Synthese und Charakterisierung von kronenetherstabilisierten Platin(IV)- Komplexen mit Aminosäureliganden / Synthesis and Characterization of Amino Acid Complexes of Platinum(IV) Stabilized by Crown Ethers

Abstract Crown ether complexed pentachloro(aqua)platinic acid, ($ H_{3} $O)[$ PtCl_{5} $($ H_{2} $O)]·2(18-cr-6)·$ 6H_{2} $O (1) reacts with glycine, L-alanine, and DL-2-aminobutyric acid to give cis-[$ PtCl_{4} $(O-glyH)($ H_{2} $O)]·(18-cr-6)·$ H_{2} $O (4a)1 and cis-[$ PtCl_{4} $(O-amacH)($ H_{2}...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Steinborn, Dirk [verfasserIn] Gravenhorst, Olaf Junicke, Henrik Heinemann, Frank W.

Format:	Artikel

Erschienen:	1998

Systematik:	VA 8360

Anmerkung:	© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Übergeordnetes Werk:	Enthalten in: Zeitschrift für Naturforschung. B, Chemical sciences - Verlag der Zeitschrift für Naturforschung, 1947, 53(1998), 5-6 vom: 01. Juni, Seite 581-586
Übergeordnetes Werk:	volume:53 ; year:1998 ; number:5-6 ; day:01 ; month:06 ; pages:581-586

Links:	Volltext

DOI / URN:	10.1515/znb-1998-5-616

Katalog-ID:	OLC2136258818

Internformat


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024	7		\|a 10.1515/znb-1998-5-616 \|2 doi
035			\|a (DE-627)OLC2136258818
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082	0	4	\|a 540 \|q VZ
084			\|a VA 8360 \|q VZ \|2 rvk
100	1		\|a Steinborn, Dirk \|e verfasserin \|4 aut
245	1	0	\|a Synthese und Charakterisierung von kronenetherstabilisierten Platin(IV)- Komplexen mit Aminosäureliganden / Synthesis and Characterization of Amino Acid Complexes of Platinum(IV) Stabilized by Crown Ethers
264		1	\|c 1998
336			\|a Text \|b txt \|2 rdacontent
337			\|a ohne Hilfsmittel zu benutzen \|b n \|2 rdamedia
338			\|a Band \|b nc \|2 rdacarrier
500			\|a © 1946 – 2014: Verlag der Zeitschrift für Naturforschung
520			\|a Abstract Crown ether complexed pentachloro(aqua)platinic acid, ($ H_{3} $O)[$ PtCl_{5} $($ H_{2} $O)]·2(18-cr-6)·$ 6H_{2} $O (1) reacts with glycine, L-alanine, and DL-2-aminobutyric acid to give cis-[$ PtCl_{4} $(O-glyH)($ H_{2} $O)]·(18-cr-6)·$ H_{2} $O (4a)1 and cis-[$ PtCl_{4} $(O-amacH)($ H_{2} $O)]·(18-cr-6) (amacH = alaH 4b, abuH 4c), respectively, as well as ($ amacH_{2} $)2[$ PtCl_{6} $]·2(18-cr-6) (amacH = glyH 5a, alaH 5b, abuH 5c). The crown ether complexed hexachloroplatinic acid, ($ H_{3} $O) 2[$ PtCl_{6} $]·2(18-cr-6) (2), reacts with glycine to afford ($ glyH_{2} $)[$ PtCl_{4} $(N,O-gly)]·2(18-cr-6)·1.$ 25H_{2} $O (6). The structures of 4b and 6 were determined by X-ray diffraction. The alanine ligand in 4b is a zwitterion that is coordinated to platinum by one oxygen atom of the carboxylate group only. The other oxygen atom is engaged in a strong hydrogen bond to the ds-coordinated aqua ligand. The glycinato ligand in 6 is N, O-coordinated at platinum forming an anion [$ PtCl_{4} $(N,O-gly)]- . The other oxygen atom of the carboxylate group is involved in a strong hydrogen bridge to the cation ($ glyH_{2} $)+. In both complexes hydrogen bridges are formed between the -$ N^{+} $$ H_{3} $ and -$ NH_{2} $ groups of the amino acid ligands and the oxygen atoms of the crown ether molecules.
