Phase transitions during compression of thaumasite, $ Ca_{3} $Si(OH)6($ CO_{3} $)($ SO_{4} $)·$ 12H_{2} $O: A high-pressure synchrotron powder X-ray diffraction study
Abstract The high-pressure behaviour of the thaumasite structure was investigated using synchrotron powder X-ray diffraction, up to 19.5 GPa. Based on Rietveld refinements, thaumasite retained the roompressure $ P6_{3} $ space group throughout the whole investigated pressure range while the pressure...
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| Autor*in: |
Ardit, M. [verfasserIn] |
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| Format: |
Artikel |
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| Erschienen: |
2014 |
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| Systematik: |
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| Anmerkung: |
© 2015 by Walter de Gruyter Berlin/Boston |
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| Übergeordnetes Werk: |
Enthalten in: Mineralogical magazine - Mineralogical Society, 1969, 78(2014), 5 vom: 01. Okt., Seite 1193-1208 |
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| Übergeordnetes Werk: |
volume:78 ; year:2014 ; number:5 ; day:01 ; month:10 ; pages:1193-1208 |
| Links: |
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| DOI / URN: |
10.1180/minmag.2014.078.5.07 |
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| Katalog-ID: |
OLC2135647470 |
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| 245 | 1 | 0 | |a Phase transitions during compression of thaumasite, $ Ca_{3} $Si(OH)6($ CO_{3} $)($ SO_{4} $)·$ 12H_{2} $O: A high-pressure synchrotron powder X-ray diffraction study |
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| 520 | |a Abstract The high-pressure behaviour of the thaumasite structure was investigated using synchrotron powder X-ray diffraction, up to 19.5 GPa. Based on Rietveld refinements, thaumasite retained the roompressure $ P6_{3} $ space group throughout the whole investigated pressure range while the pressure dependence of the refined unit-cell parameters can be cast into three different compression regimes, each corresponding to a different thaumasite phase (th-I, th-II and th-III) related by isosymmetric phase transitions. In particular, the phase transition in the 7.40-15.02 GPa P-range (i.e. from th-II to th-III) is associated with an inversion of the axial bulk moduli which, by analogy with ettringite, can be rationalized as due to a change in the relative strengths of the iono-covalent bonds along the [$ Ca_{3} $Si(OH)6($ H_{2} $O)12]4+ columns parallel to the c axis vs. the O-H bonds linking the columns within the ab plane. The linear inverse relationship between the low- and high-temperature data from the literature with those collected under high-pressure conditions reveals that the same bonding regime governs the anisotropic expansion and contraction of thaumasite up to ~1.4 GPa and 400 K (HP-HT stability limits of th-I phase). | ||
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10.1180/minmag.2014.078.5.07 doi (DE-627)OLC2135647470 (DE-B1597)minmag.2014.078.5.07-p DE-627 ger DE-627 rakwb 550 VZ 13 ssgn TE 1000 VZ rvk Ardit, M. verfasserin aut Phase transitions during compression of thaumasite, $ Ca_{3} $Si(OH)6($ CO_{3} $)($ SO_{4} $)·$ 12H_{2} $O: A high-pressure synchrotron powder X-ray diffraction study 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 2015 by Walter de Gruyter Berlin/Boston Abstract The high-pressure behaviour of the thaumasite structure was investigated using synchrotron powder X-ray diffraction, up to 19.5 GPa. Based on Rietveld refinements, thaumasite retained the roompressure $ P6_{3} $ space group throughout the whole investigated pressure range while the pressure dependence of the refined unit-cell parameters can be cast into three different compression regimes, each corresponding to a different thaumasite phase (th-I, th-II and th-III) related by isosymmetric phase transitions. In particular, the