Joanneumite, Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2, a new mineral from Pabellón de Pica, Chile and the crystal structure of its synthetic analogue
Abstract The new mineral joanneumite was found at Pabellón de Pica Mountain, Iquique Province, Tarapacá Region, Chile, where it occurs as violet microcrystalline aggregates up to 2 mm in size in small cracks in a gabbroic rock, which is covered by a guano deposit. Associated minerals are salammoniac...
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| Autor*in: |
Bojar, Hans-Peter [verfasserIn] |
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| Format: |
Artikel |
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| Erschienen: |
2017 |
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| Systematik: |
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| Anmerkung: |
© 2017 by Walter de Gruyter Berlin/Boston |
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| Übergeordnetes Werk: |
Enthalten in: Mineralogical magazine - Mineralogical Society, 1969, 81(2017), 1 vom: 01. Feb., Seite 155-166 |
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| Übergeordnetes Werk: |
volume:81 ; year:2017 ; number:1 ; day:01 ; month:02 ; pages:155-166 |
| Links: |
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| DOI / URN: |
10.1180/minmag.2016.080.078 |
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| Katalog-ID: |
OLC2138835162 |
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| 100 | 1 | |a Bojar, Hans-Peter |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Joanneumite, Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2, a new mineral from Pabellón de Pica, Chile and the crystal structure of its synthetic analogue |
| 264 | 1 | |c 2017 | |
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| 337 | |a ohne Hilfsmittel zu benutzen |b n |2 rdamedia | ||
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| 520 | |a Abstract The new mineral joanneumite was found at Pabellón de Pica Mountain, Iquique Province, Tarapacá Region, Chile, where it occurs as violet microcrystalline aggregates up to 2 mm in size in small cracks in a gabbroic rock, which is covered by a guano deposit. Associated minerals are salammoniac, dittmarite, möhnite and gypsum. Joanneumite is non-fluorescent and the Mohs hardness is 1. The calculated density is 2.020 g $ cm^{-3} $. The infrared spectrum of joanneumite shows the frequencies of $ NH_{3} $ and isocyanurate groups and the absence of absorptions of $ H_{2} $O molecules and OH − ions. The chemical composition (electron microprobe data, the hydrogen was calculated from the structural formula, wt.%) is C 20.33, N 31.11, O 28.34, Cu 17.27, Zn 0.24, H 2.82, total 100.11. The empirical formula is $ Cu_{0.96} $$ Zn_{0.01} $$ N_{7.84} $$ C_{5.98} $$ O_{6.25} $$ H_{9.96} $ and the idealized formula is $ CuN_{8} $$ C_{6} $$ O_{6} $$ H_{10} $ with the structural formula Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2. Due to the lack of suitable single crystals the synthetic analogue of joanneumite was prepared for the single-crystal structure refinement. The crystal structure was solved and refined to R = 0.025 based upon 1166 unique reflections with I > 2 σ (I). Joanneumite is triclinic, space group P1̅, a = 4.982(1), b = 6.896(1), c = 9.115(2) Å, α = 90.53(3), β = 97.85(3), γ = 110.08(3)°, V = 290.8(1) $ Å^{3} $, Z = 1 obtained from single-crystal data at 100 K, which are in good agreement with cell parameters from powder diffraction data of joanneumite at 293 K: a = 5.042(1), b = 6.997(1), c = 9.099(2) Å, α = 90.05(3), β = 98.11(2), γ = 110.95(3)° and V = 296.3(1) $ Å^{3} $. The eight strongest lines of the powder X-ray diffraction pattern are [d, Å (I,%) (hkl)] 6.52 (68) (010), 5.15 (47) (011), 4.66 (21) (100, 1̅10), 4.35 (9) (1̅11), 3.29 (6) (1̅20), 3.22 (7) (1̅1̅1), 3.140 (100) (1̅21), 2.074 (7) (1̅32). The crystal structure of joanneumite is identical with the structure of synthetic bis(isocyanurato) diamminecopper(II). | ||
| 700 | 1 | |a Walter, Franz |4 aut | |
| 700 | 1 | |a Baumgartner, Judith |4 aut | |