700	1		\|a Gravenhorst, Olaf \|4 aut
700	1		\|a Junicke, Henrik \|4 aut
700	1		\|a Heinemann, Frank W. \|4 aut
773	0	8	\|i Enthalten in \|t Zeitschrift für Naturforschung. B, Chemical sciences \|d Verlag der Zeitschrift für Naturforschung, 1947 \|g 53(1998), 5-6 vom: 01. Juni, Seite 581-586 \|w (DE-627)129307386 \|w (DE-600)124635-5 \|w (DE-576)014504928 \|x 0932-0776 \|7 nnns
773	1	8	\|g volume:53 \|g year:1998 \|g number:5-6 \|g day:01 \|g month:06 \|g pages:581-586
856	4	1	\|u https://doi.org/10.1515/znb-1998-5-616 \|z lizenzpflichtig \|3 Volltext
912			\|a GBV_USEFLAG_A
912			\|a SYSFLAG_A
912			\|a GBV_OLC
912			\|a SSG-OLC-PHY
912			\|a SSG-OLC-CHE
912			\|a SSG-OLC-FOR
912			\|a SSG-OPC-FOR
912			\|a GBV_ILN_11
912			\|a GBV_ILN_20
912			\|a GBV_ILN_21
912			\|a GBV_ILN_22
912			\|a GBV_ILN_23
912			\|a GBV_ILN_24
912			\|a GBV_ILN_30
912			\|a GBV_ILN_40
912			\|a GBV_ILN_55
912			\|a GBV_ILN_59
912			\|a GBV_ILN_62
912			\|a GBV_ILN_65
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_100
912			\|a GBV_ILN_105
912			\|a GBV_ILN_120
912			\|a GBV_ILN_121
912			\|a GBV_ILN_130
912			\|a GBV_ILN_267
912			\|a GBV_ILN_285
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2018
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2185
912			\|a GBV_ILN_2221
912			\|a GBV_ILN_2237
912			\|a GBV_ILN_2279
912			\|a GBV_ILN_2409
912			\|a GBV_ILN_4012
912			\|a GBV_ILN_4027
912			\|a GBV_ILN_4035
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4046
912			\|a GBV_ILN_4116
912			\|a GBV_ILN_4266
912			\|a GBV_ILN_4277
912			\|a GBV_ILN_4302
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4306
912			\|a GBV_ILN_4307
912			\|a GBV_ILN_4310
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4314
912			\|a GBV_ILN_4316
912			\|a GBV_ILN_4317
912			\|a GBV_ILN_4319
912			\|a GBV_ILN_4320
912			\|a GBV_ILN_4321
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4700
936	r	v	\|a VA 8360
951			\|a AR
952			\|d 53 \|j 1998 \|e 5-6 \|b 01 \|c 06 \|h 581-586

Indexfelder

author_variant	d s ds o g og h j hj f w h fw fwh
matchkey_str	article:09320776:1998----::yteencaatrseugokoeehrtblsetnltnvopeemtmnsrlgnesnhssncaatrztooaiocd
hierarchy_sort_str	1998
publishDate	1998
allfields	10.1515/znb-1998-5-616 doi (DE-627)OLC2136258818 (DE-B1597)znb-1998-5-616-p DE-627 ger DE-627 rakwb 540 VZ 540 VZ VA 8360 VZ rvk Steinborn, Dirk verfasserin aut Synthese und Charakterisierung von kronenetherstabilisierten Platin(IV)- Komplexen mit Aminosäureliganden / Synthesis and Characterization of Amino Acid Complexes of Platinum(IV) Stabilized by Crown Ethers 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 1946 – 2014: Verlag der Zeitschrift für Naturforschung Abstract Crown ether complexed pentachloro(aqua)platinic acid, ($ H_{3} $O)[$ PtCl_{5} $($ H_{2} $O)]·2(18-cr-6)·$ 6H_{2} $O (1) reacts with glycine, L-alanine, and DL-2-aminobutyric acid to give cis-[$ PtCl_{4} $(O-glyH)($ H_{2} $O)]·(18-cr-6)·$ H_{2} $O (4a)1 and cis-[$ PtCl_{4} $(O-amacH)($ H_{2} $O)]·(18-cr-6) (amacH = alaH 4b, abuH 4c), respectively, as well as ($ amacH_{2} $)2[$ PtCl_{6} $]·2(18-cr-6) (amacH = glyH 5a, alaH 5b, abuH 5c). The crown ether complexed hexachloroplatinic acid, ($ H_{3} $O) 2[$ PtCl_{6} $]·2(18-cr-6) (2), reacts with glycine to afford ($ glyH_{2} $)[$ PtCl_{4} $(N,O-gly)]·2(18-cr-6)·1.