Cation Distribution in Some Natural Spinels from X-ray Diffraction and Mössbauer Spectroscopy
Abstract Three natural spinels of different places of occurrence and compositions were investigated by means of microprobe chemical analysis, single crystal X-ray diffraction and Mössbauer spectroscopy. All cation distributions between T and M sites were calculated from microprobe and XRD experiment...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Carbonin, Susanna [verfasserIn] |
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| Format: |
Artikel |
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| Erschienen: |
1996 |
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| Systematik: |
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| Anmerkung: |
© 2016 by Walter de Gruyter Berlin/Boston |
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| Übergeordnetes Werk: |
Enthalten in: Mineralogical magazine - De Gruyter, 1969, 60(1996), 2 vom: 01. Apr., Seite 355-368 |
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| Übergeordnetes Werk: |
volume:60 ; year:1996 ; number:2 ; day:01 ; month:04 ; pages:355-368 |
| Links: |
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| DOI / URN: |
10.1180/minmag.1996.060.399.10 |
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| Katalog-ID: |
OLC2137703238 |
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| 245 | 1 | 0 | |a Cation Distribution in Some Natural Spinels from X-ray Diffraction and Mössbauer Spectroscopy |
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| 520 | |a Abstract Three natural spinels of different places of occurrence and compositions were investigated by means of microprobe chemical analysis, single crystal X-ray diffraction and Mössbauer spectroscopy. All cation distributions between T and M sites were calculated from microprobe and XRD experimental data, by means of a mathematical model with appropriate assumptions. $ Fe^{2+} $ and $ Fe^{3+} $ assignments calculated in this way were compared with those observed in Mössbauer spectra. The satisfactory agreement found proves, at least in the samples studied, the reliability of the model and the assumptions used. In the spinels examined, such results show $ Fe^{2+} $ and $ Fe^{3+} $ virtually ordered in T and M sites respectively. Mössbauer data also revealed $ Fe^{2+} $ in different tetrahedral sites due to the next-nearest neighbour effect, probably as a consequence of spinel genetic conditions. | ||
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| 700 | 1 | |a Giusta, Antonio Della |4 aut | |
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10.1180/minmag.1996.060.399.10 doi (DE-627)OLC2137703238 (DE-B1597)minmag.1996.060.399.10-p DE-627 ger DE-627 rakwb 550 VZ 13 ssgn TE 1000 VZ rvk Carbonin, Susanna verfasserin aut Cation Distribution in Some Natural Spinels from X-ray Diffraction and Mössbauer Spectroscopy 1996 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 2016 by Walter de Gruyter Berlin/Boston Abstract Three natural spinels of different places of occurrence and compositions were investigated by means of microprobe chemical analysis, single crystal X-ray diffraction and Mössbauer spectroscopy. All cation distributions between T and M sites were calculated from microprobe and XRD experimental data, by means of a mathematical model with appropriate assumptions. $ Fe^{2+} $ and $ Fe^{3+} $ assignments calculated in this way were compared with those observed in Mössbauer spectra. The satisfactory agreement found proves, at least in the samples studied, the reliability of the model and the assumptions used. In the spinels examined, such results show $ Fe^{2+} $ and $ Fe^{3+} $ virtually ordered in T and M sites respectively. Mössbauer data also revealed $ Fe^{2+} $ in different tetrahedral sites due to the next-nearest neighbour effect, probably as a consequence of spinel genetic conditions. Russo, Umberto aut Giusta, Antonio Della aut Enthalten in Mineralogical magazine De Gruyter, 1969 60(1996), 2 vom: 01. Apr., Seite 355-368 (DE-627)13069617X (DE-600)956157-2 (DE-576)016244141 0026-461X nnns volume:60 year:1996 number:2 day:01 month:04 pages:355-368 https://doi.org/10.1180/minmag.1996.060.399.10 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_22 GBV_ILN_31 GBV_ILN_40 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2004 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2027 GBV_ILN_4012 GBV_ILN_4029 GBV_ILN_4112 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4319 GBV_ILN_4323 TE 1000 AR 60 1996 2 01 04 355-368 |