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10.1180/minmag.2016.080.078 doi (DE-627)OLC2138835162 (DE-B1597)minmag.2016.080.078-p DE-627 ger DE-627 rakwb 550 VZ 13 ssgn TE 1000 VZ rvk Bojar, Hans-Peter verfasserin aut Joanneumite, Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2, a new mineral from Pabellón de Pica, Chile and the crystal structure of its synthetic analogue 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 2017 by Walter de Gruyter Berlin/Boston Abstract The new mineral joanneumite was found at Pabellón de Pica Mountain, Iquique Province, Tarapacá Region, Chile, where it occurs as violet microcrystalline aggregates up to 2 mm in size in small cracks in a gabbroic rock, which is covered by a guano deposit. Associated minerals are salammoniac, dittmarite, möhnite and gypsum. Joanneumite is non-fluorescent and the Mohs hardness is 1. The calculated density is 2.020 g $ cm^{-3} $. The infrared spectrum of joanneumite shows the frequencies of $ NH_{3} $ and isocyanurate groups and the absence of absorptions of $ H_{2} $O molecules and OH − ions. The chemical composition (electron microprobe data, the hydrogen was calculated from the structural formula, wt.%) is C 20.33, N 31.11, O 28.34, Cu 17.27, Zn 0.24, H 2.82, total 100.11. The empirical formula is $ Cu_{0.96} $$ Zn_{0.01} $$ N_{7.84} $$ C_{5.98} $$ O_{6.25} $$ H_{9.96} $ and the idealized formula is $ CuN_{8} $$ C_{6} $$ O_{6} $$ H_{10} $ with the structural formula Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2. Due to the lack of suitable single crystals the synthetic analogue of joanneumite was prepared for the single-crystal structure refinement. The crystal structure was solved and refined to R = 0.025 based upon 1166 unique reflections with I > 2 σ (I). Joanneumite is triclinic, space group P1̅, a = 4.982(1), b = 6.896(1), c = 9.115(2) Å, α = 90.53(3), β = 97.85(3), γ = 110.08(3)°, V = 290.8(1) $ Å^{3} $, Z = 1 obtained from single-crystal data at 100 K, which are in good agreement with cell parameters from powder diffraction data of joanneumite at 293 K: a = 5.042(1), b = 6.997(1), c = 9.099(2) Å, α = 90.05(3), β = 98.11(2), γ = 110.95(3)° and V = 296.3(1) $ Å^{3} $. The eight strongest lines of the powder X-ray diffraction pattern are [d, Å (I,%) (hkl)] 6.52 (68) (010), 5.15 (47) (011), 4.66 (21) (100, 1̅10), 4.35 (9) (1̅11), 3.29 (6) (1̅20), 3.22 (7) (1̅1̅1), 3.140 (100) (1̅21), 2.074 (7) (1̅32). The crystal structure of joanneumite is identical with the structure of synthetic bis(isocyanurato) diamminecopper(II). Walter, Franz aut Baumgartner, Judith aut Enthalten in Mineralogical magazine Mineralogical Society, 1969 81(2017), 1 vom: 01. Feb., Seite 155-166 (DE-627)13069617X (DE-600)956157-2 (DE-576)016244141 0026-461X nnns volume:81 year:2017 number:1 day:01 month:02 pages:155-166 https://doi.org/10.1180/minmag.2016.080.078 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_65 GBV_ILN_2014 GBV_ILN_4323 TE 1000 AR 81 2017 1 01 02 155-166 |
| spelling |
10.1180/minmag.2016.080.078 doi (DE-627)OLC2138835162 (DE-B1597)minmag.2016.080.078-p DE-627 ger DE-627 rakwb 550 VZ 13 ssgn TE 1000 VZ rvk Bojar, Hans-Peter verfasserin aut Joanneumite, Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2, a new mineral from Pabellón de Pica, Chile and the crystal structure of its synthetic analogue 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 2017 by Walter de Gruyter Berlin/Boston Abstract The new mineral joanneumite was found at Pabellón de Pica Mountain, Iquique Province, Tarapacá Region, Chile, where it occurs as violet microcrystalline aggregates up to 2 mm in size in small cracks in a gabbroic rock, which is covered by a guano deposit. Associated minerals are salammoniac, dittmarite, möhnite and gypsum. Joanneumite is non-fluorescent and the Mohs hardness is 1. The calculated density is 2.020 g $ cm^{-3} $. The infrared spectrum of joanneumite shows the frequencies of $ NH_{3} $ and isocyanurate groups and the absence of absorptions of $ H_{2} $O molecules and OH − ions. The chemical composition (electron microprobe data, the hydrogen was calculated from the structural formula, wt.