phase transition in the 7.40-15.02 GPa P-range (i.e. from th-II to th-III) is associated with an inversion of the axial bulk moduli which, by analogy with ettringite, can be rationalized as due to a change in the relative strengths of the iono-covalent bonds along the [$ Ca_{3} $Si(OH)6($ H_{2} $O)12]4+ columns parallel to the c axis vs. the O-H bonds linking the columns within the ab plane. The linear inverse relationship between the low- and high-temperature data from the literature with those collected under high-pressure conditions reveals that the same bonding regime governs the anisotropic expansion and contraction of thaumasite up to ~1.4 GPa and 400 K (HP-HT stability limits of th-I phase). Cruciani, G. aut Dondi, M. aut Garbarino, G. L. aut Nestola, F. aut Enthalten in Mineralogical magazine Mineralogical Society, 1969 78(2014), 5 vom: 01. Okt., Seite 1193-1208 (DE-627)13069617X (DE-600)956157-2 (DE-576)016244141 0026-461X nnns volume:78 year:2014 number:5 day:01 month:10 pages:1193-1208 https://doi.org/10.1180/minmag.2014.078.5.07 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2010 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2027 GBV_ILN_4323 TE 1000 AR 78 2014 5 01 10 1193-1208 |
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10.1180/minmag.2014.078.5.07 doi (DE-627)OLC2135647470 (DE-B1597)minmag.2014.078.5.07-p DE-627 ger DE-627 rakwb 550 VZ 13 ssgn TE 1000 VZ rvk Ardit, M. verfasserin aut Phase transitions during compression of thaumasite, $ Ca_{3} $Si(OH)6($ CO_{3} $)($ SO_{4} $)·$ 12H_{2} $O: A high-pressure synchrotron powder X-ray diffraction study 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 2015 by Walter de Gruyter Berlin/Boston Abstract The high-pressure behaviour of the thaumasite structure was investigated using synchrotron powder X-ray diffraction, up to 19.5 GPa. Based on Rietveld refinements, thaumasite retained the roompressure $ P6_{3} $ space group throughout the whole investigated pressure range while the pressure dependence of the refined unit-cell parameters can be cast into three different compression regimes, each corresponding to a different thaumasite phase (th-I, th-II and th-III) related by isosymmetric phase transitions. In particular, the phase transition in the 7.40-15.02 GPa P-range (i.e. from th-II to th-III) is associated with an inversion of the axial bulk moduli which, by analogy with ettringite, can be rationalized as due to a change in the relative strengths of the iono-covalent bonds along the [$ Ca_{3} $Si(OH)6($ H_{2} $O)12]4+ columns parallel to the c axis vs. the O-H bonds linking the columns within the ab plane. The linear inverse relationship between the low- and high-temperature data from the literature with those collected under high-pressure conditions reveals that the same bonding regime governs the anisotropic expansion and contraction of thaumasite up to ~1.4 GPa and 400 K (HP-HT stability limits of th-I phase). Cruciani, G. aut Dondi, M. aut Garbarino, G. L. aut Nestola, F. aut Enthalten in Mineralogical magazine Mineralogical Society, 1969 78(2014), 5 vom: 01. Okt., Seite 1193-1208 (DE-627)13069617X (DE-600)956157-2 (DE-576)016244141 0026-461X nnns volume:78 year:2014 number:5 day:01 month:10 pages:1193-1208 https://doi.org/10.1180/minmag.2014.078.5.07 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2010 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2027 GBV_ILN_4323 TE 1000 AR 78 2014 5 01 10 1193-1208 |