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10.1180/minmag.1996.060.399.10 doi (DE-627)OLC2137703238 (DE-B1597)minmag.1996.060.399.10-p DE-627 ger DE-627 rakwb 550 VZ 13 ssgn TE 1000 VZ rvk Carbonin, Susanna verfasserin aut Cation Distribution in Some Natural Spinels from X-ray Diffraction and Mössbauer Spectroscopy 1996 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 2016 by Walter de Gruyter Berlin/Boston Abstract Three natural spinels of different places of occurrence and compositions were investigated by means of microprobe chemical analysis, single crystal X-ray diffraction and Mössbauer spectroscopy. All cation distributions between T and M sites were calculated from microprobe and XRD experimental data, by means of a mathematical model with appropriate assumptions. $ Fe^{2+} $ and $ Fe^{3+} $ assignments calculated in this way were compared with those observed in Mössbauer spectra. The satisfactory agreement found proves, at least in the samples studied, the reliability of the model and the assumptions used. In the spinels examined, such results show $ Fe^{2+} $ and $ Fe^{3+} $ virtually ordered in T and M sites respectively. Mössbauer data also revealed $ Fe^{2+} $ in different tetrahedral sites due to the next-nearest neighbour effect, probably as a consequence of spinel genetic conditions. Russo, Umberto aut Giusta, Antonio Della aut Enthalten in Mineralogical magazine De Gruyter, 1969 60(1996), 2 vom: 01. Apr., Seite 355-368 (DE-627)13069617X (DE-600)956157-2 (DE-576)016244141 0026-461X nnns volume:60 year:1996 number:2 day:01 month:04 pages:355-368 https://doi.org/10.1180/minmag.1996.060.399.10 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_22 GBV_ILN_31 GBV_ILN_40 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2004 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2027 GBV_ILN_4012 GBV_ILN_4029 GBV_ILN_4112 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4319 GBV_ILN_4323 TE 1000 AR 60 1996 2 01 04 355-368 |
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10.1180/minmag.1996.060.399.10 doi (DE-627)OLC2137703238 (DE-B1597)minmag.1996.060.399.10-p DE-627 ger DE-627 rakwb 550 VZ 13 ssgn TE 1000 VZ rvk Carbonin, Susanna verfasserin aut Cation Distribution in Some Natural Spinels from X-ray Diffraction and Mössbauer Spectroscopy 1996 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 2016 by Walter de Gruyter Berlin/Boston Abstract Three natural spinels of different places of occurrence and compositions were investigated by means of microprobe chemical analysis, single crystal X-ray diffraction and Mössbauer spectroscopy. All cation distributions between T and M sites were calculated from microprobe and XRD experimental data, by means of a mathematical model with appropriate assumptions. $ Fe^{2+} $ and $ Fe^{3+} $ assignments calculated in this way were compared with those observed in Mössbauer spectra. The satisfactory agreement found proves, at least in the samples studied, the reliability of the model and the assumptions used. In the spinels examined, such results show $ Fe^{2+} $ and $ Fe^{3+} $ virtually ordered in T and M sites respectively. Mössbauer data also revealed $ Fe^{2+} $ in different tetrahedral sites due to the next-nearest neighbour effect, probably as a consequence of spinel genetic conditions. Russo, Umberto aut Giusta, Antonio Della aut Enthalten in Mineralogical magazine De Gruyter, 1969 60(1996), 2 vom: 01. Apr., Seite 355-368 (DE-627)13069617X (DE-600)956157-2 (DE-576)016244141 0026-461X nnns volume:60 year:1996 number:2 day:01 month:04 pages:355-368 https://doi.org/10.1180/minmag.1996.060.399.10 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_22 GBV_ILN_31 GBV_ILN_40 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2004 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2027 GBV_ILN_4012 GBV_ILN_4029 GBV_ILN_4112 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4319 GBV_ILN_4323 TE 1000 AR 60 1996 2 01 04 355-368 |
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10.1180/minmag.1996.060.399.10 doi (DE-627)OLC2137703238 (DE-B1597)minmag.1996.060.399.10-p DE-627 ger DE-627 rakwb 550 VZ 13 ssgn TE 1000 VZ rvk Carbonin, Susanna verfasserin aut Cation Distribution in Some Natural Spinels from X-ray Diffraction and Mössbauer Spectroscopy 1996 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 2016 by Walter de Gruyter Berlin/Boston Abstract Three natural spinels of different places of occurrence and compositions were investigated by means of microprobe chemical analysis, single crystal X-ray diffraction and Mössbauer spectroscopy. All cation distributions between T and M sites were calculated from microprobe and XRD experimental data, by means of a mathematical model with appropriate assumptions. $ Fe^{2+} $ and $ Fe^{3+} $ assignments calculated in this way were compared with those observed in Mössbauer spectra. The satisfactory agreement found proves, at least in the samples studied, the reliability of the model and the assumptions used. In the spinels examined, such results show $ Fe^{2+} $ and $ Fe^{3+} $ virtually ordered in T and M sites respectively. Mössbauer data also revealed $ Fe^{2+} $ in different tetrahedral sites due to the next-nearest neighbour effect, probably as a consequence of spinel genetic conditions. Russo, Umberto aut Giusta, Antonio Della aut Enthalten in Mineralogical magazine De Gruyter, 1969 60(1996), 2 vom: 01. Apr., Seite 355-368 (DE-627)13069617X (DE-600)956157-2 (DE-576)016244141 0026-461X nnns volume:60 year:1996 number:2 day:01 month:04 pages:355-368 https://doi.org/10.1180/minmag.1996.060.399.10 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_22 GBV_ILN_31 GBV_ILN_40 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2004 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2027 GBV_ILN_4012 GBV_ILN_4029 GBV_ILN_4112 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4319 GBV_ILN_4323 TE 1000 AR 60 1996 2 01 04 355-368 |