$ 25H_{2} $O (6). The structures of 4b and 6 were determined by X-ray diffraction. The alanine ligand in 4b is a zwitterion that is coordinated to platinum by one oxygen atom of the carboxylate group only. The other oxygen atom is engaged in a strong hydrogen bond to the ds-coordinated aqua ligand. The glycinato ligand in 6 is N, O-coordinated at platinum forming an anion [$ PtCl_{4} $(N,O-gly)]- . The other oxygen atom of the carboxylate group is involved in a strong hydrogen bridge to the cation ($ glyH_{2} $)+. In both complexes hydrogen bridges are formed between the -$ N^{+} $$ H_{3} $ and -$ NH_{2} $ groups of the amino acid ligands and the oxygen atoms of the crown ether molecules. Gravenhorst, Olaf aut Junicke, Henrik aut Heinemann, Frank W. aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Verlag der Zeitschrift für Naturforschung, 1947 53(1998), 5-6 vom: 01. Juni, Seite 581-586 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:53 year:1998 number:5-6 day:01 month:06 pages:581-586 https://doi.org/10.1515/znb-1998-5-616 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_30 GBV_ILN_40 GBV_ILN_55 GBV_ILN_59 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_100 GBV_ILN_105 GBV_ILN_120 GBV_ILN_121 GBV_ILN_130 GBV_ILN_267 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2026 GBV_ILN_2185 GBV_ILN_2221 GBV_ILN_2237 GBV_ILN_2279 GBV_ILN_2409 GBV_ILN_4012 GBV_ILN_4027 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4116 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4310 GBV_ILN_4313 GBV_ILN_4314 GBV_ILN_4316 GBV_ILN_4317 GBV_ILN_4319 GBV_ILN_4320 GBV_ILN_4321 GBV_ILN_4323 GBV_ILN_4700 VA 8360 AR 53 1998 5-6 01 06 581-586
spelling	10.1515/znb-1998-5-616 doi (DE-627)OLC2136258818 (DE-B1597)znb-1998-5-616-p DE-627 ger DE-627 rakwb 540 VZ 540 VZ VA 8360 VZ rvk Steinborn, Dirk verfasserin aut Synthese und Charakterisierung von kronenetherstabilisierten Platin(IV)- Komplexen mit Aminosäureliganden / Synthesis and Characterization of Amino Acid Complexes of Platinum(IV) Stabilized by Crown Ethers 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 1946 – 2014: Verlag der Zeitschrift für Naturforschung Abstract Crown ether complexed pentachloro(aqua)platinic acid, ($ H_{3} $O)[$ PtCl_{5} $($ H_{2} $O)]·2(18-cr-6)·$ 6H_{2} $O (1) reacts with glycine, L-alanine, and DL-2-aminobutyric acid to give cis-[$ PtCl_{4} $(O-glyH)($ H_{2} $O)]·(18-cr-6)·$ H_{2} $O (4a)1 and cis-[$ PtCl_{4} $(O-amacH)($ H_{2} $O)]·(18-cr-6) (amacH = alaH 4b, abuH 4c), respectively, as well as ($ amacH_{2} $)2[$ PtCl_{6} $]·2(18-cr-6) (amacH = glyH 5a, alaH 5b, abuH 5c). The crown ether complexed hexachloroplatinic acid, ($ H_{3} $O) 2[$ PtCl_{6} $]·2(18-cr-6) (2), reacts with glycine to afford ($ glyH_{2} $)[$ PtCl_{4} $(N,O-gly)]·2(18-cr-6)·1.$ 25H_{2} $O (6). The structures of 4b and 6 were determined by X-ray diffraction. The alanine ligand in 4b is a zwitterion that is coordinated to platinum by one oxygen atom of the carboxylate group only. The other oxygen atom is engaged in a strong hydrogen bond to the ds-coordinated aqua ligand. The glycinato ligand in 6 is N, O-coordinated at platinum forming an anion [$ PtCl_{4} $(N,O-gly)]- . The other oxygen atom of the carboxylate group is involved in a strong hydrogen bridge to the cation ($ glyH_{2} $)+. In both complexes hydrogen bridges are formed between the -$ N^{+} $$ H_{3} $ and -$ NH_{2} $ groups of the amino acid ligands and the oxygen atoms of the crown ether molecules. Gravenhorst, Olaf aut Junicke, Henrik aut Heinemann, Frank W. aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Verlag der Zeitschrift für Naturforschung, 1947 53(1998), 5-6 vom: 01. Juni, Seite 581-586 