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10.1180/minmag.2014.078.5.07 doi (DE-627)OLC2135647470 (DE-B1597)minmag.2014.078.5.07-p DE-627 ger DE-627 rakwb 550 VZ 13 ssgn TE 1000 VZ rvk Ardit, M. verfasserin aut Phase transitions during compression of thaumasite, $ Ca_{3} $Si(OH)6($ CO_{3} $)($ SO_{4} $)·$ 12H_{2} $O: A high-pressure synchrotron powder X-ray diffraction study 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 2015 by Walter de Gruyter Berlin/Boston Abstract The high-pressure behaviour of the thaumasite structure was investigated using synchrotron powder X-ray diffraction, up to 19.5 GPa. Based on Rietveld refinements, thaumasite retained the roompressure $ P6_{3} $ space group throughout the whole investigated pressure range while the pressure dependence of the refined unit-cell parameters can be cast into three different compression regimes, each corresponding to a different thaumasite phase (th-I, th-II and th-III) related by isosymmetric phase transitions. In particular, the phase transition in the 7.40-15.02 GPa P-range (i.e. from th-II to th-III) is associated with an inversion of the axial bulk moduli which, by analogy with ettringite, can be rationalized as due to a change in the relative strengths of the iono-covalent bonds along the [$ Ca_{3} $Si(OH)6($ H_{2} $O)12]4+ columns parallel to the c axis vs. the O-H bonds linking the columns within the ab plane. The linear inverse relationship between the low- and high-temperature data from the literature with those collected under high-pressure conditions reveals that the same bonding regime governs the anisotropic expansion and contraction of thaumasite up to ~1.4 GPa and 400 K (HP-HT stability limits of th-I phase). Cruciani, G. aut Dondi, M. aut Garbarino, G. L. aut Nestola, F. aut Enthalten in Mineralogical magazine Mineralogical Society, 1969 78(2014), 5 vom: 01. Okt., Seite 1193-1208 (DE-627)13069617X (DE-600)956157-2 (DE-576)016244141 0026-461X nnns volume:78 year:2014 number:5 day:01 month:10 pages:1193-1208 https://doi.org/10.1180/minmag.2014.078.5.07 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2010 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2027 GBV_ILN_4323 TE 1000 AR 78 2014 5 01 10 1193-1208 |
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10.1180/minmag.2014.078.5.07 doi (DE-627)OLC2135647470 (DE-B1597)minmag.2014.078.5.07-p DE-627 ger DE-627 rakwb 550 VZ 13 ssgn TE 1000 VZ rvk Ardit, M. verfasserin aut Phase transitions during compression of thaumasite, $ Ca_{3} $Si(OH)6($ CO_{3} $)($ SO_{4} $)·$ 12H_{2} $O: A high-pressure synchrotron powder X-ray diffraction study 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 2015 by Walter de Gruyter Berlin/Boston Abstract The high-pressure behaviour of the thaumasite structure was investigated using synchrotron powder X-ray diffraction, up to 19.5 GPa. Based on Rietveld refinements, thaumasite retained the roompressure $ P6_{3} $ space group throughout the whole investigated pressure range while the pressure dependence of the refined unit-cell parameters can be cast into three different compression regimes, each corresponding to a different thaumasite phase (th-I, th-II and th-III) related by isosymmetric phase transitions. In particular, the phase transition in the 7.40-15.02 GPa P-range (i.e. from th-II to th-III) is associated with an inversion of the axial bulk moduli which, by analogy with ettringite, can be rationalized as due to a change in the relative strengths of the iono-covalent bonds along the [$ Ca_{3} $Si(OH)6($ H_{2} $O)12]4+ columns parallel to the c axis vs. the O-H bonds linking the columns within the ab plane. The linear inverse relationship between the low- and high-temperature data from the literature with those collected under high-pressure conditions reveals that the same bonding regime governs the anisotropic expansion and contraction of thaumasite up to ~1.4 GPa and 400 K (HP-HT stability limits of th-I phase). Cruciani, G. aut Dondi, M. aut Garbarino, G. L. aut Nestola, F. aut Enthalten in Mineralogical magazine Mineralogical Society, 1969 78(2014), 5 vom: 01. Okt., Seite 1193-1208 (DE-627)13069617X (DE-600)956157-2 (DE-576)016244141 0026-461X nnns volume:78 year:2014 number:5 day:01 month:10 pages:1193-1208 https://doi.org/10.1180/minmag.2014.078.5.07 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2010 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2027 GBV_ILN_4323 TE 1000 AR 78 2014 5 01 10 1193-1208 |