%) is C 20.33, N 31.11, O 28.34, Cu 17.27, Zn 0.24, H 2.82, total 100.11. The empirical formula is $ Cu_{0.96} $$ Zn_{0.01} $$ N_{7.84} $$ C_{5.98} $$ O_{6.25} $$ H_{9.96} $ and the idealized formula is $ CuN_{8} $$ C_{6} $$ O_{6} $$ H_{10} $ with the structural formula Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2. Due to the lack of suitable single crystals the synthetic analogue of joanneumite was prepared for the single-crystal structure refinement. The crystal structure was solved and refined to R = 0.025 based upon 1166 unique reflections with I > 2 σ (I). Joanneumite is triclinic, space group P1̅, a = 4.982(1), b = 6.896(1), c = 9.115(2) Å, α = 90.53(3), β = 97.85(3), γ = 110.08(3)°, V = 290.8(1) $ Å^{3} $, Z = 1 obtained from single-crystal data at 100 K, which are in good agreement with cell parameters from powder diffraction data of joanneumite at 293 K: a = 5.042(1), b = 6.997(1), c = 9.099(2) Å, α = 90.05(3), β = 98.11(2), γ = 110.95(3)° and V = 296.3(1) $ Å^{3} $. The eight strongest lines of the powder X-ray diffraction pattern are [d, Å (I,%) (hkl)] 6.52 (68) (010), 5.15 (47) (011), 4.66 (21) (100, 1̅10), 4.35 (9) (1̅11), 3.29 (6) (1̅20), 3.22 (7) (1̅1̅1), 3.140 (100) (1̅21), 2.074 (7) (1̅32). The crystal structure of joanneumite is identical with the structure of synthetic bis(isocyanurato) diamminecopper(II). Walter, Franz aut Baumgartner, Judith aut Enthalten in Mineralogical magazine Mineralogical Society, 1969 81(2017), 1 vom: 01. Feb., Seite 155-166 (DE-627)13069617X (DE-600)956157-2 (DE-576)016244141 0026-461X nnns volume:81 year:2017 number:1 day:01 month:02 pages:155-166 https://doi.org/10.1180/minmag.2016.080.078 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_65 GBV_ILN_2014 GBV_ILN_4323 TE 1000 AR 81 2017 1 01 02 155-166 |
| allfields_unstemmed |
10.1180/minmag.2016.080.078 doi (DE-627)OLC2138835162 (DE-B1597)minmag.2016.080.078-p DE-627 ger DE-627 rakwb 550 VZ 13 ssgn TE 1000 VZ rvk Bojar, Hans-Peter verfasserin aut Joanneumite, Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2, a new mineral from Pabellón de Pica, Chile and the crystal structure of its synthetic analogue 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 2017 by Walter de Gruyter Berlin/Boston Abstract The new mineral joanneumite was found at Pabellón de Pica Mountain, Iquique Province, Tarapacá Region, Chile, where it occurs as violet microcrystalline aggregates up to 2 mm in size in small cracks in a gabbroic rock, which is covered by a guano deposit. Associated minerals are salammoniac, dittmarite, möhnite and gypsum. Joanneumite is non-fluorescent and the Mohs hardness is 1. The calculated density is 2.020 g $ cm^{-3} $. The infrared spectrum of joanneumite shows the frequencies of $ NH_{3} $ and isocyanurate groups and the absence of absorptions of $ H_{2} $O molecules and OH − ions. The chemical composition (electron microprobe data, the hydrogen was calculated from the structural formula, wt.%) is C 20.33, N 31.11, O 28.34, Cu 17.27, Zn 0.24, H 2.82, total 100.11. The empirical formula is $ Cu_{0.96} $$ Zn_{0.01} $$ N_{7.84} $$ C_{5.98} $$ O_{6.25} $$ H_{9.96} $ and the idealized formula is $ CuN_{8} $$ C_{6} $$ O_{6} $$ H_{10} $ with the structural formula Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2. Due to the lack of suitable single crystals the synthetic analogue of joanneumite was prepared for the single-crystal structure refinement. The crystal structure was solved and refined to R = 0.025 based upon 1166 unique reflections with I > 2 σ (I). Joanneumite is triclinic, space group P1̅, a = 4.982(1), b = 6.896(1), c = 9.115(2) Å, α = 90.53(3), β = 97.85(3), γ = 110.08(3)°, V = 290.8(1) $ Å^{3} $, Z = 1 obtained from single-crystal data at 100 K, which are in good agreement with cell parameters from powder diffraction data of joanneumite at 293 K: a = 5.042(1), b = 6.997(1), c = 9.099(2) Å, α = 90.05(3), β = 98.11(2), γ = 110.95(3)° and V = 296.3(1) $ Å^{3} $. The eight strongest lines of the powder X-ray diffraction pattern are [d, Å (I,%) (hkl)] 6.52 (68) (010), 5.15 (47) (011), 4.66 (21) (100, 1̅10), 4.35 (9) (1̅11), 3.29 (6) (1̅20), 3.22 (7) (1̅1̅1), 3.140 (100) (1̅21), 2.074 (7) (1̅32). The crystal structure of joanneumite is identical with the structure of synthetic bis(isocyanurato) diamminecopper(II). Walter, Franz aut Baumgartner, Judith aut Enthalten in Mineralogical magazine Mineralogical Society, 1969 81(2017), 1 vom: 01. Feb., Seite 155-166 (DE-627)13069617X (DE-600)956157-2 (DE-576)016244141 0026-461X nnns volume:81 year:2017 number:1 day:01 month:02 pages:155-166 https://doi.org/10.1180/minmag.2016.080.078 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_65 GBV_ILN_2014 GBV_ILN_4323 TE 1000 AR 81 2017 1 01 02 155-166 |