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:53 year:1998 number:5-6 day:01 month:06 pages:581-586 https://doi.org/10.1515/znb-1998-5-616 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_30 GBV_ILN_40 GBV_ILN_55 GBV_ILN_59 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_100 GBV_ILN_105 GBV_ILN_120 GBV_ILN_121 GBV_ILN_130 GBV_ILN_267 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2026 GBV_ILN_2185 GBV_ILN_2221 GBV_ILN_2237 GBV_ILN_2279 GBV_ILN_2409 GBV_ILN_4012 GBV_ILN_4027 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4116 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4310 GBV_ILN_4313 GBV_ILN_4314 GBV_ILN_4316 GBV_ILN_4317 GBV_ILN_4319 GBV_ILN_4320 GBV_ILN_4321 GBV_ILN_4323 GBV_ILN_4700 VA 8360 AR 53 1998 5-6 01 06 581-586
allfields_unstemmed	10.1515/znb-1998-5-616 doi (DE-627)OLC2136258818 (DE-B1597)znb-1998-5-616-p DE-627 ger DE-627 rakwb 540 VZ 540 VZ VA 8360 VZ rvk Steinborn, Dirk verfasserin aut Synthese und Charakterisierung von kronenetherstabilisierten Platin(IV)- Komplexen mit Aminosäureliganden / Synthesis and Characterization of Amino Acid Complexes of Platinum(IV) Stabilized by Crown Ethers 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 1946 – 2014: Verlag der Zeitschrift für Naturforschung Abstract Crown ether complexed pentachloro(aqua)platinic acid, ($ H_{3} $O)[$ PtCl_{5} $($ H_{2} $O)]·2(18-cr-6)·$ 6H_{2} $O (1) reacts with glycine, L-alanine, and DL-2-aminobutyric acid to give cis-[$ PtCl_{4} $(O-glyH)($ H_{2} $O)]·(18-cr-6)·$ H_{2} $O (4a)1 and cis-[$ PtCl_{4} $(O-amacH)($ H_{2} $O)]·(18-cr-6) (amacH = alaH 4b, abuH 4c), respectively, as well as ($ amacH_{2} $)2[$ PtCl_{6} $]·2(18-cr-6) (amacH = glyH 5a, alaH 5b, abuH 5c). The crown ether complexed hexachloroplatinic acid, ($ H_{3} $O) 2[$ PtCl_{6} $]·2(18-cr-6) (2), reacts with glycine to afford ($ glyH_{2} $)[$ PtCl_{4} $(N,O-gly)]·2(18-cr-6)·1.$ 25H_{2} $O (6). The structures of 4b and 6 were determined by X-ray diffraction. The alanine ligand in 4b is a zwitterion that is coordinated to platinum by one oxygen atom of the carboxylate group only. The other oxygen atom is engaged in a strong hydrogen bond to the ds-coordinated aqua ligand. The glycinato ligand in 6 is N, O-coordinated at platinum forming an anion [$ PtCl_{4} $(N,O-gly)]- . The other oxygen atom of the carboxylate group is involved in a strong hydrogen bridge to the cation ($ glyH_{2} $)+. In both complexes hydrogen bridges are formed between the -$ N^{+} $$ H_{3} $ and -$ NH_{2} $ groups of the amino acid ligands and the oxygen atoms of the crown ether molecules. Gravenhorst, Olaf aut Junicke, Henrik aut Heinemann, Frank W. aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Verlag der Zeitschrift für Naturforschung, 1947 53(1998), 5-6 vom: 01. Juni, Seite 581-586 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:53 year:1998 number:5-6 day:01 month:06 pages:581-586 https://doi.org/10.1515/znb-1998-5-616 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_30 GBV_ILN_40 GBV_ILN_55 GBV_ILN_59 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_100 GBV_ILN_105 GBV_ILN_120 GBV_ILN_121 GBV_ILN_130 GBV_ILN_267 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2026 GBV_ILN_2185 GBV_ILN_2221 GBV_ILN_2237 GBV_ILN_2279 GBV_ILN_2409 GBV_ILN_4012 GBV_ILN_4027 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4116 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4310 GBV_ILN_4313 GBV_ILN_4314 GBV_ILN_4316 GBV_ILN_4317 GBV_ILN_4319 GBV_ILN_4320 GBV_ILN_4321 GBV_ILN_4323 GBV_ILN_4700 VA 8360 AR 53 1998 5-6 01 06 581-586