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10.1180/minmag.2014.078.5.07 doi (DE-627)OLC2135647470 (DE-B1597)minmag.2014.078.5.07-p DE-627 ger DE-627 rakwb 550 VZ 13 ssgn TE 1000 VZ rvk Ardit, M. verfasserin aut Phase transitions during compression of thaumasite, $ Ca_{3} $Si(OH)6($ CO_{3} $)($ SO_{4} $)·$ 12H_{2} $O: A high-pressure synchrotron powder X-ray diffraction study 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 2015 by Walter de Gruyter Berlin/Boston Abstract The high-pressure behaviour of the thaumasite structure was investigated using synchrotron powder X-ray diffraction, up to 19.5 GPa. Based on Rietveld refinements, thaumasite retained the roompressure $ P6_{3} $ space group throughout the whole investigated pressure range while the pressure dependence of the refined unit-cell parameters can be cast into three different compression regimes, each corresponding to a different thaumasite phase (th-I, th-II and th-III) related by isosymmetric phase transitions. In particular, the phase transition in the 7.40-15.02 GPa P-range (i.e. from th-II to th-III) is associated with an inversion of the axial bulk moduli which, by analogy with ettringite, can be rationalized as due to a change in the relative strengths of the iono-covalent bonds along the [$ Ca_{3} $Si(OH)6($ H_{2} $O)12]4+ columns parallel to the c axis vs. the O-H bonds linking the columns within the ab plane. The linear inverse relationship between the low- and high-temperature data from the literature with those collected under high-pressure conditions reveals that the same bonding regime governs the anisotropic expansion and contraction of thaumasite up to ~1.4 GPa and 400 K (HP-HT stability limits of th-I phase). Cruciani, G. aut Dondi, M. aut Garbarino, G. L. aut Nestola, F. aut Enthalten in Mineralogical magazine Mineralogical Society, 1969 78(2014), 5 vom: 01. Okt., Seite 1193-1208 (DE-627)13069617X (DE-600)956157-2 (DE-576)016244141 0026-461X nnns volume:78 year:2014 number:5 day:01 month:10 pages:1193-1208 https://doi.org/10.1180/minmag.2014.078.5.07 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2010 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2027 GBV_ILN_4323 TE 1000 AR 78 2014 5 01 10 1193-1208 |
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Ardit, M. ddc 550 ssgn 13 rvk TE 1000 Phase transitions during compression of thaumasite, $ Ca_{3} $Si(OH)6($ CO_{3} $)($ SO_{4} $)·$ 12H_{2} $O: A high-pressure synchrotron powder X-ray diffraction study |
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550 VZ 13 ssgn TE 1000 VZ rvk Phase transitions during compression of thaumasite, $ Ca_{3} $Si(OH)6($ CO_{3} $)($ SO_{4} $)·$ 12H_{2} $O: A high-pressure synchrotron powder X-ray diffraction study |
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Phase transitions during compression of thaumasite, $ Ca_{3} $Si(OH)6($ CO_{3} $)($ SO_{4} $)·$ 12H_{2} $O: A high-pressure synchrotron powder X-ray diffraction study |
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Phase transitions during compression of thaumasite, $ Ca_{3} $Si(OH)6($ CO_{3} $)($ SO_{4} $)·$ 12H_{2} $O: A high-pressure synchrotron powder X-ray diffraction study |
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Ardit, M. Cruciani, G. Dondi, M. Garbarino, G. L. Nestola, F. |
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phase transitions during compression of thaumasite, $ ca_{3} $si(oh)6($ co_{3} $)($ so_{4} $)·$ 12h_{2} $o: a high-pressure synchrotron powder x-ray diffraction study |
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Phase transitions during compression of thaumasite, $ Ca_{3} $Si(OH)6($ CO_{3} $)($ SO_{4} $)·$ 12H_{2} $O: A high-pressure synchrotron powder X-ray diffraction study |
