Cyclische Diazastannylene, $ IV^{1} $ Zur Oxidation von 1.3-Di-tert-butyl-2.2-dimethyl-1.3.2.$ 4λ^{2} $ -diazasilastannetidin / Cyclic Diazastannylenes, $ IV^{1} $ Oxidation of 1,3-Di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $ -diazasilastannetidine

Abstract The reactions of 1,3-di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $-diazasilastannetidine (1) with $ O_{2} $ and $ S_{8} $ or $ SnCl_{4} $ proceed in two steps: In a first redoxtype reaction an intermediate containing tetravalent tin is formed. Some of these intermediates are unstable with res...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Veith, M. [verfasserIn] Recktenwald, O. Humpfer, E.

Format:	Artikel

Erschienen:	1978

Systematik:	VA 8360

Anmerkung:	© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Übergeordnetes Werk:	Enthalten in: Zeitschrift für Naturforschung. B, Chemical sciences - Verlag der Zeitschrift für Naturforschung, 1947, 33(1978), 1 vom: 01. Jan., Seite 14-19
Übergeordnetes Werk:	volume:33 ; year:1978 ; number:1 ; day:01 ; month:01 ; pages:14-19

Links:	Volltext

DOI / URN:	10.1515/znb-1978-0104

Katalog-ID:	OLC213832642X

Internformat


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245	1	0	\|a Cyclische Diazastannylene, $ IV^{1} $ Zur Oxidation von 1.3-Di-tert-butyl-2.2-dimethyl-1.3.2.$ 4λ^{2} $ -diazasilastannetidin / Cyclic Diazastannylenes, $ IV^{1} $ Oxidation of 1,3-Di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $ -diazasilastannetidine
264		1	\|c 1978
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520			\|a Abstract The reactions of 1,3-di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $-diazasilastannetidine (1) with $ O_{2} $ and $ S_{8} $ or $ SnCl_{4} $ proceed in two steps: In a first redoxtype reaction an intermediate containing tetravalent tin is formed. Some of these intermediates are unstable with respect to the starting material stannylene 1 and undergo a substitution reaction to yield a spirotetraazastannane. Under appropriate conditions the intermediate from the sulfur- and SnCLi- reaction can be isolated and turns out to be either dispiro[3,3,3]distanna-disulfadisila- tetrazane or a diaza-dichlorostannane respectively. Crystal and kinetic data of some products/reactions are reported.
700	1		\|a Recktenwald, O. \|4 aut
700	1		\|a Humpfer, E. \|4 aut
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Indexfelder