allfieldsGer	10.1515/znb-1998-5-616 doi (DE-627)OLC2136258818 (DE-B1597)znb-1998-5-616-p DE-627 ger DE-627 rakwb 540 VZ 540 VZ VA 8360 VZ rvk Steinborn, Dirk verfasserin aut Synthese und Charakterisierung von kronenetherstabilisierten Platin(IV)- Komplexen mit Aminosäureliganden / Synthesis and Characterization of Amino Acid Complexes of Platinum(IV) Stabilized by Crown Ethers 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 1946 – 2014: Verlag der Zeitschrift für Naturforschung Abstract Crown ether complexed pentachloro(aqua)platinic acid, ($ H_{3} $O)[$ PtCl_{5} $($ H_{2} $O)]·2(18-cr-6)·$ 6H_{2} $O (1) reacts with glycine, L-alanine, and DL-2-aminobutyric acid to give cis-[$ PtCl_{4} $(O-glyH)($ H_{2} $O)]·(18-cr-6)·$ H_{2} $O (4a)1 and cis-[$ PtCl_{4} $(O-amacH)($ H_{2} $O)]·(18-cr-6) (amacH = alaH 4b, abuH 4c), respectively, as well as ($ amacH_{2} $)2[$ PtCl_{6} $]·2(18-cr-6) (amacH = glyH 5a, alaH 5b, abuH 5c). The crown ether complexed hexachloroplatinic acid, ($ H_{3} $O) 2[$ PtCl_{6} $]·2(18-cr-6) (2), reacts with glycine to afford ($ glyH_{2} $)[$ PtCl_{4} $(N,O-gly)]·2(18-cr-6)·1.$ 25H_{2} $O (6). The structures of 4b and 6 were determined by X-ray diffraction. The alanine ligand in 4b is a zwitterion that is coordinated to platinum by one oxygen atom of the carboxylate group only. The other oxygen atom is engaged in a strong hydrogen bond to the ds-coordinated aqua ligand. The glycinato ligand in 6 is N, O-coordinated at platinum forming an anion [$ PtCl_{4} $(N,O-gly)]- . The other oxygen atom of the carboxylate group is involved in a strong hydrogen bridge to the cation ($ glyH_{2} $)+. In both complexes hydrogen bridges are formed between the -$ N^{+} $$ H_{3} $ and -$ NH_{2} $ groups of the amino acid ligands and the oxygen atoms of the crown ether molecules. Gravenhorst, Olaf aut Junicke, Henrik aut Heinemann, Frank W. aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Verlag der Zeitschrift für Naturforschung, 1947 53(1998), 5-6 vom: 01. Juni, Seite 581-586 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:53 year:1998 number:5-6 day:01 month:06 pages:581-586 https://doi.org/10.1515/znb-1998-5-616 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_30 GBV_ILN_40 GBV_ILN_55 GBV_ILN_59 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_100 GBV_ILN_105 GBV_ILN_120 GBV_ILN_121 GBV_ILN_130 GBV_ILN_267 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2026 GBV_ILN_2185 GBV_ILN_2221 GBV_ILN_2237 GBV_ILN_2279 GBV_ILN_2409 GBV_ILN_4012 GBV_ILN_4027 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4116 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4310 GBV_ILN_4313 GBV_ILN_4314 GBV_ILN_4316 GBV_ILN_4317 GBV_ILN_4319 GBV_ILN_4320 GBV_ILN_4321 GBV_ILN_4323 GBV_ILN_4700 VA 8360 AR 53 1998 5-6 01 06 581-586
allfieldsSound	10.1515/znb-1998-5-616 doi (DE-627)OLC2136258818 (DE-B1597)znb-1998-5-616-p DE-627 ger DE-627 rakwb 540 VZ 540 VZ VA 8360 VZ rvk Steinborn, Dirk verfasserin aut Synthese und Charakterisierung von kronenetherstabilisierten Platin(IV)- Komplexen mit Aminosäureliganden / Synthesis and Characterization of Amino Acid Complexes of Platinum(IV) Stabilized by Crown Ethers 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 1946 – 2014: Verlag der Zeitschrift für Naturforschung Abstract Crown ether complexed pentachloro(aqua)platinic acid, ($ H_{3} $O)[$ PtCl_{5} $($ H_{2} $O)]·2(18-cr-6)·$ 6H_{2} $O (1) reacts with glycine, L-alanine, and DL-2-aminobutyric acid to give cis-[$ PtCl_{4} $(O-glyH)($ H_{2} $O)]·(18-cr-6)·$ H_{2} $O (4a)1 and cis-[$ PtCl_{4} $(O-amacH)($ H_{2} $O)]·(18-cr-6) (amacH = alaH 4b, abuH 4c), respectively, as well as ($ amacH_{2} $)2[$ PtCl_{6} $]·2(18-cr-6) (amacH = glyH 5a, alaH 5b, abuH 5c). The crown ether complexed hexachloroplatinic acid, ($ H_{3} $O) 2[$ PtCl_{6} $]·2(18-cr-6) (2), reacts with glycine to afford ($ glyH_{2} $)[$ PtCl_{4} $(N,O-gly)]·2(18-cr-6)·1.