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Abstract The high-pressure behaviour of the thaumasite structure was investigated using synchrotron powder X-ray diffraction, up to 19.5 GPa. Based on Rietveld refinements, thaumasite retained the roompressure $ P6_{3} $ space group throughout the whole investigated pressure range while the pressure dependence of the refined unit-cell parameters can be cast into three different compression regimes, each corresponding to a different thaumasite phase (th-I, th-II and th-III) related by isosymmetric phase transitions. In particular, the phase transition in the 7.40-15.02 GPa P-range (i.e. from th-II to th-III) is associated with an inversion of the axial bulk moduli which, by analogy with ettringite, can be rationalized as due to a change in the relative strengths of the iono-covalent bonds along the [$ Ca_{3} $Si(OH)6($ H_{2} $O)12]4+ columns parallel to the c axis vs. the O-H bonds linking the columns within the ab plane. The linear inverse relationship between the low- and high-temperature data from the literature with those collected under high-pressure conditions reveals that the same bonding regime governs the anisotropic expansion and contraction of thaumasite up to ~1.4 GPa and 400 K (HP-HT stability limits of th-I phase). © 2015 by Walter de Gruyter Berlin/Boston |
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Abstract The high-pressure behaviour of the thaumasite structure was investigated using synchrotron powder X-ray diffraction, up to 19.5 GPa. Based on Rietveld refinements, thaumasite retained the roompressure $ P6_{3} $ space group throughout the whole investigated pressure range while the pressure dependence of the refined unit-cell parameters can be cast into three different compression regimes, each corresponding to a different thaumasite phase (th-I, th-II and th-III) related by isosymmetric phase transitions. In particular, the phase transition in the 7.40-15.02 GPa P-range (i.e. from th-II to th-III) is associated with an inversion of the axial bulk moduli which, by analogy with ettringite, can be rationalized as due to a change in the relative strengths of the iono-covalent bonds along the [$ Ca_{3} $Si(OH)6($ H_{2} $O)12]4+ columns parallel to the c axis vs. the O-H bonds linking the columns within the ab plane. The linear inverse relationship between the low- and high-temperature data from the literature with those collected under high-pressure conditions reveals that the same bonding regime governs the anisotropic expansion and contraction of thaumasite up to ~1.4 GPa and 400 K (HP-HT stability limits of th-I phase). © 2015 by Walter de Gruyter Berlin/Boston |
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Abstract The high-pressure behaviour of the thaumasite structure was investigated using synchrotron powder X-ray diffraction, up to 19.5 GPa. Based on Rietveld refinements, thaumasite retained the roompressure $ P6_{3} $ space group throughout the whole investigated pressure range while the pressure dependence of the refined unit-cell parameters can be cast into three different compression regimes, each corresponding to a different thaumasite phase (th-I, th-II and th-III) related by isosymmetric phase transitions. In particular, the phase transition in the 7.40-15.02 GPa P-range (i.e. from th-II to th-III) is associated with an inversion of the axial bulk moduli which, by analogy with ettringite, can be rationalized as due to a change in the relative strengths of the iono-covalent bonds along the [$ Ca_{3} $Si(OH)6($ H_{2} $O)12]4+ columns parallel to the c axis vs. the O-H bonds linking the columns within the ab plane. The linear inverse relationship between the low- and high-temperature data from the literature with those collected under high-pressure conditions reveals that the same bonding regime governs the anisotropic expansion and contraction of thaumasite up to ~1.4 GPa and 400 K (HP-HT stability limits of th-I phase). © 2015 by Walter de Gruyter Berlin/Boston |
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Phase transitions during compression of thaumasite, $ Ca_{3} $Si(OH)6($ CO_{3} $)($ SO_{4} $)·$ 12H_{2} $O: A high-pressure synchrotron powder X-ray diffraction study |
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