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10.1180/minmag.1996.060.399.10 doi (DE-627)OLC2137703238 (DE-B1597)minmag.1996.060.399.10-p DE-627 ger DE-627 rakwb 550 VZ 13 ssgn TE 1000 VZ rvk Carbonin, Susanna verfasserin aut Cation Distribution in Some Natural Spinels from X-ray Diffraction and Mössbauer Spectroscopy 1996 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 2016 by Walter de Gruyter Berlin/Boston Abstract Three natural spinels of different places of occurrence and compositions were investigated by means of microprobe chemical analysis, single crystal X-ray diffraction and Mössbauer spectroscopy. All cation distributions between T and M sites were calculated from microprobe and XRD experimental data, by means of a mathematical model with appropriate assumptions. $ Fe^{2+} $ and $ Fe^{3+} $ assignments calculated in this way were compared with those observed in Mössbauer spectra. The satisfactory agreement found proves, at least in the samples studied, the reliability of the model and the assumptions used. In the spinels examined, such results show $ Fe^{2+} $ and $ Fe^{3+} $ virtually ordered in T and M sites respectively. Mössbauer data also revealed $ Fe^{2+} $ in different tetrahedral sites due to the next-nearest neighbour effect, probably as a consequence of spinel genetic conditions. Russo, Umberto aut Giusta, Antonio Della aut Enthalten in Mineralogical magazine De Gruyter, 1969 60(1996), 2 vom: 01. Apr., Seite 355-368 (DE-627)13069617X (DE-600)956157-2 (DE-576)016244141 0026-461X nnns volume:60 year:1996 number:2 day:01 month:04 pages:355-368 https://doi.org/10.1180/minmag.1996.060.399.10 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_22 GBV_ILN_31 GBV_ILN_40 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2004 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2027 GBV_ILN_4012 GBV_ILN_4029 GBV_ILN_4112 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4319 GBV_ILN_4323 TE 1000 AR 60 1996 2 01 04 355-368 |
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Enthalten in Mineralogical magazine 60(1996), 2 vom: 01. Apr., Seite 355-368 volume:60 year:1996 number:2 day:01 month:04 pages:355-368 |
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Enthalten in Mineralogical magazine 60(1996), 2 vom: 01. Apr., Seite 355-368 volume:60 year:1996 number:2 day:01 month:04 pages:355-368 |
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Cation Distribution in Some Natural Spinels from X-ray Diffraction and Mössbauer Spectroscopy |
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Abstract Three natural spinels of different places of occurrence and compositions were investigated by means of microprobe chemical analysis, single crystal X-ray diffraction and Mössbauer spectroscopy. All cation distributions between T and M sites were calculated from microprobe and XRD experimental data, by means of a mathematical model with appropriate assumptions. $ Fe^{2+} $ and $ Fe^{3+} $ assignments calculated in this way were compared with those observed in Mössbauer spectra. The satisfactory agreement found proves, at least in the samples studied, the reliability of the model and the assumptions used. In the spinels examined, such results show $ Fe^{2+} $ and $ Fe^{3+} $ virtually ordered in T and M sites respectively. Mössbauer data also revealed $ Fe^{2+} $ in different tetrahedral sites due to the next-nearest neighbour effect, probably as a consequence of spinel genetic conditions. © 2016 by Walter de Gruyter Berlin/Boston |
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Abstract Three natural spinels of different places of occurrence and compositions were investigated by means of microprobe chemical analysis, single crystal X-ray diffraction and Mössbauer spectroscopy. All cation distributions between T and M sites were calculated from microprobe and XRD experimental data, by means of a mathematical model with appropriate assumptions. $ Fe^{2+} $ and $ Fe^{3+} $ assignments calculated in this way were compared with those observed in Mössbauer spectra. The satisfactory agreement found proves, at least in the samples studied, the reliability of the model and the assumptions used. In the spinels examined, such results show $ Fe^{2+} $ and $ Fe^{3+} $ virtually ordered in T and M sites respectively. Mössbauer data also revealed $ Fe^{2+} $ in different tetrahedral sites due to the next-nearest neighbour effect, probably as a consequence of spinel genetic conditions. © 2016 by Walter de Gruyter Berlin/Boston |
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Abstract Three natural spinels of different places of occurrence and compositions were investigated by means of microprobe chemical analysis, single crystal X-ray diffraction and Mössbauer spectroscopy. All cation distributions between T and M sites were calculated from microprobe and XRD experimental data, by means of a mathematical model with appropriate assumptions. $ Fe^{2+} $ and $ Fe^{3+} $ assignments calculated in this way were compared with those observed in Mössbauer spectra. The satisfactory agreement found proves, at least in the samples studied, the reliability of the model and the assumptions used. In the spinels examined, such results show $ Fe^{2+} $ and $ Fe^{3+} $ virtually ordered in T and M sites respectively. Mössbauer data also revealed $ Fe^{2+} $ in different tetrahedral sites due to the next-nearest neighbour effect, probably as a consequence of spinel genetic conditions. © 2016 by Walter de Gruyter Berlin/Boston |
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