$ 25H_{2} $O (6). The structures of 4b and 6 were determined by X-ray diffraction. The alanine ligand in 4b is a zwitterion that is coordinated to platinum by one oxygen atom of the carboxylate group only. The other oxygen atom is engaged in a strong hydrogen bond to the ds-coordinated aqua ligand. The glycinato ligand in 6 is N, O-coordinated at platinum forming an anion [$ PtCl_{4} $(N,O-gly)]- . The other oxygen atom of the carboxylate group is involved in a strong hydrogen bridge to the cation ($ glyH_{2} $)+. In both complexes hydrogen bridges are formed between the -$ N^{+} $$ H_{3} $ and -$ NH_{2} $ groups of the amino acid ligands and the oxygen atoms of the crown ether molecules. Gravenhorst, Olaf aut Junicke, Henrik aut Heinemann, Frank W. aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Verlag der Zeitschrift für Naturforschung, 1947 53(1998), 5-6 vom: 01. Juni, Seite 581-586 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:53 year:1998 number:5-6 day:01 month:06 pages:581-586 https://doi.org/10.1515/znb-1998-5-616 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_30 GBV_ILN_40 GBV_ILN_55 GBV_ILN_59 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_100 GBV_ILN_105 GBV_ILN_120 GBV_ILN_121 GBV_ILN_130 GBV_ILN_267 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2026 GBV_ILN_2185 GBV_ILN_2221 GBV_ILN_2237 GBV_ILN_2279 GBV_ILN_2409 GBV_ILN_4012 GBV_ILN_4027 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4116 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4310 GBV_ILN_4313 GBV_ILN_4314 GBV_ILN_4316 GBV_ILN_4317 GBV_ILN_4319 GBV_ILN_4320 GBV_ILN_4321 GBV_ILN_4323 GBV_ILN_4700 VA 8360 AR 53 1998 5-6 01 06 581-586
source	Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences 53(1998), 5-6 vom: 01. Juni, Seite 581-586 volume:53 year:1998 number:5-6 day:01 month:06 pages:581-586
sourceStr	Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences 53(1998), 5-6 vom: 01. Juni, Seite 581-586 volume:53 year:1998 number:5-6 day:01 month:06 pages:581-586
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dewey-raw	540
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container_title	Zeitschrift für Naturforschung. B, Chemical sciences
authorswithroles_txt_mv	Steinborn, Dirk @@aut@@ Gravenhorst, Olaf @@aut@@ Junicke, Henrik @@aut@@ Heinemann, Frank W. @@aut@@
publishDateDaySort_date	1998-06-01T00:00:00Z
hierarchy_top_id	129307386
dewey-sort	3540
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The crown ether complexed hexachloroplatinic acid, ($ H_{3} $O) 2[$ PtCl_{6} $]·2(18-cr-6) (2), reacts with glycine to afford ($ glyH_{2} $)[$ PtCl_{4} $(N,O-gly)]·2(18-cr-6)·1.$ 25H_{2} $O (6). The structures of 4b and 6 were determined by X-ray diffraction. The alanine ligand in 4b is a zwitterion that is coordinated to platinum by one oxygen atom of the carboxylate group only. The other oxygen atom is engaged in a strong hydrogen bond to the ds-coordinated aqua ligand. The glycinato ligand in 6 is N, O-coordinated at platinum forming an anion [$ PtCl_{4} $(N,O-gly)]- . The other oxygen atom of the carboxylate group is involved in a strong hydrogen bridge to the cation ($ glyH_{2} $)+. 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author	Steinborn, Dirk