author_variant	m v mv o r or e h eh
matchkey_str	article:09320776:1978----::ylshdaatnyeevzrxdtovn3ietuy2dmty122izslsantdnylcizsanlnsvoiainf3
hierarchy_sort_str	1978
publishDate	1978
allfields	10.1515/znb-1978-0104 doi (DE-627)OLC213832642X (DE-B1597)znb-1978-0104-p DE-627 ger DE-627 rakwb 540 VZ 540 VZ VA 8360 VZ rvk Veith, M. verfasserin aut Cyclische Diazastannylene, $ IV^{1} $ Zur Oxidation von 1.3-Di-tert-butyl-2.2-dimethyl-1.3.2.$ 4λ^{2} $ -diazasilastannetidin / Cyclic Diazastannylenes, $ IV^{1} $ Oxidation of 1,3-Di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $ -diazasilastannetidine 1978 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 1946 – 2014: Verlag der Zeitschrift für Naturforschung Abstract The reactions of 1,3-di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $-diazasilastannetidine (1) with $ O_{2} $ and $ S_{8} $ or $ SnCl_{4} $ proceed in two steps: In a first redoxtype reaction an intermediate containing tetravalent tin is formed. Some of these intermediates are unstable with respect to the starting material stannylene 1 and undergo a substitution reaction to yield a spirotetraazastannane. Under appropriate conditions the intermediate from the sulfur- and SnCLi- reaction can be isolated and turns out to be either dispiro[3,3,3]distanna-disulfadisila- tetrazane or a diaza-dichlorostannane respectively. Crystal and kinetic data of some products/reactions are reported. Recktenwald, O. aut Humpfer, E. aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Verlag der Zeitschrift für Naturforschung, 1947 33(1978), 1 vom: 01. Jan., Seite 14-19 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:33 year:1978 number:1 day:01 month:01 pages:14-19 https://doi.org/10.1515/znb-1978-0104 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_24 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_55 GBV_ILN_59 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_105 GBV_ILN_120 GBV_ILN_121 GBV_ILN_130 GBV_ILN_252 GBV_ILN_259 GBV_ILN_267 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2016 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2110 GBV_ILN_2185 GBV_ILN_2221 GBV_ILN_2237 GBV_ILN_2279 GBV_ILN_2360 GBV_ILN_4012 GBV_ILN_4027 GBV_ILN_4028 GBV_ILN_4029 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4103 GBV_ILN_4112 GBV_ILN_4116 GBV_ILN_4126 GBV_ILN_4155 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4309 GBV_ILN_4310 GBV_ILN_4314 GBV_ILN_4315 GBV_ILN_4316 GBV_ILN_4317 GBV_ILN_4318 GBV_ILN_4319 GBV_ILN_4321 GBV_ILN_4323 GBV_ILN_4700 VA 8360 AR 33 1978 1 01 01 14-19
spelling	10.1515/znb-1978-0104 doi (DE-627)OLC213832642X (DE-B1597)znb-1978-0104-p DE-627 ger DE-627 rakwb 540 VZ 540 VZ VA 8360 VZ rvk Veith, M. verfasserin aut Cyclische Diazastannylene, $ IV^{1} $ Zur Oxidation von 1.3-Di-tert-butyl-2.2-dimethyl-1.3.2.$ 4λ^{2} $ -diazasilastannetidin / Cyclic Diazastannylenes, $ IV^{1} $ Oxidation of 1,3-Di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $ -diazasilastannetidine 1978 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 1946 – 2014: Verlag der Zeitschrift für Naturforschung Abstract The reactions of 1,3-di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $-diazasilastannetidine (1) with $ O_{2} $ and $ S_{8} $ or $ SnCl_{4} $ proceed in two steps: In a first redoxtype reaction an intermediate containing tetravalent tin is formed. Some of these intermediates are unstable with respect to the starting material stannylene 1 and undergo a substitution reaction to yield a spirotetraazastannane. Under appropriate conditions the intermediate from the sulfur- and SnCLi- reaction can be isolated and turns out to be either dispiro[3,3,3]distanna-disulfadisila- tetrazane or a diaza-dichlorostannane respectively. Crystal and kinetic data of some products/reactions are reported. Recktenwald, O. aut Humpfer, E. aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Verlag der Zeitschrift für Naturforschung, 1947 33(1978), 1 vom: 01. Jan., Seite 14-19 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:33 year:1978 number:1 day:01 month:01 pages:14-19 https://doi.org/10.1515/znb-1978-0104 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_24 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_55 GBV_ILN_59 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_105 GBV_ILN_120 GBV_ILN_121 GBV_ILN_130 GBV_ILN_252 GBV_ILN_259 GBV_ILN_267 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2016 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2110 GBV_ILN_2185 GBV_ILN_2221 GBV_ILN_2237 GBV_ILN_2279 GBV_ILN_2360 GBV_ILN_4012 GBV_ILN_4027 GBV_ILN_4028 GBV_ILN_4029 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4103 GBV_ILN_4112 GBV_ILN_4116 GBV_ILN_4126 GBV_ILN_4155 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4309 GBV_ILN_4310 GBV_ILN_4314 GBV_ILN_4315 GBV_ILN_4316 GBV_ILN_4317 GBV_ILN_4318 GBV_ILN_4319 GBV_ILN_4321 GBV_ILN_4323 GBV_ILN_4700 VA 8360 AR 33 1978 1 01 01 14-19