| allfieldsGer |
10.1180/minmag.2016.080.078 doi (DE-627)OLC2138835162 (DE-B1597)minmag.2016.080.078-p DE-627 ger DE-627 rakwb 550 VZ 13 ssgn TE 1000 VZ rvk Bojar, Hans-Peter verfasserin aut Joanneumite, Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2, a new mineral from Pabellón de Pica, Chile and the crystal structure of its synthetic analogue 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 2017 by Walter de Gruyter Berlin/Boston Abstract The new mineral joanneumite was found at Pabellón de Pica Mountain, Iquique Province, Tarapacá Region, Chile, where it occurs as violet microcrystalline aggregates up to 2 mm in size in small cracks in a gabbroic rock, which is covered by a guano deposit. Associated minerals are salammoniac, dittmarite, möhnite and gypsum. Joanneumite is non-fluorescent and the Mohs hardness is 1. The calculated density is 2.020 g $ cm^{-3} $. The infrared spectrum of joanneumite shows the frequencies of $ NH_{3} $ and isocyanurate groups and the absence of absorptions of $ H_{2} $O molecules and OH − ions. The chemical composition (electron microprobe data, the hydrogen was calculated from the structural formula, wt.%) is C 20.33, N 31.11, O 28.34, Cu 17.27, Zn 0.24, H 2.82, total 100.11. The empirical formula is $ Cu_{0.96} $$ Zn_{0.01} $$ N_{7.84} $$ C_{5.98} $$ O_{6.25} $$ H_{9.96} $ and the idealized formula is $ CuN_{8} $$ C_{6} $$ O_{6} $$ H_{10} $ with the structural formula Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2. Due to the lack of suitable single crystals the synthetic analogue of joanneumite was prepared for the single-crystal structure refinement. The crystal structure was solved and refined to R = 0.025 based upon 1166 unique reflections with I > 2 σ (I). Joanneumite is triclinic, space group P1̅, a = 4.982(1), b = 6.896(1), c = 9.115(2) Å, α = 90.53(3), β = 97.85(3), γ = 110.08(3)°, V = 290.8(1) $ Å^{3} $, Z = 1 obtained from single-crystal data at 100 K, which are in good agreement with cell parameters from powder diffraction data of joanneumite at 293 K: a = 5.042(1), b = 6.997(1), c = 9.099(2) Å, α = 90.05(3), β = 98.11(2), γ = 110.95(3)° and V = 296.3(1) $ Å^{3} $. The eight strongest lines of the powder X-ray diffraction pattern are [d, Å (I,%) (hkl)] 6.52 (68) (010), 5.15 (47) (011), 4.66 (21) (100, 1̅10), 4.35 (9) (1̅11), 3.29 (6) (1̅20), 3.22 (7) (1̅1̅1), 3.140 (100) (1̅21), 2.074 (7) (1̅32). The crystal structure of joanneumite is identical with the structure of synthetic bis(isocyanurato) diamminecopper(II). Walter, Franz aut Baumgartner, Judith aut Enthalten in Mineralogical magazine Mineralogical Society, 1969 81(2017), 1 vom: 01. Feb., Seite 155-166 (DE-627)13069617X (DE-600)956157-2 (DE-576)016244141 0026-461X nnns volume:81 year:2017 number:1 day:01 month:02 pages:155-166 https://doi.org/10.1180/minmag.2016.080.078 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_65 GBV_ILN_2014 GBV_ILN_4323 TE 1000 AR 81 2017 1 01 02 155-166 |
| allfieldsSound |
10.1180/minmag.2016.080.078 doi (DE-627)OLC2138835162 (DE-B1597)minmag.2016.080.078-p DE-627 ger DE-627 rakwb 550 VZ 13 ssgn TE 1000 VZ rvk Bojar, Hans-Peter verfasserin aut Joanneumite, Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2, a new mineral from Pabellón de Pica, Chile and the crystal structure of its synthetic analogue 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 2017 by Walter de Gruyter Berlin/Boston Abstract The new mineral joanneumite was found at Pabellón de Pica Mountain, Iquique Province, Tarapacá Region, Chile, where it occurs as violet microcrystalline aggregates up to 2 mm in size in small cracks in a gabbroic rock, which is covered by a guano deposit. Associated minerals are salammoniac, dittmarite, möhnite and gypsum. Joanneumite is non-fluorescent and the Mohs hardness is 1. The calculated density is 2.020 g $ cm^{-3} $. The infrared spectrum of joanneumite shows the frequencies of $ NH_{3} $ and isocyanurate groups and the absence of absorptions of $ H_{2} $O molecules and OH − ions. The chemical composition (electron microprobe data, the hydrogen was calculated from the structural formula, wt.