spellingShingle	Steinborn, Dirk ddc 540 rvk VA 8360 Synthese und Charakterisierung von kronenetherstabilisierten Platin(IV)- Komplexen mit Aminosäureliganden / Synthesis and Characterization of Amino Acid Complexes of Platinum(IV) Stabilized by Crown Ethers
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topic_title	540 VZ VA 8360 VZ rvk Synthese und Charakterisierung von kronenetherstabilisierten Platin(IV)- Komplexen mit Aminosäureliganden / Synthesis and Characterization of Amino Acid Complexes of Platinum(IV) Stabilized by Crown Ethers
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title	Synthese und Charakterisierung von kronenetherstabilisierten Platin(IV)- Komplexen mit Aminosäureliganden / Synthesis and Characterization of Amino Acid Complexes of Platinum(IV) Stabilized by Crown Ethers
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title_full	Synthese und Charakterisierung von kronenetherstabilisierten Platin(IV)- Komplexen mit Aminosäureliganden / Synthesis and Characterization of Amino Acid Complexes of Platinum(IV) Stabilized by Crown Ethers
author_sort	Steinborn, Dirk
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journalStr	Zeitschrift für Naturforschung. B, Chemical sciences
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author_browse	Steinborn, Dirk Gravenhorst, Olaf Junicke, Henrik Heinemann, Frank W.
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class	540 VZ VA 8360 VZ rvk
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author-letter	Steinborn, Dirk
doi_str_mv	10.1515/znb-1998-5-616
dewey-full	540
title_sort	synthese und charakterisierung von kronenetherstabilisierten platin(iv)- komplexen mit aminosäureliganden / synthesis and characterization of amino acid complexes of platinum(iv) stabilized by crown ethers
title_auth	Synthese und Charakterisierung von kronenetherstabilisierten Platin(IV)- Komplexen mit Aminosäureliganden / Synthesis and Characterization of Amino Acid Complexes of Platinum(IV) Stabilized by Crown Ethers
abstract	Abstract Crown ether complexed pentachloro(aqua)platinic acid, ($ H_{3} $O)[$ PtCl_{5} $($ H_{2} $O)]·2(18-cr-6)·$ 6H_{2} $O (1) reacts with glycine, L-alanine, and DL-2-aminobutyric acid to give cis-[$ PtCl_{4} $(O-glyH)($ H_{2} $O)]·(18-cr-6)·$ H_{2} $O (4a)1 and cis-[$ PtCl_{4} $(O-amacH)($ H_{2} $O)]·(18-cr-6) (amacH = alaH 4b, abuH 4c), respectively, as well as ($ amacH_{2} $)2[$ PtCl_{6} $]·2(18-cr-6) (amacH = glyH 5a, alaH 5b, abuH 5c). The crown ether complexed hexachloroplatinic acid, ($ H_{3} $O) 2[$ PtCl_{6} $]·2(18-cr-6) (2), reacts with glycine to afford ($ glyH_{2} $)[$ PtCl_{4} $(N,O-gly)]·2(18-cr-6)·1.$ 25H_{2} $O (6). The structures of 4b and 6 were determined by X-ray diffraction. The alanine ligand in 4b is a zwitterion that is coordinated to platinum by one oxygen atom of the carboxylate group only. The other oxygen atom is engaged in a strong hydrogen bond to the ds-coordinated aqua ligand. The glycinato ligand in 6 is N, O-coordinated at platinum forming an anion [$ PtCl_{4} $(N,O-gly)]- . The other oxygen atom of the carboxylate group is involved in a strong hydrogen bridge to the cation ($ glyH_{2} $)+. In both complexes hydrogen bridges are formed between the -$ N^{+} $$ H_{3} $ and -$ NH_{2} $ groups of the amino acid ligands and the oxygen atoms of the crown ether molecules. © 1946 – 2014: Verlag der Zeitschrift für Naturforschung
