Reaction of Hexagonal Boron Nitride Nano-crystals under Mild Hydrothermal Conditions

The reaction between hexagonal boron nitride (hBN) nano-crystals and water at low temperature and low pressure has been investigated. The results reveal that this reaction can be greatly promoted by increasing the hot-pressing temperature. However, when the temperature is above 280 °C, the reaction...
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Autor*in:	Zhu, Lingling [verfasserIn] Lian, Gang Tan, Miao Wang, Qilong Zhao, Xian Cui, Deliang Tao, Xutang

Format:	Artikel

Erschienen:	2008

Systematik:	VA 8360

Anmerkung:	© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Übergeordnetes Werk:	Enthalten in: Zeitschrift für Naturforschung. B, Chemical sciences - Verlag der Zeitschrift für Naturforschung, 1947, 63(2008), 6 vom: 01. Juni, Seite 742-746
Übergeordnetes Werk:	volume:63 ; year:2008 ; number:6 ; day:01 ; month:06 ; pages:742-746

Links:	Volltext

DOI / URN:	10.1515/znb-2008-0623

Katalog-ID:	OLC2136362305

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520			\|a The reaction between hexagonal boron nitride (hBN) nano-crystals and water at low temperature and low pressure has been investigated. The results reveal that this reaction can be greatly promoted by increasing the hot-pressing temperature. However, when the temperature is above 280 °C, the reaction is too fast to be controlled by varying the hot-pressing pressure and time. On the other hand, stress and defects are induced in hBN nano-crystals by the hydrothermal hot-pressing process, resulting in a shift of the IR absorption bands and a deterioration of crystalline perfection. These results may be useful for synthesizing cBN by the hydrothermal method and converting hBN nanocrystals into cBN under moderate conditions.
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allfields	10.1515/znb-2008-0623 doi (DE-627)OLC2136362305 (DE-B1597)znb-2008-0623-p DE-627 ger DE-627 rakwb 540 VZ 540 VZ VA 8360 VZ rvk Zhu, Lingling verfasserin aut Reaction of Hexagonal Boron Nitride Nano-crystals under Mild Hydrothermal Conditions 2008 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 1946 – 2014: Verlag der Zeitschrift für Naturforschung The reaction between hexagonal boron nitride (hBN) nano-crystals and water at low temperature and low pressure has been investigated. The results reveal that this reaction can be greatly promoted by increasing the hot-pressing temperature. However, when the temperature is above 280 °C, the reaction is too fast to be controlled by varying the hot-pressing pressure and time. On the other hand, stress and defects are induced in hBN nano-crystals by the hydrothermal hot-pressing process, resulting in a shift of the IR absorption bands and a deterioration of crystalline perfection. These results may be useful for synthesizing cBN by the hydrothermal method and converting hBN nanocrystals into cBN under moderate conditions. Lian, Gang aut Tan, Miao aut Wang, Qilong aut Zhao, Xian aut Cui, Deliang aut Tao, Xutang aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Verlag der Zeitschrift für Naturforschung, 1947 63(2008), 6 vom: 01. Juni, Seite 742-746 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:63 year:2008 number:6 day:01 month:06 pages:742-746 https://doi.org/10.1515/znb-2008-0623 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_22 GBV_ILN_24 GBV_ILN_30 GBV_ILN_40 GBV_ILN_59 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_120 GBV_ILN_121 GBV_ILN_267 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2027 GBV_ILN_2185 GBV_ILN_4012 GBV_ILN_4027 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4116 GBV_ILN_4125 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4314 GBV_ILN_4317 GBV_ILN_4320 VA 8360 AR 63 2008 6 01 06 742-746
spelling	10.1515/znb-2008-0623 doi (DE-627)OLC2136362305 (DE-B1597)znb-2008-0623-p DE-627 ger DE-627 rakwb 540 VZ 540 VZ VA 8360 VZ rvk Zhu, Lingling verfasserin aut Reaction of Hexagonal Boron Nitride Nano-crystals under Mild Hydrothermal Conditions 2008 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 1946 – 2014: Verlag der Zeitschrift für Naturforschung The reaction between hexagonal boron nitride (hBN) nano-crystals and water at low temperature and low pressure has been investigated. The results reveal that this reaction can be greatly promoted by increasing the hot-pressing temperature. However, when the temperature is above 280 °C, the reaction is too fast to be controlled by varying the hot-pressing pressure and time. On the other hand, stress and defects are induced in hBN nano-crystals by the hydrothermal hot-pressing process, resulting in a shift of the IR absorption bands and a deterioration of crystalline perfection. These results may be useful for synthesizing cBN by the hydrothermal method and converting hBN nanocrystals into cBN under moderate conditions. Lian, Gang aut Tan, Miao aut Wang, Qilong aut Zhao, Xian aut Cui, Deliang aut Tao, Xutang aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Verlag der Zeitschrift für Naturforschung, 1947 63(2008), 6 vom: 01. Juni, Seite 742-746 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:63 year:2008 number:6 day:01 month:06 pages:742-746 https://doi.org/10.1515/znb-2008-0623 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_22 GBV_ILN_24 GBV_ILN_30 GBV_ILN_40 GBV_ILN_59 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_120 GBV_ILN_121 GBV_ILN_267 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2027 GBV_ILN_2185 GBV_ILN_4012 GBV_ILN_4027 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4116 GBV_ILN_4125 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4314 GBV_ILN_4317 GBV_ILN_4320 VA 8360 AR 63 2008 6 01 06 742-746