%) is C 20.33, N 31.11, O 28.34, Cu 17.27, Zn 0.24, H 2.82, total 100.11. The empirical formula is $ Cu_{0.96} $$ Zn_{0.01} $$ N_{7.84} $$ C_{5.98} $$ O_{6.25} $$ H_{9.96} $ and the idealized formula is $ CuN_{8} $$ C_{6} $$ O_{6} $$ H_{10} $ with the structural formula Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2. Due to the lack of suitable single crystals the synthetic analogue of joanneumite was prepared for the single-crystal structure refinement. The crystal structure was solved and refined to R = 0.025 based upon 1166 unique reflections with I > 2 σ (I). Joanneumite is triclinic, space group P1̅, a = 4.982(1), b = 6.896(1), c = 9.115(2) Å, α = 90.53(3), β = 97.85(3), γ = 110.08(3)°, V = 290.8(1) $ Å^{3} $, Z = 1 obtained from single-crystal data at 100 K, which are in good agreement with cell parameters from powder diffraction data of joanneumite at 293 K: a = 5.042(1), b = 6.997(1), c = 9.099(2) Å, α = 90.05(3), β = 98.11(2), γ = 110.95(3)° and V = 296.3(1) $ Å^{3} $. The eight strongest lines of the powder X-ray diffraction pattern are [d, Å (I,%) (hkl)] 6.52 (68) (010), 5.15 (47) (011), 4.66 (21) (100, 1̅10), 4.35 (9) (1̅11), 3.29 (6) (1̅20), 3.22 (7) (1̅1̅1), 3.140 (100) (1̅21), 2.074 (7) (1̅32). The crystal structure of joanneumite is identical with the structure of synthetic bis(isocyanurato) diamminecopper(II). Walter, Franz aut Baumgartner, Judith aut Enthalten in Mineralogical magazine Mineralogical Society, 1969 81(2017), 1 vom: 01. Feb., Seite 155-166 (DE-627)13069617X (DE-600)956157-2 (DE-576)016244141 0026-461X nnns volume:81 year:2017 number:1 day:01 month:02 pages:155-166 https://doi.org/10.1180/minmag.2016.080.078 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO SSG-OPC-GGO GBV_ILN_65 GBV_ILN_2014 GBV_ILN_4323 TE 1000 AR 81 2017 1 01 02 155-166 |
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Associated minerals are salammoniac, dittmarite, möhnite and gypsum. Joanneumite is non-fluorescent and the Mohs hardness is 1. The calculated density is 2.020 g $ cm^{-3} $. The infrared spectrum of joanneumite shows the frequencies of $ NH_{3} $ and isocyanurate groups and the absence of absorptions of $ H_{2} $O molecules and OH − ions. The chemical composition (electron microprobe data, the hydrogen was calculated from the structural formula, wt.%) is C 20.33, N 31.11, O 28.34, Cu 17.27, Zn 0.24, H 2.82, total 100.11. The empirical formula is $ Cu_{0.96} $$ Zn_{0.01} $$ N_{7.84} $$ C_{5.98} $$ O_{6.25} $$ H_{9.96} $ and the idealized formula is $ CuN_{8} $$ C_{6} $$ O_{6} $$ H_{10} $ with the structural formula Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2. Due to the lack of suitable single crystals the synthetic analogue of joanneumite was prepared for the single-crystal structure refinement. The crystal structure was solved and refined to R = 0.025 based upon 1166 unique reflections with I > 2 σ (I). Joanneumite is triclinic, space group P1̅, a = 4.982(1), b = 6.896(1), c = 9.115(2) Å, α = 90.53(3), β = 97.85(3), γ = 110.08(3)°, V = 290.8(1) $ Å^{3} $, Z = 1 obtained from single-crystal data at 100 K, which are in good agreement with cell parameters from powder diffraction data of joanneumite at 293 K: a = 5.042(1), b = 6.997(1), c = 9.099(2) Å, α = 90.05(3), β = 98.11(2), γ = 110.95(3)° and V = 296.3(1) $ Å^{3} $. The eight strongest lines of the powder X-ray diffraction pattern are [d, Å (I,%) (hkl)] 6.52 (68) (010), 5.15 (47) (011), 4.66 (21) (100, 1̅10), 4.35 (9) (1̅11), 3.29 (6) (1̅20), 3.22 (7) (1̅1̅1), 3.140 (100) (1̅21), 2.074 (7) (1̅32). 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Bojar, Hans-Peter |
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Bojar, Hans-Peter ddc 550 ssgn 13 rvk TE 1000 Joanneumite, Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2, a new mineral from Pabellón de Pica, Chile and the crystal structure of its synthetic analogue |