abstractGer	Abstract Crown ether complexed pentachloro(aqua)platinic acid, ($ H_{3} $O)[$ PtCl_{5} $($ H_{2} $O)]·2(18-cr-6)·$ 6H_{2} $O (1) reacts with glycine, L-alanine, and DL-2-aminobutyric acid to give cis-[$ PtCl_{4} $(O-glyH)($ H_{2} $O)]·(18-cr-6)·$ H_{2} $O (4a)1 and cis-[$ PtCl_{4} $(O-amacH)($ H_{2} $O)]·(18-cr-6) (amacH = alaH 4b, abuH 4c), respectively, as well as ($ amacH_{2} $)2[$ PtCl_{6} $]·2(18-cr-6) (amacH = glyH 5a, alaH 5b, abuH 5c). The crown ether complexed hexachloroplatinic acid, ($ H_{3} $O) 2[$ PtCl_{6} $]·2(18-cr-6) (2), reacts with glycine to afford ($ glyH_{2} $)[$ PtCl_{4} $(N,O-gly)]·2(18-cr-6)·1.$ 25H_{2} $O (6). The structures of 4b and 6 were determined by X-ray diffraction. The alanine ligand in 4b is a zwitterion that is coordinated to platinum by one oxygen atom of the carboxylate group only. The other oxygen atom is engaged in a strong hydrogen bond to the ds-coordinated aqua ligand. The glycinato ligand in 6 is N, O-coordinated at platinum forming an anion [$ PtCl_{4} $(N,O-gly)]- . The other oxygen atom of the carboxylate group is involved in a strong hydrogen bridge to the cation ($ glyH_{2} $)+. In both complexes hydrogen bridges are formed between the -$ N^{+} $$ H_{3} $ and -$ NH_{2} $ groups of the amino acid ligands and the oxygen atoms of the crown ether molecules. © 1946 – 2014: Verlag der Zeitschrift für Naturforschung
abstract_unstemmed	Abstract Crown ether complexed pentachloro(aqua)platinic acid, ($ H_{3} $O)[$ PtCl_{5} $($ H_{2} $O)]·2(18-cr-6)·$ 6H_{2} $O (1) reacts with glycine, L-alanine, and DL-2-aminobutyric acid to give cis-[$ PtCl_{4} $(O-glyH)($ H_{2} $O)]·(18-cr-6)·$ H_{2} $O (4a)1 and cis-[$ PtCl_{4} $(O-amacH)($ H_{2} $O)]·(18-cr-6) (amacH = alaH 4b, abuH 4c), respectively, as well as ($ amacH_{2} $)2[$ PtCl_{6} $]·2(18-cr-6) (amacH = glyH 5a, alaH 5b, abuH 5c). The crown ether complexed hexachloroplatinic acid, ($ H_{3} $O) 2[$ PtCl_{6} $]·2(18-cr-6) (2), reacts with glycine to afford ($ glyH_{2} $)[$ PtCl_{4} $(N,O-gly)]·2(18-cr-6)·1.$ 25H_{2} $O (6). The structures of 4b and 6 were determined by X-ray diffraction. The alanine ligand in 4b is a zwitterion that is coordinated to platinum by one oxygen atom of the carboxylate group only. The other oxygen atom is engaged in a strong hydrogen bond to the ds-coordinated aqua ligand. The glycinato ligand in 6 is N, O-coordinated at platinum forming an anion [$ PtCl_{4} $(N,O-gly)]- . The other oxygen atom of the carboxylate group is involved in a strong hydrogen bridge to the cation ($ glyH_{2} $)+. In both complexes hydrogen bridges are formed between the -$ N^{+} $$ H_{3} $ and -$ NH_{2} $ groups of the amino acid ligands and the oxygen atoms of the crown ether molecules. © 1946 – 2014: Verlag der Zeitschrift für Naturforschung
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title_short	Synthese und Charakterisierung von kronenetherstabilisierten Platin(IV)- Komplexen mit Aminosäureliganden / Synthesis and Characterization of Amino Acid Complexes of Platinum(IV) Stabilized by Crown Ethers
url	https://doi.org/10.1515/znb-1998-5-616
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Synthese und Charakterisierung von kronenetherstabilisierten Platin(IV)- Komplexen mit Aminosäureliganden / Synthesis and Characterization of Amino Acid Complexes of Platinum(IV) Stabilized by Crown Ethers

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