allfields_unstemmed	10.1515/znb-1978-0104 doi (DE-627)OLC213832642X (DE-B1597)znb-1978-0104-p DE-627 ger DE-627 rakwb 540 VZ 540 VZ VA 8360 VZ rvk Veith, M. verfasserin aut Cyclische Diazastannylene, $ IV^{1} $ Zur Oxidation von 1.3-Di-tert-butyl-2.2-dimethyl-1.3.2.$ 4λ^{2} $ -diazasilastannetidin / Cyclic Diazastannylenes, $ IV^{1} $ Oxidation of 1,3-Di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $ -diazasilastannetidine 1978 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 1946 – 2014: Verlag der Zeitschrift für Naturforschung Abstract The reactions of 1,3-di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $-diazasilastannetidine (1) with $ O_{2} $ and $ S_{8} $ or $ SnCl_{4} $ proceed in two steps: In a first redoxtype reaction an intermediate containing tetravalent tin is formed. Some of these intermediates are unstable with respect to the starting material stannylene 1 and undergo a substitution reaction to yield a spirotetraazastannane. Under appropriate conditions the intermediate from the sulfur- and SnCLi- reaction can be isolated and turns out to be either dispiro[3,3,3]distanna-disulfadisila- tetrazane or a diaza-dichlorostannane respectively. Crystal and kinetic data of some products/reactions are reported. Recktenwald, O. aut Humpfer, E. aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Verlag der Zeitschrift für Naturforschung, 1947 33(1978), 1 vom: 01. Jan., Seite 14-19 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:33 year:1978 number:1 day:01 month:01 pages:14-19 https://doi.org/10.1515/znb-1978-0104 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_24 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_55 GBV_ILN_59 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_105 GBV_ILN_120 GBV_ILN_121 GBV_ILN_130 GBV_ILN_252 GBV_ILN_259 GBV_ILN_267 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2016 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2110 GBV_ILN_2185 GBV_ILN_2221 GBV_ILN_2237 GBV_ILN_2279 GBV_ILN_2360 GBV_ILN_4012 GBV_ILN_4027 GBV_ILN_4028 GBV_ILN_4029 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4103 GBV_ILN_4112 GBV_ILN_4116 GBV_ILN_4126 GBV_ILN_4155 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4309 GBV_ILN_4310 GBV_ILN_4314 GBV_ILN_4315 GBV_ILN_4316 GBV_ILN_4317 GBV_ILN_4318 GBV_ILN_4319 GBV_ILN_4321 GBV_ILN_4323 GBV_ILN_4700 VA 8360 AR 33 1978 1 01 01 14-19
allfieldsGer	10.1515/znb-1978-0104 doi (DE-627)OLC213832642X (DE-B1597)znb-1978-0104-p DE-627 ger DE-627 rakwb 540 VZ 540 VZ VA 8360 VZ rvk Veith, M. verfasserin aut Cyclische Diazastannylene, $ IV^{1} $ Zur Oxidation von 1.3-Di-tert-butyl-2.2-dimethyl-1.3.2.$ 4λ^{2} $ -diazasilastannetidin / Cyclic Diazastannylenes, $ IV^{1} $ Oxidation of 1,3-Di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $ -diazasilastannetidine 1978 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 1946 – 2014: Verlag der Zeitschrift für Naturforschung Abstract The reactions of 1,3-di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $-diazasilastannetidine (1) with $ O_{2} $ and $ S_{8} $ or $ SnCl_{4} $ proceed in two steps: In a first redoxtype reaction an intermediate containing tetravalent tin is formed. Some of these intermediates are unstable with respect to the starting material stannylene 1 and undergo a substitution reaction to yield a spirotetraazastannane. Under appropriate conditions the intermediate from the sulfur- and SnCLi- reaction can be isolated and turns out to be either dispiro[3,3,3]distanna-disulfadisila- tetrazane or a diaza-dichlorostannane respectively. Crystal and kinetic data of some products/reactions are reported. Recktenwald, O. aut Humpfer, E. aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Verlag der Zeitschrift für Naturforschung, 1947 33(1978), 1 vom: 01. Jan., Seite 14-19 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:33 year:1978 number:1 day:01 month:01 pages:14-19 https://doi.org/10.1515/znb-1978-0104 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_24 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_55 GBV_ILN_59 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_105 GBV_ILN_120 GBV_ILN_121 GBV_ILN_130 GBV_ILN_252 GBV_ILN_259 GBV_ILN_267 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2016 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2110 GBV_ILN_2185 GBV_ILN_2221 GBV_ILN_2237 GBV_ILN_2279 GBV_ILN_2360 GBV_ILN_4012 GBV_ILN_4027 GBV_ILN_4028 GBV_ILN_4029 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4103 GBV_ILN_4112 GBV_ILN_4116 GBV_ILN_4126 GBV_ILN_4155 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4309 GBV_ILN_4310 GBV_ILN_4314 GBV_ILN_4315 GBV_ILN_4316 GBV_ILN_4317 GBV_ILN_4318 GBV_ILN_4319 GBV_ILN_4321 GBV_ILN_4323 GBV_ILN_4700 VA 8360 AR 33 1978 1 01 01 14-19