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550 VZ 13 ssgn TE 1000 VZ rvk Joanneumite, Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2, a new mineral from Pabellón de Pica, Chile and the crystal structure of its synthetic analogue |
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Joanneumite, Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2, a new mineral from Pabellón de Pica, Chile and the crystal structure of its synthetic analogue |
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Joanneumite, Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2, a new mineral from Pabellón de Pica, Chile and the crystal structure of its synthetic analogue |
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Bojar, Hans-Peter Walter, Franz Baumgartner, Judith |
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Bojar, Hans-Peter |
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10.1180/minmag.2016.080.078 |
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550 |
| title_sort |
joanneumite, cu($ c_{3} $$ n_{3} $$ o_{3} $$ h_{2} $)2($ nh_{3} $)2, a new mineral from pabellón de pica, chile and the crystal structure of its synthetic analogue |
| title_auth |
Joanneumite, Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2, a new mineral from Pabellón de Pica, Chile and the crystal structure of its synthetic analogue |
| abstract |
Abstract The new mineral joanneumite was found at Pabellón de Pica Mountain, Iquique Province, Tarapacá Region, Chile, where it occurs as violet microcrystalline aggregates up to 2 mm in size in small cracks in a gabbroic rock, which is covered by a guano deposit. Associated minerals are salammoniac, dittmarite, möhnite and gypsum. Joanneumite is non-fluorescent and the Mohs hardness is 1. The calculated density is 2.020 g $ cm^{-3} $. The infrared spectrum of joanneumite shows the frequencies of $ NH_{3} $ and isocyanurate groups and the absence of absorptions of $ H_{2} $O molecules and OH − ions. The chemical composition (electron microprobe data, the hydrogen was calculated from the structural formula, wt.%) is C 20.33, N 31.11, O 28.34, Cu 17.27, Zn 0.24, H 2.82, total 100.11. The empirical formula is $ Cu_{0.96} $$ Zn_{0.01} $$ N_{7.84} $$ C_{5.98} $$ O_{6.25} $$ H_{9.96} $ and the idealized formula is $ CuN_{8} $$ C_{6} $$ O_{6} $$ H_{10} $ with the structural formula Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2. Due to the lack of suitable single crystals the synthetic analogue of joanneumite was prepared for the single-crystal structure refinement. The crystal structure was solved and refined to R = 0.025 based upon 1166 unique reflections with I > 2 σ (I). Joanneumite is triclinic, space group P1̅, a = 4.982(1), b = 6.896(1), c = 9.115(2) Å, α = 90.53(3), β = 97.85(3), γ = 110.08(3)°, V = 290.8(1) $ Å^{3} $, Z = 1 obtained from single-crystal data at 100 K, which are in good agreement with cell parameters from powder diffraction data of joanneumite at 293 K: a = 5.042(1), b = 6.997(1), c = 9.099(2) Å, α = 90.05(3), β = 98.11(2), γ = 110.95(3)° and V = 296.3(1) $ Å^{3} $. The eight strongest lines of the powder X-ray diffraction pattern are [d, Å (I,%) (hkl)] 6.52 (68) (010), 5.15 (47) (011), 4.66 (21) (100, 1̅10), 4.35 (9) (1̅11), 3.29 (6) (1̅20), 3.22 (7) (1̅1̅1), 3.140 (100) (1̅21), 2.074 (7) (1̅32). The crystal structure of joanneumite is identical with the structure of synthetic bis(isocyanurato) diamminecopper(II). © 2017 by Walter de Gruyter Berlin/Boston |
| abstractGer |
Abstract The new mineral joanneumite was found at Pabellón de Pica Mountain, Iquique Province, Tarapacá Region, Chile, where it occurs as violet microcrystalline aggregates up to 2 mm in size in small cracks in a gabbroic rock, which is covered by a guano deposit. Associated minerals are salammoniac, dittmarite, möhnite and gypsum. Joanneumite is non-fluorescent and the Mohs hardness is 1. The calculated density is 2.020 g $ cm^{-3} $. The infrared spectrum of joanneumite shows the frequencies of $ NH_{3} $ and isocyanurate groups and the absence of absorptions of $ H_{2} $O molecules and OH − ions. The chemical composition (electron microprobe data, the hydrogen was calculated from the structural formula, wt.