allfields_unstemmed	10.1515/znb-2008-0623 doi (DE-627)OLC2136362305 (DE-B1597)znb-2008-0623-p DE-627 ger DE-627 rakwb 540 VZ 540 VZ VA 8360 VZ rvk Zhu, Lingling verfasserin aut Reaction of Hexagonal Boron Nitride Nano-crystals under Mild Hydrothermal Conditions 2008 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 1946 – 2014: Verlag der Zeitschrift für Naturforschung The reaction between hexagonal boron nitride (hBN) nano-crystals and water at low temperature and low pressure has been investigated. The results reveal that this reaction can be greatly promoted by increasing the hot-pressing temperature. However, when the temperature is above 280 °C, the reaction is too fast to be controlled by varying the hot-pressing pressure and time. On the other hand, stress and defects are induced in hBN nano-crystals by the hydrothermal hot-pressing process, resulting in a shift of the IR absorption bands and a deterioration of crystalline perfection. These results may be useful for synthesizing cBN by the hydrothermal method and converting hBN nanocrystals into cBN under moderate conditions. Lian, Gang aut Tan, Miao aut Wang, Qilong aut Zhao, Xian aut Cui, Deliang aut Tao, Xutang aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Verlag der Zeitschrift für Naturforschung, 1947 63(2008), 6 vom: 01. Juni, Seite 742-746 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:63 year:2008 number:6 day:01 month:06 pages:742-746 https://doi.org/10.1515/znb-2008-0623 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_22 GBV_ILN_24 GBV_ILN_30 GBV_ILN_40 GBV_ILN_59 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_120 GBV_ILN_121 GBV_ILN_267 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2027 GBV_ILN_2185 GBV_ILN_4012 GBV_ILN_4027 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4116 GBV_ILN_4125 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4314 GBV_ILN_4317 GBV_ILN_4320 VA 8360 AR 63 2008 6 01 06 742-746
allfieldsGer	10.1515/znb-2008-0623 doi (DE-627)OLC2136362305 (DE-B1597)znb-2008-0623-p DE-627 ger DE-627 rakwb 540 VZ 540 VZ VA 8360 VZ rvk Zhu, Lingling verfasserin aut Reaction of Hexagonal Boron Nitride Nano-crystals under Mild Hydrothermal Conditions 2008 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 1946 – 2014: Verlag der Zeitschrift für Naturforschung The reaction between hexagonal boron nitride (hBN) nano-crystals and water at low temperature and low pressure has been investigated. The results reveal that this reaction can be greatly promoted by increasing the hot-pressing temperature. However, when the temperature is above 280 °C, the reaction is too fast to be controlled by varying the hot-pressing pressure and time. On the other hand, stress and defects are induced in hBN nano-crystals by the hydrothermal hot-pressing process, resulting in a shift of the IR absorption bands and a deterioration of crystalline perfection. These results may be useful for synthesizing cBN by the hydrothermal method and converting hBN nanocrystals into cBN under moderate conditions. Lian, Gang aut Tan, Miao aut Wang, Qilong aut Zhao, Xian aut Cui, Deliang aut Tao, Xutang aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Verlag der Zeitschrift für Naturforschung, 1947 63(2008), 6 vom: 01. Juni, Seite 742-746 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:63 year:2008 number:6 day:01 month:06 pages:742-746 https://doi.org/10.1515/znb-2008-0623 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_22 GBV_ILN_24 GBV_ILN_30 GBV_ILN_40 GBV_ILN_59 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_120 GBV_ILN_121 GBV_ILN_267 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2027 GBV_ILN_2185 GBV_ILN_4012 GBV_ILN_4027 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4116 GBV_ILN_4125 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4314 GBV_ILN_4317 GBV_ILN_4320 VA 8360 AR 63 2008 6 01 06 742-746
allfieldsSound	10.1515/znb-2008-0623 doi (DE-627)OLC2136362305 (DE-B1597)znb-2008-0623-p DE-627 ger DE-627 rakwb 540 VZ 540 VZ VA 8360 VZ rvk Zhu, Lingling verfasserin aut Reaction of Hexagonal Boron Nitride Nano-crystals under Mild Hydrothermal Conditions 2008 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 1946 – 2014: Verlag der Zeitschrift für Naturforschung The reaction between hexagonal boron nitride (hBN) nano-crystals and water at low temperature and low pressure has been investigated. The results reveal that this reaction can be greatly promoted by increasing the hot-pressing temperature. However, when the temperature is above 280 °C, the reaction is too fast to be controlled by varying the hot-pressing pressure and time. On the other hand, stress and defects are induced in hBN nano-crystals by the hydrothermal