allfieldsSound	10.1515/znb-1978-0104 doi (DE-627)OLC213832642X (DE-B1597)znb-1978-0104-p DE-627 ger DE-627 rakwb 540 VZ 540 VZ VA 8360 VZ rvk Veith, M. verfasserin aut Cyclische Diazastannylene, $ IV^{1} $ Zur Oxidation von 1.3-Di-tert-butyl-2.2-dimethyl-1.3.2.$ 4λ^{2} $ -diazasilastannetidin / Cyclic Diazastannylenes, $ IV^{1} $ Oxidation of 1,3-Di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $ -diazasilastannetidine 1978 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 1946 – 2014: Verlag der Zeitschrift für Naturforschung Abstract The reactions of 1,3-di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $-diazasilastannetidine (1) with $ O_{2} $ and $ S_{8} $ or $ SnCl_{4} $ proceed in two steps: In a first redoxtype reaction an intermediate containing tetravalent tin is formed. Some of these intermediates are unstable with respect to the starting material stannylene 1 and undergo a substitution reaction to yield a spirotetraazastannane. Under appropriate conditions the intermediate from the sulfur- and SnCLi- reaction can be isolated and turns out to be either dispiro[3,3,3]distanna-disulfadisila- tetrazane or a diaza-dichlorostannane respectively. Crystal and kinetic data of some products/reactions are reported. Recktenwald, O. aut Humpfer, E. aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Verlag der Zeitschrift für Naturforschung, 1947 33(1978), 1 vom: 01. Jan., Seite 14-19 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:33 year:1978 number:1 day:01 month:01 pages:14-19 https://doi.org/10.1515/znb-1978-0104 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_24 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_55 GBV_ILN_59 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_105 GBV_ILN_120 GBV_ILN_121 GBV_ILN_130 GBV_ILN_252 GBV_ILN_259 GBV_ILN_267 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2016 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2110 GBV_ILN_2185 GBV_ILN_2221 GBV_ILN_2237 GBV_ILN_2279 GBV_ILN_2360 GBV_ILN_4012 GBV_ILN_4027 GBV_ILN_4028 GBV_ILN_4029 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4103 GBV_ILN_4112 GBV_ILN_4116 GBV_ILN_4126 GBV_ILN_4155 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4309 GBV_ILN_4310 GBV_ILN_4314 GBV_ILN_4315 GBV_ILN_4316 GBV_ILN_4317 GBV_ILN_4318 GBV_ILN_4319 GBV_ILN_4321 GBV_ILN_4323 GBV_ILN_4700 VA 8360 AR 33 1978 1 01 01 14-19
source	Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences 33(1978), 1 vom: 01. Jan., Seite 14-19 volume:33 year:1978 number:1 day:01 month:01 pages:14-19
sourceStr	Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences 33(1978), 1 vom: 01. Jan., Seite 14-19 volume:33 year:1978 number:1 day:01 month:01 pages:14-19
format_phy_str_mv	Article
institution	findex.gbv.de
dewey-raw	540
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container_title	Zeitschrift für Naturforschung. B, Chemical sciences
authorswithroles_txt_mv	Veith, M. @@aut@@ Recktenwald, O. @@aut@@ Humpfer, E. @@aut@@
publishDateDaySort_date	1978-01-01T00:00:00Z
hierarchy_top_id	129307386
dewey-sort	3540
id	OLC213832642X
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author	Veith, M.
spellingShingle	Veith, M. ddc 540 rvk VA 8360 Cyclische Diazastannylene, $ IV^{1} $ Zur Oxidation von 1.3-Di-tert-butyl-2.2-dimethyl-1.3.2.$ 4λ^{2} $ -diazasilastannetidin / Cyclic Diazastannylenes, $ IV^{1} $ Oxidation of 1,3-Di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $ -diazasilastannetidine
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topic_title	540 VZ VA 8360 VZ rvk Cyclische Diazastannylene, $ IV^{1} $ Zur Oxidation von 1.3-Di-tert-butyl-2.2-dimethyl-1.3.2.$ 4λ^{2} $ -diazasilastannetidin / Cyclic Diazastannylenes, $ IV^{1} $ Oxidation of 1,3-Di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $ -diazasilastannetidine
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title	Cyclische Diazastannylene, $ IV^{1} $ Zur Oxidation von 1.3-Di-tert-butyl-2.2-dimethyl-1.3.2.$ 4λ^{2} $ -diazasilastannetidin / Cyclic Diazastannylenes, $ IV^{1} $ Oxidation of 1,3-Di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $ -diazasilastannetidine
