-letter |
Zeghioud, Hicham |
| doi_str_mv |
10.1007/s11270-023-06251-6 |
| normlink |
(ORCID)0000-0002-3113-041X |
| normlink_prefix_str_mv |
(orcid)0000-0002-3113-041X |
| dewey-full |
570 333.7 |
| title_sort |
dye removal characteristics of magnetic biochar derived from sewage sludge: isotherm, thermodynamics, kinetics, and mechanism |
| title_auth |
Dye Removal Characteristics of Magnetic Biochar Derived from Sewage Sludge: Isotherm, Thermodynamics, Kinetics, and Mechanism |
| abstract |
Abstract The efficient and relatively simple modification of various biochars to facilitate their environmental applications and enhance the cost/effectiveness ratio is still a challenge. In this work, biochar prepared by pyrolysis of wastewater sewage sludge at 400 °C and 750 °C was tested for methylene blue (MB) adsorption. Biochar which was prepared at 750 °C (SSB) and presented high adsorption capacity was magnetized by applying co-precipitation techniques. The magnetic biochar was obtained (SSMB) and the pristine biochar for methylene blue (MB) was removed in an aqueous solution. The sewage sludge biochar (SSB) and the magnetic sewage sludge biochar (SSMB) were characterized by SEM-EDS, BET, mercury porosimeter, FTIR, and Raman spectroscopy. The results showed a decrease in specific surface area and total pore volume after magnetization from 51.82 to 3.37 $ m^{2} $/g and from 0.899 to 0.588 $ cm^{3} $/g, respectively. An increase in the average pore diameter (from 0.086 to 1.109 μm) and surface functional groups was recorded in SSMB compared to SSB. SSMB presented 55.6 mg/g of adsorption capacity meanwhile SSB presented a value of 54.23 mg/g for the removal of C0 = 40 mg/L of MB under an optimized pH and biochar dose. The kinetic study and isotherm modeling revealed that the adsorption of MB on SSB and SSMB is driven by physical interactions on heterogenous sites dominated by pore filling, hydrogen bonding, π-π, and n-π interaction mechanism. The thermodynamic study showed that the adsorption is endothermic and favorable on both biochars. The regeneration tests exhibit NaOH treatment for MB desorption as a promising technique with a minor loss of adsorption capacities of 7.6 and 5.8% for SSB and SSMB, respectively. © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstractGer |
Abstract The efficient and relatively simple modification of various biochars to facilitate their environmental applications and enhance the cost/effectiveness ratio is still a challenge. In this work, biochar prepared by pyrolysis of wastewater sewage sludge at 400 °C and 750 °C was tested for methylene blue (MB) adsorption. Biochar which was prepared at 750 °C (SSB) and presented high adsorption capacity was magnetized by applying co-precipitation techniques. The magnetic biochar was obtained (SSMB) and the pristine biochar for methylene blue (MB) was removed in an aqueous solution. The sewage sludge biochar (SSB) and the magnetic sewage sludge biochar (SSMB) were characterized by SEM-EDS, BET, mercury porosimeter, FTIR, and Raman spectroscopy. The results showed a decrease in specific surface area and total pore volume after magnetization from 51.82 to 3.37 $ m^{2} $/g and from 0.899 to 0.588 $ cm^{3} $/g, respectively. An increase in the average pore diameter (from 0.086 to 1.109 μm) and surface functional groups was recorded in SSMB compared to SSB. SSMB presented 55.6 mg/g of adsorption capacity meanwhile SSB presented a value of 54.23 mg/g for the removal of C0 = 40 mg/L of MB under an optimized pH and biochar dose. The kinetic study and isotherm modeling revealed that the adsorption of MB on SSB and SSMB is driven by physical interactions on heterogenous sites dominated by pore filling, hydrogen bonding, π-π, and n-π interaction mechanism. The thermodynamic study showed that the adsorption is endothermic and favorable on both biochars. The regeneration tests exhibit NaOH treatment for MB desorption as a promising technique with a minor loss of adsorption capacities of 7.6 and 5.8% for SSB and SSMB, respectively. © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstract_unstemmed |
Abstract The efficient and relatively simple modification of various biochars to facilitate their environmental applications and enhance the cost/effectiveness ratio is still a challenge. In this work, biochar prepared by pyrolysis of wastewater sewage sludge at 400 °C and 750 °C was tested for methylene blue (MB) adsorption. Biochar which was prepared at 750 °C (SSB) and presented high adsorption capacity was magnetized by applying co-precipitation techniques. The magnetic biochar was obtained (SSMB) and the pristine biochar for methylene blue (MB) was removed in an aqueous solution. The sewage sludge biochar (SSB) and the magnetic sewage sludge biochar (SSMB) were characterized by SEM-EDS, BET, mercury porosimeter, FTIR, and Raman spectroscopy. The results showed a decrease in specific surface area and total pore volume after magnetization from 51.82 to 3.37 $ m^{2} $/g and from 0.899 to 0.588 $ cm^{3} $/g, respectively. An increase in the average pore diameter (from 0.086 to 1.109 μm) and surface functional groups was recorded in SSMB compared to SSB. SSMB presented 55.6 mg/g of adsorption capacity meanwhile SSB presented a value of 54.23 mg/g for the removal of C0 = 40 mg/L of MB under an optimized pH and biochar dose. The kinetic study and isotherm modeling revealed that the adsorption of MB on SSB and SSMB is driven by physical interactions on heterogenous sites dominated by pore filling, hydrogen bonding, π-π, and n-π interaction mechanism. The thermodynamic study showed that the adsorption is endothermic and favorable on both biochars. The regeneration tests exhibit NaOH treatment for MB desorption as a promising technique with a minor loss of adsorption capacities of 7.6 and 5.8% for SSB and SSMB, respectively. © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| collection_details |
GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-UMW SSG-OLC-TEC SSG-OLC-FOR SSG-OLC-IBL SSG-OPC-GGO |
| container_issue |
4 |
| title_short |
Dye Removal Characteristics of Magnetic Biochar Derived from Sewage Sludge: Isotherm, Thermodynamics, Kinetics, and Mechanism |
| url |
https://doi.org/10.1007/s11270-023-06251-6 |
| remote_bool |
false |
| author2 |
Mouhamadou, Sali |
| author2Str |
Mouhamadou, Sali |
| ppnlink |
12929134X |
| mediatype_str_mv |
n |
| isOA_txt |
false |
| hochschulschrift_bool |
false |
| doi_str |
10.1007/s11270-023-06251-6 |
| up_date |
2024-07-04T01:56:21.574Z |
| _version_ |
1803611727804235776 |
| fullrecord_marcxml |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">OLC2134625686</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230510162759.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">230510s2023 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s11270-023-06251-6</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2134625686</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)s11270-023-06251-6-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">570</subfield><subfield code="a">333.7</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">12</subfield><subfield code="a">13</subfield><subfield code="2">ssgn</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">BIODIV</subfield><subfield code="q">DE-30</subfield><subfield code="2">fid</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">ZC 7520</subfield><subfield code="q">VZ</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">ZC 7520</subfield><subfield code="q">VZ</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Zeghioud, Hicham</subfield><subfield code="e">verfasserin</subfield><subfield code="0">(orcid)0000-0002-3113-041X</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Dye Removal Characteristics of Magnetic Biochar Derived from Sewage Sludge: Isotherm, Thermodynamics, Kinetics, and Mechanism</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2023</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© The Author(s), under exclusive licence to Springer Nature Switzerland AG 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The efficient and relatively simple modification of various biochars to facilitate their environmental applications and enhance the cost/effectiveness ratio is still a challenge. In this work, biochar prepared by pyrolysis of wastewater sewage sludge at 400 °C and 750 °C was tested for methylene blue (MB) adsorption. Biochar which was prepared at 750 °C (SSB) and presented high adsorption capacity was magnetized by applying co-precipitation techniques. The magnetic biochar was obtained (SSMB) and the pristine biochar for methylene blue (MB) was removed in an aqueous solution. The sewage sludge biochar (SSB) and the magnetic sewage sludge biochar (SSMB) were characterized by SEM-EDS, BET, mercury porosimeter, FTIR, and Raman spectroscopy. The results showed a decrease in specific surface area and total pore volume after magnetization from 51.82 to 3.37 $ m^{2} $/g and from 0.899 to 0.588 $ cm^{3} $/g, respectively. An increase in the average pore diameter (from 0.086 to 1.109 μm) and surface functional groups was recorded in SSMB compared to SSB. SSMB presented 55.6 mg/g of adsorption capacity meanwhile SSB presented a value of 54.23 mg/g for the removal of C0 = 40 mg/L of MB under an optimized pH and biochar dose. The kinetic study and isotherm modeling revealed that the adsorption of MB on SSB and SSMB is driven by physical interactions on heterogenous sites dominated by pore filling, hydrogen bonding, π-π, and n-π interaction mechanism. The thermodynamic study showed that the adsorption is endothermic and favorable on both biochars. The regeneration tests exhibit NaOH treatment for MB desorption as a promising technique with a minor loss of adsorption capacities of 7.6 and 5.8% for SSB and SSMB, respectively.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Magnetic biochar</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Adsorption</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Methylene blue</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Mechanism</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Modeling</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Mouhamadou, Sali</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Water, air & soil pollution</subfield><subfield code="d">Springer International Publishing, 1971</subfield><subfield code="g">234(2023), 4 vom: 27. März</subfield><subfield code="w">(DE-627)12929134X</subfield><subfield code="w">(DE-600)120499-3</subfield><subfield code="w">(DE-576)014472643</subfield><subfield code="x">0049-6979</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:234</subfield><subfield code="g">year:2023</subfield><subfield code="g">number:4</subfield><subfield code="g">day:27</subfield><subfield code="g">month:03</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/s11270-023-06251-6</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">FID-BIODIV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-UMW</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-FOR</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-IBL</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OPC-GGO</subfield></datafield><datafield tag="936" ind1="r" ind2="v"><subfield code="a">ZC 7520</subfield></datafield><datafield tag="936" ind1="r" ind2="v"><subfield code="a">ZC 7520</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">234</subfield><subfield code="j">2023</subfield><subfield code="e">4</subfield><subfield code="b">27</subfield><subfield code="c">03</subfield></datafield></record></collection>
|
| score |
7.4014435 |