hot-pressing process, resulting in a shift of the IR absorption bands and a deterioration of crystalline perfection. These results may be useful for synthesizing cBN by the hydrothermal method and converting hBN nanocrystals into cBN under moderate conditions. Lian, Gang aut Tan, Miao aut Wang, Qilong aut Zhao, Xian aut Cui, Deliang aut Tao, Xutang aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Verlag der Zeitschrift für Naturforschung, 1947 63(2008), 6 vom: 01. Juni, Seite 742-746 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:63 year:2008 number:6 day:01 month:06 pages:742-746 https://doi.org/10.1515/znb-2008-0623 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_22 GBV_ILN_24 GBV_ILN_30 GBV_ILN_40 GBV_ILN_59 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_120 GBV_ILN_121 GBV_ILN_267 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2027 GBV_ILN_2185 GBV_ILN_4012 GBV_ILN_4027 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4116 GBV_ILN_4125 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4314 GBV_ILN_4317 GBV_ILN_4320 VA 8360 AR 63 2008 6 01 06 742-746
source	Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences 63(2008), 6 vom: 01. Juni, Seite 742-746 volume:63 year:2008 number:6 day:01 month:06 pages:742-746
sourceStr	Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences 63(2008), 6 vom: 01. Juni, Seite 742-746 volume:63 year:2008 number:6 day:01 month:06 pages:742-746
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author	Zhu, Lingling
spellingShingle	Zhu, Lingling ddc 540 rvk VA 8360 Reaction of Hexagonal Boron Nitride Nano-crystals under Mild Hydrothermal Conditions
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topic_title	540 VZ VA 8360 VZ rvk Reaction of Hexagonal Boron Nitride Nano-crystals under Mild Hydrothermal Conditions
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title	Reaction of Hexagonal Boron Nitride Nano-crystals under Mild Hydrothermal Conditions
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title_full	Reaction of Hexagonal Boron Nitride Nano-crystals under Mild Hydrothermal Conditions
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author_browse	Zhu, Lingling Lian, Gang Tan, Miao Wang, Qilong Zhao, Xian Cui, Deliang Tao, Xutang
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title_sort	reaction of hexagonal boron nitride nano-crystals under mild hydrothermal conditions
title_auth	Reaction of Hexagonal Boron Nitride Nano-crystals under Mild Hydrothermal Conditions
abstract	The reaction between hexagonal boron nitride (hBN) nano-crystals and water at low temperature and low pressure has been investigated. The results reveal that this reaction can be greatly promoted by increasing the hot-pressing temperature. However, when the temperature is above 280 °C, the reaction is too fast to be controlled by varying the hot-pressing pressure and time. On the other hand, stress and defects are induced in hBN nano-crystals by the hydrothermal hot-pressing process, resulting in a shift of the IR absorption bands and a deterioration of crystalline perfection. These results may be useful for synthesizing cBN by the hydrothermal method and converting hBN nanocrystals into cBN under moderate conditions. © 1946 – 2014: Verlag der Zeitschrift für Naturforschung
abstractGer	The reaction between hexagonal boron nitride (hBN) nano-crystals and water at low temperature and low pressure has been investigated. The results reveal that this reaction can be greatly promoted by increasing the hot-pressing temperature. However, when the temperature is above 280 °C, the reaction is too fast to be controlled by varying the hot-pressing pressure and time. On the other hand, stress and defects are induced in hBN nano-crystals by the hydrothermal hot-pressing process, resulting in a shift of the IR absorption bands and a deterioration of crystalline perfection. These results may be useful for synthesizing cBN by the hydrothermal method and converting hBN nanocrystals into cBN under moderate conditions. © 1946 – 2014: Verlag der Zeitschrift für Naturforschung
abstract_unstemmed	The reaction between hexagonal boron nitride (hBN) nano-crystals and water at low temperature and low pressure has been investigated. The results reveal that this reaction can be greatly promoted by increasing the hot-pressing temperature. However, when the temperature is above 280 °C, the reaction is too fast to be controlled by varying the hot-pressing pressure and time. On the other hand, stress and defects are induced in hBN nano-crystals by the hydrothermal hot-pressing process, resulting in a shift of the IR absorption bands and a deterioration of crystalline perfection. These results may be useful for synthesizing cBN by the hydrothermal method and converting hBN nanocrystals into cBN under moderate conditions. © 1946 – 2014: Verlag der Zeitschrift für Naturforschung
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title_short	Reaction of Hexagonal Boron Nitride Nano-crystals under Mild Hydrothermal Conditions
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author2	Lian, Gang Tan, Miao Wang, Qilong Zhao, Xian Cui, Deliang Tao, Xutang
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