ctrlnum	(DE-627)OLC213832642X (DE-B1597)znb-1978-0104-p
title_full	Cyclische Diazastannylene, $ IV^{1} $ Zur Oxidation von 1.3-Di-tert-butyl-2.2-dimethyl-1.3.2.$ 4λ^{2} $ -diazasilastannetidin / Cyclic Diazastannylenes, $ IV^{1} $ Oxidation of 1,3-Di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $ -diazasilastannetidine
author_sort	Veith, M.
journal	Zeitschrift für Naturforschung. B, Chemical sciences
journalStr	Zeitschrift für Naturforschung. B, Chemical sciences
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container_start_page	14
author_browse	Veith, M. Recktenwald, O. Humpfer, E.
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class	540 VZ VA 8360 VZ rvk
format_se	Aufsätze
author-letter	Veith, M.
doi_str_mv	10.1515/znb-1978-0104
dewey-full	540
title_sort	cyclische diazastannylene, $ iv^{1} $ zur oxidation von 1.3-di-tert-butyl-2.2-dimethyl-1.3.2.$ 4λ^{2} $ -diazasilastannetidin / cyclic diazastannylenes, $ iv^{1} $ oxidation of 1,3-di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $ -diazasilastannetidine
title_auth	Cyclische Diazastannylene, $ IV^{1} $ Zur Oxidation von 1.3-Di-tert-butyl-2.2-dimethyl-1.3.2.$ 4λ^{2} $ -diazasilastannetidin / Cyclic Diazastannylenes, $ IV^{1} $ Oxidation of 1,3-Di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $ -diazasilastannetidine
abstract	Abstract The reactions of 1,3-di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $-diazasilastannetidine (1) with $ O_{2} $ and $ S_{8} $ or $ SnCl_{4} $ proceed in two steps: In a first redoxtype reaction an intermediate containing tetravalent tin is formed. Some of these intermediates are unstable with respect to the starting material stannylene 1 and undergo a substitution reaction to yield a spirotetraazastannane. Under appropriate conditions the intermediate from the sulfur- and SnCLi- reaction can be isolated and turns out to be either dispiro[3,3,3]distanna-disulfadisila- tetrazane or a diaza-dichlorostannane respectively. Crystal and kinetic data of some products/reactions are reported. © 1946 – 2014: Verlag der Zeitschrift für Naturforschung
abstractGer	Abstract The reactions of 1,3-di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $-diazasilastannetidine (1) with $ O_{2} $ and $ S_{8} $ or $ SnCl_{4} $ proceed in two steps: In a first redoxtype reaction an intermediate containing tetravalent tin is formed. Some of these intermediates are unstable with respect to the starting material stannylene 1 and undergo a substitution reaction to yield a spirotetraazastannane. Under appropriate conditions the intermediate from the sulfur- and SnCLi- reaction can be isolated and turns out to be either dispiro[3,3,3]distanna-disulfadisila- tetrazane or a diaza-dichlorostannane respectively. Crystal and kinetic data of some products/reactions are reported. © 1946 – 2014: Verlag der Zeitschrift für Naturforschung
abstract_unstemmed	Abstract The reactions of 1,3-di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $-diazasilastannetidine (1) with $ O_{2} $ and $ S_{8} $ or $ SnCl_{4} $ proceed in two steps: In a first redoxtype reaction an intermediate containing tetravalent tin is formed. Some of these intermediates are unstable with respect to the starting material stannylene 1 and undergo a substitution reaction to yield a spirotetraazastannane. Under appropriate conditions the intermediate from the sulfur- and SnCLi- reaction can be isolated and turns out to be either dispiro[3,3,3]distanna-disulfadisila- tetrazane or a diaza-dichlorostannane respectively. Crystal and kinetic data of some products/reactions are reported. © 1946 – 2014: Verlag der Zeitschrift für Naturforschung
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container_issue	1
title_short	Cyclische Diazastannylene, $ IV^{1} $ Zur Oxidation von 1.3-Di-tert-butyl-2.2-dimethyl-1.3.2.$ 4λ^{2} $ -diazasilastannetidin / Cyclic Diazastannylenes, $ IV^{1} $ Oxidation of 1,3-Di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $ -diazasilastannetidine
url	https://doi.org/10.1515/znb-1978-0104
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author2	Recktenwald, O. Humpfer, E.
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doi_str	10.1515/znb-1978-0104
up_date	2024-07-03T16:10:18.394Z
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Cyclische Diazastannylene, $ IV^{1} $ Zur Oxidation von 1.3-Di-tert-butyl-2.2-dimethyl-1.3.2.$ 4λ^{2} $ -diazasilastannetidin / Cyclic Diazastannylenes, $ IV^{1} $ Oxidation of 1,3-Di-tert-butyl-2,2-dimethyl-1,3,2,$ 4λ^{2} $ -diazasilastannetidine

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