%) is C 20.33, N 31.11, O 28.34, Cu 17.27, Zn 0.24, H 2.82, total 100.11. The empirical formula is $ Cu_{0.96} $$ Zn_{0.01} $$ N_{7.84} $$ C_{5.98} $$ O_{6.25} $$ H_{9.96} $ and the idealized formula is $ CuN_{8} $$ C_{6} $$ O_{6} $$ H_{10} $ with the structural formula Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2. Due to the lack of suitable single crystals the synthetic analogue of joanneumite was prepared for the single-crystal structure refinement. The crystal structure was solved and refined to R = 0.025 based upon 1166 unique reflections with I > 2 σ (I). Joanneumite is triclinic, space group P1̅, a = 4.982(1), b = 6.896(1), c = 9.115(2) Å, α = 90.53(3), β = 97.85(3), γ = 110.08(3)°, V = 290.8(1) $ Å^{3} $, Z = 1 obtained from single-crystal data at 100 K, which are in good agreement with cell parameters from powder diffraction data of joanneumite at 293 K: a = 5.042(1), b = 6.997(1), c = 9.099(2) Å, α = 90.05(3), β = 98.11(2), γ = 110.95(3)° and V = 296.3(1) $ Å^{3} $. The eight strongest lines of the powder X-ray diffraction pattern are [d, Å (I,%) (hkl)] 6.52 (68) (010), 5.15 (47) (011), 4.66 (21) (100, 1̅10), 4.35 (9) (1̅11), 3.29 (6) (1̅20), 3.22 (7) (1̅1̅1), 3.140 (100) (1̅21), 2.074 (7) (1̅32). The crystal structure of joanneumite is identical with the structure of synthetic bis(isocyanurato) diamminecopper(II). © 2017 by Walter de Gruyter Berlin/Boston |
| abstract_unstemmed |
Abstract The new mineral joanneumite was found at Pabellón de Pica Mountain, Iquique Province, Tarapacá Region, Chile, where it occurs as violet microcrystalline aggregates up to 2 mm in size in small cracks in a gabbroic rock, which is covered by a guano deposit. Associated minerals are salammoniac, dittmarite, möhnite and gypsum. Joanneumite is non-fluorescent and the Mohs hardness is 1. The calculated density is 2.020 g $ cm^{-3} $. The infrared spectrum of joanneumite shows the frequencies of $ NH_{3} $ and isocyanurate groups and the absence of absorptions of $ H_{2} $O molecules and OH − ions. The chemical composition (electron microprobe data, the hydrogen was calculated from the structural formula, wt.%) is C 20.33, N 31.11, O 28.34, Cu 17.27, Zn 0.24, H 2.82, total 100.11. The empirical formula is $ Cu_{0.96} $$ Zn_{0.01} $$ N_{7.84} $$ C_{5.98} $$ O_{6.25} $$ H_{9.96} $ and the idealized formula is $ CuN_{8} $$ C_{6} $$ O_{6} $$ H_{10} $ with the structural formula Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2. Due to the lack of suitable single crystals the synthetic analogue of joanneumite was prepared for the single-crystal structure refinement. The crystal structure was solved and refined to R = 0.025 based upon 1166 unique reflections with I > 2 σ (I). Joanneumite is triclinic, space group P1̅, a = 4.982(1), b = 6.896(1), c = 9.115(2) Å, α = 90.53(3), β = 97.85(3), γ = 110.08(3)°, V = 290.8(1) $ Å^{3} $, Z = 1 obtained from single-crystal data at 100 K, which are in good agreement with cell parameters from powder diffraction data of joanneumite at 293 K: a = 5.042(1), b = 6.997(1), c = 9.099(2) Å, α = 90.05(3), β = 98.11(2), γ = 110.95(3)° and V = 296.3(1) $ Å^{3} $. The eight strongest lines of the powder X-ray diffraction pattern are [d, Å (I,%) (hkl)] 6.52 (68) (010), 5.15 (47) (011), 4.66 (21) (100, 1̅10), 4.35 (9) (1̅11), 3.29 (6) (1̅20), 3.22 (7) (1̅1̅1), 3.140 (100) (1̅21), 2.074 (7) (1̅32). The crystal structure of joanneumite is identical with the structure of synthetic bis(isocyanurato) diamminecopper(II). © 2017 by Walter de Gruyter Berlin/Boston |
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| title_short |
Joanneumite, Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2, a new mineral from Pabellón de Pica, Chile and the crystal structure of its synthetic analogue |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">OLC2138835162</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230810092735.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">230810s2017 xx ||||| 00| ||und c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1180/minmag.2016.080.078</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2138835162</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-B1597)minmag.2016.080.078-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">550</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">13</subfield><subfield code="2">ssgn</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">TE 1000</subfield><subfield code="q">VZ</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Bojar, Hans-Peter</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Joanneumite, Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2, a new mineral from Pabellón de Pica, Chile and the crystal structure of its synthetic analogue</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2017</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© 2017 by Walter de Gruyter Berlin/Boston</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The new mineral joanneumite was found at Pabellón de Pica Mountain, Iquique Province, Tarapacá Region, Chile, where it occurs as violet microcrystalline aggregates up to 2 mm in size in small cracks in a gabbroic rock, which is covered by a guano deposit. Associated minerals are salammoniac, dittmarite, möhnite and gypsum. Joanneumite is non-fluorescent and the Mohs hardness is 1. The calculated density is 2.020 g $ cm^{-3} $. The infrared spectrum of joanneumite shows the frequencies of $ NH_{3} $ and isocyanurate groups and the absence of absorptions of $ H_{2} $O molecules and OH − ions. The chemical composition (electron microprobe data, the hydrogen was calculated from the structural formula, wt.%) is C 20.33, N 31.11, O 28.34, Cu 17.27, Zn 0.24, H 2.82, total 100.11. The empirical formula is $ Cu_{0.96} $$ Zn_{0.01} $$ N_{7.84} $$ C_{5.98} $$ O_{6.25} $$ H_{9.96} $ and the idealized formula is $ CuN_{8} $$ C_{6} $$ O_{6} $$ H_{10} $ with the structural formula Cu($ C_{3} $$ N_{3} $$ O_{3} $$ H_{2} $)2($ NH_{3} $)2. Due to the lack of suitable single crystals the synthetic analogue of joanneumite was prepared for the single-crystal structure refinement. The crystal structure was solved and refined to R = 0.025 based upon 1166 unique reflections with I > 2 σ (I). Joanneumite is triclinic, space group P1̅, a = 4.982(1), b = 6.896(1), c = 9.115(2) Å, α = 90.53(3), β = 97.85(3), γ = 110.08(3)°, V = 290.8(1) $ Å^{3} $, Z = 1 obtained from single-crystal data at 100 K, which are in good agreement with cell parameters from powder diffraction data of joanneumite at 293 K: a = 5.042(1), b = 6.997(1), c = 9.099(2) Å, α = 90.05(3), β = 98.11(2), γ = 110.95(3)° and V = 296.3(1) $ Å^{3} $. The eight strongest lines of the powder X-ray diffraction pattern are [d, Å (I,%) (hkl)] 6.52 (68) (010), 5.15 (47) (011), 4.66 (21) (100, 1̅10), 4.35 (9) (1̅11), 3.29 (6) (1̅20), 3.22 (7) (1̅1̅1), 3.140 (100) (1̅21), 2.074 (7) (1̅32). The crystal structure of joanneumite is identical with the structure of synthetic bis(isocyanurato) diamminecopper(II).</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Walter, Franz</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Baumgartner, Judith</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Mineralogical magazine</subfield><subfield code="d">Mineralogical Society, 1969</subfield><subfield code="g">81(2017), 1 vom: 01. Feb., Seite 155-166</subfield><subfield code="w">(DE-627)13069617X</subfield><subfield code="w">(DE-600)956157-2</subfield><subfield code="w">(DE-576)016244141</subfield><subfield code="x">0026-461X</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:81</subfield><subfield code="g">year:2017</subfield><subfield code="g">number:1</subfield><subfield code="g">day:01</subfield><subfield code="g">month:02</subfield><subfield code="g">pages:155-166</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1180/minmag.2016.080.078</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-GEO</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OPC-GGO</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="936" ind1="r" ind2="v"><subfield code="a">TE 1000</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">81</subfield><subfield code="j">2017</subfield><subfield code="e">1</subfield><subfield code="b">01</subfield><subfield code="c">02</subfield><subfield code="h">155-166</subfield></datafield></record></collection>
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